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4507317 |
Acaricidal 2,2'-bridged[1,1'-biphenyl]-3-ylmethyl esters
2,2'-Bridged[1,1'-biphenyl]-3-ylmethyl carboxylates and insecticidal compositions containing these esters are useful for the control of a broad range of insects and acarids. Certain...
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4506091 |
Removal of catalyst residues from polyesters
A process for preparing esters which comprises reacting a polycarboxylic acid with an excess of alcohol and in the presence of an organotitanate catalyst, treating the crude mixture with a suitable...
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4500733 |
Process for preparing dihalovinylcyclopropanecarboxylic acids
A cyclopropanecarboxylic acid of the formula ##STR1## is prepared by the reaction of a compound of the formula ##STR2## with an alkali metal hydroxide or alkaline earth metal hydroxide in an ether...
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4496586 |
Cyclopropanecarboxylates, their production and insecticide containing them as an active ingredient
The present invention relates to carboxylic acid esters of the formula (I), ##STR1## wherein R 1 is a hydrogen atom or a methyl group, and when R 1 is a hydrogen atom, R 2 is a group of the...
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4496584 |
Amidine derivatives with anti-complement activity
Amidino compounds represented by the formula ##STR1## and pharmaceutically acceptable acid addition salts thereof are novel compounds and are useful as powerful antitrypsin, antiplasmin,...
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4496389 |
Amide derivatives of N-trifluoroacetyl-N-phosphonomethylglycine, herbicidal compositions and use
This disclosure relates to alkyl N-trifluoroacetyl-N-phosphonomethylglycine amide and hydrazide derivatives, to herbicidal compositions containing same and to the herbicidal use thereof. These...
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4493844 |
Insecticidal 2,2'-bridged(1,1'-biphenyl)-3-ylmethyl carboxamides
2,2'-Bridged[1,1'-biphenyl]-3-ylmethyl carboxamides and insecticidal compositions containing these carboxamides are useful for the control of a broad range of insects and acarids.
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4492800 |
Process for the preparation of 1,1-dichloro-alkenes
A process for the preparation of a 1,1-dichloro-alkene of the formula ##STR1## in which R 1 is hydrogen, or an optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, aralkyl, aralkenyl or...
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4490552 |
Preparation of aryl esters by decomposing an aryl thallium carboxylate
A novel process for the preparation of aryl esters of organic carboxylic acids in high isomer purity by decomposing a compound of the formula ##STR1## wherein Ar is an aryl radical, X is an acyloxy...
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4489093 |
Insecticidal esters
Novel esters in all possible isomeric forms of the formula ##STR1## wherein R is selected from the group consisting of (a) optionally unsaturated alkyl of 1 to 8 carbon atoms and optionally...
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4487956 |
Menthyl 2,2-dimethylcyclopropanecarboxylate and resolution of the same
An ester obtained from 2,2-dimethylcyclopropanecarboxylic acid and optically active menthol, represented by the formula, ##STR1## is effectively resolved into diastereomers, which upon...
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4487955 |
Process for preparing cis or trans, optically active monoalkyl esters of cyclopropane-1,3-dicarboxylic acids
A novel process for the preparation of esters of 2,2-dimethyl-cyclopropane-1,3-dicarboxylic acids in their optically active forms having a cis or trans configuration I comprising salifying the ...
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4482570 |
Pyrethroids
Pyrethroid type insecticides described having the formula: ##STR1## wherein A=CF 3 -CC-, ##STR2## (X=H, F, Cl, Br: Y=Cl, Br) ##STR3## (group ##STR4## is bound to the hererocyclic ring in...
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4479898 |
Oligopeptide prodrugs
Prodrugs are described whose structures have a oligopeptide chain which is substituted by a nucleophilic chemotherapeutic residue at the α-position. The products have increased cell membrane...
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4474980 |
Process for the preparation of intermediates for pyrethroids
There is described a process for the preparation of 2,2-dimethyl-cyclopropanecarboxylates carrying in position 3 a halosubstituted dienic substituent. Said compounds are intermediates for the...
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4474977 |
Amino-alcohol derivatives
The new amino-alcohol derivatives according to the invention have the formula: ##STR1## wherein: (a) R 1 is hydrogen, an alkylthio C 1 -C 5 radical, a cycloalkylthio C 5 -C 6 radical, an...
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4473703 |
Method of epimerization of alkyl chrysanthemate
A process for isomerization of cis-chrysanthemate esters by contacting a chrysanthemate ester containing a cis-chrysanthemate ester with a Lewis acid, to transform the cis-chrysanthemate ester into...
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4472313 |
Cyclopropanation of olefins
The invention provides a method of converting ethylenically unsaturated units of an olefinic substrate to corresponding cyclopropanyl units, comprising treating the olefinic substrate, in an ether...
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4468521 |
Method of producing gamma-halogeno-delta unsaturated carboxylic acid esters
Novel γ-lactone derivatives are provided. These lactone derivatives, when reacted with hydrogen halide in alcohol, yield γ-halogeno-δ-unsaturated carboxylic acid esters. This ring-opening...
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4463014 |
Cyclopropane carboxylates
Esters in their stereoisomeric form or mixtures thereof of the formula ##STR1## wherein R 1 and R are different and individually selected from the group consisting of hydrogen, fluorine and...
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4459308 |
Pyrethroids
There are described 2,2-dimethyl-cyclopropanecarboxylates having in position 3 of the cyclopropane ring, a polyhalogenated chain having from 3 to 6 carbon atoms. Said compounds are insecticide and...
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4459305 |
Cyclopropanecarboxylic acid ester derivatives, a method of manufacturing them, and their uses
The present invention relates to a cyclopropanecarboxylic acid ester derivative of the general formula I: ##STR1## in which R 1 stands for a hydrogen atom, a methyl group, a halogen atom or a...
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4458090 |
Method of producing cyclopropanecarboxylic acids and esters
Novel γ-lactone derivatives are provided. These lactone derivatives, when reacted with hydrogen halide in alcohol, yield γ-halogeno-δ-unsaturated carboxylic acid esters. This ring-opening...
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4457940 |
Carboxylic acid ester derivatives, process for manufacturing said derivatives, insecticides and acaricides containing said derivatives, and method for killing insects and acarina by treating therewith
Novel carboxylic acid ester derivatives, of the formula (I): ##STR1## process for manufacturing said derivatives, insecticides and acaricides containing said derivatives, and a method for killing...
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4454343 |
Intermediates in a process for preparing dihalovinylcyclopropanecarboxylates
Novel syntheses of dihalovinylcyclopropanecarboxylates, including potent insecticides, are described. The processes begin with the reaction between an alkenol and an orthoester to produce a...
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4447637 |
Epimerization of trans chrysanthemates
A novel process for the epimerization of alkyl trans chrysanthemates comprising reacting at a low temperature in an anhydrous organic solvent an alkyl trans chrysanthemate of the formula ##STR1##...
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4442301 |
Process for stereoselectively synthesizing cyclopropane carboxylates
A process for stereospecifically synthesizing lower alkyl esters of the cis-2,2-dimethyl-3-(β-fluoro-β-trifluoromethyl-vinyl)-cycl
opropa necarboxylic acid.
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4439446 |
Fluorine-containing oxyiminocyclopropanecarboxylates
Compounds of the formula ##STR1## wherein R 1 is a hydrogen atom; or a hydrocarbyl group; m and n each is 0 or 1 and m+n is 1 or 2; and D is a hydrogen atom; a cyano group; or an ethynyl group,...
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4431835 |
Hydrocarbonylation/carbonylation of alkyl carboxylates
Alkyl carboxylates are hydrocarbonylated and/or carbonylated with carbon monoxide and hydrogen, in an aqueous medium, and in the presence of a catalytically effective amount of a catalyst system...
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4431668 |
Cyclopropane carboxylic acid ester derivatives
Cyclopropane carboxylic acid ester derivatives and optical and geometrical isomers thereof expressed by the general formula: ##STR1## wherein R 1 represents hydrogen atom or methyl group, R 2 ...
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4431576 |
Perfumant cyclopropane-carboxylic acid derivatives
A compound in all its possible isomeric forms and mixtures thereof of the formula ##STR1## wherein R is selected from the group consisting of (a) alkyl of 1 to 12 carbon atoms optionally...
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4429149 |
4-Phenyl-2-indanyl esters of 1R,cis-3-(2-halo-3,3,3-trifluoropropenyl)-2,2-dimethylcyclopropanecarbox ylic acid
Insecticidal 4-phenyl-2-indanyl 1R,cis-3-(2-halo-3,3,3-trifluoro-1-propenyl)-2,2-dimethylcyc
lopropanecarbo xylates having a racemic or optically active indanyl moiety, methods of preparation and...
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4425362 |
3-Aminopropoxyphenyl derivatives and pharmaceutical compositions containing them
The compounds of formula I, ##STR1## wherein the substituents have various significances, and physiologically acceptable hydrolyzable derivatives thereof having the hydroxy group in the 2 position...
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4425360 |
Pharmacologically active novel O-substituted pyruvic acid oximes
The present invention provides pyruvic acid oximes of the general formula: ##STR1## wherein R is a hydrogen atom, a C 3 -C 8 cycloalkyl, C 1 -C 6 alkoxy, cinnamyloxy, phenylamino,...
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4424166 |
Preparation of 1,1-dihalogeno-alkenes
In the preparation of a 1,1-dihalogenoalkene of the formula ##STR1## in which R 1 is a hydrogen atom or an optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, aralkyl, aralkenyl or aryl...
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4421693 |
Aminosulfenyl chloride derivatives
An aminosulfenyl chloride derivative represented by the formula (I): ##STR1## wherein R 1 and R 2 are defined in the specification, which is useful as an intermediate for the preparation of a...
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4415748 |
Intermediates for insecticidal synthetic pyrethroids
Intermediates and Process For Insecticidal Synthetic Pyrethroids Compounds of the formulas ##STR1## and their use in a process for preparing a pyrethroid insecticide of the formula ##STR2## wherein...
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4414410 |
Process for preparing alkyl esters by homologation of the next lower alkyl ester
Alkyl esters, such as ethyl acetate, are prepared by contacting the corresponding next lower carbon number alkyl ester, such as methyl acetate, with carbon monoxide and hydrogen in the presence of...
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4410721 |
Process for the preparation of cyclopropene intermediates
A novel cyclopropene-carboxylate of the formula ##STR1## wherein R is alkyl of 1 to 6 carbon atoms and their preparation and a process using the compounds of formula I to obtain cis compounds of...
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4408066 |
Methyl cyclopropane-1,3-dicarboxylate
Novel methyl esters of cis or trans configuration in their optically active form of the formual ##STR1## which are useful as intermediates for the preparation of pesticidal compounds and a process...
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4405640 |
Substituted fluorobenzyl cyclopropane carboxylates useful as insecticides
Insecticides of the formula ##STR1## wherein R 1 and R 2 are each selected from methyl, halomethyl, and halo; X is oxygen, sulphur, sulphonyl or a group NR 4 where R 4 represents hydrogen,...
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4401673 |
Pesticidal 3-(buta-1',3'-dienyl)-cyclopropane-1-carboxylic acid esters
Novel 3-(buta-1',3'-dienyl)-cyclopropane-1-carboxylic acid compounds of the formula ##STR1## wherein X 1 and X 2 are individually a halogen and A is selected from the group consisting of (A)...
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4401601 |
Novel process for the preparation of tetra-substituted cyclopropane compounds
A process for the preparation of tetrasubstituted cyclopropane compounds of the formula ##STR1## wherein Y is selected from the group consisting of --CN and --COOR, R is selected from the group...
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4397851 |
2,3-Dihalo-2,3-(disubstituted) propanoate antimicrobial compounds
Antimicrobial compounds of the formula: ##STR1## wherein Hal is bromine or chlorine; R is C 1 -4 alkyl, straight or branched chain; and one of R 1 and R 2 is hydrogen and the other is selected...
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4395567 |
1R,Cis-3-(2-halo-3,3,3-trifluoro-1-propenyl)-2,2-di methylcyclopropanecarboxylic acid derivatives
1R,cis-trifluoromethylethenylcyclopropanecarbonyl compounds of the formula ##STR1## in which X is halogen and R is halogen, hydroxy, lower alkoxy or an optionally substituted...
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4391983 |
Carboxamidoesters
Esters of formula: ##STR1## wherein R is either (a) or a group of formula: ##STR2## where X is methyl, chlorine or bromine, or (b) a group of formula: ##STR3## where Y is methyl or chlorine and n...
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4391823 |
Novel polycyclic insecticidal esters
Dimethyl dichlorovinylcyclopropyl carboxylic acid esters of substituted (alkyl, aryl, halo, amino, etc.) polycyclic alcohols are insecticidal.
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T103205 |
Intermediates and process for insecticidal 4-phenyl-2-indanyl esters
Compounds of formulae II, III and IV: ##STR1## are useful intermediates for preparation of an insecticidal compound of formula (I): ##STR2## The intermediate II is prepared by reacting the acid...
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4390719 |
1-Methyl-2-chlorocyclopropanecarboxylic acid and its ester
1-Methyl-2-chlorocyclopropanecarboxylic acid and its lower esters are produced by the selective hydrogenating dechlorination of the corresponding 1-methyl-2,2-dichlorocyclopropane compounds. The...
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4389412 |
Substituted cyclopropanecarboxylic acid esters and pesticidal compositions containing the same as active ingredient
A new pyrethroid compound which is low in toxicity to fish and a pesticidal composition containing the same as an active ingredient are provided. The above pyrethroid compound is a substituted...
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