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7384518 |
Method for purifying lactams
A method and a plant are disclosed for purifying lactams, particularly lactams obtained by cyclizing hydrolysis of aminonitrile. The purification of ε-caprolactam obtained by cyclizing hydrolysis...
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6841709 |
Method of cutting polymer chains and method for producing chemical raw materials
The present invention is to provide a technology to establish a new cycle-based organic chemical industry, which may be called a polymer cascade (polymer reflux industry) wherein the polymer...
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6838577 |
Processes for the manufacture of lactones
Processes are disclosed for the manufacture of lactones, e.g., caprolactone, from hydoxy acids, e.g., 6-hydroxycaproic acid. The reaction is conducted over a suitable catalyst in the presence of...
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6828413 |
Process for the preparation of a polyamide
The invention relates to a process for the preparation of a polyamide comprising at least a step in which a composition that comprises at least (a) a primary aminocarbonamide and (b) an...
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6660857 |
Process for the preparation of &egr -caprolactam
A process for the preparation of ε-caprolactam starting from 6-aminocaproic acid, 6-aminocaproamide, 6-aminocaproic ester, 6-aminocapronitrile, oligomers or polymers of these compounds or mixtures...
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6632964 |
Process for production of aliphatic aldehyde-acid and/or aliphatic dicarboxylic acid and catalyst for the production
A process of producing an aliphatic aldehyde-acid (e.g., adipaldehyde-acid) and/or an aliphatic dicarboxylic acid (e.g., adipic acid) comprising oxidizing a cyclic ketone (e.g., cyclohexanone) with...
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6521752 |
Process to separate linear alkyl 5-formylvalerate
The invention relates to a process to separate linear 5-formylvalerate compound from a crude mixture comprising 5-formylvalerate compound and 2-, 3- and/or 4-formylvalerate compound by vacuum...
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6452002 |
Process to continuously prepare an aqueous mixture of &egr -caprolactam and &egr -caprolactam precursors
Process for preparing an aqueous mixture of ε-caprolactam and 6-aminocaproic acid and/or 6-aminocaproamide which involves, as the reductive amination step, contacting 5-formylvaleric acid and/or...
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6362332 |
Coproduction of a cyclic lactam and a cyclic amine
A cyclic lactam and a cyclic amine are coproduced by reacting an aliphatic alpha, omega-diamine with water in the gas phase in the presence of a heterogeneous catalyst.
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6353100 |
Process for the preparation of &egr -caprolactam
Process for the preparation of ε-caprolactam, in which in a step (a) a compound with the general formula: O=CH—(CH 2 ) 4 —C(O)—R ( 1 ) in which R is —OH, —NH 2 or O—R′, in which...
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6333412 |
Process for the preparation of ε-caprolactam
Process to prepare ε-caprolactam starting from a starting mixture containing a 6-aminocaproate ester, in which in a first step (1) the 6-aminocaproate ester is converted into 6-aminocaproic acid...
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6331624 |
Process for preparing 6-aminocaproamide
A process for the production of 6-aminocaproamide comprising reacting 5-cyanovaleramide with hydrogen in the presence of a metal catalyst. The 6-aminocaproamide is useful, for example, in the...
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6303837 |
Process for synthesizing α-substituted ring systems
Using the process according to the invention, it is possible to provide, with few reaction steps, a novel route to α-substituted ring systems, which optionally have further substituents.
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6300496 |
Processes for producing epsilon caprolactams
This invention relates in part to processes for producing one or more substituted or unsubstituted epsilon caprolactams, e.g., epsilon caprolactam, which comprise (a) converting one or more...
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6268530 |
Process to prepare 5-formylvaleric acid
Process to separate linear 5-formylvaleric acid from a mixture of 5- and 3- and 4-formylvaleric acids, wherein the separation is performed by fractional extraction with two immiscible solvents of...
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6204379 |
Preparation of caprolactam
The present invention concerns the aminomethylation of pentenoic acid derivatives, by reaction with carbon monoxide, hydrogen and ammonia, for preparing caprolactam. More precisely, it is directed...
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6194572 |
Process to prepare ε-caprolactam
Process to prepare ε-caprolactam by treating 6-aminocaproic acid, 6-aminocaproate ester or 6-aminocaproamide or mixtures comprising at least two of these compounds in the presence of superheated...
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6147208 |
Process for simultaneously preparing caprolactam and hexamethylene diamine
Caprolactam and hexamethylenediamine are prepared simultaneously starting from adiponitrile.
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6013816 |
Process for the preparation of a linear formyl compound
Process for the preparation of a linear ω-formyl-carboxylic acid or a corresponding linear formylnitrile compound starting from an internally unsaturated C 4 -C 12 carboxylic acid or a...
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6011153 |
Process for the preparation of a mixture of ε-caprolactam, 6-aminocaproic acid and 6-aminocaproic amide
Process for the preparation of a mixture of ε-caprolactam, 6-aminocaproic acid and 6-aminocaproic amide by heating an aqueous mixture containing ammonia and oligomers of 6-aminocaproic acid and/or...
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5977356 |
Process for preparing caprolactam
A simple and single step process for producing caprolactam comprising reacting 5-formylvaleric acid or an ester thereof in a solvent of water and/or an alcohol with hydrogen and ammonia in the...
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5973143 |
Process to prepare ε-caprolactam from 6-aminocaproic acid
Process to prepare ε-caprolactam starting from a liquid aqueous mixture containing an alcohol and 6-aminocaproic acid by cyclization of 6-aminocaproic acid in the aqueous mixture at an elevated...
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5962680 |
Processes for producing epsilon caprolactams
This invention relates in part to processes for producing one or more substituted or unsubstituted epsilon caprolactams, e.g., epsilon caprolactam, which comprises: (a) subjecting one or more...
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5922863 |
Diene cyclization using ruthenium and osmium carbene complexes
Disclosed are ruthenium and osmium carbene compounds which are stable in the presence of a variety of functional groups and which can be used to catalyze olefin metathesis reactions on unstrained...
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5877314 |
Process to continuously prepare an aqueous mixture of episilon caprolactum and episilon caprolactum precursors
This continuous process for preparing an aqueous mixture of .di-elect cons.-caprolactam and 6-aminocaproic acid and/or 6-aminocaproamide by involves, as the reductive amination step, continuously...
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5717090 |
Simultaneous preparation of caprolactam and hexamethylenediamine
Caprolactam and hexamethylenediamine are prepared simultaneously starting from adiponitrile by a process in which (a) adiponitrile is partially hydrogenated to give a mixture containing...
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5717089 |
Process for the preparation of E-caprolactam
Process for the preparation of ε-caprolactam starting from an aldehyde compound comprising at least one member from among 5-formylvaleric acid, ester or amide in which the aldehyde compound is...
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5700934 |
Process for the preparation of epsilon-caprolactam and epsilon-caprolactam precursors
A process for the preparation of ε-caprolactam and ε-caprolactam precursors, starting from the corresponding 5-formylvalerate ester, ammonia and hydrogen in the presence of a hydrogenation...
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5652362 |
Preparation of caprolactam
A method of making caprolactam from aminohexanoic acid or aminohexanoate ester comprising the steps of: (a) obtaining a reactor containing at least one catalyst, the catalyst being a metal oxide...
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5502185 |
Preparation of lactams
Cyclic lactams are prepared by reacting an aminocarboxylic acid compound of the formula I H 2 N--(CH 2 ) m --COR 1 I where R 1 is --OH, --O--C 1 -C 12 -alkyl or --NR 2 R...
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5395974 |
Lewis acid catalyzed ammonolysis of nylon
The present invention relates to a method of reacting polyamides or mixtures thereof with ammonia to obtain a mixture of monomers. The reaction is carried out in the presence of certain Lewis Acid...
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5310905 |
Conversion of nylon 6 and/or nylon 6,6 to monomers
Waste nylon 6 and/or nylon 6,6 are treated with aliphatic monocarboxylic acid to depolymerize the polymer to desirable monomer.
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5302756 |
Ammonolysis of nylon
Useful monomeric products are obtained in the reaction of nylon 6,6 with ammonia. Increased yield of monomer products from nylon 6,6 is obtained from ammonolysis when a mixture with nylon 6 is...
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5276165 |
Preparation of N-substituted lactams
A process for the preparation of N-substituted lactams of the formula I ##STR1## where Z is C 2 - to C 10 -alkylene, C 7 - to C 12 -aralkylene, phenylene or naphthylene, and R 1 is C 1 -...
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4963673 |
Preparation of caprolactam
Caprolactam is prepared by heating a 6-aminocaproic ester in liquid phase in the presence of water to 230°-350° C. under superatmospheric pressure in a reaction medium comprising a liquid...
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4873326 |
Process for the preparation of N-alkylated caprolactams
This invention relates to a process for the preparation of N-alkylated caprolactams by the cyclization of N-alkylated caproic acids.
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4873325 |
Process for the production of amides
Oximes can be converted to the corresponding amides by contacting the oximes with a non-zeolitic molecular sieve, which has in its calcined form an adsorption of isobutane of at least about 2...
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4870173 |
Lactam formation by a selective cyclization process
This invention provides a process for preparing lactams, by selectively reacting a novel 1-hydrocarbyl-amino (or heteroatom-substituted hydrocarbylamino); 1,1-dicarboxylic acid, alkylesters;...
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4800227 |
Process for the production of lactams
A one-step method for the reductive amination of a heterocyclic to produce a nitrogen-containing heterocyclic. The feedstock is contacted with a mixed metal catalyst in which the metal comprises...
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4731445 |
Preparation of epsilon-caprolactam
Caprolactam is prepared by a process in which (a) the 5-formylvalerate is reacted with excess ammonia and hydrogen in the presence of an alkanol as the solvent and in the presence of a...
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4730041 |
Preparation of ε-caprolactams
Caprolactam is prepared by a process in which (a) a 5-formylvalerate is reacted with excess ammonia and hydrogen in the presence of an alkanol as a solvent and in the presence of a hydrogenation...
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4730040 |
Preparation of caprolactam
ε-caprolactam is prepared by a process in which (a) a 5-formylvalerate is reacted with water in the presence of an acidic agent at from 30° to 200° C., (b) the 5-formylvaleric acid thus...
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4605762 |
Depolymerization of condensation polymers
A process for the neutral hydrolytic depolymerization of condensation polymers is described. The process is conducted in a continuous manner and comprises introducing condensation polymer waste...
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4599199 |
Obtaining caprolactam from epsilon-aminocaproic acid
Caprolactam is obtained by treating ε-aminocaproic acid with steam at elevated temperatures in the presence of a catalyst by a process in whcih ε-aminocaproic acid is introduced into a fluidized...
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4329498 |
Preparation of 6-aminocaproic acid via muconic acid mononitrile
Phenol, catechol and orthobenzoquinone are converted to muconic acid mononitrile by reaction with a copper(II)-ammonia reagent. The copper(II)-ammonia reagents can be prepared by the reaction of...
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3988319 |
Process for producing caprolactam from 6-aminocaproic acid
Caprolactam is obtained in high yield and in short reaction time by completely dissolving 6-aminocaproic acid in methanol or ethanol and heating the solution at 170°-200° C.
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3857510 |
KETONE CLEAVAGE AND PRODUCTS THEREFROM
A method of cleaving ketones at a carbon-carbon bond adjacent to the ketonic carbon to produce a terminal carboxylic ester and a terminal oxime group, which comprises, nitrosating the ketone in the...
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3485821 |
PROCESS FOR PREPARING CAPROLACTAM AND ITS ALKYL SUBSTITUTED DERIVATIVES
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3360514 |
Process for preparing epsiloncaprolactams
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3337585 |
Process for making pyrrolidones and piperidones
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