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7652180 |
Process for preparing alkyl chlorides
The invention relates to a process for preparing alkyl chlorides by reacting alcohols with gaseous hydrogen chloride in the presence of a catalyst, wherein the catalyst comprises at least one...
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7304192 |
Method for producing chlorinated hydrocarbon having chlorinated tertiary carbon
The present invention relates to a simple method for efficiently producing aromatic-substituted chlorinated hydrocarbons, for example, high-purity cumyl chloride...
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6992038 |
Zinc chloride-loaded support and method for producing the same
The present invention is to solve the problems caused by a conventional method for producing a zinc chloride-loaded support wherein zinc chloride is adsorbed on a solid support in an aqueous...
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6989175 |
Acyl fluoride activation of carboxysilyl-coated glass substrates
A method for the acyl fluoride activation of a carboxysilyl-coated glass is described. The method includes providing a glass substrate having a surface with at least one pendant carboxysilyl linker...
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6414204 |
Process for producing allyl chloride
In a process for production of allyl chloride whereby allyl alcohol and hydrogen chloride are reacted in the presence of a catalyst and the resulting allyl chloride is distilled off from the...
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6326519 |
Diallylic sulfides and processes for preparing the same
Diallylic sulfides represented by Formula I ##STR1##wherein: R1 and R2 are independently chosen from the group consisting of --CHO, --CH2 Cl, --CH2 Br, --CH2 I, --CH2 OH, CH2 OSO2 CF3, --CH2 OSO2...
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6206819 |
Halogenation catalyst
N,N-disubstituted formamides, wherein the substituents are selected to provide formamides which have low volatility, are useful as halogenation catalysts. Such catalysts are generally less...
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6111153 |
Process for manufacturing methyl chloride
A process for manufacturing methyl chloride. The process consists essentially of contacting hydrogen chloride with at least a stoichiometric amount of methanol split into at least two portions with...
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6077981 |
Process for the production of cyclopropylmethyl halides
Disclosed is a process for the production of cyclopropylmethyl halides (CPMX) such as cyclopropylmethyl chloride (CPMCl) and cyclopropylmethyl bromide (CPMBr) wherein cyclopropanemethanol (CPMO) is...
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5917099 |
Preparation of methyl chloride
Methyl chloride is prepared by effecting liquid-phase reaction between hydrogen chloride and methanol in the absence of a catalyst. The reaction is effected in divided stages including at least an...
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5910617 |
Process for the preparation of aliphatic or cycloaliphatic chlorides
The process according to the invention consists in preparing chlorides of aliphatic or cycloaliphatic hydrocarbons by reacting the corresponding mono- or polyalcohol with phosgene or thionyl...
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5859070 |
Catalytic process
Synthesis of small quantities of compounds such as methanol from reagents, especially radio-labelled reagents such as 11 C oxides, in a carrier gas by a catalytic reaction using a catalyst that has...
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5767330 |
Process for preparing alkyl chlorides
The preparation of long-chain alkyl chlorides from alcohols and hydrogen chloride is improved by carrying out the reaction at a temperature below the boiling point of the alkyl chloride, and...
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5723704 |
Process for the preparation of alkyl chlorides
Process for the preparation of alkyl chlorides, characterized in that: a) in a first stage a primary mono- or polyhydric alcohol, which has a C4 -C30 carbon chain which is saturated, substituted or...
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5637781 |
Process for the alcoholysis of carbon tetrachloride
The invention relates to a process for the alcoholysis of carbon tetrachloride which consists in simultaneously sending, on the one hand, carbon tetrachloride and, on the other hand, an alcohol...
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5384415 |
Process for the preparation of brominated compounds, especially from alcohols
A process for the preparation of a brominated compound which comprises the step of reacting at least one compound selected from the group consisting of a chloroformate, a chlorosulfite and a...
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5321171 |
Method for producing methyl chloride
A method for producing methyl chloride, which comprises reacting methanol and hydrogen chloride in a gas phase in the presence of a catalyst, wherein a zirconium oxide catalyst or a composite...
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5227550 |
Method for preparation of methyl chloride
Carbon tetrachloride, which is a material of low value and may be banned due to the problem of the destructiveness against the stratospheric ozone layer, can be efficiently utilized in the...
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5202512 |
Process for the preparation of halogenoalkanes
Process for the preparation of methyl chloride, which comprises reacting methanol with hydrogen chloride in a concentration below the particular ageotropic concentration in the liquid phase in the...
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5196618 |
Method for the preparation of methyl chloride from carbon tetrachloride and methyl alcohol
An improvement is proposed in the method for the preparation of methyl chloride from carbon tetrachloride and methyl alcohol by the reaction including the partial reactions of, first, the...
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5138110 |
Process for the preparation of alkyl-halides
A process for preparing lower alkyl-halides from the reaction of HX and the corresponding lower alcohol, wherein X represents a halogen atom, comprises continuously feeding HX and a lower alcohol...
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5132476 |
Process for producing C3 -C4 monoalkylchlorides
The vaporous reaction product from the continuous reaction of C3 -C4 monoalkanols with hydrogen chloride is removed, condensed, and split into a light organic phase and a heavy aqueous phase. The...
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5109138 |
Process and catalyst for hydrohalogenation of hydrocarbons
A process for hydrohalogenating methanol with a hydrogen halide using a catalyst having an initial zone of lower activity and subsequent zones of higher activity so that coke formation and pressure...
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4935564 |
Process for preparing alkyl halides
A process for preparation of an alkyl halide, RX, from reaction between the corresponding alcohol, ROH, and a hydrogen halide, HX, which improves conversion of the hydrogen halide to the alkyl...
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4935565 |
Process and catalyst for hydrochlorination of hydrocarbons
Methyl chloride is produced by contacting methanol and hydrogen chloride in the vapor phase in the presence of KZnCl3 supported on silica. The process produces methyl chloride in good yield with...
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4922043 |
Manufacture of methyl chloride by hydrochlorinating methanol, using a split methanol feed
In a process for making methyl chloride by the catalytic hydrochlorination of methanol in the liquid phase, the common formation of unwanted dimethyl ether by-product is reduced by conducting the...
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4808761 |
Demethanolization of aqueous CH3 OH/HCl solutions
Residual aqueous phases, emanating from the synthesis of methyl chloride by reacting methanol with hydrochloric acid, are conveniently demethanolized by maintaining same in liquid phase and in the...
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4794204 |
Process for the removal of dimethyl ether in methyl chloride
A process is described for the removal of dimethyl ether in methyl chloride by catalytic cleavage by means of hydrogen chloride. Dimethyl ether is present as an impurity in crude methyl chloride...
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4465880 |
Process for the manufacture of methyl chloride
Methyl chloride is manufactured from methanol and hydrogen chloride in the gaseous phase in the presence of an aluminum oxide catalyst. The reaction is carried out in the presence of from 1 to 80...
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4351972 |
Process for making anhydrous alkyl iodides
The invention relates to the production of anhydrous alkyl iodides. To this end, carboxylic acid alkyl esters of the formula R1 COOR2, in which R1 stands for hydrogen or an alkyl or aryl radical...
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4220609 |
Process for the recovery of alkyl chlorides
Crude gaseous C1 -C3 alkyl chlorides, prepared by reacting the corresponding alcohol with hydrogen chloride, are freed from by-product water, unreacted hydrogen chloride and unreacted alcohol by...
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4073816 |
Process for the continuous production of monochloroalkanes
Monochloroalkanes are produced by reacting the corresponding alcohol with hydrogen chloride in the presence of a solution of zinc chloride. The mixture of alcohol and zinc chloride solution is...
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3983180 |
Process for preparing methyl chloride
A process for preparing methyl chloride by reacting hydrogen chloride with methanol in the liquid-phase non-catalytic reaction, employing a reaction system comprising a reactor and two distillation...
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3981438 |
Centrifuge rotor having swinging members with variable pivot points
A centrifuge rotor has a plurality of swinging buckets or bucket carriers disposed on its periphery. Mounting pins, having an oblong cross-section, for the buckets are secured to the rotor itself....
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3981938 |
Method for producing dry alkyl halides
A method for producing alkyl halides by reacting the corresponding alkanol with at least 10% molar excess of hydrogen halide at a temperature of at least 50°C. and under sufficient pressure to ...
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3925460 |
Esters of cyclopropane substituted carboxylic acids
Esters of cyclopropane substituted carboxylic acids, syntheses thereof, compositions thereof, and use for the control of mites and ticks.
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3917729 |
Process for deuterating bromide derivatives
The invention relates to a process wherein a mixture comprising a secondary or tertiary acyclic bromide or an alicyclic bromide, deuteriobromic acid and deuterium oxide is permitted to react for...
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3852368 |
AMINE PROMOTERS FOR HYDROHALOGENATION
Tertiary alcohols and Type III olefins are hydrohalogenated in the presence of an amine which acts as a reaction promoter. The amine speeds up the reaction between the hydrogen chloride and...
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3649197 |
PREPARATION OF ALKYL HALIDES AND SULFUR FROM HYDROGEN SULFIDE, ALCOHOLS AND HALIDES
Alkyl halides and sulfur are formed and recovered by reacting hydrogen sulfide, bromine or iodine and ethyl or methyl alcohol in the presence of an acid and an alkali metal halide.
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3527820 |
PRODUCTION OF ALKYL CHLORIDES CONTAINING FROM 3 TO 6 CARBON ATOMS
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3502733 |
PRODUCTION OF CHLOROMETHANES
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3663619 |
PROCESS FOR THE PREPARATION OF 2,2',6,6'-TETRABROMO-4,4'-METHYLENEDIANILINE
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3819721 |
PREPARATION OF HALOADAMANTANES
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3784518 |
METHOD FOR PRODUCING ALKYL IODIDES
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3484495 |
CATALYTIC PROCESS FOR PREPARING ALKYL CHLORIDES OR BROMIDES
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3484494 |
CATALYTIC PROCESS FOR THE MANUFACTURE OF ALKYL HALIDES AND CATALYSTS THEREFOR
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3374278 |
Preparation of alkyl iodides from alkyl alcohols and organotin iodides
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3341579 |
Preparation of acetic acid and alkyl chlorides from ester-alcohol mixtures
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3340246 |
Process for the synthesis of amides, esters, alkyl halides, carboxylic acid anhydrides, and peptides employing aminoacetylenes as water acceptors
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3234289 |
Method of making a tetrabromobisphenol
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