[0001] This is a continuation of pending U.S. patent application Ser. No. 08/887,074, filed Jul. 2, 1997.
[0002] The present invention relates generally to molds suitable for use in forming cube corner retroreflective sheeting, to methods for making the same, and to retroreflective sheeting formed from such molds. In particular, the invention relates to molds formed from a plurality of thin laminae and to methods for making the same.
[0003] Retroreflective materials are characterized by the ability to redirect light incident on the material back toward the originating light source. This property has led to the wide-spread use of retroreflective sheeting in a variety of conspicuity applications. Retroreflective sheeting is frequently applied to flat, rigid articles such as, for example, road signs and barricades; however, it is also used on irregular or flexible surfaces. For example, retroreflective sheeting can be adhered to the side of a truck trailer, which requires the sheeting to pass over corrugations and protruding rivets, or the sheeting can be adhered to a flexible body portion such as a road worker's safety vest or other such safety garment. In situations where the underlying surface is irregular or flexible, the retroreflective sheeting desirably possesses the ability to conform to the underlying surface without sacrificing retroreflective performance. Additionally, retroreflective sheeting is frequently packaged and shipped in roll form, thus requiring the sheeting to be sufficiently flexible to be rolled around a core.
[0004] Two known types of retroreflective sheeting are microsphere-based sheeting and cube corner sheeting. Microsphere-based sheeting, sometimes referred to as “beaded” sheeting, employs a multitude of microspheres typically at least partially embedded in a binder layer and having associated specular or diffuse reflecting materials (e.g., pigment particles, metal flakes or vapor coats, etc.) to retroreflect incident light. Illustrative examples are disclosed in U.S. Pat. No. 3,190,178 (McKenzie), U.S. Pat. No. 4,025,159 (McGrath), and U.S. Pat. No. 5,066,098 (Kult). Advantageously, microsphere-based sheeting can generally be adhered to corrugated or flexible surfaces. Also, due to the symmetry of beaded retroreflectors, microsphere based sheeting exhibits a relatively orientationally uniform total light return when rotated about an axis normal to the surface of the sheeting. Thus, such microsphere-based sheeting has a relatively low sensitivity to the orientation at which the sheeting is placed on a surface. In general, however, such sheeting has a lower retroreflective efficiency than cube corner sheeting.
[0005] Cube corner retroreflective sheeting comprises a body portion typically having a substantially planar base surface and a structured surface comprising a plurality of cube corner elements opposite the base surface. Each cube-corner element comprises three mutually substantially perpendicular optical faces that intersect at a single reference point, or apex. The base of the cube corner element acts as an aperture through which light is transmitted into the cube corner element. In use, light incident on the base surface of the sheeting is refracted at the base surface of the sheeting, transmitted through the bases of the cube corner elements disposed on the sheeting, reflected from each of the three perpendicular cube-corner optical faces, and redirected toward the light source. The symmetry axis, also called the optical axis, of a cube corner element is the axis that extends through the cube corner apex and forms an equal angle with the three optical faces of the cube corner element. Cube corner elements typically exhibit the highest optical efficiency in response to light incident on the base of the element roughly along the optical axis. The amount of light retroreflected by a cube corner retroreflector drops as the incidence angle deviates from the optical axis.
[0006] The maximum retroreflective efficiency of cube corner retroreflective sheeting is a function of the geometry of the cube corner elements on the structured surface of the sheeting. The terms ‘active area’ and ‘effective aperture’ are used in the cube corner arts to characterize the portion of a cube corner element that retroreflects light incident on the base of the element. A detailed teaching regarding the determination of the active aperture for a cube corner element design is beyond the scope of the present disclosure. One procedure for determining the effective aperture of a cube corner geometry is presented in Eckhardt, Applied Optics, v. 10, n. Jul. 7, 1971 pp. 1559-1566. U.S. Pat. No. 835,648 to Straubel also discusses the concept of effective aperture. At a given incidence angle, the active area can be determined by the topological intersection of the projection of the three cube corner faces onto a plane normal to the refracted incident light with the projection of the image surfaces for the third reflections onto the same plane. The term ‘percent active area’ is then defined as the active area divided by the total area of the projection of the cube corner faces. The retroreflective efficiency of retroreflective sheeting correlates directly to the percentage active area of the cube corner elements on the sheeting.
[0007] Predicted total light return (TLR) for a cube corner matched pair array can be calculated from a knowledge of percent active area and ray intensity. Ray intensity may be reduced by front surface losses and by reflection from each of the three cube corner surfaces for a retroreflected ray. Total light return is defined as the product of percent active area and ray intensity, or a percentage of the total incident light which is retroreflected. A discussion of total light return for directly machined cube corner arrays is presented in U.S. Pat. No. 3,712,706 (Stamm).
[0008] Additionally, the optical characteristics of the retroreflection pattern of retroreflective sheeting are, in part, a function of the geometry of the cube corner elements. Thus, distortions in the geometry of the cube corner elements can cause corresponding distortions in the optical characteristics of the sheeting. To inhibit undesirable physical deformation, cube corner elements of retroreflective sheeting are typically made from a material having a relatively high elastic modulus sufficient to inhibit the physical distortion of the cube corner elements during flexing or elastomeric stretching of the sheeting. As discussed above, it is frequently desirable that retroreflective sheeting be sufficiently flexible to allow the sheeting to be adhered to a substrate that is corrugated or that is itself flexible, or to allow the retroreflective sheeting to be wound into a roll for storage and shipping.
[0009] Cube corner retroreflective sheeting is manufactured by first manufacturing a master mold that includes an image, either negative or positive, of a desired cube corner element geometry. The mold can be replicated using nickel electroplating, chemical vapor deposition or physical vapor deposition to produce tooling for forming cube corner retroreflective sheeting. U.S. Pat. No. 5,156,863 to Pricone, et al. provides an illustrative overview of a process for forming tooling used in the manufacture of cube corner retroreflective sheeting. Known methods for manufacturing the master mold include pin-bundling techniques, direct machining techniques, and laminate techniques. Each of these techniques has benefits and limitations.
[0010] In pin bundling techniques, a plurality of pins, each having a geometric shape on one end, are assembled together to form a cube-corner retroreflective surface. U.S. Pat. No. 1,591,572 (Stimson), U.S. Pat. No. 3,926,402 (Heenan), U.S. Pat. No. 3,541,606 (Heenan et al.), and U.S. Pat. No. 3,632,695 to Howell provide illustrative examples. Pin bundling techniques offer the ability to manufacture a wide variety of cube corner geometries in a single mold. However, pin bundling techniques are economically and technically impractical for making small cube corner elements (e.g. less than about 1.0 millimeters).
[0011] In direct machining techniques, a series of grooves are formed in a unitary substrate to form a cube-corner retroreflective surface. U.S. Pat. No. 3,712,706 to Stamm and U.S. Pat. No. 4,588,258 to Hoopman provide illustrative examples. Direct machining techniques offer the ability to accurately machine very small cube corner elements which are compatible with flexible retroreflective sheeting. However, it is not presently possible to produce certain cube corner geometries that have very high effective apertures at low entrance angles using direct machining techniques. By way of example, the maximum theoretical total light return of the cube corner element geometry depicted in U.S. Pat. No. 3,712,706 is approximately 67%.
[0012] In laminate techniques, a plurality of laminae, each lamina having geometric shapes on one end, are assembled to form a cube-corner retroreflective surface. German Provisional Publication (OS) 19 17 292, International Publication Nos. WO 94/18581 (Bohn, et al.), WO 97/04939 (Mimura et al.), and WO 97/04940 (Mimura et al.), each disclose a molded reflector wherein a grooved surface is formed on a plurality of plates. The plates are then tilted by a certain angle and each second plate is shifted crosswise. This process results in a plurality of cube corner elements, each element formed by two machined surfaces on a first plate and one side surface on a second plate. German Patent DE 42 36 799 to Gubela discloses a method for producing a molding tool with a cubical surface for the production of cube comers. An oblique surface is ground or cut in a first direction over the entire length of one edge of a band. A plurality of notches are then formed in a second direction to form cube corner reflectors on the band. Finally, a plurality of notches are formed vertically in the sides of the band. German Provisional Patent 44 10 994 C2 to Gubela is a related patent. The reflectors disclosed in Patent 44 10 994 C2 are characterized by the reflecting surfaces having concave curvature.
[0013] The present invention relates to a master mold suitable for use in forming retroreflective sheeting from a plurality of laminae and methods of making the same. Advantageously, master molds manufactured according to methods disclosed herein enable the manufacture of retroreflective cube corner sheeting that exhibits retroreflective efficiency levels approaching 100%. To facilitate the manufacture of flexible retroreflective sheeting, the disclosed methods enable the manufacture of cube corner retroreflective elements having a width as small as 0.010 millimeters. Additionally, the present application enables the manufacture of a cube corner retroreflective sheeting that exhibits symmetrical retroreflective performance in at least two different orientations. Efficient, cost-effective methods of making molds formed from a plurality of laminae are also disclosed.
[0014] A plurality of laminae are machined simultaneously to form a plurality of cube corner elements. The three mutually perpendicular optical faces of each cube corner element are preferably formed on one of the plurality of laminae. That is, individual or discrete cube corner elements preferably do not extend across more than one lamina. All three optical faces are preferably formed by the machining process to ensure optical quality surfaces. A planar interface is preferably maintained between adjacent laminae during the machining phase and subsequent thereto so as to minimize alignment problems and damage due to handling of the laminae.
[0015] A plurality of laminae are manufactured for use in a mold suitable for use in forming retroreflective cube corner articles. Each lamina has opposing first and second major surfaces defining therebetween a first reference plane. Each lamina further includes a working surface connecting the first and second major surfaces. The working surface defines a second reference plane substantially parallel to the working surface and perpendicular to the first reference plane and a third reference plane perpendicular to the first reference plane and the second reference plane. The method includes orienting a plurality of laminae to have their respective first reference planes parallel to each other and disposed at a first angle relative to a fixed reference axis. At least two groove sets are formed in the working surface. Each groove set includes at least two parallel adjacent V-shaped grooves in the working surface of the laminae. The at least two groove sets form first, second and third groove surfaces that intersect substantially orthogonally to form a plurality of cube corner elements. Each cube corner element is preferably located on essentially one of the plurality of lamina. The plurality of laminae can be oriented at a second angle relative to the fixed reference axis prior to forming at least one of the groove sets.
[0016] In one embodiment, the step of forming at least two groove sets includes forming a first groove set including at least two parallel adjacent V-shaped grooves in the working surface of each of the laminae. Each of the adjacent grooves defines a first groove surface and a second groove surface that intersect substantially orthogonally to form a first reference edge on each of the respective laminae. A second groove set is formed including at least one groove in the working surfaces of the plurality of laminae. Each groove in the second groove set defines a third groove surface that intersects substantially orthogonally with the first and second groove surfaces to form at least one first cube corner element located on essentially a single lamina.
[0017] The first cube corner element preferably comprises a plurality of cube corner elements. Each of the plurality of cube corner elements are located on essentially one lamina. An interface between adjacent first and second major surfaces is preferably planar. Each lamina measures between about 0.025 millimeters and about 1.0 millimeters in thickness, and more preferably from about 0.1 to about 0.6 millimeters.
[0018] The method includes the step of orienting the plurality of laminae including assembling the laminae in a fixture defining a base plane. The first angle measures between about 5° and about 85° from a fixed reference axis normal to the base plane, and more preferably between about 10° and about 65° and most preferably about 25° to about 45°.
[0019] The step of forming the groove sets comprises forming at least one of the groove sets parallel to the base plane defined by the fixture. Alternatively, the groove sets can be formed at an acute angle relative to the base plane defined by the fixture. The groove sets can also be formed to vary the distance between adjacent grooves at different depths in the working surface of the laminae.
[0020] The process of forming the groove sets can comprise removing portions of each of the plurality of lamina proximate the working surface of the plurality of laminae using a material removal technique. The first, second and third groove surfaces are formed essentially from the material removal technique. The groove sets can be formed by inducing relative motion between the plurality of laminae and a cutting tool. The step of forming the groove sets comprises a machining operation selected from the group of machining operations consisting of ruling, fly-cutting, grinding, and milling. The grooves preferably have an included angle that measures between about 10° and about 170°.
[0021] In one embodiment, the plurality of lamina can be oriented to have their respective first reference planes parallel to each other and disposed at a second angle relative to the fixed reference axis prior to forming the second groove set. The step of orienting the plurality of laminae to have their respective first reference planes parallel to each other and disposed at a second angle relative to the fixed reference axis comprises re-assembling the plurality of lamina in a suitable fixture. In one embodiment, the step of orienting the plurality of laminae to have their respective first reference planes parallel to each other and disposed at a second angle relative to the fixed reference axis comprises rotating a plurality of the laminae 180° about an axis perpendicular to the second reference plane.
[0022] The cube corner elements are typically arranged in opposing pairs. In an alternate embodiment, optical axes of the cube corner elements can be generally parallel to provide an asymmetrical total light return about a 360° range of orientation angles.
[0023] Also disclosed is a method of replicating the working surface of the mold to form a negative copy of the plurality of cube corner elements suitable for use as a mold for forming retroreflective articles, and a mold formed therefrom. A retroreflective article can be formed from the mold forming the negative copy.
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[0051] A plurality of laminae are machined simultaneously to form a plurality of full cube corner elements. The three mutually perpendicular optical faces of each cube corner element are preferably formed on a single lamina. All three optical faces are preferably formed by the machining process to ensure optical quality surfaces. A planar interface is preferably maintained between adjacent laminae during the machining phase and subsequent thereto so as to minimize alignment problems and damage due to handling of the laminae.
[0052] In describing the various embodiments, specific terminology will be used for the sake of clarity. Such terminology is not, however, intended to be limiting and it is to be understood that each term so selected includes all technical equivalents that function similarly. The disclosed methods can be used to form retroreflective elements of a variety of sizes and shapes, such as fall cube corner elements and truncated cube corner elements. The base edges of adjacent truncated cube corner elements in an array are typically coplanar. The base edges of adjacent full cube corner elements in an array are not in the same plane. Related applications filed on the same date herewith include: Cube Corner Sheeting Mold and Method Making the Same (Atty. Docket No. 51946USA9A); Retroreflective Cube Corner Sheeting Mold and Sheeting Formed Therefrom (Atty. Docket No. 53305USA5A); Retroreflective Cube Corner Sheeting, Molds Therefore, and Methods of Making the Same (Atty. Docket No. 53318USA8A); Tiled Retroreflective Sheeting Composed of Highly Canted Cube Corner Elements (Atty. Docket No. 53285USA9A); Dual Orientation Retroreflective Sheeting (Atty. Docket No. 52303USA8B).
[0053] For purposes of description, a Cartesian coordinate system can be superimposed onto lamina
[0054] One embodiment of a lamina, as well as a method of making the same, will now be described with reference to FIGS.
[0055] FIGS.
[0056] The grooves of the second groove set define respective fifth groove surfaces
[0057] The embodiment will now be explained in greater detail. Turning back to
[0058] In
[0059] Referring to FIGS.
[0060] Grooves
[0061] In the embodiment of FIGS.
[0062] To complete the formation of cube corner elements on the working surfaces
[0063] Referring to
[0064] The second grooves
[0065] The cube corner elements
[0066] A method of the present disclosure involves simultaneously machining a plurality of laminae, each lamina comprising one or more discrete cube corner elements. The cube corner elements preferably do not extend across more than one lamina. For example, the three mutually perpendicular optical faces
[0067] FIGS.
[0068] Referring to
[0069] Referring to FIGS.
[0070] Grooves
[0071] In the embodiment of FIGS.
[0072] Referring to
[0073] Referring to FIGS.
[0074] Grooves
[0075] Referring to FIGS.
[0076] Each cube corner element
[0077] In a preferred method the plurality of laminae
[0078] As discussed in connection with FIGS.
[0079] FIGS.
[0080] Referring to
[0081] Grooves
[0082] In the embodiment of FIGS.
[0083] Referring to FIGS.
[0084] Grooves
[0085] Referring to
[0086] Formation of the fifth groove surfaces
[0087] In a preferred method the plurality of laminae
[0088] Working surface
[0089] The laminae are preferably formed from a dimensionally stable material capable of holding precision tolerances, e.g. machinable plastics (for example, polyethylene teraphthalate, polymethyl methacrylate, and polycarbonate) or metals (for example, brass, nickel, copper, or aluminum). The physical dimensions of the laminae are constrained primarily by machining limitations. Each lamina preferably measures between about 0.025 millimeters and about 1.0 millimeters in thickness, and more preferably about 0.1 to about 0.6 millimeters, between about 5 and about 100 millimeters in height, and between about 10 and about 500 millimeters in width. These measurements are provided for illustrative purposes only and are not intended to be limiting.
[0090] In the manufacture of retroreflective articles such as retroreflective sheeting, the structured surface of the plurality of laminae is used as a master mold which can be replicated using electroforming techniques or other conventional replicating technology. The plurality of laminae can include substantially identical cube corner elements or may include cube corner elements of varying sizes, geometries, or orientations. The structured surface of the replica, referred to in the art as a ‘stamper’, contains a negative image of the cube corner elements. This replica can be used as a mold for forming a retroreflective article. More commonly, however, a large number of positive or negative replicas are assembled to form a mold large enough to be useful in forming retroreflective sheeting. Retroreflective sheeting can then be manufactured as an integral material, e.g. by embossing a preformed sheet with an array of cube corner elements as described above or by casting a fluid material into a mold. See, JP 8-309851 and U.S. Pat. No. 4,601,861 (Pricone). Alternatively, the retroreflective sheeting can be manufactured as a layered product by casting the cube corner elements against a preformed film as taught in PCT application No. WO 95/11464 and U.S. Pat. No. 3,648,348 or by laminating a preformed film to preformed cube corner elements. By way of example, such sheeting can be made using a nickel mold formed by electrolytic deposition of nickel onto a master mold. The electroformed mold can be used as a stamper to emboss the pattern of the mold onto a polycarbonate film approximately 500 μm thick having an index of refraction of about 1.59. The mold can be used in a press with the pressing performed at a temperature of approximately 175° to about 200° C.
[0091] Useful materials for making such reflective sheeting are preferably materials that are dimensionally stable, durable, weatherable and readily formable into the desired configuration. Examples of suitable materials include acrylics, which generally have an index of refraction of about 1.5, such as Plexiglas resin from Rohm and Haas; thermoset acrylates and epoxy acrylates, preferably radiation cured, polycarbonates, which have an index of refraction of about 1.6; polyethylene-based ionomers (marketed under the name ‘SURLYN’); polyesters; and cellulose acetate butyrates. Generally any optically transmissive material that is formable, typically under heat and pressure, can be used. Other suitable materials for forming retroreflective sheeting are disclosed in U.S. Pat. No. 5,450,235 to Smith et al. The sheeting can also include colorants, dyes, UV absorbers, or other additives as needed.
[0092] It is desirable in some circumstances to provide retroreflective sheeting with a backing layer. A backing layer is particularly useful for retroreflective sheeting that reflects light according to the principles of total internal reflection. A suitable backing layer can be made of any transparent or opaque material, including colored materials, that can be effectively engaged with the disclosed retroreflective sheeting. Suitable backing materials include aluminum sheeting, galvanized steel, polymeric materials such as polymethyl methacrylates, polyesters, polyamids, polyvinyl fluorides, polycarbonates, polyvinyl chlorides, polyurethanes, and a wide variety of laminates made from these and other materials.
[0093] The backing layer or sheet can be sealed in a grid pattern or any other configuration suitable to the reflecting elements. Sealing can be affected by use of a number of methods including ultrasonic welding, adhesives, or by heat sealing at discrete locations on the arrays of reflecting elements (see, e.g. U.S. Pat. No. 3,924,928). Sealing is desirable to inhibit the entry of contaminants such as soil and/or moisture and to preserve air spaces adjacent the reflecting surfaces of the cube corner elements.
[0094] If added strength or toughness is required in the composite, backing sheets of polycarbonate, polybutryate or fiber-reinforced plastic can be used. Depending upon the degree of flexibility of the resulting retroreflective material, the material can be rolled or cut into strips or other suitable designs. The retroreflective material can also be backed with an adhesive and a release sheet to render it useful for application to any substrate without the added step of applying an adhesive or using other fastening means.
[0095] The cube corner elements disclosed herein can be individually tailored so as to distribute light retroreflected by the articles into a desired pattern or divergence profile, as taught by U.S. Pat. No. 4,775,219. Typically the groove half-angle error introduced will be less than ±20 arc minutes and often less than ±5 arc minutes.
[0096] For convenience, the working surfaces of a plurality of laminae when considered collectively can be referred to as a collective working surface. Thus, for example, grooves
[0097] All patents and patent applications referred to, including those disclosed in the background of the invention, are hereby incorporated by reference. The present invention has now been described with reference to several embodiments thereof. It will be apparent to those skilled in the art that many changes can be made in the embodiments described without departing from the scope of the invention. Thus, the scope of the present invention should not be limited to the preferred structures and methods described herein, but rather by the broad scope of the claims which follow.