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8030510 |
Process for the direct synthesis of alkylhalosilanes
Process for preparing alkylhalosilanes are provided. The process involve reacting an alkyl halide with a solid body formed of silicon and a catalytic system.
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7626050 |
Direct method for synthesising alkylhalogenosilanes
Process for the preparation of alkylhalosilanes by reaction of an alkyl halide, preferably CH3Cl, with a solid body, referred to as contact body, formed of silicon and of a catalytic system...
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7569716 |
Method of selecting silicon having improved performance
Chemical grade silicon metalloid having improved performance in the direct process for making organohalosilanes is selected by (A) measuring the temperature of each batch of silicon metalloid...
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7550620 |
Process for preparing methylchlorosilanes
The invention relates to a process for the direct synthesis of methylchlorosilanes by reaction of chloromethane with a contact composition comprising silicon and copper catalyst, wherein the...
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7521574 |
Making of contact mass for organohalosilane preparation and preparation of organohalosilanes
Organohalosilanes are prepared by charging a reactor with a contact mass comprising metallic silicon and a catalyst and feeding an organohalide-containing gas to the reactor. The contact mass is...
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7429672 |
Process for the direct synthesis of trialkoxysilane
This invention discloses a process to improve reaction stability in the Direct Synthesis of trialkoxysilanes. The process is particularly effective in the Direct Synthesis of triethoxysilane and...
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7420075 |
Preparation of organohalosilanes
Organohalosilanes are prepared by charging a reactor with a contact mass of metallic silicon and a catalyst and feeding an organohalide-containing gas to the reactor. Tin or a tin compound is used...
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7323583 |
Catalysts for the production of methylchlorosilanes using zinc oxide promoters
The present invention provides a catalyst that may be used to facilitate the formation of dimethylchlorosilanes. A catalyst in which copper oxide and zinc oxide are in intimate contact and form...
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7279590 |
Preparation of organohalosilanes
Organohalosilanes are prepared by reacting metallic silicon particles with an organohalide in the presence of a copper catalyst. A contact mass composed of metallic silicon and copper catalyst...
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7265235 |
Method for producing halosilanes by impinging microwave energy
Silanes containing halogen which is bound to silicon are prepared using microwave energy. Silicon is reacted with mixtures of elements or compounds selected from the group consisting of halogen or...
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7238638 |
Composite copper/tin/alkali metal catalysts for the direct synthesis of alkylhalosilanes
The alkylhalosilanes are directly synthesized while diminishing the formation of coke by reacting an alkyl halide with silicon in the presence of a catalytically effective amount of (α) a copper ...
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7202192 |
Composite catalysts for the direct synthesis of alkylhalosilanes
The alkylhalosilanes are directly synthesized by reacting an alkyl halide with silicon in the presence of a catalytically effective amount of (α) a copper metal or a copper-based compound catalyst ...
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7153991 |
Rochow-Müller direct synthesis using nanosized copper catalyst precursors
A Direct Synthesis of making organohalosilanes with greater selectivity to the dialkyldihalosilane is disclosed herein. By using nanosized copper catalyst precursors, and preferably nanosized...
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7108734 |
Silicon powder for preparing alkyl- or aryl-halogenosilanes
The invention concerns a silicon powder for making alkyl- or aryl-halogenosilanes, with particle-size distribution less than 350 μm, and containing less than 3% and preferably less than 2% of ...
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6984748 |
Co-catalyst and process for the preparation of organohalosilanes
In a Rochow process, organohalosilanes are prepared by reacting metallic silicon particles with an organohalide in the presence of a copper catalyst and a co-catalyst. The invention uses as the...
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6911552 |
Preparation method of alkyldichlorosilanes
A method for preparing alkyldichlorosilanes having a Si—H bond by directly reacting metallic silicon with a mixture of alkyl chloride and (i) hydrogen chloride, or (ii) an alkyl chloride which c...
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6894181 |
Preparation of organohalosilanes
In an industrial process for preparing organohalosilanes by reacting metallic silicon particles with an organohalide in the presence of a copper catalyst, a contact mass composed of the metallic...
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6768018 |
Preparation of organohalosilanes
When oganohalosilanes are prepared by charging a reactor with a contact mass containing metallic silicon and a copper catalyst, and introducing an organohalide-containing gas feed into the reactor,...
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6717004 |
Method for making alkylhalosilanes
A method for making alkylhalosilanes is provided comprising reacting an alkyl halide and silicon in the presence of a copper catalyst comprising copper powder, particulated copper, copper flake, or...
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6686312 |
Metallic copper catalyst and process for making organohalosilanes
In the synthesis of organohalosilanes by the direct process of reacting an organic halogen with metallic silicon powder, a metallic copper catalyst in the form of a thermally active metallic copper...
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6528674 |
Method for preparing a contact mass
A method for making an alkylhalosilane is provided wherein the method comprises heat treating silicon and a form of copper at a temperature greater than about 500° C. to produce a contact mass and ...
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6465674 |
Dust recirculation in the direct synthesis of chlorosilanes and methylchlorosilanes in a fluidized bed
A continuous process for the direct synthesis of silanes of the formula 1 RaSiCl4−a (1)involves reacting finely divided silicon metal with R—Cl in a fluidized bed, whereR is hydrogen, methyl or eth...
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6433205 |
Magnetic separation for silicon-containing materials
Magnetic separators are used for treating silicon-containing materials from chlorosilane reactors to remove magnetically influenced components in the silicon-containing materials. The removal of...
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6425850 |
Method for determining eta phase copper
A proportion of Cu3Si in a contact mass is determined by treating the mass with an inorganic ammonium salt, which selectively dissolves all forms of copper including free copper in deference to...
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6423860 |
Method for promoting dialkyldihalosilane formation during direct method alkylhalosilane production
Dialkyldihalosilane formation during direct method alkylhalosilane production is promoted by effecting reaction between alkyl halide and powdered silicon in the presence of a catalyst comprising...
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6407276 |
Method for improving selectivity for dialkyldichlorosilane
A method for forming a dialkyldichlorosilane, comprising reacting elemental silicon with an alkyl chloride using copper as a catalyst together with promoters zinc, tin, and a special promoter. The...
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6395917 |
Preparation of organohalosilanes
When oganohalosilanes are prepared by charging a reactor with a contact mass containing a metallic silicon powder, a copper catalyst and a co-catalyst, and introducing an organohalide-containing...
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6365766 |
Metallic copper catalyst and process for the synthesis of organohalosilanes
Organohalosilanes are prepared by reacting an organic halide with metallic silicon particles in the presence of a metallic copper catalyst which is a metallic copper powder in flake form having a...
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6339167 |
Process for preparing organohalosilanes
Organohalosilanes are prepared by reacting metallic silicon with a halogenated hydrocarbon in the presence of a copper or copper compound catalyst and an activated aluminum, aluminum alloy or...
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6323357 |
Process for the direct synthesis of organochlorosilanes using recovered CuCl catalyst
A process for the direct synthesis of organochlorosilanes using CuCl prepared from the copper-containing residues from the direct synthesis of organochlorosilanes, where, in the preparation of the...
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6258970 |
Method for promoting dialkyldihalosilane formation during direct method alkylhalosilane production
A method is described for enhancing the formation of alkylhalosilane during the direct method reaction between powdered silicon and a catalyst comprising copper, zinc, tin, and phosphorus. An...
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6252102 |
Process for the preparation of methylchlorosilanes
In the process for the direct synthesis of methylchlorosilanes from chloromethane and silicon in the presence of a copper catalyst and promoter, the reaction mixture comprising chloromethane,...
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6211394 |
Process for the preparation of organochlorosilanes
The invention relates to a continuous process for the direct synthesis of methylchlorosilanes by reacting chloromethane with a catalyst composition comprising silicon, zinc promoter and copper...
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6169195 |
Process for the removal of chlorohydrocarbons from organochlorosilanes
The invention relates to a process for cleavage of chlorohydrocarbons which are present as an impurity in organochlorosilanes, in which the chlorohydrocarbons are brought into contact with steel...
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6090966 |
Preparation of contract mass for alkylhalosilane production and process for producing alkylhalosilanes
Alkylhalosilanes are produced by first fluidizing a metallic silicon powder with an inert gas, preheating the silicon powder at a temperature between 200° C. and a steady reaction temperature ...
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6057469 |
Process for manufacturing active silicon powder for the preparation of alkyl- or aryl-halosilanes
A process for the preparation of active silicon powder for use in the Rochow reaction consisting of grinding metallurgical silicon to a particle size less than 350 μm in the presence of at least ...
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6025513 |
Preparation of alkylhalosilanes
An alkylhalosilane is prepared by charging a reactor with a contact mass comprising a metallic silicon powder and a copper catalyst, and feeding an alkyl halide into the reactor whereby the silane...
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5986123 |
Preparation of alkylhalosilanes
An alkylhalosilane is prepared by charging a reactor with a contact mass comprising a metallic silicon powder and a copper catalyst, and feeding an alkyl halide into the reactor whereby the silane...
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5973177 |
Method for selecting silicon metalloid having improved performance in the direct process for making organohalosilanes
A method for selecting chemical grade silicon metalloid having improved performance in a direct process for making organohalosilanes. The method comprises (A) heating a chemical grade silicon...
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5880307 |
Process for the preparation of alkylhalosilanes
A process for the use of water granulated silicon in the preparation of alkylhalosilanes. The process comprises contacting an alkyl halide described by formula RX, with a particulate water...
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5876609 |
Process for treating methylchlorosilanes by-products
The instant invention relates to a novel process for the hydrolysis of the by-products produced during the manufacture of methyldichlorosilanes comprising combining the by-products with an aqueous...
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5877337 |
Process for preparing alkylchlorosilanes from the residues of direct synthesis of alkylchlorosilanes
Alkylchlorosilanes are prepared continuously from the residue of direct synthesis of alkylchlorosilanes containing liquid constituents with a boiling point of at least 70° C. at 1013 hPa and solid ...
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5874604 |
Process for preparing alkyl halosilanes
The present invention relates to a process for preparing alkyl halosilanes by reacting a contact material which comprises, in addition to silicon, at least one copper-containing compound as...
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5817855 |
Copper-based catalysts, processes for their production and their use and a process for the production of alkyl halosilanes
The invention relates to copper-based catalysts, processes for their production and their use and to a process for the production of alkyl halosilanes in the presence of said catalysts.
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5783721 |
Preparation of silanes
An (alkylhalo)silane is prepared by charging a reactor with a contact mass comprising metallic silicon powder and a copper catalyst and feeding a gas containing an alkyl halide into the reactor...
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5777146 |
Process for preparing methylchlorosilanes
In a process for the direct synthesis of methylchlorosilanes by reacting methyl chloride with a catalytic composition comprising silicon, copper catalyst and promoters, where at least some of the...
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5756794 |
Process for producing alkylhalogenosilanes
The process for producing alkylhalogenosilanes, which comprises reacting a physical mixture of silicon, a selenium or tellurium promoter and a copper catalyst with an alkyl halide.
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5714131 |
Metallurgical silicon containing phosphorus for the preparation of organohalogenosilanes
A metallurgical silicon is disclosed which contains substantially from 30 to 180 ppm of phosphorus comprised of a crystalline phase of primary silicon having a dissolved phosphorus content between...
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5712405 |
Preparation of silanes
An (alkylhalo)silane is prepared by using a fluidized bed reactor equipped with a feed line for reactant gas and a delivery line for product gas, charging the reactor with a contact mass comprising...
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5679823 |
Method of producing alkyl halogen silanes
A method of producing alkyl halogen silanes, more particularly methyl chlorosilanes, by reacting silicon with an alkyl halide in the presence of at least one catalyst and easily volatile or gaseous...
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