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4963583 |
Beta-ionone derivatives as antifungal agents
Novel 3-acyloxy-4-keto-β-ionone derivatives of the formula I ##STR1## wherein Z is either the radical ##STR2## in which R 1 represents C 2 -C 5 alkyl, C 1 -C 5 alkoxy-C 1 -C 5 alkyl having...
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4962233 |
Process for preparing racemic dihalovinylcyclopropane carboxylic acid halides
Racemic dihalovinylcyclopropane carboxylic acid halides, which are intermediates of such insecticides as permethrin, cypermethrin etc., are prepared by allowing phosphorus iodides, silicon iodides...
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4948914 |
Process for preparing trans-2,2-dimethyl-3-(2,2-dihalovinyl)cyclopropane carboxylic acid esters
Trans-2,2-dimethyl-3-(2,2-dihalovinyl)-cyclopropane carboxylic acid esters which are intermediate of insecticides are prepared by allowing (1) alkali metal alkoxides and titanium alkoxides or (2)...
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4936906 |
Agents for regulating plant growth
Agents for regulating plant growth containing an effective amount of at least one cyclohexanone derivative of the formula I ##STR1## where A, X, n, Y, Z and R have the meanings given in the...
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4935434 |
Antiarthritic isoxazole-4-carboxamides
Disclosed herein are isoxazole-4-carboxamides having the formula ##STR1## wherein R 1 is C 3 -6 cycloalkyl and R 2 is selected from the group consisting of C 1 -5 alkyl, C 2 -5 alkenyl, C 2 -5...
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4929751 |
Vinyl tricarbonyl compounds and methods of making the same
A vinyl tricarbonyl compound of the formula ##STR1## or its monohydrate of the formula ##STR2## wherein R 1 is a hydrogen, halogen, unsubstituted or substituted C 1 to C 30 alkyl, unsubstituted...
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4927964 |
Method for production of 2-oxyimino-3-oxobutyric acids
An advantageous method of producing in large amounts on a commercial scale 2-substituted oxyimino-3-oxobutyric acids, which are useful as intermediates in the synthesis of e.g. aminothiazole...
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4927852 |
Insecticidal compounds characterized by enhanced knockdown effect
The invention provides insecticidal compositions exhibiting excellent knockdown activity against public health pests, in particular cockroach species, comprising compounds of formula (I): ##STR1##...
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4920231 |
Process of braking triflouromethyl compounds
A process for the preparation of trifluoromethylvinyl compounds in all their possible streoisomeric forms and mixtures thereof comprising reacting a salt of trifluoroacetic acid with a halovinyl...
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4916229 |
Pyridine carboxylic acid derivates
The present invention covers a novel process for preparing substituted naphthyridines which are useful as intermediates in the production of certain antibacterial agents such as enoxacin. Also...
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4916156 |
Aromatic derivatives, their preparation and their use as antimicrobial agents
The present invention relates to aromatic derivatives of the formula: ##STR1## in which: n represents an integer between 2 and 10; R 1 and R 2 are identical or different and represent a...
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4902818 |
Process for the manufacture of optically active compounds
The manufacture of optically active bifunctional compounds of the general formula ##STR1## wherein R represents protected hydroxymethyl, protected formyl or alkoxycarbonyl and R 1 represents a...
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4902814 |
Fluorobenzyl esters
A compound of formula: ##STR1## wherein R is selected from hydrogen, cyano, methyl, and ethynyl, and X represents the residue of any carboxylic acid of formula X-COOH which forms an insecticidally...
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4902697 |
Derivatives of 2,2-dimethyl-cyclopropanecarboxylic acid
Derivatives of 2,2-dimethylcyclopropanecarboxylic acid endowed with insecticidal and acaricidal activity, and having the formula ##STR1## wherein: R is an alkyl, cycloalkyl, alkenyl or alkynyl...
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4898968 |
Cyclopropane derivatives
Compounds of the formula ##STR1## wherein R 2 represents an α-branched alkyl group containing from 3 to 6 carbon atoms, and R represents either (a) hydroxy, halo or alkoxy of up to six carbon...
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4889872 |
2,3,5,6-Tetrafluorobenzyl (+) 1r-trans-2,2-dimethyl-3-(2,2-dichlorovinyl)-cyclopropanecarboxylate
The novel compound 2,3,5,6-Tetrafluorobenzyl (+)1R-trans-2,2-dimethyl-3-(2,2-dichlorovinyl)-cyclopropanec
arboxylate of the formula ##STR1## is highly active insecticidally.
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4888042 |
Cyclohexenone derivative, process for producing the same and herbicides comprising the same as active ingredient
The present compounds have a high herbicidal activity against various problematic weeds in soil treatment and foliage treatment in plow field as well as in treatment under flooded condition in...
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4883806 |
Certain cyclopropanedicarboxylates with an unsaturated side chain having insecticidal activity
Novel isomers and mixtures thereof of cyclopropane carboxylic acid derivatives with a 3-unsaturated side chain of the formula ##STR1## wherein A' is selected from the group consisting of (1) alkyl...
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4880561 |
Optically active compound and liquid crystalline composition
Disclosed is an optically active cyclopropane compound represented by the formula (1): ##STR1## wherein R is an alkyl or cycloalkyl group, n is 0 or 1, Y 4 is --CO 2 CH 2 --, --OCO-- or --OCH 2 ...
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4879302 |
Certain oximino-cyclopropane carboxylates having insecticidal activity
All possible stereoisomeric forms and mixtures thereof of a compound of the formula ##STR1## wherein A is selected from the group consisting of hydrogen, optionally unsaturated alkyl and haloalkyl...
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4874887 |
Process for the preparation of pyrethroid type ester compounds
The present invention relates to a novel process for the preparation of insecticidally active esters of the general formula (I) ##STR1## wherein R 1 and R 2 are the same or diferent from each...
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4874822 |
Process for the acrylamidoacylation of alcohols
The present invention provides a dramatically improved process for the preparation of acrylamide and methacrylamide functional monomers, oligomers, and polymers that avoids the use of acidic...
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4874473 |
Separation of diastereomers by extractive distillation
Diastereomers can be separated with good industrial success with the aid of extractive distillation. The separation process is characterized in that an auxiliary which changes the partial pressure...
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4868209 |
Halogenated esters
Compounds of formula I wherein R 1 and R 2 are haloalkyl or halo, X is O, S, S(O), SO 2 or NR 4 where R 4 is H or alkyl, R 3 is alkyl and n is 1 to 4, and compositions comprising them, useful...
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4864052 |
2,2-Dimethylcyclopropane-carboxylic acid derivatives
A 2,2-dimethylcyclopropanecarboxylic acid derivative having the formula: ##STR1## wherein R 1 is an alkyl group or an aryl group, R 2 is a hydrogen atom, an acyl group, a sulfonyl group or an...
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4853414 |
Halogenated esters
Compounds of formula (I), useful as insecticides and knockdown agents: ##STR1## where Y is C 1 -6 alkoxy, Z is halo or C 1 -6 alkoxy; R is --(CH 2 ) p --(O) m --R 3 where m and p may be 0 or 1;...
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4835304 |
High density ester damping fluids
Esters having the general formula: ##STR1## where X is a halogen, n is 1-5, Y is an alkyl, ether, ester, or nitro substituent, m is 0-2, Z is an ester linkage --OCO-- or --CO 2 --, R' is a...
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4833163 |
Novel cyclopropane carboxylic acid derivatives
Novel isomers and mixtures thereof of cyclopropane carboxylic acid derivatives with a 3-unsaturated side chain of Z geometry of the formula ##STR1## wherein A' is ##STR2## wherein R 13 is selected...
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4820735 |
Vinylcyclopropanecarboxylic acid esters
Novel insecticidally and acarididally active vinylcyclopropanecarboxylic acid esters of the formula ##STR1## in which R represents alkylthio, alkylsulphinyl, alkylsulphonyl, amino,...
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4816598 |
4-Amino-butanoic acid derivatives
The invention relates to 4-amino-butanoic acid derivatives of general formula: ##STR1## in which: M represents an alkali metal atom, R represents a protected amino group, R 1 represents a...
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4812592 |
Process for the preparation of the esters of an acid
The invention concerns a process for the preparation of the esters of an alkyltartronic acid by direct oxidation, with O 2 or the like, at 30°-200° C., of the corresponding alkyl-malonic esters,...
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4808749 |
Cyclopropane carboxylic esters and acids
Novel esters in all possible isomeric forms of the formula ##STR1## wherein R is selected from the group consisting of (a) optionally unsaturated alkyl of 1 to 8 carbon atoms and optionally...
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4793993 |
Crosslinking of hair thiols
Keratinous material, such as human hair, in which disulfide linkages have been ruptured to form disulfide linkages can be set using diimidates, and disuccinimidyl compounds as disclosed herein.
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4788218 |
17 a β-hydroxy-7 α-methyl-d-homo-19-norandrost-4,16-diene-3-one and the 17-esters thereof: methods of preparation and uses
Novel compounds having the general formula: ##STR1## wherein: R 1 is hydrogen or an acyl substituent of the formula: --(CO)--R 2 wherein: R 2 is an alkyl, alkenyl, alkynyl, cycloalkyl,...
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4782087 |
Insecticidal prop-1-ynyl-3-phenoxybenzyl-2,2-dimethyl-3-(2,2-dihalovinyl)-cyclopropan e-1-carboxylates
Prop-1-ynyl-3-phenoxybenzyl-2,2-dimethyl-3-(2',2'-dihaloviny
l)-cyclopropane -1-carboxylates of the formula ##STR1## in which X 1 if fluorine, chlorine or bromine, and their use in combating pests.
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4778920 |
Process for the production of chlorine-free cyclopropanecarboxylic acid esters
For the production of chlorine-free cyclopropanecarboxylic acid esters, gamma-butyrolactone and butanol are reacted, in a first step, with hydrogen chloride in the absence of a catalyst at a...
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4778822 |
Insecticidally active ester
The invention relates to a method of combating soil-dwelling root worms of the genus Diabrotica which comprises treating the soil in which said root worms dwell with the compound 2-chloro-3,...
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4778630 |
Microbial desaturase enzyme inhibitors and their use in a method of producing lipids
The invention provides novel cyclopropene fatty acid compounds of formula (I) ##STR1## wherein R is a straight chain aliphatic group of 1 to 6 carbon atoms, n is an integer of from 10 to 15; Z is a...
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4759880 |
Alkanoarachidonic acids
A series of alkanoarachidonic acids have been prepared as modulators of the arachidonic acid cascade to increase the production of biologically desirable compounds and minimize the production of...
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4740612 |
Process for production of β-dihalogenoethenylcyclopropane derivatives
A novel process for producing a β-dihalogenoethenylcyclopropane derivative of the formula, ##STR1## wherein R 1 is a hydrogen atom or an alkyl group, R 3 is a hydrogen atom, lower alkyl, acyl,...
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4740331 |
Salts useful as corrosion inhibitors
Salts having the formula: Y--NH 3 ♁.RCO 2 .crclbar . I in which Y is a group of formula R 1 XCH 2 CH(OH)CH 2 --, R and R 1 are the same or different and each is a straight- or...
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4739107 |
Process for the preparation of a diester of a dicarboxylic acid
Process for the preparation of dicarboxylate esters by reacting an optionally substituted ethylenically unsaturated hydrocarbon having two carbon atoms less than said dicarboxylic acid, CO and an...
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4739071 |
Process for the preparation of enantiomers
Enantiomers of optically active dicarboxylic acid monoesters are obtained by subjecting them to intramolecular rearrangement involving reversal of the direction of rotation.
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4734120 |
Dipeptides containing C-terminal phosphinothricin, a process for their preparation and their use for controlling undesirable plant growth
Dipeptides containing C-terminal phosphinothricin of the formula ##STR1## in which phosphinothricin is attached to a--preferably natural--amino acids at the amino group are effective herbicides in...
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4732903 |
Certain cyclopropyl dicarboxylates having pesticidal and insecticidal activity
Novel isomers and mixtures thereof of cyclopropane carboxylic acid derivatives with a 3-unsaturated side chain of the formula ##STR1## wherein A' is selected from the group consisting of wherein...
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4723035 |
Method for racemization of chrysanthemic acid or its ester
Racemization of optically active, particularly the (-)-form of chrysanthemic acid or its ester of the formula: ##STR1## wherein R is, for example, hydrogen or an alkyl group, is effected by...
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4714790 |
Fluoro alcohols and insecticidal esters thereof
The invention concerns a process for preparing 2-substituted-3,4,5,6-tetrafluorobenzyl alcohols by reaction of pentafluorobenzyl alcohol with a Grignard reagent under specified conditions. The...
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4714777 |
Cyclopropanone hydrate derivatives
The subject invention relates to novel cyclopropanone hydrate derivatives of the structural formula ##STR1## wherein R 1 and R 2 are selected from the group consisting of --H, --(CH 2 ) n --...
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4714712 |
Carboxylic acid esters and insecticides containing them as the active ingredient
This invention relates to novel carboxylic acid esters represented by the formula (I) below, methods for production thereof and insecticides containing them as the active ingredient, and an alcohol...
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4713479 |
Synthesis of high-purity dialkyl 2-vinylcyclopropane-1,1-dicarboxylate
This invention relates to a two-step synthesis of high purity dialkyl 2-vinyl-cyclopropane-1,1-dicarboxylate in which a mixture of trans- and cis-1,4-dihalobutene-2 is first isomerized to...
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