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7964743 |
Catalyst for asymmetric synthesis, ligand for use therein, and process for producing optically active compound through asymmetric synthesis reaction using them
Compounds represented by the following general formula (1a) or (1b). A complex comprising a center metal of rhodium and a compound represented by the following general formula (1a) or (1b) as a...
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7960589 |
Synthesis of sphingosines and their derivatives
Embodiments of the present disclosure provide for methods of making sphingosines and derivatives thereof, and the like.
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7700805 |
Process for preparing amines
An amine is prepared by cleaving a carbamate of the formula I wherein R1=hydrogen, alkyl, aryl or phenyl group, R2=alkyl, aryl or phenyl group, wherein R1 and R2 are independently substituted or...
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7687666 |
Methods for preparing sulfonamide substituted alcohols and intermediates thereof
Processes for preparing amino alcohols or salts thereof and sulfonamide substituted alcohol compounds are provided. Desirably, the sulfonamide substituted alcohol compounds are heterocyclic...
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7612239 |
Method for asymmetric alkynylation of alpha-imino esters
Method for the preparation of asymmetric alkynylated α-amino esters of the formula wherein R1 and R2 are independently optionally substituted alkyl cycloalkyl, aryl or heteroaryl, and Y is ...
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7538251 |
Synthesis of severely sterically hindered secondary aminoether alcohols from a ketene and/or carboxylic acid halide and/or carboxylic acid anhydride
Severely sterically hindered secondary aminoether alcohols are prepared by a process comprising reacting a ketene with sulfuric acid to produce an anhydride which is then reacted with, to cleave...
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7485756 |
Continuous process for decarboxylating carboxylic acids
A continuous process for decarboxylating carboxylic acids proceeds by I.) initially charging a carbonyl compound as a catalyst in a solvent at reaction temperature, to obtain a catalyst solution;...
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7429680 |
Synthesis of sterically hindered secondary aminoether alcohols
Severely sterically hindered secondary aminoether alcohols are prepared by reacting an organic carboxylic acid or alkali metal salt of an organic carboxylic acid with a sulfonyl halide, a sulfuryl...
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7235695 |
Cycloalkyl substituted polyamines for cancer therapy and methods of synthesis therefor
Conformationally restricted polyamine compounds useful in treatment of cancer and other diseases marked by abnormal cell proliferation are disclosed. Improved methods of synthesizing such compounds...
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6852892 |
Process for the synthesis of sphingosine
This invention relates to a method for the production of a sphingoid base according to formula comprising the steps of (1) dissolving a starting compound according to formula III or a salt thereof...
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6794542 |
Method for the preparation of enantiomerically enriched compounds
Process for the preparation of a diasteromerically enriched phenylglycine amide derivative in which an enantiomerically enriched phenylglycine amide is converted into the corresponding Schiff base...
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6534682 |
N(CF3)2 anion generation and its use
The invention relates to a process of generating N(CF3)2 anions by reacting a metal fluoride of formula MFx with a compound of formula RFSO2N(CF3)2, (CF3)2N(SO2CF2)mSO2N(CF3)2 or RFCON(CF3)2. The...
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6500985 |
Process for producing alpha-aminoketones
An amino group of an α-amino acid ester is protected as an imine, and it is then reacted with a halomethyllithium to obtain an N-protected-α-aminohalomethylketone. Further, this N...
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6417403 |
Process for preparing chiral (s)-2,3-disubstituted-1-propylamine derivatives
A process for the preparation of chiral (S)-2,3-disubstituted-1-propylamine derivatives, in which a carbonyl group of (S) 3,4-disubstituted-1-butanecarbonyl derivatives is converted to an amine...
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6417402 |
Squaraine based dyes and process for preparation thereof
The present invention relates to squaraine dye containing terminal aminoanthracene or acridine groups and to a process for preparation thereof.
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6258976 |
Process for the preparation of polyamines and polyamine derivatives
Disclosed are processes for the preparation of compounds of the formula (I): H2N--(CH2)n--A--(CH2)m--NH2, or (II): H2N--(CH2)n--NH--C(NR1)--NH--(CH2)m--NH2, wherein n and m are each i...
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6235940 |
Method for producing oxalkylated amines or alcohols
In a process for preparing alkoxylated amines or alcohols in which a reaction mixture comprising an amine or an alcohol or a mixture of two or more amines and/or alcohols and an alkylene oxide, or...
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6040464 |
Process for the preparation of protected 3-amino-1,2-dihydroxypropane acetal and derivatives thereof
A process for producing protected 3-amino-1,2-dihydroxypropane acetal, particularly in chiral forms, for use as an intermediate in the preparation of various 3-carbon compounds which are chiral. In...
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6005146 |
Stabilized non-polymeric acetoacetate esters that promote adhesion to metallic and oxidized substrates
The present invention provides improved adhesion promoters for latex paints. The adhesion promoters are enamines of acetoacetate esters, or substituted acetoacetate esters. The invention also...
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5981802 |
Simple allylic amination procedure
The subject invention provides a method of preparing an allylic amine having the structure: ##STR1## wherein R1, R2, R3, R4 and R5 are each independently hydrogen, halogen, cyano, nitro, linear or...
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5925792 |
Process for preparing 2-amino-1,3-alkanediol or derivative thereof, process for preparing optically active dihydrosphingosine derivative, and intermediates for optically active dihydrosphingosine derivative
A process for preparing an optically active dihydrosphingosine derivative is disclosed, comprising reducing a (2R,3R)-2-amino-3-hydroxyalkanoic acid derivative represented by formula (III):...
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5874520 |
Preparation of nylon salts from diamine carbamates and dicarboxylic acids
Substantially anhydrous nylon salts are made in a solid state process in which solid diamine carbamates are contacted and mixed with solid dicarboxylic acids in a near instantaneous reaction to...
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5874623 |
Process for the production of polyether aminoalcohols
Disclosed herein is a method of preparing polyether aminoalcohol by reacting a primary aminoalcohol with a polyether terminated with a good leaving group.
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5801278 |
Low water diamine-dicarboxylic acid salt preparation
The invention provides a process for directly manufacturing a diamine/dicarboxylic acid salt with a low water content. The process includes reacting a diamine with a dicarboxylic acid to form a...
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5763737 |
S-(2-disopropylamino) ethyl methylphonothioate ION with hydrogen peroxide
A method for the reduction of toxicity of S-(2-diisopropylamino)ethyl methylphosphonothioate ions in a medium or mixture by reaction with hydrogen peroxide and a strong inorganic acid.
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5728884 |
Process for the work-up of complex amine hydrofluroides
The invention relates to a process for the work-up of a liquid complex hydrofluoride of a tertiary amine of the formula (I) R1 R2 R3 Nn HF!, where the radicals R1, R2 and R3 are C1 -C8 -alkyl g...
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5672753 |
Method of producing racemic amino alcohols
α-oximino carboxylic acids or their esters are reduced with an alkali boron hydride and hydrogen chloride or sulfuric acid to yield racemic amino alcohols (e.g. (RS)-tert-leucinol).
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5654467 |
Process for the production of C-substituted diethylenetriamines
The invention relates to a process for the production of C-substituted diethylenetriamines of general formula ##STR1## in which R1, R2, R3 and R4 have different meanings.
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5648544 |
Process for the preparation of 2-aminoalkane-1,3-diols
A process for the preparation of 2-aminoalkane-1,3-diols by a single step reduction of alkyl 2-oximino-3-oxoalkanoates. The reduction is carried out in the presence of at least one hydride, in a...
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5639895 |
Process for producing β-nitroenamine
Disclosed is a process for producing β-nitroenamine represented by the formula I: ##STR1## wherein R1 and R2 are the same or different and independently indicate a hydrogen atom or a C1 -C10 alkyl ...
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5563288 |
Process for the preparation of tertiary aminocarbonates and aminoethers
The invention relates to processes for producing di-(tertiary aminoalkyl) carbonate including the step of reacting a tertiary alkanolamine with methyl alkyl carbonate in the presence of a...
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5536888 |
Process for producing diol compounds
A diol compound, for example, hexanediol, is produced with a high efficiency by esterifying a carboxylic acid mixture, collected from a reaction product mixture of a liquid phase oxidation of...
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5527949 |
Method for making an amine and an alkyl ester and method for reducing hydrogen cyanide levels in alkyl ester
A method for making an amine includes the steps of heating a reaction mixture including a nitrile, an acid, water and a substrate compound capable of generating a carbonium ion by reaction with the...
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5442121 |
Process for producing N,N-disubstituted aminophenol
A process for producing N,N-disubstituted aminophenol which comprises the steps of:obtaining a reaction mixture containing N-substituted aminophenol by reacting a dihydric phenol and an...
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5399763 |
Process for preparing optically active 2-aminopropanal
A process for preparing an optically active 2-aminopropanal through oxidative cleavage of the corresponding optically active 3-amino-1,2-butanediol of the following formula (2): ##STR1## wherein R1...
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5331100 |
Self-building detergents
Self-building laundry detergents are organic polyamine amides, which contain a plurality of carboxylate radicals and an amide ester. These compounds are useful individually as detergents or as...
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5326911 |
Process for the preparation of ortho-amides
Ortho-amides of the formula ##STR1## can be prepared by reacting salts of the formula ##STR2## with alcoholates of the formula M1 OR1 (III)where the radicals R1 to R4, M1 and X.crclbar. have the...
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5283364 |
Hydrolysis process for polyamines
Polyamines containing primary amino groups are made by hydrolyzing an isocyanate with water in the presence of a solvent which is a carboxylic acid amide. The solvent must be used in a quantity of...
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5231217 |
Process for the preparation of amine-terminated compounds
The present invention is directed to a novel solvent-free process for preparing amine terminated compounds by reacting a polyfunctional acetoacetic acid ester with either ammonia or an organic...
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5220069 |
Processes for the preparation of carbamates
A process for preparing nitrogen-containing compounds which comprises contacting a carboxylated N-monosubstituted nitrogen-containing compound or a carboxylated N,N-disubstituted...
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5208379 |
Hydrolysis of polyurethanes
Waste or scrap polyurethane may be conveniently and economically converted to useful active-hydrogen containing polyethers and polyamines by contacting the polyurethane with water, strong base, and...
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5164497 |
Decarboxylation processes using mixed metal oxide catalysts
A decarboxylation process which comprises contacting a carboxylated compound with a metal oxide catalyst under conditions effective to decarboxylate the carboxylated compound.
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5149861 |
Recovery of trialkylamines and methyl formate from mixtures obtained in the preparation of trimethylolalkanes
Trialkylamines and methyl formate are recovered from reaction mixtures obtained in the preparation of trimethylolalkanes by reaction of n-alkanals with from 2.2 to 4.5 moles of formaldehyde in...
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5128471 |
Process for the production of organic amines, polyamine mixtures and their use as hardeners for polymer precursors
The present invention relates to a process for the production of primary amines containing aliphatically or cycloaliphatically bound amino groups, characterized in that the isocyanate groups of...
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5066824 |
Novel process for the preparation of amine-terminated compounds
The present invention is directed to a process for preparing amine terminated compounds by reacting a polyfunctional acetoacetic acid ester with either ammonia or an organic compound which contains...
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4985556 |
Perfluoro(dialkylaminopropene) derivatives
Perfluorocarboxylic acid fluorides represented by the formula A-B, wherein A is either ##STR1## and B stands for a perfluoro-di-substituted amino group, and perfluoro(dialkylaminopropenes)...
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4935546 |
Process for the production of long chain alkylamines and dimethylalkylamines and catalysts therefor catalysts therefor
A process for the production of a primary alkylamine or a dimethylalkylamine in a single stage comprising heating a reaction medium comprising a long chain carboxylic acid ester with ammonia and...
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4931595 |
Catalytic hydrolysis process for polyamines
Polyamines containing primary amino groups are prepared in a single stage process by hydrolyzing an isocyanate in the presence of a catalyst incorporable through an NCO reactive group and a...
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4912216 |
Method for production of perfluoro-(N-vinylamine) compounds
A perfluoro-(N-vinylamine) compound containing a >NCFCF2 group is produced from a perfluoro-compound containing a group of the general formula: ##STR1## (wherein X stands for a fluorine atom or a...
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RE32677 |
Polyamines, a process for the production of polyamines and their use in the production of polyurethanes
The invention relates to a simplified, economic process for the production of polyamines by the alkaline hydrolysis of compounds containing terminal aromatic and/or aliphatic isocyanate groups...
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