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RE39794 |
Process for the simultaneous production of maleic anhydride and its hydrogenated derivatives
A process is described for the co-production of maleic anhydride and at least one C 4 compound selected from butane-1,4-diol, γ-butyrolactone, and tetrahydrofuran in which maleic anhydride is...
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6989454 |
Method for producing maleic anhydride
A process for preparing maleic anhydride by heterogeneously catalyzed gas-phase oxidation of an n-butene-containing hydrocarbon stream by means of oxygen-containing gases in a shell-and-tube...
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6960670 |
Method for production of maleic anhydride
This invention discloses a method for producing maleic anhydride comprising an azeotropic distillation step to dehydrate a crude maleic acid-containing aqueous solution, which method is...
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6956004 |
Vanadium/phosphorus mixed oxide catalyst
Active vanadium/phosphorus mixed oxide catalyst for the conversion of non-aromatic hydrocarbons, e.g., n-butane, into maleic anhydride. The catalyst is prepared from the catalyst precursor, that...
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6921830 |
Method for purifying an organic solvent for the purposes of absorption of maleic acid anhydride
In a process for purifying an organic solvent for the absorption of maleic anhydride from a gaseous mixture, in which the maleic anhydride is separated off from the solvent, a substream is taken...
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6657097 |
Fluidized bed reactor
Disclosed is a fluidized bed reactor wherein the average cross-sectional area occupied by a cooling coil, a dummy pipe and/or a cyclone leg is 10% or more of the average cross-sectional area of...
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6652823 |
Process for the synthesis of VPO catalysts
Process for the preparation of a vanadium phosphate catalyst comprising treatment of a vanadium compound with formic acid, water and a phosphorus compound.
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6602476 |
Apparatus and process for heat exchange with fluid beds
Apparatus and process for heat exchange with fluid beds comprises heat-exchange tubes located longitudinally with respect to the axis of a fluidization zone with a rectangular pitch, one side of...
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6590071 |
Reversible aqueous pH sensitive lipidizing reagents, compositions and methods of use
The present invention provides lipidized conjugates comprising an amino group-containing biologically active substance and a lipophilic group capable of penetrating a biological membrane. Under...
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6344568 |
Catalyst for gas phase partial oxidation
This invention relates to a method for producing a partially oxidized organic compound, e.g., an unsaturated aldehyde/carboxylic acid having three or more carbon atoms, or an organic acid...
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6329532 |
Method for separating maleic anhydride from maleic anhydride-containing mixtures by stripping
The invention relates to a process for the separation of maleic anhydride from the maleic anhydride-containing reactor offgases from the preparation of maleic anhydride by the oxidation of...
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6093835 |
Process for producing maleic anhydride
A process for producing maleic anhydride is described, which comprises (i) reacting a hydrocarbon with oxygen in a vapor phase in the presence of a catalyst to yield a reaction mixture gas...
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6040460 |
High productivity process to produce maleic anhydride from n-butane
In producing maleic anhydride by catalytic oxidation of n-butane in vapor phase using oxygen or enriched air as oxidation medium, the reaction mixture consists of butane, oxygen and a recycling...
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6018057 |
Process for producing acid anhydrides
A process for producing anhydrides by passing a solution of the acid, preferably an organic polyacid, which is to undergo anhydridation over an acidified clay and a process for producing the...
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5973166 |
Method for the preparation of maleimides
In accordance with the present invention, there are provided improved methods for the preparation of maleimide monomers. This new method for the synthesis of maleimides is clearly superior to those...
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5942628 |
Method for the preparation of sulfo-N-hydroxy succinimade salts
The salt of a sulfonated succinic acid is cyclized, then converted to novel sulfonated hydroxamic acids by reaction with hydroxylamine (which is added or formed in situ), and the novel hydroxamic...
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5929255 |
Process for coproducing fumaric acid and maleic anhydride
The present invention provides a process for recovering fumaric acid formed as a by-product during the production of maleic anhydride so that both fumaric acid and maleic anhydride are obtained....
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5892057 |
Preparation of sulfo-N-hydroxysuccinimide salts
The salt of a sulfonated succinic acid is cyclized, then converted to novel sulfonated hydroxamic acids by reaction with hydroxylamine (which is added or formed in situ), and the novel hydroxamic...
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5731443 |
Liquid phthalic anhydride recovery process using a rectification tower
A process for recovering phthalic anhydride as a liquid from a vapor phase oxidation product which comprises mixing the vapor phase oxidation product having a temperature in the range of about...
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5688970 |
Process to recycle exhaust gases from n-butane conversion into maleic anhydride
In producing maleic anhydride by catalytic oxidation of butane in vapor phase, the reaction mixture consists of butane and a recycle gaseous current made of compressed air and exhaust gas recovered...
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5670660 |
Process for collecting airborne anhydrides
An apparatus and process for the recovery of airborne anhydrides such as anhydride vapor or dust wherein these airborne anhydrides are contacted with hot glycol, such as diethylene glycol, in the...
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5670659 |
Preparation of citraconic anhydride
Citraconic anhydride is prepared in a single step by heating itaconic acid, optionally in an inert organic solvent medium, in the presence of a catalytically effective amount of an at least...
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5631387 |
Process for the preparation and recovery of maleic anhydride
An improved process for the preparation and recovery of maleic anhydride in which the recovery of maleic anhydride from a gaseous reaction mixture includes absorbing the maleic anhydride in a...
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5591870 |
Process for producing a vanadium-phosphorus oxide catalyst precursor
A process for producing a vanadium-phosphorus oxide-containing catalyst precursor, which comprises (a) introducing into an organic solvent a vanadium alkoxide as a pentavalent vanadium compound and...
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5585502 |
Process and plant for the purification of raw maleic anhydride recovered from gaseous reaction mixtures
In the purification of maleic anhydride obtained with an oxidation process, by means of absorption with an organic solvent and fractionation of the resulting liquid phase and purification of the...
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5532384 |
Process for producing hydrocarbon partial oxidation products
Hydrocarbon derivatives are produced by contacting a hydrocarbon with oxygen obtained from an air separation unit in the presence of a partial oxidation reaction catalyst. After separation of the...
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5530144 |
Process for producing a phosphorus-vanadium oxide catalyst precursor, process for producing a phosphorus-vanadium oxide catalyst, and process for producing maleic anhydride by vapor phase oxidation using the catalyst
A process for producing a precursor of a phosphorus-vanadium oxide catalyst for production of maleic anhydride by vapor phase oxidation of a hydrocarbon having 4 carbon atoms, which comprises...
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5520891 |
Cross-flow, fixed-bed catalytic reactor
Disclosed are a fixed-bed, cross-flow catalytic reactor wherein reaction heat can be exchanged against a heat exchange medium circulating indirectly through the catalyst bed, and a catalytic...
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5449792 |
Method for the production of maleic anhydride
A method for the production of maleic anhydride in which a hydrocarbon of 4 to 6 carbon atoms is subjected to a vapor phase catalytic oxidation reaction in the presence of a metal oxide catalyst,...
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5430181 |
Process for improving a controlled oxidation reaction
Process for improving a controlled oxidation reaction between at least one reactant and oxygen, in which at least one reactant is reacted with oxygen or an oxygen containing gas, constituting a...
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5360603 |
Packed bed arrangement useful for mixing and/or oxidation
The present invention relates to processes and apparatus for mixing oxidizable reactants with oxidant and/or oxidizing oxidizable reactants. Through using particular mixing and/or oxidizing...
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5319106 |
Stabilization of mixtures of maleic anhydride and acrylic acid during distillation
In the production of maleic anhydride, a crude maleic anhydride is produced which contains acrylic acid and other by-products. The crude maleic anhydride is dissolved in a solvent and the acrylic...
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5266291 |
Packed bed arrangement for oxidation reaction system
The present invention relates to processes and apparatus for mixing oxidizable reactants with oxidant and oxidizing oxidizable reactants. When ammonia is used as the reactant, nitric acid can be...
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5262548 |
Phosphorous/vanadium oxidation catalyst
An improvement in the oxidation catalyst used for the partial oxidation of n-butane and containing vanadium and phosphorus, zinc and lithium mixed oxides which comprises adding a molybdenum...
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5262547 |
Process for the production of petrochemicals
Petrochemicals are produced by the vapor phase reaction of a hydrocarbon with substantially pure oxygen in the presence of a suitable catalyst. In the improved process, the principal product is...
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5260456 |
Process for producing itaconic anhydride
A process for producing anhydrides by passing a solution of the acid, preferably an organic polyacid, which is to undergo anhydridation over an acidified clay and a process for producing the...
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5252752 |
Process for the production of carboxylic anhydrides
A process for the production of carboxylic anhydrides from aromatic hydrocarbons in gas phase oxidation by using a high activity and high selectivity fluid catalyst, comprising 50 to 95% by weight...
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5245093 |
Reaction processes in a multi-stage fluidized bed
A process for reacting a fluid phase (gaseous and/or liquid phase) in contact with a solid phase in a reaction zone, wherein the improvement in said process comprises reacting the fluid phase in...
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5185455 |
Method for improving the performance of VPO catalysts
An improvement in a process for the manufacture of maleic anhydride by catalytic oxidation of n-butane in the presence of trimethyl phosphate over a fixed bed vanadium phosphorus oxide catalyst in...
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5157130 |
Method of preventing discoloring of maleic anhydride
A monochloro-substituted aliphatic alcohol containing 3-8 carbon atoms, a copper compound and a zinc compound are added to maleic anhydride to prevent discoloration of the maleic anhydride....
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5155235 |
Catalyst for producing maleic anhydride from butane and process for preparing same
A catalyst for producing maleic anhydride by oxidation of n-butane comprising V,P and additionally Mg or Zr is prepared by (a) heating a pentavalent vanadium compound in an organic medium to...
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5126463 |
Process for the production of anhydrides
This invention provides a process for the production of an anhydride by the vapor phase reaction of a hydrocarbon with substantially pure oxygen in the presence of a suitable catalyst. In the...
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5069687 |
Process of recovery of maleic anhydride from reaction gaseous mixtures
Process for the recovery of maleic anhydride from a gaseous mixture thereof, in which the gaseous mixture containing maleic anhydride is contacted with an absorbant for the maleic anhydride to give...
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5059697 |
Preparation of halogenated phthalic anhydrides
A process for the aromatization of 4-chlorotetrahydrophthalic anhydride and 4,5-dichlorotetrahydrophthalic anhydride which comprises heating a solution of either substance in the presence of...
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5026876 |
Process for producing maleic anhydride
Crude maleic anhydride produced by catalytic oxidation is distilled and then n-propyl gallate, cuprous chloride and zinc chloride are added thereto. Alternatively, crude maleic anhydride is...
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5019545 |
Process for manufacture of maleic anhydride catalysts
Novel maleic anhydride catalysts comprising phosphorus-vanadium oxides and phosphorus-vanadium-co-metal oxides wherein said catalysts do not expand under reaction conditions for the manufacture of...
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4968818 |
Gamma-butyrolactone production process and catalyst therefor
A catalytic hydrogenation process for converting maleic anhydride and/or succinic anhydride to gamma-butyrolactone, a novel selective catalyst for use in such process and a method of preparing the...
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4961827 |
Obtaining very pure maleic anhydride from crude maleic anhydride
Very pure maleic anhydride having a stable color is obtained by fractional distillation of crude maleic anhydride by a method in which the maleic anhydride vapor separated off from low boilers and...
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4941895 |
Process for the continuous separation of maleic anhydride from process gases
A process is disclosed for increasing the recovery of maleic anhydride from the product condenser. Maleic anhydride is added to the oxidation reactor gaseous effluent. Maleic acid buildup in the...
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4921977 |
Obtaining maleic anhydride not prone to discolor
Process for obtaining maleic anhydride that is not prone to discolor by treating crude maleic anhydride with oxygen, a gas mixture containing oxygen, or a substance that releases oxygen before or...
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