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7285684 |
Process for separating imide compounds
A reaction mixture obtained by reacting a substrate in the presence of an imide compound having an imide unit represented by the formula (1) can be efficiently separated through crystallization...
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7282611 |
Process for the preparations of a mixture of alcohols and ketones
The present invention provides a process for the preparation of a mixture of alcohols and ketones by the liquid phase oxidation of isoalkanes to alkyl hydroperoxides with simultaneous transfer of...
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7145041 |
Method for producing saturated alcohols, ketones, aldehydes and carboxylic acids
The invention relates to a method for catalytically oxidizing unsaturated hydrocarbons to form oxidation products, and to the production of saturated alcohols, ketones, aldehydes or carboxylic...
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7087793 |
Process for producing cycloalkanol and/or cycloalkanone
The present invention provides a process for producing cycloalkanol and/or cycloalkanone by oxidizing cycloalkane with molecular oxygen in the presence of a heteropolyacid compound comprising a...
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6806390 |
Hydroperoxide decomposition catalyst
An improved catalytic process for decomposing alkyl or aromatic hydroperoxides is disclosed which utilizes a caalytic amount of a heterogeneous Au catalyst that has been treated with an...
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6703529 |
Process for oxidation of cyclohexane
Disclosed herein is a process for the production of a mixture of cyclohexanone and cyclohexanol by oxidation of cyclohexane and decomposition of cyclohexyl hydroperoxide.
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6677490 |
Method for producing alcohol/ketone mixtures
The invention relates to a method for producing a mixture of alcohols/ketones by decomposing an alkyl hydroperoxide, particularly to a method for producing a cyclohexanol/cyclohexanone by...
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6482989 |
Method for oxidizing alkanes and cycloalkanes with aldehydes in the presence of copper-based catalysts and nitrogen-containing compounds
A method for oxidizing an alkane, comprising the step of oxidizing said alkane with oxygen in the presence of an aldehyde, a copper-based catalyst and a nitrogen-containing compound. This method...
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6468487 |
Nitration or carboxylation catalysts
In the presence of an imide compound (e.g., N-hydroxyphthalimide) shown by the following formula (1): wherein R 1 and R 2 represent a hydrogen atom, a halogen atom, an alkyl group, an aryl...
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6462239 |
Oxidation catalyst and oxidation process using the same
In the presence of (1) an oxidation catalyst comprising a crystalline complex of manganese with an N,N′-disalicylidenediamine (e.g. N,N′-disalicylidene C 2-8 alkylenediamines and...
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6433229 |
Method of producing cyclic, α, β-unsaturated ketones
Preparation of cyclic, α,β-unsaturated ketones of formula II by dehydrogenation of cyclic ketones which conform to formula I in which n denotes an integer from 1 to 10, and which may be...
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6410797 |
Process for the production of ketoisophorone derivatives and equipment therefor
In the presence of an oxidizing catalyst, a β-isophorone derivative of the following formula (1) is oxidized in a solvent substantially from acid components (organic carboxylic acids) to form a...
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6346651 |
Process and apparatus for producing ketoisophorone
β-isophorone is formed by isomerizing α-isophorone in the presence of an isomerizing catalyst (an aliphatic C 5-20 polycarboxylic acid) in an isomerizing-reaction unit 1 . The β-isophorone...
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6316676 |
Process for the preparation of α-diketones from ketols or ketals from ketols
The process for the preparation of carbonyl compounds of the formula I ##STR1## where R 1 and R 2 are a hydrocarbon radical, or R 1 and R 2 together are an unsubstituted or substituted...
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6300521 |
Process for preparing oxoisophorone
The present invention relates to a process for preparing 3,5, 5-trimethylcyclohex -2-ene-1,4-dione (oxoisophorone; OIP) by oxidation of 3,5,5-trimethylcyclohex-3-en-1-one (β-isophorone, β-IP)...
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6297404 |
Process for preparing oxoisophorone using additives
The present invention relates to a process for preparing 3,5,5-trimethylcyclohex-2-ene-1,4-dione (oxoisophorone; OIP) by oxidation of 3,5,5-trimethylcyclohex-3-en-1-one (β-isophorone, β-IP) with...
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6229050 |
Process for the preparation of hydroxyadamantanone derivatives
The invented process produces a corresponding 5-hydroxy-2-adamantanone derivative by allowing a 2-adamantanone derivative of the following formula (1): ##STR1## wherein each of R a , R b , and R c ...
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6166261 |
Oxidation catalytic system and process for producing ketoisophorone using the same
In the presence of a catalytic system comprising a cyclic base and a complex of a transition metal with an N,N'-disalicylidenediamine, ketoisophorone or a derivative thereof is produced by...
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5892123 |
Process for reproducing a mixture containing cyclododecanone and cyclododecanol
A method is disclosed for catalytically decomposing cyclododecyl hydroperoxide into cyclododecanone and cyclododecanol using a chromium catalyst.
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5874632 |
Method of producing ketoisophorone
An improved method of producing 3,5,5-trimethylcyclohex-2-ene-1,4-dione (KIP) by the oxidation of 3,5,5-trimethylcyclohex-3-ene-1-one (β-IP) in the presence of managansalene-like catalysts and...
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5847226 |
Process for the preparation of nootkatone
A method for preparing nootkatone, nootkatol or mixtures thereof by oxidizing valencene, wherein the valencene is exposed to an oxygenated atmosphere in a suitable reaction medium and in the...
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5773635 |
Preparation of polyenecarbonyl compounds having a high content of the all-E isomer, and of their acetals or ketals
A process for preparing polyenecarbonyl compounds having a high all-E content and their acetals or ketals by aldol condensation or Horner-Emmons reaction comprises carrying out the reaction, for...
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5030739 |
Process for the catalytic oxidation of isoprenoids having allylic groups
The invention is directed to a process for the catalytic oxidation of an isoprenoid containing at least one allylic hydrogen atom, which process comprises reacting the isoprenoid with oxygen or an...
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4970347 |
Method of producing 2,6,6-trimethyl-2-cyclohexane-1,4-dione
A method of producing 2,6,6-trimethyl-2-cyclohexene-1,4-dione. Cu(II)acetylacetonate is used as a catalyst, with a suitable amount of pyridine, in the absence of solvents. The product may be used...
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4898985 |
Process for preparing 3,5,5-trimethylcyclohexa-2-en-1,4-dione
3,5,5-Trimethylcyclohexa-2-en-1,4-diones is prepared by oxidizing 3,5,5-trimethylcyclohexa-3-en-one with molecular oxygen or a molecular oxygen-containing gas in the presence of an organic base and...
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4873364 |
Process for the preparation of methylene diphenylene diisocyanates and polymethylene polyphenylene poly (diisocyanates)
An improved process is provided for the preparation of methylene diphenylene diisocyanates (MDI) and polymethylene polyphenylene poly (diisocyanates) by the thermal decomposition of a methylene...
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4644084 |
Preparation of tetrahydroisohumulones
Tetrahydroisohumulones are prepared from beta-acids without using objectionable organic solvents by treating the beta-acids to form desoxytetrahydrohumulones which are dissolved in an aqueous...
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4590296 |
Process for separation of beta-acids from extract containing alpha-acids and beta-acids
Beta-acids are separated from alpha-acids in a hop extract without using organic solvents by bubbling CO 2 through an aqueous hop extract having a pH of about 9.6 to about 13 to lower the pH to...
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4510321 |
Autoxidative cleavage of ketones in the presence of pulverized alkali metal hydroxide
Processes for the autoxidative cleavage of selected ketones such as C 4 -C 10 cycloalkanones having at least one hydrogen or at least one R group on a carbon alpha to the carbonyl carbon or aryl...
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4393243 |
Carotenoid intermediate by an oxidation process
A process for synthesizing 3,5,5-trimethyl-4-[(E)-3-oxo-1-butenyl]-2-cyclohexen-1-one which is a known intermediate in a process for preparing a carotenoid.
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4340763 |
Winning bitter substances from hops
The process for producing hulupones by oxidation of lupulones, using an oxygen-containing gas, in a substantially aqueous, alkaline reaction medium is improved by carrying out the reaction using...
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4267376 |
Steroid synthesis
A compound having the general formula ##STR1## wherein R 1 is a lower alkyl group, R 2 is hydrogen or a lower alkyl group and Y is a protected hydroxyl group, for example,...
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4181683 |
1,7-Octadien-3-one and process for preparing the same
1,7-Octadien-3-one of the formula: ##STR1## and a process for preparing the same by oxidizing 1,7-octadien-3-ol.
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4157352 |
Process for the manufacture of a cyclopentenedione
A process for the manufacture of 2,2,4-trimethyl-cyclopent-4-ene-1,3-dione by oxidizing 3,5,5-trimethyl-cyclohex-2-ene-1,4-dione with oxygen or an oxygen-containing gas in the present of a...
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4092361 |
Process for the preparation of 3,5,5-trimethyl-cyclohex-2-ene-1,4-dione
3,5,5-Trimethyl-cyclohex-2-ene-1,4-dione is prepared by a liquid phase oxidation of β-isophorone using carbon black as catalyst in the presence of a base.
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4060555 |
Process for the production of chlorofluorinated aliphatic ketones
Chlorofluorinated aliphatic ketones may be effectively produced by an oxychlorofluorination process by reacting a gaseous mixture of a starting material selected from an aliphatic ketone and a...
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4046813 |
Process for producing ketoisophorone
Process for producing ketoisophorone from β-isophorone by oxidation utilizing a metal salt catalyst and an organic nitrogen base.
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4026948 |
Process for the preparation of 2,2,6-trimethyl-cyclohex-5-en-1,4-dione
Process for the preparation of a diketone derivative useful as perfuming and taste-modifying agent as well as intermediate for the preparation of compounds having utility in the pharmaceutical and...
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4026947 |
Process for the oxidation of β-isophorone
A process for the oxidation of β-ethylenically unsaturated ketones, especially β-isophorone, is provided whereby the ketone is oxidized with a source of molecular oxygen in an organic liquid...
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4018827 |
Process for the preparation of cycloalkane-1,2-diones
Cycloalkanones (C 5 -12) are converted to the corresponding 1,2-cycloalkanediones by autoxidation in the presence of a base catalyst (potassium t-butoxide preferred) and a polar organic solvent.
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4013721 |
Process of catalytic oxidation of lupulones to hulupones
A method for the production of hulupones by oxidizing lupulones with oxygen in the presence of a catalyst in a polar alkaline medium. The catalysts used include noble metals, oxides of transition...
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4010205 |
Process for the preparation of a diketone derivative
Process for the preparation of a diketone derivative useful as perfuming and taste-modifying agent as well as intermediate for the preparation of compounds having utility in the pharmaceutical and...
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3962147 |
Perfume composition containing 6,10 dimethyl - spiro [4.5]decane-type compounds
Use of bicyclic compounds, some of which are new, as perfuming and/or flavoring ingredients in the manufacture of perfumes and perfumed products and/or in the preparation of artificial flavors for...
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3960966 |
Ketoisophorone manufacture
A process for the manufacture of ketoisophorone by the oxidation of α-isophorone employing oxygen gas in the presence of a catalyst.
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3944620 |
Process for the preparation of oxophorones
Process for the preparation of a diketone derivative, viz 2,2,6-trimethyl-cyclohex-5-en-1,4-dione, an organoleptically interesting ingredient for the perfumery and the flavour industry, as well as...
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3931327 |
Process for the preparation of a diketone derivative
Process for the preparation of a diketone derivative useful as perfuming and taste-modifying agent as well as intermediate for the preparation of compounds having utility in the pharmaceutical and...
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3673255 |
CATALYTIC OXIDATIVE DEHYDROGENATION OF KETONES WITH IMPROVED SUPPORTED GOLD CATALYST
An improvement is provided in a process in which ketones and mixtures of ketones and alcohols having at lest one pair of hydrogen atoms on the alpha and beta carbon atoms are oxidatively...
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3607942 |
SYNTHESIS OF 1-HYDROXY-4-KETO-α-IONONE
Air oxidation of 4-keto-α-ionone on solid surfaces to produce 4 -(1-hydroxy-4-oxo-2,6,6-trimethyl-2 -cyclohexene-1 -yl)-3-butene-2-one.
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3523125 |
LIQUID PHASE OXIDATIVE DEHYDROGENATION OF ALDEHYDES AND KETONES
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3514475 |
OXIDATION OF THE ENAMINE OF ALPHA,BETA-UNSATURATED KETONES
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