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7491852 |
Process for preparing aldehyde or ketone by oxidation of alcohol with a catalyst having a core-porous shell structure
The present invention discloses a novel use of a catalyst with core-porous shell structure, which includes carrying out an oxidation of an alcohol in vapor phase and in the presence of the catalyst...
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7423184 |
Method of making carbonyl compounds
A method of making a carbonyl compound comprises contacting a compound comprising a secondary hydroxyl group with a basic metal oxide catalyst at a temperature sufficient to maintain the compound...
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7235701 |
Process for producing aldehyde
The invention provides a film-type dehydrogenation reaction catalyst for aldehyde production, which is used in producing an aldehyde from an alcohol as a starting material, as well as a process for...
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7208634 |
Oxidation method of primary or secondary alcohol
A method for preparing an aldehyde or ketone by oxidizing a primary or secondary alcohol in the presence of a nitroxyl radical compound and a co-oxidant in an organic solvent, which process is...
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7169954 |
Method for preparing ruthenium-carrying alumina and method for oxidizing alcohol
A ruthenium-carrying alumina, which is prepared by suspending alumina in a solution containing trivalent ruthenium and adding a base to the suspension, is provided. This ruthenium-carrying alumina...
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7118920 |
Multiphasic microchannel reactions
Multiphasic reactions, especially those reactions using a phase transfer catalyst, are conducted in microchannel apparatus. Advantageously, these reactions can be conducted with two, planar...
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7034170 |
Manganese(IV) complex salts and their use as oxidation catalysts
Manganese(IV) complex salts of formula [LMn(μ-O) 3 MnL] n [XM 12 O 40 ] m , (I), wherein L is 1,4,7-trimethyl-1,4,7-triazacyclononane, X is P or Si, M is Mo or W, n is 2 or 3, and m is 1 or 2,...
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7030279 |
Process for transition metal free catalytic aerobic oxidation of alcohols under mild conditions using stable free nitroxyl radicals
An alcohol can be oxidized by a process in which a primary or secondary alcohol are reacted with an oxygen-containing gas in the presence of a catalyst composition containing (i) a stable free...
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7000382 |
Partial oxidation of alcohols
A method of partially oxidizing an alcohol to an aldehyde or ketone comprises contacting a gas containing the alcohol with a solid catalyst containing molybdenum, preferably in a +6 oxidation...
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6995291 |
Process for the oxidation of unsaturated alcohols
The present invention relates to the field of organic synthesis and more precisely to a process for the synthesis of an unsaturated aldehyde or ketone by oxidation of the corresponding alcohol. The...
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6897342 |
Method for producing aldehydes
A process for making aldehydes involving: (a) providing a fatty alcohol; (b) providing an oxidic copper/zinc catalyst; and (c) continuously dehydrogenating the fatty alcohol, in the presence of the...
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6878847 |
Catalyst for preparation of unsaturated aldehyde and unsaturated carboxylic acid
A catalyst useful for catalytic vapor-phase oxidation of isobutylene, t-butanol or propylene to produce respectively corresponding unsaturated aldehyde and unsaturated carboxylic acid is provided....
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6825384 |
Bromine free TEMPO based catalyst system for oxidation of primary and secondary alcohols using NaOCl as an oxidant
The present invention relates to a process of oxidation of alcohols selectively to aldehydes or ketones with NaOCl using a TEMPO—borate catalyst system. It is shown that the oxidation can be...
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6768013 |
Intrinsically safe oxidation process
A novel process for the direct oxidation of hydrogen and hydrocarbons is disclosed, where the explosion risks inherent in gas phase oxidations are substantially eliminated. Gaseous oxidation...
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6750371 |
Process for the oxidation of alcohols to aldehydes and ketones in the presence of nitroxyl compounds as catalysts
An alcohol is oxidized to an aldehyde or a ketone in the presence of a nitroxyl compound as catalyst, wherein the alcohol to be oxidized is contained in an organic liquid phase, and is reacted in...
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6624332 |
In situ formation of metal-molybdate catalysts for methanol oxidation to formaldehyde
The method of the present invention involves the in situ formation of metal-molybdate catalyst particles active for methanol oxidation to formaldehyde, with iron as an example, the catalyst is made...
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6531635 |
Precursors of 3-alkoxyalkanols and processes for the preparation of 3-alkoxyalkanols
Processes for the preparation of 3-alkoxyalkanols useful as solvents for coating materials, photoresists, or the like. Specifically, (1) a process which comprises reacting an α,β-unsaturated...
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6512144 |
Oxidation of hydrocarbons using crystalline manganese (II/III) phosphate compositions
Processes for oxidizing hydrocarbons using a new family of crystalline manganese phosphate compositions have been developed. These compositions have an extended network which network can be a one-,...
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6486357 |
Catalytic oxidation of alcohols using manganese oxides
A method of oxidizing an organic alcohol, wherein the organic alcohol is contacted with a stoichiometric excess of oxygen in the presence of an effective catalytic amount of a maganese-containing...
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6476260 |
Method of producing aldehydes and carboxylic acids by oxidizing primary alcohols
The invention relates to a method for oxidizing primary alcohols in order to obtain aldehydes and/or carboxylic acids. The reaction takes place in the presence of a catalyst supported on aluminium...
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6399818 |
Process for producing unsaturated aldehydes and unsaturated carboxylic acids
As an improvement in the process for preparing unsaturated aldehydes and unsaturated carboxylic acids through vapor-phase catalytic oxidation of at least one starting compound selected from...
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6350916 |
Selective oxidation of alcohols to aldehydes or ketones
Alcohols are oxidized to their corresponding ketone or aldehyde using an aryl chloride oxidant and a metal-ligand complex or metal/ligand composition. This reaction is particularly applicable to...
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6350918 |
Alcohol conversion
Preparing an aldehyde from an alcohol by contacting the alcohol in the presence of oxygen with a catalyst prepared by contacting an intimate mixture containing metal oxide support particles and...
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6313343 |
Process for the preparation of alpha-oxoaldehydes
Alkylene glycol is oxidized in a vapor phase in the presence of alcohol (a), oxygen, and a catalyst (a) (primary reaction). α-oxoaldehyde, and alcohol (b) or olefin, are oxidized in a vapor phase...
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6255534 |
Preparation of carbonyl compounds
Carbonyl compounds of the formula ##STR1## where R 1 is a hydrogen atom or an alkyl radical having from 1 to 3 carbon atoms, R 2 is a hydrogen atom, an unsubstituted or C 1 -C 3 ...
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6169214 |
Catalyst consisting of a hollow cylindrical carrier having a catalytically active oxide material applied to the outer surface of the carrier, and process for using said catalyst
A coated catalyst which consists of a hollow cylindrical carrier and a catalytically active oxide material applied to the outer surface of the carrier, the applied catalytically active oxide...
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6166264 |
Oxidation catalyst system and method of oxidation with the same
The oxidation catalyst system of the invention is composed of (A) a ruthenium compound and (B) a dioxybenzene or its oxidant. The ruthenium compound (A) includes...
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6165352 |
Process for dehydrogenating hydrocarbons and oxygenated hydrocarbons
A continuous process for the dehydrogenation of a hydrocarbon and/or oxygenated hydrocarbon feed, comprising contacting the hydrocarbon and/or oxygenated hydrocarbon feed with a dehydrogenation...
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6156931 |
Crystalline manganese (II/III) phosphate compositions
A new family of crystalline manganese phosphate compositions has been prepared. These compositions have an extended network which network can be a one-, two-, or three-dimensional network. The...
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6133482 |
Method for producing carbonyl compounds
In a process for preparing carbonyl compounds of the formula ##STR1## where R 1 is a hydrogen atom or an alkyl radical having from 1 to 3 carbon atoms, R 2 is a hydrogen atom or a radical of the...
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6013843 |
Continuous industrial production of unsaturated aliphatic aldehydes in a tube bundle reactor
A process for continuous industrial production of unsaturated aliphatic aldehydes having a boiling range from 95 to 136° C. by oxidative dehydrogenation of the corresponding alcohols with an...
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5990358 |
Process for the preparation of formaldehyde
A process for preparing formaldehyde by oxidative dehydrogenation of methanol comprises passing a gas mixture (i) comprising a) from 0.1 to 50% by volume of methanol, b) from 0.1 to 30% by...
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5912388 |
Preparation of aldehydes or ketones from alcohols
A process for preparing an aldehyde or ketone comprising reacting a primary or secondary alcohol with oxygen in the presence of a base, a catalytic amount of a copper salt and a suitable lignad...
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5808143 |
Catalyst based on oxides of Fe, Co, Bi and Mo
Catalysts of the formula I A a B b O x ! p C c D d Fe e Co f E i F j O y ! q I, where A is bismuth, tellurium, antimony, tin and/or copper, B...
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5336779 |
Method of producing formylimidazoles
In producing formylimidazoles by catalytically oxidizing the corresponding 4- or 5-hydroxymethylimidazoles, the catalytic oxidation is carried out in the presence of a noble metal catalyst while...
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5274187 |
Process for producing compound having carbonyl and/or carboxyl group
A compound having a carbonyl group and/or a carboxyl group is produced by catalytically oxidizing a polyhydric alcohol having at least one primary hydroxyl group and at least one secondary hydroxyl...
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5252758 |
Process for oxidizing organic compounds
Process for oxidizing organic compounds with hydrogen peroxide in the presence of titanium-silicalite and of a water-alcohol solvent which, after the preliminary separation of the oxidation product...
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5245083 |
Method for preparing methacrolein and method for preparing a catalyst for use in the preparation of methacrolein
A catalyst is herein disclosed, which comprises a mixture of a composition (1) represented by the following general formula (1): (Mo) a (Bi) b (Fe) c (X) d (Z) f (O) g (1) (wherein X...
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5241122 |
Catalysts comprising group IB metals
Catalysts, catalyst precursors, and catalytic systems are provided. The catalysts generally comprise a substrate that includes a group IB metal and a porous, microcrystalline layer that includes...
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5196609 |
Preparation of 3-alkoxycarbonyl propenals and 3-dialkoxymethyl propenals
The preparation of 3-alkoxycarbonyl propenals and 3-dialkoxymethyl propenals of the general formulae Ia and Ib respectively: ##STR1## (R 1 =C 1 -C 3 -alkyl group; R 2 and R 3 =hydrogen,...
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5196608 |
Use of an allylchloride for preparing an aldehyde
The present invention relates to the use of an allylchloride of the general formula ##STR1## wherein R is a C 1 -C 12 alkyl group or a C 2 -C 12 alkenyl group, which groups may be substituted...
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5155280 |
Process for the oxidation of alcohols to aldehydes
A process for the preparation of an aldehyde which comprises reacting the corresponding alkanol with a solubilized stable free radical nitroxide having the formula: ##STR1## wherein each of R 1 , R...
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5149884 |
Tube bundle reactor, use thereof in exothermic organic reactions, and preparation of ketones and aldehydes using same
In a tube bundle reactor for carrying out catalytic organic reactions in the gas phase, comprising reaction tubes (A) arranged between tubesheets (B), the reaction tubes have an inside diameter...
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5144090 |
Method for preparing acrolein or methacrolein
A method for preparing acrolein or methacrolein comprises subjecting propylene, secondary propanol, isobutylene or tertiary butanol to gas phase catalytic oxidation with molecular oxygen in the...
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5026922 |
Process for preparing glycol aldehyde
There is disclosed a process for preparing glycol aldehyde from ethylene glycol by use of a complex system catalyst comprising copper and other inorganic component, which comprises permitting 0.001...
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4996007 |
Process for the oxidation of alcohols to aldehydes/acids/esters
The instant invention relates to a process for the oxidation of primary alcohols to aldehydes, acids and esters, particularly to aldehydes. In this process and alcohol and oxygen are contacted and...
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4987252 |
Quenching process of reaction product gas containing methacrylic acid and treatment method of quenched liquid
In order to recover methacrolein and/or methacrylic acid by quenching a reaction product gas obtained by catalytic oxidation of isobutylene or the like, the reaction product gas is charged into a...
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4978803 |
Vapor phase oxidation process for making glyoxal
In the process for making glyoxal by catalytic oxidation of ethylene glycol in contact with catalyst comprising copper, glyoxal yield is improved and catalyst life is improved by the presence of a...
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4959494 |
Oxidation of organic compounds with pyrochlore catalysts
A method for oxidizing organic compounds by contacting organic compounds with molecular oxygen in the presence of a noble metal pyrochlore having the formula: A 2 +x B 2 -x O 7 -y wherein A is a...
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4929763 |
Alcohol conversion
Conversion of alcohol to organic compounds which comprises contacting the alcohol with a heterogeneous catalyst composition comprising at least one member selected from the group consisting of ...
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