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7358402 |
Reduced coenzyme Q10 crystal with excellent stability and composition containing said reduced coenzyme Q10 crystal
The present invention provides a reduced coenzyme Q 10 crystal with excellent stability and a composition containing said reduced coenzyme Q 10 crystals. According to the present invention,...
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7230141 |
Method for producing toluol derivatives
A process for preparing toluene derivatives of the formula I,
where R 1 , R 2 and R 3 independently of one another are hydrogen, halogen, C 1 –C 6 -alkyl, hydroxyl or C 1 –C 6 -alkoxy, by...
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6989467 |
Microwave induced process for the preparation of substituted 4-vinylphenols
The present invention relates to “a microwave induced process for the preparation of 4-vinylphenols or its derivatives” in which commercially important FEMA GRAS approved perfumery and...
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6881868 |
Process for the preparation of (R)-2-alkyl-3-phenyl-1-propanols
Compounds of formula (I), wherein R 1 and R 2 are, independently of one another, H,C 1 -C 6 alkyl, C 1 -C 6 halogenalkyl, C 1 -C 6 alkoxyl, C 1 -C 6 alkoxy-C 1 -C 6 alkyl, or C 1 -C 6 alkoxy-C 1...
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6852895 |
Practical, cost-effective synthesis of CoQ10
The present invention provides a convergent method for the synthesis of ubiquinones and ubiquinone analogues. Also provided are precursors of ubiquinones and their analogues that are useful in the...
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6828466 |
Process for the synthesis of phenols from arenes
A process to synthesize substituted phenols such as those of the general formula RR′R″Ar(OH) wherein R, R′, and R″ are each independently hydrogen or any group which does not interfere in...
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6541673 |
Process for oxyalkylating phenolic compounds
Phenolic polyether polyols are prepared by a two stage oxyalkylation process, a first stage performed at a high oxyalkylation temperature and a second stage at a lower oxyalkylation temperature....
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6512147 |
Apparatus and process for generating mixed multi-component vapor
A mixed liquid of two or more components different in boiling temperature from each other and soluble in or compatible with each other is evaporated into a mixed vapor having a similar composition...
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6274635 |
Alkylated resorcinol derivatives for the treatment of immune diseases
The present invention provides a method, compounds, and compositions for treating a disease associated with immune dysfunction. In accordance with the method, a pharmacologically-acceptable...
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6271423 |
Preparation of butenyl ethers
A process for preparing butenyl ethers of the formula I CH 3 --CHCH--CH 2 --OR I by reacting butadiene or butadiene-containing hydrocarbon streams with alcohols of the formula II ROH II...
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6013841 |
Method for the conversion of 3- and 4-methylcatechol to benzaldehyde
The 3- and 4-methylcatechols are converted to the corresponding benzaldehyde by first alkylating the hydroxyl groups to form an alkylated methylcatechol. The methyl group is then converted to a...
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5977416 |
Dehydration catalyst and process for producing a monoalkylether of a dihydric phenolic compound using same
A dehydration catalyst useful for producing a monoalkylether of dihydric phenolic compound by a dehydration reaction of a dihydric phenolic compound with a lower alkyl alcohol with a high...
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5936102 |
Process for the preparation of 2,2,3,3-tetrafluoro-1,4-benzodioxanes, novel o-(2-bromo-1,1,2,2-tetrafluoroethoxy)-phenols, and novel 2-bromo-1,1,2,2-tetrafluoroethoxy-containing phenyl ethers
The present invention is drawn to a process for preparing a 2,2,3,3-tetrafluoro-1,4-benzodioxane, by cyclocondensing a o-(2-bromo-tetrafluoroethoxy)-phenol in the presence of an acid binder.
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RE36139 |
Hydroquinone derivative
Novel hydroquinone derivatives of the formulae (I) and (II), ##STR1## wherein R 1 is an alkyl group having 7 to 11 carbon atoms, ##STR2## wherein each of R 2 to R 5 is independently a hydrogen...
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5840997 |
Method for the production of alkoxy- and aryloxy-phenols
Alkoxybenzaldehydes and aryloxybenzaldehydes are converted to the corresponding phenols by reacting the benzaldehydes in an organic solvent phase with formic acid and hydrogen peroxide in an...
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5536882 |
Preparation of polyether glycols and alcohols by the polymerization 3,4-epoxy-1-butene
Disclosed are novel polyether compounds obtained by the reaction or polymerization of 3,4-epoxy-1-butene in the presence of an acidic catalyst and a nucleophilic initiator compound. The polyether...
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5446186 |
Structure and synthesis of nitrophenyl-EGTA, a caged calcium, intermediates thereof and a method of producing a high photochemical yield of liberated calcium
The synthesis and compound of a new caged calcium which is an ortho-nitrophenyl derivative of EGTA and various intermediates. It is synthesized in ten steps and 24% overall yield. The...
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5393776 |
Tocotrienol analogs in the treatment of hypercholesterolemia and hyperlipidemia
This invention relates to structurally novel acyclic tocotrienol analogs, which are useful for cholesterol/lipid lowering in cases of hypercholesterolemia and hyperlipidemia, and for...
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5248835 |
Method of producing a monoalkylether of a dihydric phenol compound
A monoalkylether of a dihydric phenol compound is produced at a high conversion and selectivity by catalytically dehydration reacting a dihydric phenol compound with a lower monohydric alcohol in...
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5206396 |
Telomerization of 1,3-butadiene
Octyl ethers and octadienyl ethers of glucose, sucrose, bisphenol A, 4-substituted-2,2,6,6-tetramethylpiperidines are disclosed. Compositions comprised of a mixture of octyl ethers of glucose and...
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5198571 |
Monofunctionalization of phenolic hydroxy onto a polyphenol
A region-specific monofunctionalization of a phenolic hydroxy onto a polyphenol for the preparation of a compound of the formula ##STR1## wherein R is selected from the group consisting of...
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5146010 |
Pyrolysis of naturally occurring cresylic acid mixtures
A process for removing guaiacols from naturally-occurring cresylic acid mixtures by pyrolysis is described.
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5097078 |
Catalytic hydroxylation of phenols/phenol ethers
The phenols and phenol ethers are hydroxylated by reacting such phenols/phenol ethers with hydrogen peroxide, in the presence of (a) a catalytically effective amount of an alkali metal or alkaline...
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5082978 |
Selective monomethylation of phenolic compounds
Mono-, di- and triphenols are selectively monomethylated by reaction with para-dimethoxybenzene in the presence of a catalytically effective amount of an acid catalyst.
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5043494 |
Preparation of methylhydroquinone
Methylhydroquinone (MeHQ) or methyl ether derivative thereof is prepared by contacting paramethoxyphenol or para-dimethoxybenzene with an acid catalyst, preferably a solid acid catalyst, at a...
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4954659 |
1,4-bis (dihydroxyphenyl) butane and analogs
A grignard synthesis of pharmacologically active 1,4-bis(dihydroxyphenyl)butane and analogs, as well as novel intermediates, is provided, comprising preparing a grignard reagent preferably, a...
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4946865 |
Dipropargyloxybenzene compounds and their production
A compound of the formula: ##STR1## wherein X is a hydrogen atom, a halogen atom, a C 1 -C 3 alkyl group or a C 1 -C 3 alkoxy group and Y is a hydrogen atom, a halogen atom, a cyano group, a...
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4897420 |
Benzoquinone derivatives, their production and use
Compounds of the formula: ##STR1## wherein l is an integer of 0 to 18, X is hydrogen, an alkyl having 1 to 4 carbon atoms or a carboxylic acyl having 2 to 4 carbon atoms and Y is a phenylene, a...
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4885403 |
Process for making propargyl ethers of bisphenols
A process for preparing an aromatic propargyl ether, preferably bispropargyl ether, from phenolic compounds comprising vigorously stirring a propargyl halide, preferably propargyl chloride, with a...
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4825011 |
Method of preparing substituted dihydroxy-benzenes
The nuclear hydroxylation of substituted phenols is performed by using aqueous hydrogen peroxide in the presence of sulfur dioxide or selenium dioxide as catalyst in a simple manner with very good...
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4610996 |
Fungicidal phenoxytriazolyl ketones and carbinols
Phenoxytriazolyl ketones and carbinols of the formula ##STR1## in which A represents the keto group or the CH(OH) grouping and R represents hydrogen, alkenyl, alkinyl, halogenoalkyl,...
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4588835 |
Process for preparing alkoxyphenols
A process for preparing an alkoxyphenol represented by the formula: ##STR1## wherein R is hydrogen, alkyl having 1 to 4 carbon atoms, formyl, hydroxymethyl, alkoxymethyl, dialkoxymethyl,...
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4582919 |
Process for the manufacture of optically active compounds
There is described a novel process for producing hydroquinone derivatives of the formula ##STR1## wherein R is an ether protecting group, and their conversion into d-α-tocopherol, starting from...
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4559177 |
Quinone derivatives
A compound of the formula: ##STR1## wherein m is an integer of 11 to 22; R 1 is alkyl having 1 to 4 carbon atoms; R 2 is hydrogen, alkyl having 1 to 4 carbon atoms or carboxylic acyl having 1 to...
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4504685 |
Oxyalkylation process
Hydroxyl compounds are oxyalkylated by contacting them with an alkylene oxide, such as ethylene oxide or propylene oxide, in the presence of a perfluorocarbon polymer containing pendant sulfonic...
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4496771 |
Process for preparing the compound 1-decyloxy-4-[(7-oxa-4-octynyl)-oxy]-benzene
There is described a process for preparing the compound 1-decyloxy-4-[(7-oxa-4-octynyl)-oxy]-benzene consisting in condensing methyl-propargyl-ether with 1-bromo-3-chloro-propane and in reacting...
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4495104 |
Quinone carboxylic acids and ester derivatives
A compound of the general formula ##STR1## wherein n is an integer of 10 to 21, inclusive; R is H or lower alkyl having 1 to 4 carbon atoms has pharmaceutical activities such as hypotensive, tissue...
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4473713 |
Hydrolysis of aryl-aliphatic ethers
At least one of the other functions comprising an aryl-aliphatic ether, e.g., veratrol, is catalytically hydrolyzed with water, e.g., to guaiacol, in the presence of a catalytically effective...
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4435601 |
Preparation of polyphenols by oxidation of hydroxybenzaldehydes
Optionally aldehyde substituted polyphenols are prepared by oxidizing, with hydrogen peroxide, a hydroxybenzaldehyde bearing at least one aldehyde substituent ortho- and/or para- to the nuclear...
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4390733 |
Process for preparing the mono-methallyl ether of pyrocatechin
The mono-methallyl ether of pyrocatechin of formula (I): ##STR1## is prepared by reacting pyrocatechin of formula (II): ##STR2## with a methallyl halide of formula (III): ##STR3## in a homogeneous...
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4336382 |
1,4-Disubstituted piperazine compounds
There are disclosed compounds of the formula ##STR1## wherein R 1 is selected from the group consisting of lower alkyl; R 8 is selected from the group consisting of --O--(CH 2 ) n --wherein n is...
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4314086 |
Preparation of aliphatic/aromatic ethers
Aliphatic/aromatic ethers are prepared by reacting an aliphatic halide with either an alkali or alkaline earth metal, or ammonium phenolate or naphtholate, in an inert organic solvent, and in the...
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4307253 |
Process for the preparation of alkyl aryl ethers
Procecss for the preparation of alkyl aryl ethers by reacting phenols with aliphatic ethers in the presence of strongly acid cation exchangers.
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4294991 |
Process for monoalkylation of dihydric phenols
A process for the preparation of a monoalkyl ether having the formula ##STR1## wherein R is an alkyl radical having 1 to 18 carbon atoms or C 2 H 5 --O--CH 2 CH 2 -- and R 1 is hydrogen or an...
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4283565 |
Process for preparing benzylalcohols
There is described an essentially two step process for the preparation of benzylalcohols including those benzylalcohols having substituents on the benzyene ring by reaction of a substituted or...
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4252985 |
Process for the preparation of o-methallyloxyphenol by the selective monoetherification of pyrocatechol
The process relates to the preparation of o-methallyloxyphenol by the action of methallyl chloride on pyrocatechol in the presence of a basic agent. It consists in carrying out the reaction in a...
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4247710 |
Intermediate in the production of adrenergic blocking agents
There are disclosed compounds of the formula ##STR1## wherein R 1 is selected from the group consisting of lower alkyl; R 8 is selected from the group consisting of --O--(CH 2 ) n --wherein n is...
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4226800 |
Synthesis of acetylene-terminated compounds
Phenolic materials containing propargyl groups are prepared by reacting a polyhydric, phenolic material with propargyl bromide, the reaction being conducted in an aqueous sodium hydroxide solution....
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4192949 |
Preparation of aralkyl phenyl ethers and alkyl phenyl ethers
Phenol ethers are prepared by reacting phenols with dialkyl carbonates in the presence of tertiary amines and/or phosphines. The aralkyl aryl ethers and alkyl aryl ethers obtained are starting...
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4163864 |
Process for preparing 2-methyl-3-prenyl-4,5,6-trimethoxyphenol
2-METHYL-3-PRENYL-4,5,6-TRIMETHOXYPHENOL OF THE FORMULA: ##STR1## wherein R represents a group of the formula: ##STR2## WHEREIN N IS AN INTEGER OF 0 TO 9 AND A and B represent hydrogen atom or A--B...
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