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7582786 |
Synthetic catalytic free radical scavengers useful as antioxidants for prevention and therapy of disease
The invention provides antioxidant salen-metal complexes, compositions of such antioxidant salen-metal complexes having superoxide activity, catalase activity, and/or peroxidase activity,...
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7572731 |
Unsymmetrical ligand sources, reduced symmetry metal-containing compounds, and systems and methods including same
The present invention provides metal-containing compounds that include at least one β-diketiminate ligand, and methods of making and using the same. In some embodiments, the metal-containing...
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7439338 |
Beta-diketiminate ligand sources and metal-containing compounds thereof, and systems and methods including same
The present invention provides metal-containing compounds that include at least one β-diketiminate ligand, and methods of making and using the same. In certain embodiments, the metal-containing...
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7435270 |
Pigment/dye mixtures
A composition comprising (A) at least one nickel complex pigment and (B) at least one disperse dye of formula (1) or (2) wherein R 1 is hydrogen, hydroxy or a radical —NHCO—R 6 wherein R 6 ...
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7279588 |
Dinuclear metal complex and pyrophosphate assay using the same
A novel coordination complex formed by dinuclear metal complexation is provided. The complex is a dinuclear metal complex of a compound, wherein the compound comprises a conjugation ring system...
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7105672 |
Cyclometallated catalysts
A catalyst compound of formula I or II:
(wherein R 1 –R 11 , M, E, T, X, Y, m and n are defined herein). The compound, when combined with a suitable activator, is active for the polymerization...
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6974878 |
Catalyst ligands, catalytic metal complexes and processes using same
A new ligands that include a benzene ring in the backbone can be combined with a metal or metal precursor compound or formed into a metal-ligand complex catalyze a number of different chemical...
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6897272 |
α-olefins and olefin polymers and processes therefor
Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The...
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6800775 |
Metal complexes of tripodal ligands
Novel metal complexes of tripoadal ligands are useful as catalysts to enhance the action of peroxygen compounds in washing, cleaning and disinfecting processes.
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6800774 |
Catalysts used for olefine polymerization and the preparation thereof
The present invention provides a polynuclear α-diimine Ni(II) complex used as the precursor of the catalyst in polymerizing polyolefine, represented by the following formula: wherein M is Ni; X...
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6794526 |
Process for the preparation of manganese complexes of salen compounds
A process for the preparation of manganese complexes of salen compounds which comprises carrying out the reaction of a salen compound with a manganese compound in DMF is described. In a preferred...
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6781006 |
Active catalysts for stereoselective ring-opening reactions
A method for making a chiral transition metal-ligand catalyst complex that is active in catalyzing stereoselective ring opening reactions includes contacting an asymmetric tetradentate ligand, in...
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6780947 |
Metal complexes comprising a 2,6-diacylpyridine-ligand and their use in the polymerization of ethylene
Organometallic complex having the formula (IAP)M(X) n which can be used for die formation of catalytic systems wherein: M is a metal selected from transition metals and lanthanides, in oxidation...
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6747105 |
Bis-Schiff base ligand-containing mono-metallocene olefin polymerization catalyst, its preparation process and application
A catalyst for olefin polymerization having the following structural formula (I): wherein R 1 is selected from the group consisting of hydrogen, C 1 -C 12 alkyl, C 1 -C 12 alkoxy, or C 6 -C...
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6677423 |
Polymerization of ethylene
Polyethylene is formed by contacting ethylene with a novel iron or cobalt complex of a selected 1,4,7-triaza-3-oxa-1,4,6-heptatriene or 2,5,8-triaza-1,8-nonadiene, optionally in the presence of a...
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6627580 |
Chelating agents and their manganic chelates
Chelating agents (chelants) of the general structure: wherein: n=2-4 whereby at least two of X are of formula III Y=COOH, —PO 3 H 2 or o-hydroxyphenyl R 1 , R 2 and R 3 are independently H...
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6534657 |
Chiral ferrocene phosphines and their use in asymmetric catalytic reactions
Ferrocene anchored chiral ligands and metal complexes based on such chiral ligands useful in asymmetric catalysis are disclosed. The metal complexes according to the present invention are useful as...
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6002034 |
Bis(arylimino)acenaphthene nickel(II) complexes
Certain olefins such as ethylene, α-olefins and cyclopentene can be polymerized by using catalyst system containing a nickel or palladium α-diimine complex, a metal containing hydrocarbylation...
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5942461 |
Polymerizable compositions comprising alpha-olefin hydrocarbon monomers and methods of use therefor
A polymerizable composition comprises an alpha-olefin hydrocarbon monomer, an effective amount of an organometallic catalyst of a Group VIII metal, preferably Ni or Pd, and at least one of water...
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5741920 |
Inhibition of re-absorption of migrating dyes in the wash liquor
A process for inhibiting the re-absorption of migrating dyes in the wash liquor comprises introducing into a wash liquor containing a peroxide-containing detergent, from 0.5 to 150 mg, per liter of...
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5663393 |
Chiral catalysts and epoxidation reactions
Chiral catalysts for enantioselectively epoxidizing a prochiral olefin and for enantioselectively oxidizing a prochiral sulfide are disclosed, together with methods of using such catalysts. In...
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5514823 |
Bis-(alkylsalicylidene)ethylene or phenylene diamines and transition metal complexes thereof
Preparation of N,N'-bis(alkylsalicylidene)ethylene or phenylene diamines, and transition metal complexes thereof, particularly copper, and their use as an additive to diesel fuel to reduce soot...
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5463098 |
Clear antiperspirant gel stick and method for making same
A residue free, antiperspirant gel stick composition is disclosed which comprises an antiperspirant compound which is soluble in a diol, a normally liquid, water soluble diol, a gelling agent and a...
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4861904 |
Schiff base metal complex compounds, and organometallic ultrathin film composed thereof and oxygen separation films composed thereof
A Schiff base metal complex compound represented by formula (I) ##STR1## wherein rings A and B each denote an o-phenylene or o-naphthylene group having at least one long-chain hydrocarbon group...
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4785088 |
Pigments and their preparation
Pigments of the general formula FHet (I). where F is the cation of a cationic dye which has an absorption maximum at >700 nm and may or may not...
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4746748 |
Method for reducing hydroxocobalt (III) Schiff base complex
A method is described for reducing a hydroxocobalt (III) Schiff base complex to a cobalt (II) Schiff base complex by heating the former complex to a temperature below the decomposition point of the...
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4680385 |
Metal dye complexes containing an azo or azomethine dye and a colorless ligand with the CN--NC group
Metal complex dyes that produce level, fast dyeings on textile materials are provided according to the formula ##STR1## wherein: D is a benzene, naphthalene or heterocyclic radical of a diazo...
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4655785 |
Process for photochemical stabilization of polyamide and polyurethane fiber materials with metal complex compounds
A process for the photochemical stabilization of undyed and dyed polyamide or polyurethane fibre material that is characterized in that the fibre material is treated with a water soluble, organic...
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4652631 |
Bis 1:2 chromium complexes of disazo and azo or azomethine dyes
1:2 chromium complex dyes suitable for dyeing nitrogen-containing materials and materials which contain hydroxyl groups, are disclosed which, in the form of the free acid, have the formula ##STR1##...
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4562277 |
Process for the preparation of a bis-salicylidene-alkylene-diaminocobaltous ion complex
Improved process for the preparation of salcomine useful as an oxidation catalyst for the oxidation of alkylated phenols to the corresponding alkylated p-benzoquinones by reacting salicylaldehyde...
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4440693 |
Preparation of electrically conductive products
A process for the preparation of electrically conductive products which are stable to air and have conductivities greater than 1 ×10 -3 S/cm, by reacting a cation of a metal of group VII or VIII...
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4410705 |
Novel spiro oxazoline compounds and methods for their preparation and use
A process for preparing substituted or unsubstituted benzoxazoline compound by reacting ammonia, a cycloalkanone and oxygen in the presence of metal cations.
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4399148 |
Hydroxyarylalkyleneaminoaryl carbamates and derivatives thereof useful as insecticidal compositions
This invention relates to novel hydroxyarylalkyleneaminoaryl carbamate compounds and derivatives thereof and to their preparation. This invention is also directed to insecticidal compositions...
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4322563 |
Substituted biphenyl-2-carboxaldehydes
Substituted biphenyl-2-carboxaldehydes are prepared in good yield by reacting palladium complexes of substituted benzaldehyde aniline Schiff bases with substituted phenylmagnesium bromides in the...
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4318849 |
Novel metallized dyes, their manufacture and use
The present invention relates to copper, nickel, chromium or cobalt complexes of azo or azomethine dyes which contain a group of the formula --NNAr) m -1 Z--R 2 --U wherein Z is a bridge...
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4294749 |
Process for the coloration of thermoplastic polymers and polycondensates in the mass with water-insoluble disazo-methine compounds
For coloring in the mass and spin dyeing water-insoluble thermoplastic polymers and polycondensates, especially polyesters, nickel complex disazomethine compounds are used consisting of 2 molecules...
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4290961 |
Process for catalytically reducing carbonyl compounds
Catalytic reduction of carbonyl compounds by transfer of hydrogen from alcohols to aliphatic, alicyclic, aromatic, homo- and heterocyclic ketones or aldehydes, catalyzed by rhodium or iridium...
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4266945 |
Molybdenum-containing compositions and lubricants and fuels containing them
Molybdenum-containing compositions are prepared by the reaction of an acid of molybdenum or salt thereof, phenol or aldehyde condensation product therewith, and a primary or secondary amine. The...
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4264494 |
Chromium complex dyestuffs for natural polyamides and synthetic nylons
Metal complex compounds which in the form of the free acids correspond to the formula I ##STR1## where A is an aliphatic, carbocyclic or heterocyclic radical, E is an aliphatic or carbocyclic...
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4231950 |
Yellow azomethine dye developers
Novel yellow ortho, ortho' dihydroxy azomethine dyes and metal complexes of such dyes which are particularly useful in photographic products and processes are presented by this invention. The novel...
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4226792 |
Lead chelate complex compounds
1. Lead chelate complex compounds selected from the group consisting of lead 3-nitrosalicylaldehyde, lead 5-nitrosalicylaldehyde, lead 5-chlorosalicylaldehyde, lead 2, 4-dihydroxybenzophenone, lead...
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4221735 |
Complexed manganese catalyst
A novel catalyst system is disclosed that is useful in the polymerization of polyphenylene oxide resins. The catalysts are manganese complexes that are derived from a manganese salt and an imine...
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4212801 |
Unsymmetrical 1:2-chromium complexes containing an azo and an azomethine bond
2:1-chromium complex dyes of the formula: ##STR1## in which: A is the radical of a carbocyclic diazo component with a complex-forming hydroxy or carboxy group adjacent to the azo bridge; B is...
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4206139 |
Synthesis of benzaldehydes
Novel benzaldehydes of the formula: ##STR1## Where n 1 is the integer 1-8 and each OR 1 group is hydroxy or a protective group which can be converted or removed to provide the dihydroxyphenyl...
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4204879 |
Amino acid salts of anionic dyestuffs which have high solubility in organic solvents
This invention concerns a range of amino-acid salts of anionic dyestuffs which have a high solubility in organic solvents, particularly oxygenated, halogenated and amido organic solvents. The...
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4202714 |
Ballistic modifiers and synthesis of the ballistic modifiers
A new class of ballistic modifiers and the synthesis thereof is disclosed rein and are used in propellants either individually or as admixtures in percentages of approximately 0.5 to 6 weight...
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4202685 |
2-1-(2-Hydroxy alkyl imino)-ethyl-1-hydroxy-4,4,6,6-tetramethyl cyclohexen-3,5-diones
Compounds having the following structural formula ##STR1## wherein R is hydrogen or alkyl and R 1 is hydrogen or alkyl which are useful as post-emergent herbicides.
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4198345 |
Process for the production of bis-azomethine pigments
A process for the production of a bis-azomethine pigment having the formula ##STR1## in the pigmentary form in which it has an orange red color and, under the conditions defined by the C.I.E....
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4171300 |
Process for the manufacture of metal complex dyes
A process for the manufacture of metal complex dyes, wherein a metallisable dye is reacted with a metal compound in a solvent and in the presence of a hydroxycarboxylate.
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4157265 |
Water-insoluble disazomethine mixed metal-complex compounds, process for preparing them and their use as colorants
New valuable, water-insoluble mixed diaminophenylenedisazomethine-naphthalene metal-complex compounds had been found consisting of two or more metal-complex disazomethine compounds of different...
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