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7759528 |
Acetonitrile removal from the olefinic feed of ether production processes using ionic liquids
An enhanced ether production process from an olefinic cut containing at least one iso-olefin and from an alcohol comprises a stage of removal of the acetonitrile present in the hydrocarbon feed by...
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7732648 |
Multistage catalytic process for olefin etherification
A process for producing ethers by reacting alcohols and olefins in successive catalytic stages is disclosed. The process includes alternating catalytic reaction stages and separation stages.
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7553994 |
Method for producing ditrimethylolpropane
In the method of producing ditrimethylolpropane of the present invention, the distillation still residue obtained in the production of trimethylolpropane is subjected to crystallizing treatment...
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7439405 |
Purification of propylene glycol monoalkyl ether
The invention is a method of purifying a propylene glycol monoalkyl ether containing carbonyl impurities which comprises contacting the propylene glycol monoalkyl ether stream in the liquid phase...
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7414159 |
Separation of liquid mixtures in a film evaporator
A liquid mixture comprising at least one readily volatile and at least one sparingly volatile component is separated in a film evaporator by a process in which (i) a continuous stream of a liquid...
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7335801 |
Polyglycerols and production thereof
A polyglycerol composition contains diglycerol, triglycerol, and tetraglycerol each in a content of 5 percent by weight or more, has a total content of diglycerol, triglycerol, and tetraglycerol of...
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7332634 |
Method for the continuous purification by distillation of 1,2-propylene glycol that accumulates during the synthesis of propylene oxide without coupling products
The invention relates to a continuously operated process for the purification by distillation of the 1,2-propylene glycol formed as by-product in the synthesis of propylene oxide, wherein the...
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7304188 |
Preparation of highly pure methyl tert-butyl ether
The invention relates to a process for preparing methyl tert-butyl ether (MTBE) in qualities which are suitable for organic syntheses and for use as a specialty solvent from MTBE in fuel quality.
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7141705 |
Etherification process
A process for the etherification of C4, C5 and/or C6 tertiary olefins in a hydrocarbon feed with at least one C1 to C6 alcohol, preferably C1–C4 alcohols in a distillation column reactor, p...
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7060865 |
Recovery of C4 olefins from a product stream comprising C4 olefins, dimethyl ether and C5+ hydrocarbons
Disclosed is a process for removing DME from a stream containing C4 olefins. The process includes providing a first stream comprising C4 olefins, C5+ hydrocarbons, DME, and methanol. The first...
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7022885 |
Purification on methyl tertiary butyl ether
The present invention relates to purification of an MTBE process stream by contact in the liquid phase with a large pore zeolite such as 13X or Zeolite Y.
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6984765 |
Separation of methanol, ethanol and/or dimethyl ether from hydrocarbon mixtures
The present invention is a separation process for producing a methanol, ethanol and/or dimethyl ether stream from a first stream containing C3+ hydrocarbons. The first stream comprises C3+...
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6977290 |
Process for preparing oligomeric aliphatic diols, polycarbonatediols based thereon and prepolymers thereof
The present invention relates to a method for preparing oligomeric aliphatic diols, polycarbonatediols based thereon and NCO-terminated prepolymers obtainable therefrom. The inventive compounds may...
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6927310 |
Tripropylene glycol production
A method for forming multiple tripropylene glycol products of acrylate grade comprising forming a composition of dipropylene glycol, tripropylene glycol, tetrapropylene glycol and heavier, and at...
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6924399 |
Method of manufacturing dimethyl ether
Dimethyl ether is obtained with at low cost by transporting methanol under room temperature and atmospheric pressure from the methanol producing district to the dimethyl ether consuming district or...
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6822125 |
Method for preparing dimethylether using a membrane reactor for separation and reaction
The present invention relates to a method for preparing dimethylether from methanol using a membrane reactor, more particularly to a method for preparing dimethylether from methanol using a...
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6613197 |
Method for isolation of barely volatile organic compounds
A method and apparatus for isolation of a barely volatile organic compound in a sample suspected to contain the same, e.g. a dioxin, which includes continuously adding superheated steam and a...
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6472568 |
Reaction and distillation device and etherification process
The invention relates to a process for preparing at least one aliphatic monoalcohol, generally in excess, and at least one olefin. The process is performed in a distillation and reaction device...
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6458856 |
Separation process for one-step production of dimethyl ether from synthesis gas
An improvement to the process for separating dimethyl ether (DME) from byproducts in a one-step catalytic conversion of synthesis gas (syngas), the improvement comprising using a scrubbing solvent...
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6417408 |
Production process for (poly)alkylene glycol monoalkyl ether
The present invention provides a process for producing a (poly)alkylene glycol monoalkyl ether with high selectivity and high yield. In this process, the (poly)alkylene glycol monoalkyl ether is...
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6387222 |
Continuous isolation of a high-melting material by distillation
A method of distillation for separating a material which is solid at ambient temperature from a lower boiling and lower melting point material, and the apparatus.
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6278029 |
Process for eliminating polar compounds on an etherification unit
A process for eliminating at least pollutants including polar compounds present in a first fluid, with said first fluid sent to a subsequent treatment, e.g., an etherification process: a) the first...
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6264800 |
Purification process
A procedure is provided for the separation of close boiling impurities from products which have slightly higher polarity than the impurities, for example, separation of di-propylene glycol...
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6232508 |
Process for manufacturing ether and high purity butene-1
A process for the manufacture of ether from a feedstock containing isoolefins and linear olefins. The process is one which has a high conversion of isoolefins thereby permitting the separation of...
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6218582 |
Method for the reduced formation of tertiary butyl alcohol in a finishing reactor in the manufacture of methyl tertiary butyl ether
A method for the preparation of methyl tertiary butyl ether is provided wherein a mixture of methanol and substantially peroxides-free tertiary butyl alcohol are catalytically reacted to form a...
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6214172 |
Preparation of methylglyoxal dimethyl acetal
In a process for the preparation of methylglyoxal dimethyl acetal from methylglyoxal and methanol in the presence of an acidic ion exchanger, water is introduced in an amount sufficient to form an...
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6197163 |
Process for removing impurities from petroleum products
The impurity content, e.g. propionitrile, in a fraction containing C5 or C6 tertiary olefins obtained by cracking hydrocarbons is reduced by distilling with an alkanol and removing the impurity as...
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6159344 |
Reaction and distillation device
The invention relates to a distillation and reaction device having a reaction section and a distillation-reaction section. The distillation-reaction section has a distillation zone with at least...
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6107526 |
Process for producing ethyl tertiary butyl ether
A catalytic distillation process for producing high purity ethyl tertiary butyl ether that contains less than 0.6 weight percent ethanol, and preferably less than 0.07 weight percent ethanol, has...
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6087539 |
Process for producing an ether compound
A process for producing an ether compound represented by the general formula (II) or (III): ##STR1## wherein R1 and R2 represent each an alkyl group or a cycloalkyl group and n represents an...
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6069284 |
Process for separating diisopropyl ether from isopropyl alcohol and water
A process to separate diisopropyl ether from a mixture of diisopropyl ether, isopropyl alcohol, and water has been developed. The process begins with distilling, in a distillation column, the...
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6037502 |
Etherification process
This invention provides an improved etherification process that reduces the amount of acidic-ion-exchange-resin catalyst that is deactivated by nitriles. This process uses a water phase to remove...
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5998675 |
Process for preparing tertiary alkyl ethers
A process for preparing tertiary alkyl ethers comprises the steps of reacting C4-7 isoolefins of an olefinic hydrocarbon feedstock with an alkanol in the presence of a first catalyst in a reaction...
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5985100 |
Process for separating butanol and dibutyl ether by means of dual-pressure distillation
Butanol and dibutyl ether are separated from a mixture containing water, dibutyl ether and n-butanol, 2-butanol and/or isobutanol by a process in which a) the mixture is introduced into a first...
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5973096 |
Process for purifying a polyether
A process for purifying a polyether, which comprises adding to a polyether (A) containing a first salt, water (B) and a compound (C) which is capable of reacting with an ion constituting the first...
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5908964 |
Process for preparing alkyl ethers and mixtures thereof
The invention concerns a process for preparing a tertiary alkyl ether product. The process comprises reacting the isoolefins of an olefinic hydrocarbon feedstock in a reaction zone (1-3) with an...
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5882485 |
Process for the separation of dimethyl ether and chloromethane in mixtures
A process for the separation of dimethyl ether and chloromethane in mixturesA process for the separation of dimethyl ether and chloromethane in mixtures by two distillation steps. In the first...
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5847224 |
Method for improving the color of MTBE, ETBE and TAME
A process for improving the color of oxygenates, such as MTBE, ETBE and TAME, which utilizes a hydrogenation treater in the presence of a catalyst, containing at least one noble metal, along with a...
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5847230 |
Nitrile removal in an etherification process
In an etherification process that uses an FCC effluent as a source of isoolefins, the buildup of nitrites in an alcohol-containing stream that is recycled to the etherification zone is prevented by...
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5843286 |
Process for the preparation and fractionation of a mixture of dimethyl ether and chloromethane with water as extractant
A process for the preparation and fractionation of a mixture of dimethyl ether and chloromethane by extractive distillation with water as extractant. The mixture is prepared by reacting methanol...
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5817906 |
Process for producing light olefins using reaction with distillation as an intermediate step
The present invention relates to a process for the production of light olefins comprising olefins having from 2 to 4 carbon atoms per molecule from a crude oxygenate feedstock. The crude oxygenate...
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5811597 |
Method for the manufacture of methyl tertiary butyl ether from tertiary butyl alcohol and methanol
Methyl tertiary butyl ether is prepared from contaminated TBA by reactively distilling the contaminated TBA in a reactive distillation column to provide a lower boiling isobutylene fraction and a...
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5792899 |
Process for the management of polynuclear aromatic compounds produced in a hydrocarbon dehydrogenation reaction zone
A process for the management of polynuclear aromatic compounds produced in a hydrocarbon dehydrogenation zone wherein the effluent from the hydrocarbon dehydrogenation zone is contacted with an...
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5763685 |
Use of a second stage reactor in the manufacture and recovery of methyl tertiary butyl ether
MTBE is prepared from TBA and MeOH by passing a feed mixture comprising TBA and MeOH through a primary MTBE reaction zone to form a primary reaction product containing MTBE, unreacted TBA,...
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5750800 |
Process for producing diisopropyl ether from propane
An integrated process to produce diisopropyl ether from propane has been developed. In a first reaction zone the propane in a feedstock, after any hydrocarbons containing four or more carbon atoms...
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5750799 |
Dimethyl ether production and recovery from methanol
A process for production and recovery of dimethyl ether by dehydration of methanol which significantly reduces the distillation duties associated to the preparation of the fresh methanol feed stock...
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5741951 |
Conjoint manufacture of MTBE and diisobutylene
Methyl tertiary butyl ether and diisobutylene are prepared by reacting methanol with tertiary butyl alcohol to provide an etherification reaction product containing methyl tertiary butyl ether,...
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5741953 |
Use of reactive distillation in the manufacture of methyl tertiary butyl ether
An aqueous methanol feed stream contaminated with tertiary butyl alcohol is charged to a reactive distillation column having a reaction distillation section in the upper portion thereof containing...
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5741952 |
Catalytic decomposition of peroxides to purify a methyl tertiary butyl ether recycle stream
An MTBE recycle stream (which consists mainly of TBA and methanol) contaminated with residual amounts of tertiary butyl hydroperoxide, ditertiary butyl peroxide and allyl tertiary butyl peroxide...
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5723698 |
Catalytic decomposition of formate impurities in tertiary butyl alcohol and methyl tertiary butyl ether streams
Disclosed is a method for decomposing formate esters, free acids and peroxides in a tertiary butyl alcohol stream to produce noncondensible gas products which comprises reacting said tertiary butyl...
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