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7619099 |
Reduction of acrylic acid in the production of maleic anhydride
An improved process for the production of maleic anhydride by the catalytic oxidation of n-butane. Maleic anhydride is produced by reacting n-butane gas with oxygen gas or an oxygen-containing gas,...
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7589217 |
Yield improvement in the production of maleic anhydride
An improved process for the production of maleic anhydride by the catalytic oxidation of n-butane. Maleic anhydride is produced by reacting n-butane gas with oxygen or an oxygen-containing gas, in...
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7345167 |
Method for the production of maleic anhydride
A process for preparing maleic anhydride by oxidizing n-butane in the gas phase under heterogeneous catalysis with oxygen-containing gases over a vanadium-, phosphorus- and oxygen-containing...
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7198845 |
Shaped trilobal particles
An elongate, shaped particle having three protrusions each extending from and attached to a central position aligned along the central longitudinal axis of the particle, the cross-section of the...
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7157403 |
Catalyst-precursor for the production of maleic acid anhydride and method for the production thereof
A process for preparing a vanadium, phosphorus, and oxygen catalyst precursor for preparing maleic anhydride by heterogeneously catalyzed gas-phase oxidation of a hydrocarbon having at least four...
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7087767 |
Method for producing maleic anhydride
Process for preparing maleic anhydride by heterogeneously catalyzed gas-phase oxidation of hydrocarbons having at least four carbon atoms by means of oxygen-containing gases at from 350 to 500° C....
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6956004 |
Vanadium/phosphorus mixed oxide catalyst
Active vanadium/phosphorus mixed oxide catalyst for the conversion of non-aromatic hydrocarbons, e.g., n-butane, into maleic anhydride. The catalyst is prepared from the catalyst precursor, that...
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6921830 |
Method for purifying an organic solvent for the purposes of absorption of maleic acid anhydride
In a process for purifying an organic solvent for the absorption of maleic anhydride from a gaseous mixture, in which the maleic anhydride is separated off from the solvent, a substream is taken...
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6812351 |
Hollow cylindrical catalyst and a method for producing a maleic acid anhydride
A catalyst used in a process for preparing maleic anhydride by heterogeneously catalyzed gas-phase oxidation of a hydrocarbon having at least four carbon atoms by means of oxygen-containing gases...
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6803473 |
Method for producing maleic acid anhydride
In a process for preparing maleic anhydride by heterogeneously catalyzed gas-phase oxidation of hydrocarbons having at least four carbon atoms using oxygen-containing gases in the presence of a...
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6624315 |
Method of gas phase catalytic oxidation to give maleic acid anhydride
A process for the preparation of maleic anhydride by heterogeneously catalyzed gas-phase oxidation in a reactor with feed for the reaction mixture at one end of the reactor and discharge of the...
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6620948 |
Process for the preparation of maleic anhydride
Disclosed is a process for the production of maleic anhydride, which comprises: reacting a hydrocarbon with an oxygen-containing gas in the presence of a catalyst; recovering maleic anhydride from...
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6613949 |
Oxygen enrichment process for air based gas phase oxidations which use metal oxide redox catalysts
This invention is directed towards an improved process for the selective gas phase oxidation of a organic reactant using a metal oxide redox catalyst, wherein the organic reactant and air feeds are...
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6458971 |
Process for the production of maleic anhydride
Disclosed is a process for the preparation of maleic anhydride which comprises subjecting an aliphatic hydrocarbon having four or more carbon atoms to gas phase oxidation reaction in the presence...
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6417376 |
Selective oxidation process and catalyst therefor
A process for selectively oxidizing an organic molecule by reacting said organic molecule and oxygen in the presence of a selective oxidation catalyst supported on a mesh-like structure.
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6310219 |
Process for the production of maleic anhydride
Disclosed is a process for the production of maleic anhydride, which comprises: reacting a hydrocarbon with an oxygen-containing gas in the presence of a catalyst; recovering maleic anhydride from...
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6300505 |
Method and apparatus for improving the uniformity of distribution of a phosphorus-containing agent throughout a maleic anhydride catalytic reactor
Improved methods and apparatus for the preparation of maleic anhydride by reacting a hydrocarbon having at least four carbon atoms in a straight chain with molecular oxygen in a catalytic reactor,...
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6291686 |
Exothermic process
An exothermic oxidation process wherein a rotating bed containing a variable oxidation state material is cycled through a succession of stages including an oxidative regeneration stage including a...
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6194588 |
Method for production of maleic anhydride
In the production of maleic anhydride by the contact of a raw material gas containing an aliphatic hydrocarbon of not less than 4 carbon atoms and molecular oxygen with a vanadium-phosphorus oxide...
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6194587 |
Production of maleic anhydride
N-butane and molecular oxygen are reacted in a first reactor to form maleic anhydride, the produced maleic anhydride is scrubbed to separate maleic anhydride values, n-butane is added to the...
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6093835 |
Process for producing maleic anhydride
A process for producing maleic anhydride is described, which comprises (i) reacting a hydrocarbon with oxygen in a vapor phase in the presence of a catalyst to yield a reaction mixture gas...
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6048987 |
Process for producing coated catalysts for the synthesis of maleic anhydride by gas-phase oxidation
There is a process for producing coated catalysts for the gas-phase oxidation of C 4 hydrocarbons to maleic anhydride. A vanadyl phosphate catalyst precursor is prepared having a V/P ratio of from...
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6046343 |
Prevention of catalyst attrition and tar formation in manufacture of maleic anhydride
Improved methods and apparatus for manufacture of maleic anhydride by catalytic oxidation of n-butane or other hydrocarbon having four carbon atoms in a straight chain over a fixed catalyst bed...
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6005121 |
High productivity process for the production of maleic anhydride
An improved process for the manufacture of maleic anhydride by catalytic oxidation of a nonaromatic hydrocarbon having at least four carbon atoms in a straight chain, in which a gas containing...
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6002019 |
Process for the production of petrochemicals
Petrochemicals are produced by the vapor phase reaction of a hydrocarbon with air in the presence of a suitable catalyst. The petrochemical product is removed from the product gas stream, and part...
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5986110 |
Process for the selective oxidation of hydrocarbons
The invention relates to a heterogeneous vanadium-phosphorus oxide catalyst system for the selective oxidation of hydrocarbons, which may or may not be saturated, comprising a support based on one...
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5959124 |
Method of preparing maleic anhydride by vapor phase oxidation of hydrocarbon
A vanadium-phosphorus oxide having an X-ray diffraction spectrum (Cu--Kα) showing main peaks of the diffraction angle 2θ(±0.2°) at 18.5°, 23.0°, 28.4°, 29.9°, and 43.1° and having the...
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5932746 |
Vanadium catalysts and their precursors
Readily processible cluster compositions of vanadium and phosphorus are precursors to vanadium-phosphorus catalysts including vanadyl pyrophosphate and vanadylbis(metaphosphate).
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5895821 |
Process for the calcination/activation of V/P/O catalyst
An improved process for calcination and activation of a catalyst containing mixed oxides of vanadium and phosphorus (V/P/O) involving the addition of spray dried catalyst precursor to a fluidizing...
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5869700 |
Method for recovering phthalic anhydride/maleic anhydride mixtures by distillation
A process for recovering phthalic anhydride and maleic anhydride from a maleic anhydride-rich vapor phase oxidation product comprising the step of: contacting the vapor phase oxidation product...
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5847163 |
Process for the transformation of a vanadium/phosphorus mixed oxide catalyst precursor into the active catalyst for the production of maleic anhydride
A vanadium/phosphorus mixed oxide catalyst precursor is transformed into the active catalyst for the production of maleic anhydride. The activation takes place in a fluidized bed and includes the...
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5734066 |
Supression of autoignition in maleic anhydride production
An improved process for the manufacture of maleic anhydride by catalytic oxidation of n-butane in which the feed flow channel to the catalytic reactor contains an autoignition suppression agent...
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5726327 |
Process for the production of petrochemicals
Petrochemicals are produced by the vapor phase reaction of a hydrocarbon with air in the presence of a suitable catalyst. The petrochemical product is removed from the product gas stream, and...
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5707917 |
Catalyst for the selective oxidation of hydrocarbons
The invention relates to a heterogeneous vanadium-phosphorus oxide catalyst system for the selective oxidation of hydrocarbons, which may or may not be saturated, comprising a support based on one...
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5631387 |
Process for the preparation and recovery of maleic anhydride
An improved process for the preparation and recovery of maleic anhydride in which the recovery of maleic anhydride from a gaseous reaction mixture includes absorbing the maleic anhydride in a...
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5591870 |
Process for producing a vanadium-phosphorus oxide catalyst precursor
A process for producing a vanadium-phosphorus oxide-containing catalyst precursor, which comprises (a) introducing into an organic solvent a vanadium alkoxide as a pentavalent vanadium compound and...
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5550308 |
Vanadium (IV)-containing nasicon materials
The present invention provides a composition of matter having the formula A x B 1 -x V y C 1 -y P 3 O 10 -15 wherein A is Nb or Ta, B is Sb, C is Ti or Sn, and 0≤x,y≤1, a composition of...
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5532385 |
Catalytic process for the production of maleic anhydride
The invention relates to vanadium/phosphorus oxide catalyst precursors useful in preparing catalysts useful in the oxidation of hydrocarbons containing 4 carbon atoms to maleic anhydride.
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5530144 |
Process for producing a phosphorus-vanadium oxide catalyst precursor, process for producing a phosphorus-vanadium oxide catalyst, and process for producing maleic anhydride by vapor phase oxidation using the catalyst
A process for producing a precursor of a phosphorus-vanadium oxide catalyst for production of maleic anhydride by vapor phase oxidation of a hydrocarbon having 4 carbon atoms, which comprises...
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5521134 |
Method for regenerating vanadium/phosphorus oxidation catalysts
A method of regenerating V/P/O oxidation catalyst used for the partial oxidation of n-butane which comprises terminating the n-butane feed and contacting the catalyst with an oxygen containing gas,...
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5519149 |
Vapor phase catalytic oxidation of N-butane to maleic anhydride incorporating in situ catalyst calcination/activation
An improved process for selective vapor phase oxidation of n-butane to maleic anhydride involving the use of a recirculating solids reactor having a reaction zone and a catalyst regeneration zone...
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5510308 |
Cation and vanadium substituted heteropolyacid catalysts for vapor phase oxidation
This invention relates to heteropolyacids characterized by their comprising phosphorus as the heteroatom and molybdenum and/or tungsten at octahedral sites, some of the molybdenum and/or tungsten...
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5498731 |
Oxide catalyst and process for producing maleic anhydride by using oxide catalyst
An oxide catalyst for producing maleic anhydride by vapor phase oxidation of a hydrocarbon having 4 carbon atoms, obtainable by (1) reacting a pentavalent vanadium compound and a pentavalent...
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5401707 |
Vanadium/phosphorus oxide oxidation catalyst
A vanadium/phosphorus oxide oxidation catalyst suitable for catalytic oxidation of C 4 feed stock in the preparation of maleic anhydride is formed by calcining an intercalation complex of the...
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5364824 |
Catalysis for the production of maleic anhydride containing vanadium-phosphorus oxide with selected promoter elements
A phosphorus vanadium oxide catalyst for the oxidation of a C 4 hydrocarbon. The catalyst comprises a shaped body having a volume, or a fixed bed comprising shaped bodies having an average volume,...
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5360916 |
Two stage butane haleic anhydride process
Butane is oxidized with molecular oxygen in a dilute state by bringing a mixture of vaporized butane and air of controlled butane content into the presence of a contact vanadium-phosphorus-oxygen...
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5326886 |
Maintaining VPO catalyst performance by aluminizing reactor internals in oxidation of butane to maleic anhydride
Catalysts comprising a compound of vanadium, phosphorus and oxygen which are employed in the oxidation of n-butane to maleic anhydride are protected from contamination caused by side reactions...
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5296436 |
Phosphorous/vanadium oxidation catalyst
An improvement in the oxidation catalyst used for the partial oxidation of n-butane and containing vanadium and phosphorus, zinc, lithium and molybdenum mixed oxides which comprises adding the...
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5262548 |
Phosphorous/vanadium oxidation catalyst
An improvement in the oxidation catalyst used for the partial oxidation of n-butane and containing vanadium and phosphorus, zinc and lithium mixed oxides which comprises adding a molybdenum...
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5235071 |
Catalyst for producing phthalic anhydride and process by using the same
The invention relates to a catalyst for producing phthalic anhydride by gas phase catalytic oxidation of o-xylene and/or naphthalene with molecular oxygen or gas containing molecular oxygen and, to...
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