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4349485 |
Catalytic aromatic carbonate process using manganese tetradentate redox co-catalysts
An enhanced catalytic aromatic carbonate process which comprises contacting a phenol, carbon monoxide, an oxidant, a base, the Group VIIIB element selected from ruthenium, rhodium, palladium,...
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4343745 |
Process for solubilizing organic or mineral salts in organic solvents
The invention provides a process for solubilizing an organic or mineral salt in an organic solvent, said process comprising contacting an organic or mineral salt of the formula A - M + , wherein A...
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4338254 |
Process for the preparation of cobalt (III) acetylacetonate
A process for the preparation of cobalt (III) acetylacetonate by oxidation of cobalt (II) acetylacetonate by means of hydrogen peroxide in the presence of the stoichiometrically required amount of...
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4337335 |
Transition metal salt complexes of polyamino organic compounds
Described are transition metal salt complexes of available neighboring amino and hydroxyl group pairs in polyamino organic compounds, their preparation, and use as intermediates in the preparation...
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4337210 |
Process for the preparation of cobalt (II) acetylacetonate
An improved process for the preparation of cobalt (II) acetylacetonate by reaction of cobalt (II) compounds with acetylacetone at elevated temperature is disclosed, wherein the reaction is carried...
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4334051 |
Heat resistant polyvanadiosiloxanes and a process for their production
A polyvanadiosiloxane being a polymer of which the main chain skeleton consists of Si-O bonds and V-O bonds, characterized by side chains directly attached to the silicon atom being at least one...
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4328379 |
Homologation process
Disclosed is an improved process for the homologation of alkanols to obtain the next higher alkanol homolog by the cobalt-catalyzed reaction of an alkanol reactant with carbon monoxide and hydrogen...
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4313851 |
Liquid, cold-stable titanium catalyst preparation
A cold-stable catalytically active solution of diisopropoxy-bis (2,4-pentanedionato)-titanium(IV) in isopropanol, said solution containing 0.05 to 0.15 mol of water per mol of said titanium compound.
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4303578 |
Organo-antimony compounds
Organo-antimony compounds of the formula I ##STR1## wherein R is hydrogen or C 1 -C 18 acyl, R' is C 1 -C 20 alkyl or C 1 -C 18 acyl, and X is sulfur or oxygen. The compounds are stabilizers...
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4279829 |
Metal complex catalysts
Hydroperoxides are catalytically decomposed using a novel metal complex of the formula: ##STR1## wherein M is a positively charged metal or metal compound; Z is S, O, P, S--P, or S--S; L is...
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4263333 |
Curcumin-metal color complexes
A complex, and a process for preparing said complex, formed by the reaction of curcumin, turmeric, with certain metal ions. The metal-curcumin coloring complex is water soluble and capable of...
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4244842 |
Nickel and cobalt chelate complexes and their use
The invention provides nickel and cobalt chelate complexes of a nickel or cobalt salt and a succinosuccinate of the formula I ##STR1## wherein R represents a substituted or unsubstituted...
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4187241 |
Metal phosphine complex
Novel Group IB and IIB metal phosphine complexes are disclosed. These complexes are reacted with rhodium complex precursors to form useful enantioselective hydrogenation catalysts. Also disclosed...
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4180386 |
Hexacoordinated transition metal compounds containing at least one polyfluoroalkyl substituent
Hexacoordinated transition metal compounds, useful as antiknocks, having the structure ##STR1## wherein M is a divalent metal selected from the group Mn, Fe, Co and Ni, L 1 and L 2 are the...
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T989005 |
Nickel organic compositions to improve dyeability of polymers
Nickel organic compositions prepared from a nickel salt of a 1,3-diketone of the formula ##STR1## wherein R and R' are independently C 1 -C 8 alkyl; and sulfonyl dialkylphenols of the formula...
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4170602 |
Method of producing acicular metal crystal
Improved processes and products based on the discovery that metal atoms in complex relationship with complexing agents can be used to moderate the formation of organic salt seed crystals which...
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4157975 |
Electrical insulators having increased resistance to partial discharges
The invention relates to electrical insulators having increased resistance to partial discharges and electrical equipment comprising such electrical insulators. These electrical insulators are...
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4150047 |
Process for preparing halogenated metal chelates
This invention relates to an improved process for preparing halogenated metal chelates of beta-dicarbonyl compounds, particularly the tris-brominated acetylacetonates. The process comprises passing...
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4148940 |
Method for depositing films containing cobalt oxide
Improved methods are disclosed for depositing metal oxide films from coating compositions containing dehydrated cobaltous acetylacetonate.
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4147556 |
Nonflammable beta diketonate composition
A composition suitable for producing a metal oxide coating on the surface of a heated refractory substrate is disclosed. The composition comprises a metal beta diketonate dissolved in a...
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4141911 |
Production of polynuclear dicarboxylatotetrachromium (III) complexes
Polynuclear dicarboxylatotetrachromium (III) complexes are produced by reacting a dicarboxylic acid with a monobasic chromic (III) salt in a proportion of 4 moles of monobasic chromic (III) salt to...
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4138385 |
Substituted acetylacetonate cobaltic promoters for unsaturated polyester resin
This invention relates to an improvement in a process for curing unsaturated polyester resins, preferably chemically thickened with a Group II metal oxide or hydroxide, and to the resulting...
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4136097 |
Process and promoting agents for the preparation of loweralkyl 2-(N-R'-pyrryl)-alpha-loweralkanoic acid esters
A process for the preparation of loweralkyl 2-(N-R'-pyrryl)-α- loweralkanoic acid esters in increased yield and/or isomeric purity, and copper (II) 1,3-diketonate, copper (II) salicylaldehyde,...
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4136254 |
Process of selectively blocking amino functions in aminoglycosides using transition metal salts and intermediates used thereby
Selective blocking of some amino groups in a polyamino organic compound having at least one pair of available neighboring hydroxyl and amino groups is effected by first preparing in situ transition...
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4115420 |
Catalytic conversion of thallium (I) to thallium (III)
A monovalent thallium compound is converted to a trivalent thallium compound by treating the thallium (I) compound with molecular oxygen in the presence of a Group VIII noble metal catalyst to...
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4111678 |
Foliar feeding organometallic composition
Disclosed is a foliar feeding spray composition for supplying trace metals to plants comprising a thermally-treated trace metal chelate dissolved in a hydrocarbon mineral oil carrier having a...
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4055714 |
Azo free radical initiators containing ultraviolet light stabilizing groups
Compounds which contain azo or peroxide linkages as well as the radical of an ultraviolet light stabilizing group are described. These compounds function as polymerization initiators which cause an...
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4017429 |
Preparation of 2-hydroxyalkyl esters
This patent describes the catalytic promotion of the reaction of oxirane-containing compounds with carboxylic acid compounds at high, ambient, and low temperature. Specifically, this patent...
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4015980 |
Use of fluorinated β-diketones in the solvent extraction of zinc
Zinc is extracted from aqueous ammoniacal solutions using fluorinated β-diketones of the structure ##STR1## where n is a whole integer of 1 to 4, m is 0, 1 or 2 and R is an alkyl group of 1-25...
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4008260 |
Process for preparing cobalt(III)acetylacetonate
Process for preparing cobalt(III)acetylacetonate comprising the steps of adding to cobalt(II)acetylacetonate in an organic solvent, at least the stoichiometric amount of acetylacetone, oxidizing...
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3972868 |
Method for selectively guiding and limiting the reactions of hydroxyl compounds
The present invention relates to a method for producing, from a hydroxyl compound, a sequence of metal derivatives, which are subsequently made to react selectively for a certain purpose. The...
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3968135 |
Chromium salt catalysts
This patent describes the catalytic promotion of the reaction of oxirane-containing compounds with carboxylic acid compounds at high, ambient, and low temperature. Specifically, this patent...
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3960909 |
Process for preparing palladium(II)acetylacetonate
A process for preparing palladium(II)acetylacetonate having a low content in organically linked chlorine by reaction of acetylacetone with palladium dichloride or the complex...
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3946057 |
Preparation of metal complexes of 1,3-diketones
Process for preparing metal complexes of organic 1,3-diketones, which comprises, reacting in the presence of an alkylene oxide, a metal halide or hydrates thereof, and an organic 1,3-diketone.
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3919275 |
Chelated beta dicarbonyl compounds
Beta dicarbonyl compounds are prepared by reacting an enol ester with aluminum chloride in the presence of an inert solvent at a temperature range of 20° to 50°C. An isopropenyl ester of an...
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3917722 |
Process for condensation of alcohols
A process for producing higher molecular weight alcohols by condensing at least one lower molecular weight primary alkanol having a methylene group adjacent the hydroxylated carbon atom in liquid...
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3901939 |
Process for the preparation of organic compounds
A process for preparing dimerization products having the formula X -- (A) 2 -- X in which A is a divalent radical such as --CH 2 --, and X is a functional group such as --NO 2 , wherein a...
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3895041 |
Metallised pigments
An unsymmetrical compound having either the formula: ##SPC1## Wherein M is a transition metal atom, X and Y are the same or different, and each is hydrogen or each represents a non water...
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3894164 |
Chemical vapor deposition of luminescent films
Method for depositing a luminescent film comprising vaporizing into a nonreactive carrier gas at least one betadiketonate of yttrium, lanthanum, gadolinium, and lutetium, and at least one...
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3888895 |
Production of titanium acetylacetonate bis(dimethylamine)
A novel chelated ester of orthotitanic acid is provided having the chemical structure of titanium acetylacetonate bis(dimethylamine). The titanium chelate may be formed by reacting...
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3884979 |
Synthesis of unsaturated diketones
This invention relates to a process for the preparation of 2-alkenyl-4-hydroxy-3-methyl-2-cyclopenten-1-ones from the reaction product of 2,4-pentane dione and a 2-propen-or 2-propyn-1-ol...
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3867418 |
EUROPIUM COMPLEX OF 1,1,1,2,2,6,6,7,7,7-DECAFLUORO-3,5-HEPTANEDIONE
A paramagnetic shift reagent, consisting of the europium (Eu) complex of 1,1,1,2,2,6,6,7,7,7-decafluoro-3,5-heptanedione [H(FHD)], said complex having the general formula Eu(FHD) 3 .
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3864407 |
Catalytic Process For Producing Higher Molecular Weight
A process for producing higher molecular weight alcohols by condensing at least one lower molecular weight primary alkanol having a methylene group adjacent the hydroxylated carbon atom in liquid...
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3856839 |
ALKANEDIOXY TITANIUM CHELATES
Alkanedioxy titanium chelates have the formula: Wherein R 2 is a radical selected from the group consisting of hydrogen, hydrocarbyl having not more than about 8 carbon atoms, carboxyalkyl and...
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3856750 |
POLYOLEFINS STABILIZED WITH NICKEL OR COBALT COMPLEXES OF HALOGENATED MONO OR DITHIO BETA DIKETONES
Polyolefin resin compositions having improved ultra violet and thermal stability properties are obtained by incorporating with the resins small amounts of a cobalt or nickel complex of a partially...
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3843691 |
CATALYTIC EPOXIDATION WITH MOLECULAR OXYGEN
Direct epoxidation of olefins is carried out in the liquid phase with molecular oxygen in the presence of transition metal complexes of fluorinated diketones. The additional presence of carboxylic...
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3835170 |
HYPOTENSIVE AGENT, OUDENONE, ITS SALTS AND PROCESSES FOR PRODUCTION AND PREPARATION THEREOF
A hypotensive compound designated oudenone and metal salts of oudenone, oudenone being produced by a process which comprises cultivating a strain of a mushroom in an aqueous nutrient medium until...
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3716567 |
SIMULTANEOUS PRODUCTION OF ALCOHOLATES AND TRIVALENT TITANIUM COMPLEXES OF BETA-DIKETONES
Tetravalent titanium alcoholate-beta diketone complexes, e.g. titanium isopropylate-triacetylacetonate, are reacted with an alkali metal amalgam in a non-polar solvent to reduce the titanium to...
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3700710 |
METHYLENE BIS(ALUMINUM DIHALIDES) USEFUL AS POLYMERIZATION CATALYST COMPONENTS
An electrolytic process is described for making certain bis-(halometal)methanes such as bis(dichloroaluminum)methane, Cl 2 AlCH 2 AlCl 2 , which is a new compound, and these compounds can be...
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3697642 |
METHOD OF PROTECTING THE SKIN FROM ULTRAVIOLET RADIATION WITH TITANIC ACID AND ESTERS OF TITANIC ACID
An effective ultra-violet absorber composition and process for controlling sunburn by applying to the skin a composition which comprises a hydrated, substantially transparent gel represented by the...
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