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4847431 |
Process for manufacturing a tertiary alkyl ether by reactive distillation
Process for manufacturing methyl tert-butyl ether (MTBE) by reacting methanol with isobutene-containing hydrocarbons in a reaction zone comprising alternate beds of sulfonated resin catalyst and...
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4847430 |
Process for manufacturing a tertiary alkyl ether by reactive distillation
The invention concerns a process for manufacturing methyl tert-butyl ether (MTBE) by reacting methanol with an isobutene-containing hydrocarbon mixture. This process is characterized by the steps...
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4835329 |
Process for producing high octane gasoline
An integrated process for the production of alkylate and etherate rich high octane gasoline streams comprising the etherification to produce MTBE and TAME in the presence of a high stoichiometric...
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4830635 |
Production of liquid hydrocarbon and ether mixtures
An etherification process for reacting a hydrocarbon mixture containing C 4 -C 7 iso-olefins with excess methanol to produce tertiary alkyl methyl ethers. The improved technique comprises...
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4827045 |
Etherification of extracted crude methanol and conversion of raffinate
An improved process for reacting crude aqueous methanol feedstock with iso-olefinic hydrocarbons to produce C 5 + methyl tertiary-alkly ethers, which comprises: contacting the aqueous methanol...
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4826507 |
Integrated etherification and oxygenates to gasoline process
An integrated once through process for the production of ether-rich liquid fuels containing MTBE and TAME by etherifying a hydrocarbon feedstock containing C 4 + isoalkenes in the presence of a...
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4827046 |
Extraction of crude methanol and conversion of raffinate
An improved process for reacting crude aqueous methanol feedstock with tertiary-olefinic hydrocarbons to produce C 5 + methyl tertiary-alkyl ethers, which comprises: contacting the aqueous...
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4820877 |
Etherification process improvement
An improved etherification process is described for the manufacture of methyl tertiary alkyl ethers such as methyl tertiary butyl ether and methyl tertiary amyl ether. In one embodiment...
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4816607 |
Integrated etherification process with recycle post treatment
A multistep hydrocarbon conversion process for the production of ethers including methyl tertiary butyl ether (MTBE) from light paraffins and alcohols is disclosed. A mixture of C 4 isoparaffins,...
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4814519 |
Production of ethers from olefins
A process for the production of ethers from an olefin containing feedstock. The process includes two-stages for the production of ethers which comprises, in a first stage, isomerizing an olefin...
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4814517 |
Oxygenate removal in MTBE production
Low concentrations of methanol and dimethyl ether in distillation column C 4 -C 5 raffinate produced in the formation of methyl tert.-alkyl ethers by the reaction of methanol with isoalkylenes...
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4808270 |
Process and apparatus for the preparation of ether
For the preparation of an ether, e.g., tertiary amyl methyl ether, an olefin-containing feed stream is catalytically etherified with an alcohol, e.g., methyl alcohol. The etherification product is...
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4806695 |
Process for etherification of a dehydrogenation zone effluent
A combined process for the dehydrogenation of C 3 -C 5 paraffins in a first zone and the conversion of olefins in a second zone improves efficiency by directly charging all but the lightest...
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4797133 |
Process for recovery of butene-1 from mixed C4 hydrocarbons
A process is disclosed for the recovery of butene-1 from a mixed C 4 feed stream which also contains isobutylene, butene-2, isobutane and normal butane. The C 4 feed stream is passed through an...
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4792639 |
Process for the production of methyl ethers from branched monoolefins
An improved process for the production of methyl ethers of the type in which methanol is reacted with a branched monoolefin in the presence of a catalytically effective amount of one or more acid...
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4788365 |
High octane gasoline and distillates from oxygenates
An integrated process for the conversion of methanol to high octane gasoline and distillate. Methanol is converted to olefins in the presence of zeolite type catalyst. C 4 and C 5 olefin fraction...
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4778943 |
Skeletal isomerization of olefins over halogen-containing alkaline earth oxide catalysts
A process for the skeletal isomerization of olefins wherein the olefins are contacted with a catalyst comprising at least one alkaline earth oxide which has been treated with a halogen compound.
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4774365 |
Pervaporation process for separating alcohols from ethers
The present invention is an improved process for separating alcohols from ethers and/or hydrocarbon raffinate in an etherification process. The excess alcohol reactant, which forms azeotrope...
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4774364 |
Integrated alkylation/alkyl tertiary-alkyl ether synthesis process
A process is disclosed for the preparation of alkyl tertiary-alkyl ether concurrent with the alkylation of isoparaffins with olefins. The composite zeolite catalyst is reactivated in the alkyl...
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4761504 |
Integrated process for high octane alkylation and etherification
A process is disclosed for the simultaneous alkylation of light hydrocarbons to produce gasoline blending components and the etherification of an isoolefin to produce an ether. The etherification...
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4760210 |
Partial oxidation system
Method and apparatus for partial oxidation of hydrocarbonaceous gases, wherein a hydrocarbonaceous gas is preheated, reacted with oxygen, and quenched by means of a rotating matrix comprising...
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4754078 |
Integrated etherification process with isomerization pretreatment
A multistep hydrocarbon conversion process for the production of ethers including methyl tertiary butyl ether (MTBE) from light paraffins and alcohols is disclosed. A mixture of C 4 isoparaffins,...
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4749816 |
Chemical process
A process for preparing an acetal or a ketal comprises contacting an olefin with an alcohol at elevated temperature in the presence of a dihydrocarbyl peroxide and a catalyst comprising palladium...
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4748281 |
Recovery of methanol in an MTBE process
An adsorbent is used to recover methanol in unreacted C 4 's from the MTBE process. Methanol is desorbed from the mixture in a closed loop regeneration system utilizing a circulating vapor at an...
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4740631 |
Process for preparing ethers
In the process for preparing methyl tert.-alkyl ether comprising the steps of (a) contacting and reacting in the liquid phase a reaction mixture formed by combining a stream consisting essentially...
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4740632 |
Process for removing methanol from alkylation unit feed stream
A process of removing methanol from a mixed stream comprising methanol and at least one hydrocarbon and utilizing the hydrocarbon as feed for an acid catalyzed alkylation unit which produces a...
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4731489 |
Process for production of gasoline blending stock
A process for producing a gasoline blending stock of methyl tertiary butyl ether and tertiary butyl alcohol wherein a first catalytic etherification of isobutene and methanol produces methyl...
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4731490 |
Process for methyl, tertiary butyl ether production
A process for the production of methyl tertiary butyl ether comprising dimerizing ethylene to form a first butene-containing material; isomerizing the first butene-containing material to produce a...
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4714788 |
Tertiary olefin process
In a process for separating C 4 to C 7 tertiary mono-olefins(s) present in a C 4 to C 7 hydrocarbon mixture containing diolefins which comprises selectively reacting said tertiary mono-olefin...
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4714787 |
Production of ethers from linear olefins
A catalytic process is provided for the manufacture of ethers by reacting a linear monoolefin with a primary or secondary alcohol having up to 4 carbon atoms. The process selectively forms methyl...
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4695662 |
Light paraffin dehydrogenation process
A process is disclosed for the catalytic dehydrogenation of propane or butanes. The vapor phase reaction zone effluent stream is contacted with a heavy absorption liquid and then with a light...
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4684757 |
Process for converting methanol to alkyl ethers, gasoline, distillate and alkylate liquid hydrocarbons
A multistage process for producing ethers from lower aliphatic oxygenate feedstock, such as methanol. Feedstock is catalytically converted in a primary catalyst stage at elevated temperature in...
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4665220 |
Use of stabilized pillared interlayered clays as catalysts in reactions capable of catalysis by protons
A method for carrying out processes capable of catalysis by protons using as catalyst a stabilized pillared interlayered clay.
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4664675 |
Process for upgrading olefinic gasolines by etherification
The invention concerns a process for upgrading olefinic gasolines containing C 5 hydrocarbons, but free of C 4 hydrocarbons, by etherification. It is characterized in that the tertiary olefins of...
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4665237 |
Process for producing methyl tertiary butyl ether
A process for producing methyl tertiary butyl ether is disclosed, comprising reacting isobutylene and methanol using a hydrocarbon mixture of 4 carbon atoms containing isobutylene and methanol as...
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4647703 |
Process for producing a hydrocarbon cut of high octane number by etherification of olefins
Process for producing a hydrocarbon cut of high octane number by etherification of an olefin-containing hydrocarbon cut. The olefinic cut, to which methanol is added, passes into an etherification...
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4624748 |
Catalyst system for use in a distillation column reactor
A novel catalyst system for use in a distillation column reactor is disclosed including annularly-defined spaces within the reactor comprised of vapor-permeable material with packed catalyst and...
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4605787 |
Process for the preparation of alkyl tert-alkyl ethers
Process for the preparation of alkyl tert-alkyl ethers which comprises reacting a primary alcohol with an olefin having a double bond on a tertiary carbon atom in the presence of an acidic zeolite...
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4603225 |
Process for separating dimethyl ether from a hydrocarbon mixture containing the same
A process for separating dimethyl ether from a hydrocarbon mixture which comprises contacting the hydrocarbon mixture with an aqueous solution containing a polar oxygenated hydrocarbon having a...
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4593135 |
Method for promoting the activity and/or extending the life of cation-exchangeable layered clay catalysts in proton-catalyzed reactions
A method for promoting the activity and/or extending the life of a cation-exchangeable layered clay catalyst in reactions susceptible to catalysis by protons which method comprises the addition to...
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4584415 |
Formation of alkyl ethers from alcohols and alkenes using AMS-1B crystalline borosilicate
A process to form an ether comprises contacting an alkene and an alcohol under conversion conditions with an AMS-1B borosilicate catalyst composition.
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4581474 |
Hydrocarbon conversion process
In a combination alkylation-methyltertiary butyl ether (MTBE) operation, the unreacted C 4 olefinic hydrocarbons produced by etherification are contacted with molecular sieves to absorb 2-butenes...
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4575567 |
Adsorbent regeneration in etherification processes
An improved method is disclosed for regenerating adsorbents used in an integrated process for the production of ethers such as methyl tertiary butyl ether by the reaction of an alcohol with an...
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4571439 |
Method for controlled oligomerization/etherification of propylene
Propylene contained in mixed C 3 /C 4 streams containing at least 5 wt. % isobutene, for example, catalytic cracker offgas, may be recovered as a useful gasoline component by reacting in the...
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4570026 |
Production of isobutene from methyl tertiary butyl ether
MTBE can be dissociated with high selectivity to isobutene and methanol over acid action exchange resin catalysts using very high LHSV, e.g. of 7 to 35 at pressure drops of 0.5 to 50 psig through...
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4558168 |
Production of high purity butene-1 from an n-butane feedstock
This invention relates to a process for producing a high purity butene-1 product from n-butane via a dehydrogenation process. In one embodiment of the process the n-butane is dehydrogenated over a...
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4554386 |
Process for the preparation of methyl tertiary butyl ether
A process for the preparation of methyl tertiary butyl ether (MTBE) in two stages: the first stage comprising the reaction of isobutene with methanol in the presence of an acid catalyst,...
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4546204 |
Process for the manufacture of methyl t-butyl ether
The invention concerns a process for the manufacture of methyl t-butyl ether in which: a hydrocarbon feedstock is cracked to give an ethylene-rich stream; an isobutane-rich stream is separated from...
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4546206 |
Process for producing methyl tert. alkyl ether
Methyl t-butyl ether and methyl t-amyl ether are produced by reacting methanol with isobutene and isoamylene, respectively, at a total methanol/isoolefine mole ratio of 1-1.2:1 in a series of...
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4544776 |
Process for separating methanol from the reaction products obtained in the etherification of C.sub.4 through C.sub.7 isoolefins with methanol
The reaction product from etherification of C 4 -C 7 isoolefins with methanol in the presence of an acidic catalyst is washed with water in the presence of inert hydrocarbons thereby removing...
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