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7371882 |
Reactor for producing a nitrile compound and method for operating the reactor
A reactor for producing a nitrile compound from a carbon ring or heterocyclic compound having organic substituents by a gas phase reaction using a fluidized catalyst bed with ammonia and a gas...
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7307181 |
Process for producing a nitrile compound
In a process for producing a nitrile compound comprising introducing a carbon ring or heterocyclic compound having organic substituents, ammonia and the air into a reactor and reacting the...
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7161021 |
Process for producing a polynitrile compound
In a process for producing a polynitrile compound comprising introducing a polysubstituted organic compound (POC) which is a carbon ring or heterocyclic compounds having a plurality of organic...
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6372908 |
Preparation of vanadium antimonate based catalyst using sno2h2o
A method of preparing a catalyst having the elements and the proportions indicated by the following empirical formula: VSbmAaDdOxwhereA is one or more Ti, Sn, where Sn is always presentD is one or...
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6107510 |
Process for producing nitrile compound and catalyst used therefor
There are disclosed a process for producing a nitrile compound which comprises catalytically reacting an alkyl group-substituted aromatic compound or an alkyl group-substituted heterocyclic...
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6072070 |
Vanadium/antimony/titanium mixed oxide and process of use in vapor phase ammoxidation of an alkane
Mixed oxide vanadium/antimony/titanium ammoxidation catalysts, particularly suited for the ammoxidation of alkanes and exhibiting X-ray diffraction spectra which are characteristic of a...
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6057471 |
Ammoxidation method in fluidized-bed reactor
An ammoxidation method in a fluidized-bed reactor, in which, when a starting material to be ammoxidized is ammoxidized by means of vapor-phase catalytic fluidized-bed reaction, the reaction is...
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5952262 |
Preparation of aromatic or heteroaromatic nitriles
Preparation of aromatic or heteroaromatic nitrites of the formula I ##STR1## where X is nitrogen or C-R6 and all of the R substituents represent hydrogen, alkyl, halogen, nitro, amino or similar...
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5670694 |
Process for the preparation of 2,4-dichloro-5-fluorobenzonitrile and 2,6-dichloro-3-fluorobenzonitrile
A mixture of 2,4-dichloro-5-fluorotoluene and 2,6-dichloro-3-fluorotoluene which cannot be separated in an economically efficient manner and can be reacted individually to give the corresponding...
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5554782 |
Preparation of dicyanobenzenes by ammonoxidation
A process for the preparation of dicyanobenzenes of the formula ##STR1## in which x denotes hydroxy, C1 -C4 alkoxy, nitro, amino, mono- or di-(C1 -C4 alkyl)amino, phthalimido or a nitrogenous...
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5262547 |
Process for the production of petrochemicals
Petrochemicals are produced by the vapor phase reaction of a hydrocarbon with substantially pure oxygen in the presence of a suitable catalyst. In the improved process, the principal product is...
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5183793 |
Ammoxidation catalysts and methods for their preparation for use in the production of isophthalonitrile
Catalysts having the general formula: V1 Bia Sbb Fec Xd Yc Zf Ogwherein, X=Mo, Cu, W, Nb, Te, P, Sn, Ge, As Y=Co, Ni, Ce, La, Mn, Cr Z=Alkali, alkaline earth, B, Tl and,...
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5045156 |
Distillation of isophthalonitrile with a hydrocarbon liquid
High boiling point aromatic free hydrocarbon liquids partially substituted for isophthalonitrile during its distillation fluidize the bottoms and increase isophthalonitrile yield.
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5043308 |
Crystalline rare earth aluminum borates
The preparation, structure, and properties of solid inorganic materials containing at least one rare earth element, aluminum, boron and oxygen are described. Also described is the use of such...
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5002639 |
Separation of ortho-, meta- and para-tolunitrile from ternary mixtures of the isomers
A process for the separation of ortho-, meta- and para-tolunitrile from ternary mixtures of isomers entails removing ortho-tolunitrile from these mixtures by distillation under pressures of from...
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4985581 |
Catalyst and process for producing aromatic nitriles
The present invention relates to a catalyst which comprises a vanadium oxide, a chromium oxide, a molybdenum oxide and a boron oxide supported on a silica carrier. This catalyst is suitable for use...
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4939260 |
Process for producing aromatic nitriles or heterocyclic nitriles
A process for producing aromatic or heterocyclic nitriles, which comprises reacting an alkyl-substituted aromatic hydrocarbon or an alkyl-substituted heterocyclic compound with ammonia and oxygen...
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4883897 |
Process for producing 2,6-dichlorobenzonitrile
A process for producing 2,6-dichlorobenzonitrile by ammoxidation comprising contacting a starting gas consisting of 2,6-dichlorotoluene, air and ammonia, which comprises carrying out this reaction...
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4774352 |
Process for ammoxidation
The activity of a tellurium-free metal oxide catalyst used for ammoxidation of organic compounds at a temperature of from 300° C. to 600° C. is improved in the presence of (a) elemental tellurium o...
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4709071 |
Process for improving activity of tellurium containing metal oxide catalysts
A process for improving the activity of tellurium containing metal oxide catalysts useful as catalysts for oxidation, ammoxidation or oxidative dehydrogenation of organic compounds by heating the...
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4582647 |
Process for the preparation of pure 2,6-dichlorobenzonitrile
The present invention provides a process for the preparation of pure 2,6-dichlorobenzonitrile by the ammonoxidation of 2,6-dichlorotoluene in the presence of a catalyst based on vanadium-molybdenum...
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4539409 |
Process for preparing aromatic nitriles
A process is disclosed for preparing coated catalysts, inter alia, for gas phase oxidations in organic chemistry, comprised of an inert support and a coating of catalyst material enclosing this...
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4530797 |
Process for producing polychlorobenzonitrile
A process for producing polychlorobenzonitrile having chlorine atoms at the 2,6-position by ammoxidation of toluene derivative having chlorine atoms at the 2,6-position with a gas containing...
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4502997 |
Treatment of purge gas
The invention relates to a process for treating purge gas including carbon dioxide, water vapor, organics and ammonia. In accordance with the invention, the purge gas is scrubbed with water to...
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4439371 |
Method for preparing phthalonitriles
The present invention relates to methods for preparing aromatic nitriles and, more specifically, to a method for preparing phthalonitriles.The present method for preparing phthalonitriles resides...
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4410450 |
Process for producing fluid catalyst having good activity from coarse catalyst
A process for producing a fluid catalyst having good activity from a coarse catalyst wherein said fluid catalyst is suitable for oxidation, ammoxidation or oxidative dehydrogenation reaction of...
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4406841 |
Process for producing 2,6-difluorobenzonitrile
A process for producing 2,6-difluorobenzonitrile comprises reducing a chloro fluorobenzonitrile selected from 3-chloro-2,6-difluorobenzonitrile, 3,5-dichloro-2,6-difluorobenzonitrile or a mixture...
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4336205 |
Method for producing aromatic nitriles
Aromatic nitriles can be produced in high yields by ammoxidation of an alkyl-substituted aromatic compound in the presence of a catalyst containing oxides of (1) vanadium, (2) antimony and (3) at...
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4305886 |
Process for the ammoxidation of alkylaromatic hydrocarbons
A process for the ammoxidation of aromatic hydrocarbons in a fluidized bed reactor is disclosed. The upper level of a dense bed of fluidized catalyst is maintained near the inlet of the particle...
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4284583 |
Ammoxidation process with external catalyst regeneration zone
A process for the ammoxidation of alkylaromatic hydrocarbons in a fluidized bed reactor is disclosed. A relatively small stream of catalyst is removed from an unsegregated single catalyst bed...
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4284781 |
Supported vanadia catalyst and use thereof for nitrile production
Vanadia supported on a silica-alumina or gamma-alumina support in an amount to provide a vanadia to support weight ratio ranging from about 0.3:1 to about 3:1 substantially entirely within the...
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4203906 |
Process for catalytic vapor phase oxidation
A process for catalytic vapor phase oxidation which comprises using a fixed-bed shell and tube heat exchange type reactor in which a bundle of a multiplicity of tubes filled with at least one type...
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4178304 |
Method of producing ortho-aminobenzonitrile
According to the invention, a method of producing orthoaminobenzonitrile is provided according to which ortho-toluidine is reacted with ammonia at a temperature of 360°-460° C. in the presence of o...
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4124631 |
Process for the production of aromatic nitriles
A process for the production of aromatic nitrile having the formula (I) ##STR1## wherein X represents a chlorine, bromine, iodine or fluorine atom and n is 1 or 2,By contacting aromatic compound...
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4092271 |
Supported vanadia catalyst for nitrile production and process for preparing the catalyst
Vanadia supported on a silica-alumina or gamma-alumina support in an amount to provide a vanadia to support weight ratio ranging from about 0.3:1 to about 3:1 substantially entirely within the...
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4082786 |
Process of production of aromatic nitriles
Aromatic nitriles can be produced at a high conversion and at a high selectivity by filling cylindrical wire netting into a fluidized bed reactor when the aromatic nitriles are produced by...
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4065487 |
Process for producing benzonitrile
A process for producing benzonitrile which comprises reacting toluene with ammonia in the presence of oxygen or a mixture thereof with inert gases and a catalyst; as the latter use is made of a...
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4062885 |
Process for producing phthalonitrile
A process for producing phthalonitrile, which comprises reacting o-xylene with ammonia in the presence of oxygen or a mixture thereof with inert gases and a catalyst; as the latter use is made of a...
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4055587 |
Ammoxidation of alkyl substituted organic compounds using a solution of ammonium carbonate as the ammonia source
In the process of converting alkyl substituted aromatic hydrocarbon to nitriles by ammoxidation where the aromatic hydrocarbon compound, oxygen and ammonia are reacted in the presence of an...
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3993690 |
Method of obtaining aromatic tri-or-tetracarboxylic acids
A method of obtaining aromatic tri- or tetracarboxylic acids characterized in that tri- or tetraalkylbenzenes or the derivatives thereof with a heteroatom in the side chain, are oxidized by oxygen...
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3959339 |
Process for producing aromatic nitriles
Aromatic nitriles are produced in good yield from a gas mixture comprising alkyl-substituted aromatic compound, ammonia and molecular oxygen by ammoxidation by passing the gas mixture over a...
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3944592 |
Method of producing unsaturated nitriles
A method of producing unsaturated nitriles by reaction of an unsaturated hydrocarbon with ammonia and oxygen in a reactor having a fluidized catalyst bed comprising a regeneration zone and a...
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3927007 |
Catalysts for the production of aromatic and heteroaromatic nitriles
Catalysts for the reaction of alkyl substituted aromatic and heteroaromatic hydrocarbons with ammonia and oxygen to form the corresponding nitriles are prepared by heating a compound of the...
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3925447 |
Production of nitriles
Nitriles are produced by reaction of hydrocarbon and ammonia in the presence of a supported metal oxide, wherein the support has a surface area greater than 50m2 /gm, and a porosity greater than...
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3895050 |
Disposal of waste materials from unsaturated nitrile
A method of recovering and disposing of waste materials from a plant for manufacturing unsaturated aliphatic nitriles or aromatic nitriles whereby waste water, unreacted ammonia and by-products...
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3873595 |
Production of o-phthalodinitrile
A catalyst useful in preparing o-phthalodinitrile from o-xylene comprises antimony oxide and vanadium oxide and/or antimony vanadate. The antimony oxide is present as β-antimony tetroxide.
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3870743 |
Preparation of aromatic dinitriles
In the production of nitriles of aromatic dicarboxylic acids by the reaction of alkyl-substituted benzenes with oxygen and ammonia at elevated temperatures, the improvement which comprises...
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3868400 |
Process for vapor phase ammoxidation
In the vapor phase ammoxidation of organic compounds to form nitriles where a reactant stream of ammonia, oxygen, and organic reactant is passed over catalyst, the improvement which comprises...
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3699147 |
PROCESS FOR PREPARING NITRILES
A process for the production of a nitrile having three to 12 carbon atoms per molecule by contacting at a temperature of 400° to 500° C and a contact time of 10 to 0.1 seconds a gaseous mixture o...
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3544617 |
PROCESS FOR THE MANUFACTURE OF AROMATIC NITRILES
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