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7601878 |
Process and unit for production of perfluoroalkyl iodide telomers
A solid catalyst used in, for example, production of a perfluoroalkyl iodide telomer is effectively and continuously recovered and the recovered catalyst is continuously recycled to the reactor for...
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7504358 |
Nickel-substituted and mixed nickel-and cobalt-substituted chromium oxide compositions, their preparation, and their use as catalysts and catalysts precursors
A crystalline alpha-chromium oxide where from about 0.05 atom % to about 2 atom % of the chromium atoms in the alpha-chromium oxide lattice are substituted by nickel atoms, and optionally,...
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7396965 |
Method for producing fluorinated organic compounds
A method for preparing fluorinated organic compounds wherein at least one fluorinated olefin is reacted with methyl fluoride in the gas-phase and in the presence of a Lewis Acid catalyst to form at...
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7371904 |
Processes for synthesis of 1,3,3,3-tetrafluoropropene
Disclosed is a process for the synthesis of 1,3,3,3-tetrafluoropropene which comprises, in one embodiment, reacting a compound of CF 3 X 1 with a compound of CX 2 H═CHX 3 , wherein X 1 , X 2 ,...
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7230147 |
Process for functionalizing a double bond
The invention concerns a method for functionalizing a double bond and, more particularly, a double bond bearing a metalloid atom. Said functionalization is produced by the action of perhalogenated...
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7214815 |
Metallic copper catalyst for polyfluoroalkylethyl iodide production and process for producing polyfluoroalkylethyl iodide
The present invention provides a metallic copper catalyst for use in an ethylene addition reaction to polyfluoroalkyl iodides, a process for efficiently producing a polyfluoroalkylethyl iodide...
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7109386 |
Method for preparing a halogenated olefin
Process for the preparation of a halogenated olefin by reaction of an alkyne and/or of an allene compound with a hydrogen halide in a liquid medium comprising at least one hydrohalogenation...
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7102041 |
Continuous process for preparing halogenated compounds
A process for preparing a haloalkane comprising: (a) contacting a haloalkane starting material with an alkene in the presence of an effective amount of a catalyst complex under conditions effective...
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7094936 |
Process for preparing halogenated alkanes
Methods and materials are provided for the production and purification of halogenated compounds and intermediates in the production of 1,1,1,3,3-pentafluoropropane. In a preferred embodiment, the...
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7094934 |
Production process of hydrofluorocarbons
In a process for producing a hydrogen-containing fluorinated hydrocarbon in which a halogenated hydrocarbon reaction raw material, which includes a chlorinated alkene and/or a hydrogen-containing...
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7074434 |
Process for the separation of a mixture comprising at least one hydrofluoroalkane and hydrogen fluoride, processes for the preparation of a hydrofluoroalkane and azeotropic compositions
Process for the separation of a mixture comprising at least one hydrofluoroalkane and hydrogen fluoride, according to which a hydrofluoroalkane/hydrogen fluoride mixture is reacted with at least...
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7053253 |
Process for purifying hexafluoropropene dimers
Perfluoro-4-methyl-2-pentene containing the undesirable perfluoro-2-methyl-2-pentene may be purified by contacting the mixture with at least a stoichiometric equivalent of an aqueous inorganic base...
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7038095 |
Method for producing fluoroalkyl iodide telomer mixture and method for producing mixture fluorine-containing (meth) acrylate esters
A mixture of fluoroalkyl iodide telomers represented by the formula: R f (CF 2 CF 2 ) n I wherein R f represents a fluoroalkyl group whose number of carbon atoms is in the range of 1 to 10, with...
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6958422 |
Pyrolysis process
The present invention relates to the pyrolysis of hydrochlorofluorocarbons to form fluoromonomers such as tetrafluoroethylene, the pyrolysis being carried out in a reaction zone lined with nickel...
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6924403 |
Synthesis of hexafluoropropylene
The present invention relates to the process of pyrolyzing tetrafluoroethylene to hexafluoropropylene by carrying out the pyrolysis in a tubular reactor that is lined with either nickel or nickel...
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6919490 |
Method for continuous production of a perfluoroalkyl iodide telomer
The present invention relates to a process for continuously producing a perfluoroalkyl iodide represented by the general formula R f (CF 2 CF 2 ) n I, wherein R f is a C 1-6 perfluoroalkyl and n...
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6858763 |
Process for preparing elastomeric ethylene-hexafluoropropylene copolymer
The present invention relates to a process for preparing an elastomeric ethylene-hexafluoropropylene copolymer with excellent vulcanization properties, which comprises emulsion polymerizing...
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6730817 |
Method for preparing 1,1,1,3,3-pentafluoropropane
1,1,1,3,3-Pentafluoropropane is produced by reaction between 1,1,1,3,3-pentachloropropane and hydrogen fluoride in the presence of a hydrofluorination catalyst. The 1,1,1,3,3-pentachloropropane may...
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6720466 |
1,1,1,3,3-pentachloropropane process purge stream concentration using a secondary refluxed evaporator and secondary product recovery
A process for economically producing 1,1,1,3,3-pentachloropropane under conditions which preserve the activity of the catalyst. In a preferred embodiment, a two-stage distillation process is...
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6518467 |
Method of making hydrofluorocarbons and hydrochlorofluorocarbons
A method of producing hydrofluorocarbons and/or hydrochlorofluorocarbons by using halogenated alkanes as a principal reactant. Generally, the method comprises the step of: (a) reacting a starting...
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6472574 |
Production of 1,2-dihydro and 2,2-dihydro hexafluoropropanes and azeotropes thereof with HF
CF 3 CHFCHF 2 production is disclosed which involves reacting CF 3 CF═CHF with HF at an elevated temperature over a catalyst selected from the group consisting of aluminum fluoride, fluorided...
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6452057 |
Process for preparing halohydrocarbons in the presence of a co-catalyst
Halohydrocarbons comprising at least 3 carbon atoms are obtained by batchwise reaction between a haloalkane and an olefin in the presence of a catalyst and a co-catalyst. The addition of at least...
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6441256 |
Method for preparing of halogenated hydrocarbons
Halohydrocarbons comprising at least 3 carbon atoms are obtained by reaction between a haloalkane and a haloolefin, in the substantial absence of nitrile, and by introducing the reactants in a...
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6417413 |
Process for the preparation of halogenated ethanes
A process for preparing halogenated ethanes, particularly pentafluoroethane, from a mixture produced by the reaction of perchloroethylene, hydrogen fluoride and a recycle stream. The preferred...
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6399840 |
Method for the preparation of 1,1,1,3,3-pentachlorobutane
1,1,1,3,3-pentachlorobutane is obtained by reacting carbon tetrachloride with 2-chloro-1-propene in the presence of at least one copper (I) or (II) compound as telomerization catalyst....
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6369285 |
Process for preparing halohydrocarbons
Halohydrocarbons containing at least 3 carbon atoms are obtained by reaction between a haloalkane and an olefin in the presence of a catalyst in a reaction medium which is essentially free of water.
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6365676 |
Poly-perfluoroalkyl substituted polyamines as grease proofing agents for paper and foam stabilizers in aqueous fire-fighting foams
The invention concerns a process for the reaction of a perfluoroalkyl iodide of the formula CF 3 (CF 2 ) h —I, where h is an integer from 4 to 18, with a compound having a terminal olefinic...
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6300532 |
Process for addition of haloalkanes to alkenes catalyzed by an organophosphite compound
A process for catalytic addition of haloalkanes to alkenes involving the step of reacting the haloalkane with the alkene in the presence of a catalyst. The catalyst is an organophosphite compound...
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6191327 |
Method for producing dichloropentafluoropropanes
The present invention relates to a simple method for producing 3,3-dichloro-1,1,1,2,2-pentafluoropropane (R225ca) and 1,3-dichloro-1,1,2,2,3-pentafluoropropane (R225cb) in good yield and at high...
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6187978 |
Continuous process for manufacturing halogenated compounds
A process for preparing a haloalkane comprising: (a) contacting a haloalkane starting material with a haloalkene starting material in the presence of an effective amount of a catalyst complex under...
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6184426 |
Addition of hydrofluorocarbons to fluoroolefins
A process is disclosed for forming adducts of the formula: RR 1 R 2 CCR 1 R 2 F or (FR 1 R 2 CCRR 2 CH 2 ) 2 where R is CH 3 , CH 2 F, or F(CF 2 ) n CH 2 CH 2 (where n is an integer...
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6153803 |
Process for the preparation of halohydrocarbons
Halohydrocarbons comprising at least 3 carbon atoms are obtained by reaction between a haloalkane and a haloolefin in the presence of an organonickel compound as catalyst, and optionally in the...
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6150565 |
Process using CF.sub.2 I.sub.2 and olefins for producing diiodo fluorocompounds, and products thereof
A process is disclosed for making diiodofluorinated compounds of the formula ICF 2 (A) n I wherein n is an integer of at least 1 and each A is CXYCQZ wherein each X, Y, Q, and Z are each...
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6040487 |
Process for the manufacture of halocarbons
A liquid phase process is disclosed for producing halogenated alkane adducts of the formula: CAR 1 R 2 CBR 3 R 4 (where, A, B, R 1 , R 2 , R 3 and R 4 are defined in the specification) which...
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5902914 |
Process for the preparation of halogenated alkanes
A process for the preparation of halogenated alkanes is provided. In particular, a process is provided for the highly selective preparation of haloalkanes, including 1,1,1,3,3-pentachloropropane,...
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5650545 |
Synthesis of perfluoroalkyl iodides
The invention relates to a continuous process for the preparation of perfluoroalkyl iodides by thermal telomerization, in the gas phase, of tetrafluoroethylene with pentafluoroethyl iodide or...
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5639923 |
Metal-catalyzed preparation of perfluoroalkyl iodide telomers
The selectivity of copper as the catalyst for the reaction of short-chain perfluoroalkyl iodides with tetrafluoroethylene is increased if a further transition metal is employed as a cocatalyst.
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5608126 |
Process for preparing 1,1,1,3,3-pentafluoropropane
A process for preparing 1,1,1,3,3-pentafluoropropane, which comprises reacting 1,1-difluoroethylene with dichlorofluoromethane in the presence of a Lewis acid catalyst to form...
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5574193 |
Initiators for telomerization of polyfluoroalkyl iodides with fluoroolefins
This invention relates to the telomerization of polyfluoroalkyl iodides with polyfluoroolefins in the presence of strong fluorooxidizer initiators. The products obtained are useful in the...
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5557019 |
Method for preparing dichlorodecafluoropentane and decafluoropentane
A new 3,3-dichloro-1,1,1,2,2,4,4,5,5,5-decafluoropentane as a precursor of alternatives of refrigerants, etc. A method to obtain the target products at high yield and high selectivity by reacting...
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5488189 |
Process for fluorinated propanes and pentanes
The instant invention relates to producing fluorinated propanes and pentanes. More particularly it relates to producing perhalofluoropropanes and pentanes by reacting dihalodifluoromethanes with...
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5434321 |
Method for producing dichloropentafluoropropanes
A method for producing a dichloropentafluoropropane, which comprises reacting dichlorofluoromethane (R21) with tetrafluoroethylene (4F) in the presence of a Lewis acid catalyst for addition...
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5395997 |
Process for the preparation of hydrofluorocarbons having 3 to 7 carbon atoms
The invention relates to a process for preparing hydrofluorocarbons of the formulas CF 3 (CH 2 CF 2 ) n F comprising reacting at least one reactant selected from CCl 3 (CH 2 CCl 2 ) n Cl, CCl...
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5326913 |
Process for preparing fluorinated compound
A fluorinated compound of the formula: R--CCl 2 CF 2 CF 3 (I) in which R is a perfluoroalkyl group, a perchloroalkyl group, a polyfluoroalkyl group, a...
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5254773 |
Process for preparing telomers from ethylene and alpha, omega-dibromoperfluoroalkylalkanes in the presence of organic free-radical generators
A process is disclosed wherein a telomer having the formula BrCH 2 CH 2 (CF 2 CFX) n CH 2 CH 2 Br is prepared by reacting a telogen of the formula Br(CF 2 CFX) n CH 2 CH 2 Br with...
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5185483 |
Process for preparing pentafluorodichloropropanes
1,1,1,2,2-Pentafluoro-3,3-dichloropropane and 1,1,2,2,3-pentafluoro-1,3-dichloropropane are prepared in pure forms by reacting dichlorofluoromethane and tetrafluoroethylene, or chloroform,...
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5157171 |
Process for chlorofluoropropanes
A process for the preparation of chlorofluoropropanes of the formula C 3 HCl 2 F 5 by contacting monofluorodichloromethane with tetrafluoroethylene in the presence of a modified aluminum...
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5087745 |
Process for the production of gamma-butyrobetaine
Process, which is feasible on a commercial scale, for the production of gamma-butyrobetaine. For this purpose, butyrolactone with hydrogen chloride and an alcohol is converted to the chlorobutyric...
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5087765 |
Process for preparing chlorotrifluoroethylene telomers and new telomers obtained
In the process for preparing chlorotrifluoroethylene telomers by reaction of chlorotrifluoroethylene with CF 3 CF or R x --CF 2 OF (wherein R x may be also a perfluoroalkyl radical having 1 to...
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5087777 |
Partially fluorinated alkenes having a tertiary structure
Novel partially fluorinated alkenes having the Formula: ##STR1## wherein each R is the same or different and is selected from the group consisting of CF 3 , CHF 2 , CH 2 F, and CH 3 CF 2 , and R'...
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