METHOD AND APPARATUS FOR IMAGING UTILIZING AN ULTRASONIC IMAGING SENSOR ARRAY
Cross-Reference to Related Application
The present application claims the benefit of U.S. Application Serial No. 60/773,292, filed February 14, 2006, which is hereby incorporated by reference herein in its entirety, including any figures, tables, or drawings.
Background of Invention
A conventional ultrasonic imaging system includes two elements: 1) an element that generates acoustic waves, and 2) a sensor that detects the reflected signals. In a typical ultrasonic imaging procedure, a probe is manually scanned across the imaging area. This procedure can be tedious and time consuming, and often the image quality is poor.
Brief Summary Embodiments of the subject invention pertain to a piezoelectric transducer device for improved acoustic wave sensing and/or generation. Embodiments of the invention relate to a process for making a piezoelectric transducer device. In an embodiment, a plurality of piezoelectric transducer devices can be used to form an array of piezoelectric transducers. Embodiments of the transducer array can eliminate the need for manual scanning, allow low cost fabrication, and/or enable high resolution imaging systems. In one embodiment, a piezoelectric transducer can be a thin film transistor having a composite gate dielectric layer including a dielectric film and a piezoelectric film. The thin film transistor can be a thin film field effect transistor. In a specific embodiment, the gate dielectric layer can be a composite of a dielectric film such as Siθ 2 and a piezoelectric film. In another embodiment, a piezoelectric transducer can be a thin film transistor having a piezoelectric film gate. The thin film transistor can be a thin film field effect transistor. In a specific embodiment, a single piezoelectric film can be used as the gate.
Brief Description of Drawings
Figure 1 shows an embodiment of a top gate piezoelectric thin film transducer in accordance with the subject invention.
Figure 2 shows an embodiment of a top gate piezoelectric thin film transducer in accordance with the subject invention.
Figure 3 shows an embodiment of a bottom gate piezoelectric thin film transducer in accordance with the subject invention. Figure 4 shows a schematic of a transducer for ultrasonic imaging driven by a TFT switch in accordance with an embodiment of the subject invention.
Figure 5 shows a schematic of an array of transducers for ultrasonic imaging each driven by a TFT switch in accordance with the subject invention.
Figure 6 shows a schematic of a MOCVD for depositing piezoelectric material on a substrate in accordance with an embodiment of the subject invention.
Figure 7 shows a schematic of a RF sputtering system for depositing piezoelectric material on a substrate in accordance with an embodiment of the subject invention.
Detailed Disclosure Embodiments of the subject invention pertain to a piezoelectric transducer device for improved acoustic wave sensing and/or generation. Embodiments of the invention relate to a process for making a piezoelectric transducer device. In an embodiment, a plurality of piezoelectric transducer devices can be used to form an array of piezoelectric transducers. Embodiments of the transducer array can eliminate the need for manual scanning, allow low cost fabrication, and/or enable high resolution imaging systems.
In one embodiment, a piezoelectric transducer can be a thin film transistor having a composite gate dielectric layer including a dielectric film and a piezoelectric film. The thin film transistor can be a thin film field effect transistor. In a specific embodiment, the gate dielectric layer can be a composite of a dielectric film such as S1O 2 and a piezoelectric film. In another embodiment, a piezoelectric transducer can be a thin film transistor having a piezoelectric film gate. The thin film transistor can be a thin film field effect transistor. In a specific embodiment, a single piezoelectric film can be used as the gate.
In embodiments of the subject invention, the piezoelectric thin film transducer can have a top gate device structure. The top gate device structures can incorporate a piezoelectric film or a composite of a dielectric film and piezoelectric film. Figure 1 shows an embodiment of the piezoelectric thin film transducer, where the piezoelectric thin film transducer is a thin film field effect transistor with a composite piezoelectric/insulator gate. Referring to Figure 1, the piezoelectric thin film transducer can be a thin film transistor with substrate 1 on which a bottom, or excitation, electrode 2 and a semiconductor thin film 3 are
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deposited. An active region (not shown) can be formed in the semiconductor thin film 3. A layer of dielectric film 4 and a layer of piezoelectric film 5 create a gate region. The placement of the gate region with respect to the active region defines the source and drain regions. Gate, source, and drain electrodes can be used to control the device. Figure 2 shows an embodiment of the piezoelectric thin film transducer where the piezoelectric thin film transducer is a thin film field effect transistor with a piezoelectric film gate. In this embodiment, the piezoelectric thin film transducer can also be a thin film transistor with substrate 11 on which a bottom, or excitation, electrode 12 and a semiconductor thin film 13 are deposited. Rather than having both a layer of dielectric film and a layer of piezoelectric film, the embodiment shown in Figure 2 uses a piezoelectric film 15 to create a gate region.
In embodiments of the subject invention, the piezoelectric thin film transducer can have a bottom gate device structure. Figure 3 shows an embodiment of the piezoelectric thin film transducer where the piezoelectric thin film transducer is a thin film field effect transistor having a bottom gate device structure. In a bottom gate device structure, a gate electrode is at the bottom of the semiconductor layer. Referring to Figure 3, a gate electrode 7 is formed on substrate 6. Piezoelectric film 10 and gate dielectric film 9 can be deposited on the top of the gate electrode and exposed substrate. Semiconductor thin film 8 can be deposited on the dielectric layer 9. Source, drain, and excitation electrodes can then be formed on the semiconductor thin film 8. The bottom gate device structure allows for a low temperature process for depositing the semiconductor thin film.
Embodiments of the subject invention can be used for both generating and sensing acoustic waves. In an embodiment, the piezoelectric thin film transducer can generate an acoustic wave when a signal is applied to the excitation electrode while the piezoelectric thin film transducer is in active mode, for example when — V 7 1 > 0. The echo of the acoustic wave can be sensed by the piezoelectric thin film transducer because of the effects of the acoustic wave on the piezoelectric layer. The signal can be determined by the voltage at the drain of the piezoelectric thin film transducer when the transducer is active. In a specific embodiment, a thin film transistor (TFT) switch can drive a piezoelectric thin film transducer. For a sensing mode, a signal from an acoustic wave can be collected at a readout terminal of the piezoelectric thin film transducer. In a specific embodiment, the readout terminal can be electrically connected to the drain of the piezoelectric thin film transducer. For a generating mode, an excitation signal can be applied across the piezoelectric thin film transducer while the switch is 'on' to generate an acoustic wave.
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In an embodiment, an acoustic wave can be generated by applying an ac voltage across the piezoelectric film of a piezoelectric thin film transducer. The piezoelectric thin film transducer can be of any structure as indicated above. A schematic circuit diagram is shown in Figure 4. A TFT switch 40 can be used to drive the transducer 50. A signal from a received acoustic wave can be collected at the readout terminal 51. Acoustic waves can be generated from the transducer 50 by applying an ac voltage across the piezoelectric film, such as by applying an excitation signal 54 across the transducer 50 while the TFT switch 40 is on. In a specific embodiment, an excitation signal 54 can be applied between the bottom electrode of the transducer 50 and the gate electrode 52 of the transducer 50 to generate acoustic waves. A plurality of the subject TFT switches and corresponding plurality of the subject piezoelectric thin film transducers can be formed in an array, in accordance with an embodiment of the invention. In a specific embodiment, a large area array can be fabricated of thin film transistors and transducers.
Referring to Figure 5, acoustic sensor array signals can be applied to the scan lines 42 from the scan drivers. Data can be read from the data readout lines 44. Excitation signals can be applied between the bottom electrode 54 and the gate electrode 52 to generate acoustic waves, and reflected signals can be detected by the field-effect transducers via readout terminal 51. / •
In a specific embodiment, the substrate can be formed of a glass substrate such as Corning 1737f, Al-B-Si-O (LCD-type glass). Preferably, the substrate material is selected such that the thermal expansion coefficient of the substrate material matches the thermal expansion coefficient of the piezoelectric film. As lead zirconate titanate, (PZT) Pb/Si interdiffusion can occur during annealing, and lanthanum nitrate can be used as buffer layer. The bottom electrode located on the substrate can be formed by, for example, layering 50 nm of Ti on the glass and then 200 nm of Pt on the Ti.
For embodiments having a top gate device structure, the gate, source and drain electrodes can be formed of, for example, Au, Ti/ Au, or AI.
In alternative embodiments, the substrate can be formed of polymer. The use of a polymer or plastic substrate can enhance the flexibility of the subject device. In a specific embodiment, polyimides such as Kapton, can be used in environments having temperatures up to 350 0 C. Other polymer substrates can be used. Such polymers have lower temperature limits for operation. Examples include, but are not limited to: low temperature: PET (100 0 C), polyphenil sulfides (180 0 C), polyisocyanates (140 0 C), and Polypropylene adipate (140 0 C).
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The semiconductor thin film materials incorporated with transducers in accordance with the subject invention can include amorphous silicon, polycrystalline silicon by low temperature laser annealing, organic semiconductors such as pentacene, and conjugated polymers such as polythiophene. The piezoelectric thin films can include non-ferroelectric piezoelectrics, such as ZnO and AIN, ferroelectric films, such as Pb(Zr,Ti)θ 3 (PZT), and bismuth layered oxides such as BUThOw For high sensitivity sensors and low voltage operation, the higher piezoelectric response available in ferroelectric films can be preferable.
In an embodiment, the piezoelectric layer can incorporate ceramics such as ZnO, AlN, and/or PZT. The properties of ZnO, AlN, and PZT are shown in Table I from S. Trolier- McKinstry and P. Muralt, Journal of Electroceramics, 12, 7-17, 2004.
Table 1. Thin mm piezoelectric and dielectric properties.
Coefficients/figures ZnO AlN PZT of merit [40,41] 131.421 (l-3 μm> r43J eu.f CCm- 2 ) - 1.0 -1.05 -S .. - 12 itj,χ f (pm/V) 5.9 3.9 60.. ..130
10.9 10.5 300.. 1300 e3i.f/sQS3.i (GVVm) -10.3 -11.3 -0.7 .. - 1.8
* 3 i, f/ β o β M (G Pa J 10.3 11.9 6 -. IS tan δ {@ ϊ to 1O kHz. 0.01 .. 0.1 0.003 0.03 .. 0.03
IG 5 V/m) ;
7.4 % 6.5Ψo 7% .. 15%
In another embodiment, the piezoelectric layer can be selected from Polymers such as polyvinylidene fluoride (PVDF), vinylidene fluoride - trifluoroethylene copolymer P(VDF- TrFE), vinylidene fluoride - tetrafluoroethylene copolymer P(VDF-TeFE), vinylidene cyanide - vinylacetate copolymer P(VDCN-VAC), and Nylons such as Nylon-5, Nylon-7, and Nylon-11. Characteristics of PVDF 5 VDF, TrFE, and PZT 4 can be found in the following chart from Q. X. Chen and P. A. Payne, Meas. Sci. TechnoL, 6, 249-67, 1995.
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Property PVDF VDF-TITE PZT 4
Density (tC kg πT^ 1.78 1,86 7.50 Acoustic velocity (km s~ η ) 2.26 2.40 4.B0 Acoustic Impedance (MRayi) 20 4.51 34.60 Elastic constant, C (10* N m "*) 9.10 11.30 159.00 Coupling factor, fr, 0.20 O.30 0.51 Piezoelectric constants
-o v ie -0.23 15,10
/J 35 (IO 9 V m- 1 ) -2.90 -4.30 2.70
-0.32 -0.38 0.025
25.00 12.50 -123.00
Dielectric constant, S 1 Zc 0 6.20 6.00 635.00 Mechanical Q factor 6-10 5-10 Mechanical loss tangent, tan ώ m 0.10 0.05 0.004 Dielectric loss tangent, tan <5 β 0,25 0.15 0.02 Pyroeiectric constant (μC m~* K) 35,00 50.00 CQeJCiVe IJeICi 1 E- (MVm -1 ) 45.00 36.00 Thermal stability ('C) 90.00 120-150 Transmitting efficiency, V τ 6,9 7.4 70 (PCT 5A) Receiving efficiency, V n 1.35 1.89 0.21 (PZT 5A)
9J30 14.0 14.7IPCT5A)
The piezoelectric layer can be formed by any satisfactory method. Figure 6 shows a specific embodiment of a metal organic chemical vapor deposition (MOCVD) system for piezoelectric thin film deposition. In this embodiment, the piezoelectric layer is formed of a Iead-zirconate-titanate (PZT). The compounds used as the PZT precursors are shown in Figure 6 as Pb(C 2 Hs) 4 (liquid), Ti(OC 3 H 7 )4 (liquid), and Zr(OC(CH 3 ) 3 )4 (liquid). The MOCVD system includes a resistively heated vapor delivery network 100 for delivering the PZT precursors to the quartz reactor 102 and undesired vapor to exhaust 101. The quartz reactor 102 has an inner quartz tube 103 that contains an inert gas and a resistive heater 104. The resistive heater 104 heats the substrate 50. A susceptor 105 is used to transfer heat from the resistive heater 104 to the substrate 50. The susceptor 105 can be made of a conductive material such as Iconel. A water cooled plate 106 abuts the quartz reactor 102 opposite the resistive heater 104. A thin film of piezoelectric material is deposited on the substrate 50 as the vapor with PZT precursors passes over the heated substrate 50 and under the water cooled plate 106. Undesired remnants are led to exhaust 107. Measurement of the temperature of the substrate heating region can be taken by a thermocouple 108 located within the susceptor 105.
Figure 7 shows a schematic of a RF-Sputtering system that can be used in accordance with the subject invention. This system can be used for piezoelectric thin film deposition on a substrate, such as glass. In a specific embodiment, the piezoelectric layer is formed from a sintered oxide ceramic disc (ZnO) target. The RF sputtering system can include a sputtering chamber 211 and a side arm 202. In an embodiment, the side arm plasma source 202 generates a highly ionized plasma beam of glow discharge that is directed to the target 200 by
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electromagnets such as launch electromagnet 204 and steering electromagnet 206. In a specific embodiment, a 150 W RF power input 203 can be used to produce the plasma. The RF power input 203 maintains the plasma glow discharge as it is directed to the target 200. The target 200 can be held by a rotatable target holder 201 within the sputtering chamber 2H. An argon gas feed 208 provides argon gas and a reactive gas feed 209 can provide oxygen gas. Pump systems 207 can help control the pressure in the sputtering chamber 211. In a specific embodiment, the sputtering pressure can be, for example, 1.5 x 10 '2 Torr, CVAr atmosphere. The erosion due to bombardment of glow discharge on the ZnO target 200, which is powered by a DC/RF 0-lOOOV target bias 205, can form a layer of piezoelectric material on a glass substrate. In a specific embodiment, the glass substrate can be attached to a rotating substrate table 210.
Piezoelectric thin film deposition can also be conducted through Chemical Solution Deposition (sol-gel). In a specific embodiment, the PZT precursors can include lead acetate, acetic acid, zirconium n-propoxide, titanium n-propoxide, and ethylene glycol. Li an embodiment, a piezoelectric layer can be deposited on a substrate by spin coating the substrate with a PZT chemical solution such that a PZT precursor film is formed. The PZT precursor film decomposes into a polycrystalline film during heating. A hot plate can be used to dry the substrate having PZT precursor film, and rapid thermal annealing (RTA) can be performed at a temperature such as 620 0 C to form the piezoelectric film layer. In alternative embodiments, low pressure modulated plasma jet reactive sputtering rubber stamp printing/transfer method can be used to perform piezoelectric thin film deposition.
As discussed above, embodiments of the subject invention can be fabricated on a glass or plastic substrate. In an embodiment of the subject invention, a top gate device can be fabricated by depositing and patterning metal thin film for bottom electrodes. Then a semiconductor film can be deposited. The semiconductor film can be, for example, polymer, small molecule organic, and/or inorganic semiconductors, such as amorphous silicon or polycrystalline silicon. In a specific embodiment having a composite piezoelectric/insulator gate, gate dielectric thin films can be deposited and then a piezoelectric thin film can be deposited by, for example, chemical vapor deposition. In alternate embodiments, the piezoelectric thin film can be deposited as discussed above. Once the piezoelectric film has been deposited, the gate, source and drain contacts can be patterned by, for example, photolithography. In an embodiment, the gate, source and drain electrode can be deposited by vacuum deposition.
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In another embodiment of the subject invention, a bottom gate device can be fabricated by depositing and patterning metal thin film for bottom electrodes on a glass or plastic substrate. Then a piezoelectric thin film can be deposited. In a specific embodiment, the piezoelectric thin film can be deposited by chemical vapor deposition. In an embodiment having a composite piezoelectric/insulator gate, gate dielectric thin films can be deposited on the piezoelectric thin film. A semiconductor film can then be deposited. The semiconductor film can be polymer, small molecule organic, and/or inorganic semiconductors, such as amorphous silicon or polycrystalline silicon. The gate, source and drain contact areas can be opened and accessed by, for example, photolithography and/or etching. The gate, source and drain electrode can be deposited by vacuum deposition.
The transistors can be fabricated in a range of sizes. In a specific embodiment, the thickness of piezoelectric gate can be from 20 nm to 500 nm in thickness, the thickness of the insulator gate can be 20 nm to 500 nm, and the FET channel length can be 100 nm to 10 um. In a specific embodiment, the semiconductor thin film 3 can be about 50 nm to 500 nm in thickness. In various embodiments, an array of thin film transistors can be positioned on a substrate that is at least 1 inch by 1 inch, and up to 10-20 inches by 10-20 inches. The array can have 1000 transistors by 1000 transistors, or more.
AU patents, patent applications, provisional applications, and publications referred to or cited herein are incorporated by reference in their entirety, including all figures and tables, to the extent they are not inconsistent with the explicit teachings of this specification.
It should be understood that the examples and embodiments described herein are for illustrative purposes only and that various modifications or changes in light thereof will be suggested to persons skilled in the art and are to be included within the spirit and purview of this application.
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