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7247724 |
Method for the production of phenylalanine derivatives
The invention relates to an improved method for the production of 3-amidinophenylalanine derivatives, especially triisopropylphenyl-sulfonyl-substituted 3-amidinophenylalanine derivatives.
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7183425 |
Diastereoselective reductive amination process
This invention describes a reductive amination process whereby perfluorinated ketones or ketals are combined with α-aminoesters under basic conditions to form metal carboxylates....
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7141263 |
Process for producing cinnamaldehyde derivatives, use thereof and the like
A process for conveniently and efficiently producing a highly pure cinnamaldehyde derivative, for example, (2E)-(3-hydroxy-4-methoxy)cinnamaldehyde, which comprises reacting a benzaldehyde...
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7115296 |
N-alkylaspartyl amide derivative and sweetening agent
The present invention relates to a novel N-alkylaspartyl amide derivative, a salt form thereof, a sweetening agent containing the same and a sweetened food or drink containing the N-alkylaspartyl...
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7057038 |
Kinetic resolutions of chiral 2- and 3-substituted carboxylic acids
One aspect of the present invention relates to a method for the kinetic resolution of racemic and diastereomeric mixtures of chiral compounds. The critical elements of the method are: a non-racemic...
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RE39088 |
Amide compounds and use of the same
An amide compound of the formula (I):
wherein R is amino and the like, A is alkylene and the like, X is O, S and the like, M is arylene and the like, R 1 , R 2 , R 3 and R 4 are H,...
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7026003 |
Processes for preparing an aspartame slurry
The present invention provides processes for preparing a slurry containing aspartame, which is stable and is useful as a sweetener; as well as methods of assessing the stability of an aspartame...
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6989461 |
Catalyst for asymmetric (transfer) hydrogenation
Catalyst for the asymmetric (transfer) hydrogenation represented by the formula ML a X b S c , where M is a transition metal, to be chosen from rhodium and ruthenium, and X is a counter ion and S...
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6939987 |
Method for producing Aspartame derivative, method for purifying the same, crystals thereof and uses of the same
N-[N-[3-(3-methoxy-4-hydroxyphenyl)propyl]-L-α-aspartyl]-L-
phenylalanine 1-methyl ester is prepared by a process comprising:
subjecting Aspartame and...
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6930200 |
Multicomponent synthesis of amino acids and derivatives thereof
Mono-substituted and di-substituted alpha-amino acids and derivatives thereof, substituted at the alpha positon with one (mono-) or two (di-) substituents (R 2 and/or R 3 ) as shown in Formula 1:...
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6919380 |
Derivatives of C2-substituted indan-1-ol systems for the prophylaxis or treatment of obesity
Derivatives of C2-substituted indan-1-ol compounds of formula I:
its physiologically acceptable salts, and its physiologically functional derivatives for the prophylaxis or treatment of...
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6914151 |
Crystallization processes for the formation of stable crystals of aspartame derivative
A crystallization process for forming a stable crystal of N-(3,3-dimethylbutyl)-APM, which comprises using either water or a mixture of water with a lower alcohol as the crystallizing solvent and...
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6855843 |
Inhibitors of α4 mediated cell adhesion
The present invention relates to a pharmaceutical composition comprising as an active ingredient a compound of formula (I), wherein Ring A is an aromatic or a heterocyclic ring; Q is a bond,...
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6844465 |
Method for preparing highly stable crystals of aspartame derivative
Disclosed in the present application are a method for preparing highly-stable A-type crystals by controlling and maintaining the product temperature of B-type N-(3,3-dimethylbutyl)-APM crystals at...
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6841183 |
Process for producing aspartame derivatives, process for purifying aspartame derivatives, production intermediates, and process for producing production intermediates
N-[N-[3-(2-hydroxy-substituted phenyl)propyl]-L-α-aspartyl]-L-phenylalanine 1-methyl ester derivatives, which are useful as sweeteners, may be conveniently produced by subjecting a...
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6822111 |
Process for production of aspartyl dipeptide ester derivatives
N-[N-[3-(phenyl having various substituent group(s) on the benzene ring)propyl]-L-α-aspartyl]-L-phenylalanine 1-methyl ester derivatives, which are useful as sweeteners, may be conveniently...
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6818243 |
Crystals of aspartame derivative
N-[N-[3-(3-hydroxy-4-methoxyphenyl)propyl]-L-α-aspartyl]-L-
phenylalanine 1-methyl ester useful as a sweetener with a high potency of sweetness, is provided in the crystalline form having a high...
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6794531 |
Process for production of aspartyl dipeptide ester derivative, novel production intermediate therefor, and process for production thereof
The present invention relates to a method of manufacturing aspartyl dipeptide ester compounds, which can be used as sweeteners, and aldehydes that can be used in the manufacturing processes.
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6790470 |
Aspartame derivative crystal and process for producing the same
For example, N-[N-(3,3-dimethylbutyl)-L-α-aspartyl]-L-phenylalanine methyl ester (A-type crystal) showing characteristic peaks in diffractive X-ray at diffraction angles (2θ, CuKα ray) of at...
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6784309 |
Method for the purification of N-&lsqb N-(3,3-dimethylbutyl)-L-α-aspartyl&rsqb -L-phenylalanine 1-methyl ester
This invention relates to the purification of N-[N-(3,3-dimethylbutyl)-L-α-aspartyl]-L-phenylalanine 1-methyl ester by slurrying a mixture containing...
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6720446 |
Catalyst modification to enhance neotame production
Processes for using modified catalysts with improved functionality in the production of neotame are disclosed. The modified catalysts surprisingly have been found to improve the selectivity over...
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6689902 |
Arylpropyl aldehyde derivatives, processes for producing the same, and methods of using the same
3-(3-Methyl-4-hydroxyphenyl)-3-methylbutyl aldehyde may be produced from 3-(3-methyl-4-hydroxyphenyl)-3-methylbutyric acid by converting the carboxyl group into a formyl group....
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6657073 |
Crystallization of α-L-aspartyl-L-phenylalanine methyl ester
The present invention provides a novel process for the crystallization of α-L-aspartyl-L-phenylalanine methyl ester crystals wherein initial nucleation and initial crystal growth is conducted in a...
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6642406 |
Synthesis of N-&lsqb N-(3,3-dimethylbutyl)-L-α-aspartyl&rsqb -L-phenylalanine 1-methyl ester using L-α-aspartyl-L-phenylalanine 1-methyl ester precursors
N-[N-(3,3-dimethylbutyl)-L-α-aspartyl]-L-phenylalanine 1-methyl ester is produced by hydrogenation of a mixture of 3,3-dimethylbutyraldehyde and a precursor of L-α-aspartyl-L-phenylalanine...
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6627431 |
Chemoenzymatic synthesis of neotame
A chemoenzymatic method is disclosed for preparing N-[N-(3,3-dimethylbutyl)-L-α-aspartyl]-L-phenylalanine 1-methyl ester via the enzymatic regioselective hydrolysis of neotame esters using lipases...
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6613933 |
Process for separating and purifying aspartame and a derivative thereof
A process for easily and efficiently separating aspartame (APM) from N-[N-(3,3-dimethylbutyl)-L-(α-aspartyl]-L-phenylalanine methyl ester (APM derivative), and thus separating and purifying the...
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6562782 |
Oligocycloalkanoid compounds and methods of use
The present invention related to an oligocycloalkanoid compound comprising formula (I) wherein m, n, and o are independently an integer from 0 to 2; A 1 through A 10 are independently a direct...
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6552061 |
Amino acid derivatives and anti-inflammatory agents
Provided are an anti-inflammatory agent containing, as an active ingredient, at least one selected from amino acid derivatives represented by formula (I) wherein Ar represents an optionally...
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6506434 |
Process for coating N-&lsqb N-(3,3-dimethylbutyl)-L-α-aspartyl&rsqb -L-phenylalanine 1-methyl ester onto a carrier
The present invention relates to a process for coating N-[N-(3,3-dimethylbutyl)-L-α-aspartyl]-L-phenylalanine 1-methyl ester onto a carrier. The invention also relates to...
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6495597 |
Cytostatic agents
Compounds of formula (I) wherein R 4 is an ester or thioester group and R, R 1 , R 2 and R 3 are as defined in the specification, inhibit proliferation of tumor cells.
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6465677 |
Method for the preparation of N-neohexyl-α-aspartyl-L-phenylalanine methyl ester from imidazolidin-4-one intermediates
The synthesis of N-[N-(3,3-dimethylbutyl)-L-α-aspartyl]-L-phenylalanine 1-methyl ester via conversion under reducing conditions of novel imidazolidinone(s) is disclosed.
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6444251 |
Sweetener compositions containing aspartame and aspartame derivative
A homogeneous sweetener composition containing aspartame (APM) and N-[N-(3,3-dimethylbutyl)-L-α-aspartyl]-L-phenylalanine methyl ester having tasting properties similar to sucrose, can be...
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6423864 |
Purification of N-&lsqb N-(3,3-dimethylbutyl)-L-α-aspartyl&rsqb -L-phenylalanine 1-methyl ester via crystallization
N-[N-(3,3-dimethylbutyl)-L-α-aspartyl]-L-phenylalanine 1-methyl ester is crystallized in order to give highly pure product in high yield. In a preferred embodiment of the present invention,...
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RE37795 |
Synthesis of tyrosine-derived diphenol monomers
A method for preparing diphenol compounds, which method includes the steps of coupling a hydroxyphenyl carboxylic acid with a L-tyrosine ester in a water-miscible organic reaction solvent...
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6417368 |
Amine derivative fixed to resin and method for synthesizing β-aminocarbonyl compound in a solid phase
The invention provides a resin-immobilized imine represented by the following formula: P—Q—N—═CH—R I [in the formula, P represents the principal chain of a resin polymer; Q represents...
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6368651 |
Use of additives to modify the taste characteristics of N-neohexyl-α-aspartyl-L-phenylalanine methyl ester
This invention relates to the use of at least one taste modifying ingredient to modify at least one taste characteristic imparted by N-[N-(3,3-dimethylbutyl)-L-α-aspartyl]-L-phenylalanine 1-methyl...
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6365217 |
N-&lsqb N-(3,3-dimethylbutyl)-L-α-aspartyl&rsqb -L-phenylalanine 1-methyl ester agglomerate
This invention provides a process for preparing an agglomerate of N-[N-(3,3-dimethylbutyl)-L-α-aspartyl]-L-phenylalanine 1-methyl ester and a carrier including the steps of: (a) providing a premix...
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6365216 |
Particles of N-&lsqb N-(3,3-dimethylbutyl)-L-α-aspartyl&rsqb -L-phenylalanine 1-methyl ester
N-[N-(3,3-dimethylbutyl)-L-α-aspartyl]-L-phenylalanine 1-methyl ester is converted from a light powder to relatively dustless, free-flowing particles with and without the use of binders using...
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6346642 |
Mixed crystals comprising aspartame and aspartame derivative and process for producing the same
There is provided a novel mixed crystal comprising aspartame (APM) and N-[N-(3,3-dimethylbutyl)-L-α-aspartyl]-L-phenylalanine methyl ester, which can be used as a sweetener having considerably...
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6335461 |
Process for purification of aspartame derivative
In the separation and purification of N-[N-(3,3-dimethylbutyl)-L-α-aspartyl]-L-phenylalanine methyl ester produced in the reductive alkylation of aspartame (APM) with 3,3-dimethylbutylaldehyde,...
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6333427 |
Process for preparing N-t-butoxycarbonylphenylalanine ester
A purified N-t-butoxycarbonylphenylalanine ester preparation having an enhanced optical activity can be obtained by bringing an N-t-butoxycarbonylphenylalanine ester preparation containing an...
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6331646 |
Amorphous N-[N-(3,3-dimethylbutyl)-L-α-aspartyl]-L-phenylalanine 1-methyl ester
A novel amorphous N-[N-(3,3-dimethylbutyl)-L-α-aspartyl]-L-phenylalanine 1-methyl ester compound is disclosed. Also disclosed are processes for preparing the compound. The novel compound has...
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6316657 |
Process for purification or recovery of sweetener
There is provided a process for purification of N-(3,3-dimethylbutyl)-α-L-aspartyl-L-phenylalanine methyl ester comprising the step of contacting impure...
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6316656 |
Process for making optically active alpha-amino ketones and selected novel optically active alpha-amino ketones
The invention includes selected novel optically active α-ketones which either are themselves useful or are intermediates for the preparation of known ketomethylene pseudopeptides useful as...
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6294686 |
Aspartame crystals and process for the preparation thereof
The invention provides a method of preparing new crystal forms of aspartame utilizing microemulsions comprising: (a) introducing aspartame into a microemulsion formed from an oil phase, an aqueous...
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6291004 |
Basic salts of n-[n-(3,3-dimethylbutyl)-l-α-aspartyl]-l-phenylalanine 1-methyl ester
Dipeptide sweeteners are disclosed that are basic salts of N-[N-(3,3-dimethylbutyl)-L-α-aspartyl]-L-phenylalanine 1-methyl ester represented by the formula ##STR1## wherein X m + is selected from...
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6284915 |
Process for preparing 2-amino malonic acid derivatives and 2-amino-1,3-propanediol derivatives, and intermediates for preparing the same
A process for preparing 2-amino malonic acid derivatives of formula (1): ##STR1## wherein A is linear or branched chain alkylene having from 1 to 10 carbon atoms, R 1 is linear or branched chain...
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6281380 |
Synthesis of N-(N-(3,3-dimethylbutyl)-L-α-aspartyl)L-phenylalanine1-methyl ester by reductive alkylation and crystallization/ isolation in aqueous methanol
N-[N-(3,3-dimethylbutyl)-L-α-aspartyl]-L-phenylalanine 1-methyl ester is produced by reductive alkylation and crystallization/isolation in methanol and water. The production method is efficient...
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6235929 |
Tripeptide α-ketoamides
A novel class of tripeptide α-ketoamides useful for selectively inhibiting serine proteases, selectively inhibiting cysteine proteases, generally inhibiting all serine proteases, and generally...
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6225493 |
Metal ion assisted N-[N-(3,3-dimethylbutyl)-L-α-aspartyl]-L-phenylalanine 1-methyl ester isomer resolution
This invention relates to the purification of N-[N-(3,3-dimethylbutyl)-L-α-aspartyl]-L-phenylalanine 1-methyl ester by resolving a mixture of the alpha- and beta-isomers of...
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