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7598405 |
Method for the distillative processing of tetrahydrofuran
The present invention provides a process for distillatively purifying tetrahydrofuran in the presence of a polar solvent.
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7465816 |
Production of tetrahydrofuran from 1,4-butanediol
Provided is a method for the production of tetrahydrofuran (THF) from 1,4-butanediol (BDO) using a zirconium sulfate (Zr(SO 4 ) 2 .nH 2 O) catalyst. The method of the present invention can achieve...
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7396945 |
Method of preparing tetrahydrofuran
The present invention relates to a process for preparing tetrahydrofuran from 1,4-butandiol. According to the process in the present invention, a metal sulfate catalyst selected from the group...
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7351311 |
Method for purifying tetrahydrofuran by distillation
Crude water-containing tetrahydrofuran is purified by passing the crude tetrahydrofuran through three distillation columns, withdrawing water from the bottom of the first column, recycling...
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7148318 |
Method for producing polytetrahydrofurane having a low color indices
The invention provides a process for preparing polytetrahydrofuran, tetrahydrofuran copolymers, their monoesters or diesters and the monoesters or diesters of polytetrahydrofuran having a low color...
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7098349 |
Method for producing tetrahydrofuran
The invention relates to a process for the continuous preparation of THF by reaction of a 1,4-butanediol-containing reaction mixture over a heteropolyacid catalyst which has not been predried,...
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7019155 |
Hydrogenation of tetrahydroxybutane to tetrahydrofuran
Disclosed is a method for the hydrogenation of tetrahydroxybutane in the presence of supported rhenium catalysts and an acid to form tetrahydrofuran and its precursors.
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6852869 |
Method for the production of polytetrahydrofuran with low color index
In a process for preparing polytetrahydrofuran, tetrahydrofuran copolymers, diesters or monoesters of these polymers having a low color number, the polymers obtained by cationic polymerization of...
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6844452 |
Process for the co-production of aliphatic diols and cyclic ethers
A process for the co-production of a diol product (e.g. butane-1,4-diol) and a cyclic ether (e.g. tetrahydrofuran) by hydrogenation of an aliphatic diester or lactone feedstock (e.g. dimethyl or...
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6700003 |
Process for producing a saturated cyclic ether
A method for producing a saturated cyclic ether from a fatty acid ester of an α, δ-diol stably in high yield over a long period of time, is presented. It is a process for producing a saturated...
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6593481 |
Hydrogenation of 3,4-tetrahydrofurandiol to tetrahydrofuran
Disclosed is a method whereby 3,4-tetrahydrofurandiol is hydrogenated in the presence of Rh, Re, Pd, Ru and Ni catalysts, optionally supported, to form tetrahydrofuran and its precursors.
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6521765 |
Process for the preparation of 3-methyltetrahydrofuran
Disclosed is a process for the preparation of 3-methyltetrahydrofuran (MeTHF) from 3-(hydroxymethyl)tetrahydrofuran (HOMeTHF) by contacting HOMeTHF with hydrogen in the presence of an acidic,...
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6429321 |
Depolymerization of polytetrahydrofuran derivatives
The invention discloses a method for depolymerization of a mixture containing polytetrahydrofuran derivatives, including heating the mixture comprising polytetrahydrofuran derivatives at 100-250°...
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6355814 |
Process for the preparation of 3-hydroxymethyl tetrahydrofuran
The present invention relates to a catalytic process for the preparation of 3-hydroxymethyl tetrahydrofuran of formula IV with hydroformylation as one of the key steps. The process comprises...
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6288245 |
Process for the production of tetrahydrofuran and gammabutyrolactone
A two-stage process for producing tetrahydrofuran and gammabutyrolactone in varying proportions from maleic, succinic anhydride or fumaric acid esters, by vapor phase hydrogenation. The first stage...
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6262280 |
Shilov-type reactions
The functionalization of compounds containing carbon-hydrogen bonds utilizing platinum compounds in Shilov-type reactions is improved by using hydrogen peroxide or selected Pt[IV] compounds as an...
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6204399 |
Process and arrangement for producing tetrahydrofuran
Process and arrangement for producing tetrahydrofuran from a hydrous butane diol solution contaminated by light volatile, organic compounds, comprising the following process stages: a)...
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6201137 |
Process for purifying tetrahydrofurans used as starting material for polyether polyols
Tetrahydrofurans suitable for use as starting materials in the synthesis of polyether polyols without causing coloration in the product polyether polyols can be obtained by contacting crude...
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6169189 |
Process for preparing tetrahydrofuran from dialkoxybutenes
A process for preparing tetrahydrofuran, which comprises reacting 1,4-butenediol diethers of the formulae I and/or II RO--CH 2 --CHCH--CH 2 --OR I RO--CH 2 --CH 2 CH--CH 2 --OR II,...
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6159345 |
Method and apparatus for recovering and/or recycling solvents
A method and apparatus for recycling and recovering potentially explosive solvents includes providing a contaminated solvent to a distillation tank, vaporizing the solvent in the distillation tank,...
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6147233 |
Process for the preparation of 3-methyltetrahydrofuran
Disclosed is a process for the preparation of 3-methyltetrahydrofuran (3-MeTHF) from 3-(hydroxymethyl)tetrahydrofuran (3-HOMeTHF) by a plurality of process steps comprising (1) esterifying...
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6066746 |
Radiation curing of dihydrofuran derivatives
Process for producing coatings or moldings by radiation curing, which involves using high-energy light to irradiate radiation-curable compositions containing 1-100% by weight, based on the total...
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5917061 |
Process for producing cyclic ethers by liquid phase reaction
This invention is directed to a process for producing cyclic ethers by liquid phase reaction, which comprises using a crystalline aluminosilicate zeolite as the catalyst, and subjecting an...
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5874652 |
Process for hydrogenating aqueous aldehyde mixtures
A process for hydrogenating aqueous mixtures of 4-hydroxybutanal and 3-hydroxy-2-methylpropanal is disclosed. The process uses a metallic Pt--Ru catalyst supported on γ-alumina. The process gives...
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5856531 |
Preparation of 3-methytetra-hydrofuran from 2,3-dihydrofuran
Disclosed is a two-step process wherein (1) 2,3-dihydrofuran is reacted with a trialkyl orthoformate in the presence of an acidic catalyst to produce a 2-alkoxy-3-(dialkoxymethyl)tetrahydrofuran...
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5565581 |
Epoxidation of olefins
The present invention relates to the epoxidation of olefins using cyclohexyl hydroperoxide as reactant, the improvement being using a secondary or tertiary alcohol such as cyclohexanol or tertiary...
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5559254 |
Separation of a mixture of methanol and tetrahydrofuran into its constituents
A process is disclosed for separating a mixture of methanol and tetrahydrofuran into its components. The separation is carried out in the liquid or gaseous phase through an organophilic membrane,...
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5319111 |
Preparation of tetrahydrofuran and gamma-butyrolactone
A process for the preparation of tetrahydrofuran or tetrahydrofuran and γ-butyrolactone from the product of the hydrogenation of maleic acid, succinic acid, maleic anhydride, succinic anhydride...
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5166370 |
Preparation of tetrahydrofuran using a supported transition metal
A process for producing tetrahydrofuran, 1,4-butanediol, and 2-methyl-1,3,-propanediol is disclosed. A mixture containing 4-hydroxybutanal and 3-hydroxy-2-methylpropanal is hydrogenated in the...
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5128490 |
Isolation of tetrahydrofuran from mixtures which contain tetrahydrofuran, 1,4-butanediol, gamma-butyro-lactone and succinic acid esters
A process is described for isolating tetrahydrofuran from mixtures containing tetrahydrofuran, 1,4-butanediol, -butyrolactone and succinic acid esters, in which the mixtures are heated to from...
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5099039 |
Production of the from 1,4-butanediol using a polybenzimidazole catalyst
A process for converting 1,4-butanediol to tetrahydrofuran using polybenzimidazole to catalyze the reaction. The conversion is accomplished by heating the 1,4-butanediol in the presence of the PBI....
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5008408 |
Preparation of 1,4-butanediol and tetrahydrofuran
Mixtures which contain 1,4-butanediol and tetrahydrofuran are prepared by heating 4-hydroxybutyraldehyde of the formula ##STR1## at 20°-300° C. in the presence or absence of 1,4-butanediol and...
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4919765 |
Process for the purification of tetrahydrofuran
Tetrahydrofuran is recovered by a two stage distillation procedure from a crude hydrogenation product resulting from vapor phase hydrogenation of diethyl maleate and containing water, ethanol and a...
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4918204 |
Tetrahydrofuran purification
Purification of tetrahydrofuran from the dehydrocyclization of 1,4-butanediol in the presence of an organic acid catalyst has been accomplished by the extractive distillation of crude...
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4912236 |
Purification of tetrahydrofuran by distillation
Crude water-containing tetrahydrofuran is purified by distillation by a process in which the crude tetrahydrofuran is passed through three distillation columns, water being removed from the bottom...
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4904806 |
Preparation of tetrahydrofurans from butane-1,4-diols
Tetrahydrofurans are prepared in the gas phase from butane-1,4-diols which may be substituted by alkyl, alkenyl and/or aryl radicals in the carbon skeleton. The reaction is carried out in the...
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4879420 |
Preparation of mixtures of butanediols
Process for preparing 2-alkyl-1,4-butanediols and mixtures with 1,4-butanediol which comprises bringing together, at an initial alkaline pH, and at a temperature and pressure suitable for reaction,...
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4859801 |
Synthesis of mixtures of butanediols
Process for preparing 2-alkyl-1,4-butanediols and mixtures with 1,4-butanediol which comprises bringing together, at an initial alkaline pH, and at a temperature and pressure suitable for reaction,...
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4665205 |
Process for preparing tetrahydrofuran
A process for preparing tetrahydrofuran which comprises steps of; (i) subjecting 1,4-butanediol to dehydration reaction, and (ii) subjecting the reaction product obtained from the dehydration...
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4590285 |
Process for preparing a mixture of tetrahydrofuran and 3-alkyl tetrahydrofuran and copolymers thereof
A mixture of 1,4-butanediol and 2-alkyl-1,4-butanediol is produced by catalytic hydrogenation and reaction with an aldehyde. Such mixture is cyclized to a mixture of tetrahydrofuran and 3-alkyl...
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4590312 |
Process for preparing 2-alkyl-1,4-butanediols
2-Alkyl-1,4-butanediols are prepared from 1,4-butynediol or 1,4-butenediol by catalytic hydrogenation and reaction with an aldehyde.
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4588827 |
Preparation of tetrahydrofuran
Tetrahydrofuran is prepared from a crude alkaline aqueous solution of butane-1,4-diol, as obtained by reaction of acetylene with aqueous formaldehyde and catylytic hydrogenation of the resulting...
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4536584 |
Process for the thermochemical conversion of biomass
A process is provided for the thermochemical conversion of biomass to useful gaseous and liquid organic products. The inventive process utilizes a catalyst to obtain increased yields of gaseous and...
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4474973 |
Acidic mixed oxide catalytic dealkylation to produce 1,4-butanediol and tetrahydrofuran
A coproduct continuous dealkylation process is described in which 4-t-butoxy-n-butanol is contacted with acidic silica-alumina catalyst at temperatures in the 160°-200° C. range (reactor wall...
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4413136 |
Purification of tetrahydrofuran
The amount of methacrolein impurity in tetrahydrofuran made from acetylene and formaldehyde can be significantly reduced by treating it with hydrogen peroxide during an interval in the multi-stage...
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4387236 |
Liquid phase oxidation
A process of removing solids from an aqueous redox catalyst system which solids are formed in the production of furan compounds from butadiene or a butadiene derivative by heating at 180°-280° C....
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4380657 |
Conversion of alkanols to ethers
Alkanols are converted to ethers by contact at temperature of 150° C.-550° C. with a novel siliceous composition prepared by impregnating porous silica with aluminum hydride and subsequently...
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4363924 |
Depolymerization of polytetramethylene glycol ethers
A process for depolymerizing polytetramethylene glycol ethers, wherein the latter are heated at from 90° to 180° C. in the presence of a bleaching earth.
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4288369 |
Production of cyclic ethers
A process for the preparation of cyclic ethers which comprises reacting an alkanediol in which the hydroxyl groups are separated by a chain of at least four carbon atoms in the liquid phase of a...
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4287127 |
Production of tetrahydrofuran
Tetrahydrofuran is produced by converting allyl alcohol to an allyl t-alkyl or -cycloalkyl ether of the general formula: ##STR1## wherein R 1 and R 2 each, independently of the other, represent a...
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