DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0017] Referring to the drawings, embodiments of the invention are described as follows:

[0018] FIG. 1 is a schematic view according to the present electrolytic water disinfecting apparatus. The electrolytic water disinfecting apparatus comprises the first electrolysis device 1 which generates silver ions and the second electrolysis device 2 which generates sodium hypochlorite as an example of hypochlorite. The two devices are connected in series via a communicating tube 10, and an inflow tube 11 formed on the inlet side of the first electrolysis device 1 and an outflow tube 21 formed in the second electrolysis device 2 are connected with a water supply and drain path of a swimming pool and the like (not shown). Water in the above water supply and drain path, which is disinfected by sodium hypochlorite and the like, still contains sodium chloride to act as an electrolyte component. Electrolyzation is conducted with the above water introduced into the two devices 1, 2, which generate silver ions and sodium hypochlorite. And by water containing these, water such as swimming pool water is disinfected.

[0019] The above first and second electrolysis devices 1, 2 are connected with a control unit 3 via lead wires 30, in which a controller controls current conduction to the electrodes in the above two devices 1, 2. The two devices 1, 2 may be installed forward or backward in the direction of water advection.

[0020] Because the above first and second electrolysis devices 1, 2 have almost the same structure, the two are described with reference to the same drawing. The two devices 1, 2 are different only in that they use different materials for their electrodes inside and that the second device is provided with a vent line 22 for hydrogen gas generated together with sodium hypochlorite on electrolyzation. As shown in FIG. 2, both devices 1, 2 are provided, in a casing whose longitudinal ends are closed by lids 41,42, a rectifier 5 positioned forward in the direction of water advection and an electrode assembly 6 positioned backward. One of the lids 41, 42 is connected with the inflow tube 11 or communicating tube 10, and the other is connected with the communicating tube 10 or outflow tube 21.

[0021] FIG. 3 shows an embodiment of the electrode assembly 6 for the devices 1, 2. In the drawing, four pairs of two opposing electrodes 61, 62 are retained at both their longitudinal side portions by space holding members 7, 7 so that the electrodes may be approximately evenly spaced. Terminals 60 are formed in the upper and lower longitudinal ends of the electrodes 61, 62, and connected with lead wires 30 extending from the control unit 3. In this embodiment, a pair of electrodes 61, 62 in the first electrolysis device 1 are made of silver or a silver-copper alloy. The electrodes made of these materials are immersed in the water containing sodium chloride to act as an electrolyte component. And electrolyzation with current conduction to such electrodes generates silver ions and copper ions. For example, with silver and a silver-copper alloy, or silver-copper alloys phase-inverted as counter electrodes, direct current electrolyzation generates silver ions and copper ions. With silver materials as counter electrodes, direct current electrolyzation generates silver ions alone. On the other hand, the second electrolysis device 2 employs a pair of electrodes 61, 62 made of titanium coated with platinum on one or both titanium surfaces. With these electrodes phase-inverted as counter electrodes, direct current electrolyzation generates sodium hypochlorite.

[0022] It is important that the electrode assembly 6 employs with even-numbered electrodes, e.g., a pair of electrodes. If direct current electrolyzation is conducted with odd-numbered electrodes phase-inverted, an equal amount of electric current does not flow to each electrode at phase inversion time and hardly any electrolyzation takes place. For example, if electrolyzation is conducted using seven electrodes, four of which are impressed positive and three of which are impressed negative, electric current markedly decreases at phase inversion time and electrolyzation becomes impossible.

[0023] In the embodiment shown in FIG. 4, assembled electrodes 6 in the first and second electrolysis devices 1, 2 are positioned in parallel in the latitudinal direction orthogonal to their longitudinal direction with a partition 63 interposed at their latitudinal center and are held at both longitudinal end portions by space holding member 7, 7 so that each electrode 61, 61 may be approximately evenly spaced. The electrode assembly 6 thus retained is placed in a casing 4. This allows the whole apparatus to be small, which leads to its compact installation in a swimming pool or a drinking water tank in a ship.

[0024] FIG. 5 shows a schematic block flow diagram illustrating the control of electric conduction to the electrode assembly 6. The output side of a controller 31 provided in the control unit 3 is connected with a power supply 32 and a phase inversion unit 33 controlled by a timer and the like provided in the controller 31. The output side of the phase inversion unit 33 is connected with each electrode 61, 62 of the electrode assembly 6 in the first and second electrolysis devices 1, 2. The input side of the controller 31 is connected with a detector 34 which detects the necessity of disinfecting water. The detector 34 may be a pH meter or an electric conduction meter which detects how sodium hypochlorite, silver ions and copper ions are dissolved in water.

[0025] The operation of the present electrolytic water disinfecting apparatus is described in the following. The detector 34 detects how sodium hypochlorite, silver ions and copper ions are dissolved in water. When the amount of the dissolved matter is less than a certain level and water disinfection is needed, electric current is passed, based on output from the controller unit 31, from the power supply unit 32 to each electrode 61, 62 of the electrode assembly 6 through the phase inversion unit 33.

[0026] In current conduction, positive and negative electric charges are alternately impressed on the electrodes 61,62 by phase inversion by the phase inversion unit 33 and silver ions and copper ions or silver ions are consequently generated on the electrodes in the first electrolysis device 1, which are dissolved in water. On the electrodes in the second electrolysis device 2, sodium hypochlorite is generated and dissolved in water. Water is disinfected by the water in which sodium hypochlorite, silver ions and copper ions are dissolved.

[0027] Sodium hypochlorite concentrations in water to be disinfected are preferably between 0.01 and 0.04 ppm, specifically between 0.015 and 0.03 ppm. Silver ion concentrations in water to be disinfected are preferably between 0.03 and 0.08 ppm, while copper ion concentrations in water to be disinfected are preferably between 0.1 and 0.5 ppm. As for silver ions, the more preferable concentrations are between 0.04 and 0.06 ppm. As for copper ions, more preferable concentrations are between 0.2 and 0.4 ppm. These ranges of concentrations can quickly achieve strong disinfection and sterilization effects, deter unfailingly and safely microorganisms and algae from propagating and further have exceptional deterrent effects on infectious bacteria propagation.

[0028] In the following description, the data comparison of disinfecting effects between the addition of sodium hypochlorite NaClO alone and that of sodium hypochlorite and silver ions is made.

[0029] Test 1

[0030] Make sample solutions by adding NaClO (0.02 ppm) alone to water to be disinfected or different chlorine concentrations (0.1; 0.15; 0.2; 0.35; 0.5 ppm) and additional sample solutions by dissolving this NaClO and Ag⁺ (0.06 ppm). And after making 80000 parts/ml Escherichia coli contact these sample solutions for one minute, remaining Escherichia coli parts are examined. The data are shown in Table 1.

[0031] As is obvious from Table 1, in comparison with sample solutions to which NaClO alone is added, those in which NaClO and Ag⁺ are dissolved can achieve far stronger sterilization effects and sterilize Escherichia coli with a reduced chlorine concentration, i.e., a reduced amount of NaClO usage. While, with NaClO alone added, 10000 parts of Escherichia coli still exist in water with a chlorine concentration of between 0.1 and 0.2 ppm, a solution in which NaClO and Ag⁺ are dissolved reduces remaining Escherichia coli to 600 parts and destroys almost all Escherichia coli, in water with a chlorine concentration of approximately 0.1 ppm. 1

[0032] TEST 2

[0033] Make sample solutions by adding NaClO (0.02 ppm) alone to water to be disinfected of a given chlorine concentration (0.05 ppm) and additional sample solutions by dissolving this NaClO and Ag⁺ (0.06 ppm). And after making 80000 parts/ml Escherichia coli contact these sample solutions for different periods (5; 15; 35; 60; 85; 120 seconds), remaining Escherichia coli parts are examined. The data are shown in Table 2.

[0034] As is obvious from Table 2, in comparison with a sample solution to which NaClO alone is added, that in which NaClO and Ag⁺ are dissolved can quickly achieve stronger sterilization effects and sterilize Escherichia coli in a short time. While, with NaClO alone added, Escherichia coli still exist after 85 seconds of contact time, a solution in which NaClO and Ag⁺ are dissolved can destroy almost all Escherichia coli in approximately 15 seconds. 2

[0035] While sodium hypochlorite is employed as an example of hypochlorite in the aforesaid embodiments, calcium hypochlorite may also be employed. In the case of disinfecting water in which hypochlorite are not dissolved beforehand, hypochlorite is added to the water, which is passed through the first and second electrolysis devices 1,2.

INDUSTRIAL APPLICABILITY

[0036] As described in the foregoing, the rpesent invention makes it possible to disinfect in a quick, safe and unfailing way water such as swimming pool water, washing water for food materials, sanitizing water for machines and implements or containers and drinking water in ships without any conventional drawbacks, using water containing hypochlorite and silver ions or hypochlorite, silver ions and copper ions in solution.