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7399855 |
Synthesis of caprolactam from lysine
In various embodiments, the present invention can involve a method of synthesizing α-amino-ε-caprolactam. The method can comprise heating a salt of L-lysine in a solvent comprising an alcohol. In...
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7015320 |
Process for the manufacture of optically active 3-substituted lactams by asymmetric hydrogenation of 3-alkylidenelactams
The present invention relates generally to processes for the efficient production optically active 3-substituted lactams of formula (I)
process, comprising:
contacting a compound of formula...
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6673920 |
Method for the production of N-alkenyl-amides
A process for preparing N-alkenyl-amides by reacting the corresponding NH-amides with acetylenes in the liquid phase in the presence of basic alkali metal compounds and of a cocatalyst comprises...
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6624303 |
Method for producing N-alkenyl amides
A process for preparing N-alkenyl-amides by reacting the corresponding NH-amides with acetylenes in the liquid phase in the presence of basic alkali metal compounds and of a cocatalyst comprises...
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6521613 |
Lactam compounds for penetration enhancement
Compounds, compositions and methods are disclosed useful for enhancing penetration of a pharmacologically active substances across skin or tissue membranes. Compounds for use in such compositions...
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6417353 |
Preparing amines
Amines are prepared by reacting aldehydes or ketones at elevated temperature under elevated pressure with nitrogen compounds selected from the group of ammonia, primary and secondary amines, and...
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6355794 |
Lactam derivatives for melamine impregnating resins, and resin mixtures containing them
N-Alkoxymethylactams are obtained by reacting lactams with formaldehyde and hydroxyl-containing compounds selected from diol monoethers. The substituted lactams are useful as an additive to melamne...
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6255479 |
Process for the preparation of α-oxolactams
A method for preparing an α-oxolactam comprising, reacting a corresponding α-diazolactam with an oxygen donor, in the presence of a transition metal catalyst, to yield the corresponding...
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6011153 |
Process for the preparation of a mixture of ε-caprolactam, 6-aminocaproic acid and 6-aminocaproic amide
Process for the preparation of a mixture of ε-caprolactam, 6-aminocaproic acid and 6-aminocaproic amide by heating an aqueous mixture containing ammonia and oligomers of 6-aminocaproic acid and/or...
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5986092 |
Process for the preparation of N-substituted lactams
The invention relates to a process for the preparation of N-substituted lactams by reaction of a lactam, which is unsubstituted on the nitrogen, with an organic halide in the presence of at least...
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5912189 |
Compositions containing reaction product of a cyclic compound containing both a nitrogen atom and a carbonyl group, an aldehyde or ketone, and an etheramine
The present invention is directed to a composition containing the reaction product of: (A) a cyclic compound containing a 5, 6, or 7-member ring, the ring containing at least one nitrogen and at...
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5677444 |
Method for the preparation of β-ketothioamide compound
A novel and simple method is proposed for the synthetic preparation of an N,N-disubstituted β-ketothioamide compound represented by the general formula R 1 R 2 N--CS--CH 2 --CO--R 3 , in...
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5670639 |
Preparation of n-vinyllactams
N-Vinyllactams of the general formula I ##STR1## where n is from 1 to 3, are prepared by a process which comprises reaction of a lactam of the general formula II ##STR2## where n is from 1 to 3,...
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5508396 |
Process for preparing n-alkyllactams
A process for preparing an N-alkyllactam, comprising the steps of: (a) reacting a lactam with an alkali metal alkoxide at 130°-170° C. and removing the alcohol formed by distillation; (b)...
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5470849 |
γ-turn peptidomimetics as fibrinogen antagonists
This invention relates to a method of inhibiting platelet aggregation, and compounds which are mimics of the peptide sequence Arg-Gly-Asp.
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5276165 |
Preparation of N-substituted lactams
A process for the preparation of N-substituted lactams of the formula I ##STR1## where Z is C 2 - to C 10 -alkylene, C 7 - to C 12 -aralkylene, phenylene or naphthylene, and R 1 is C 1 -...
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5124322 |
Dipeptide collagenase inhibitors
Novel compounds of formula (I), salts, solvates and hydrates thereof: ##STR1## in which: R 1 and R 2 are independently hydrogen; alkyl; alkoxy; halogen; or CF 3 ; R 3 is hydrogen; acyl, such...
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4990628 |
Catalytic preparation of thiolactams
The reaction of lactams (preferably N-methyl-2-pyrrolidone) with hydrogen sulfide to thiolactams (preferably N-methyl-2-thiopyrrolidone) is conducted in the presence of a catalyst comprising an...
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4973688 |
Process for the production of 1-n-dodecylazacycloheptan-2-one
There is disclosed a method for the production of 1-n-dodecylazacycloheptan-2-one by reacting caprolactam with 1-bromododecane in the presence of a phase transfer catalyst under anhydrous...
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4943633 |
Catalytic preparation of cyanoalkyl lactams
This invention relates to an improved process for the preparation of cyanoalkyl lactams by the reaction of an unsaturated nitrile with a lactam, said cyanoalkyl lactam of the formula ##STR1##...
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RE33073 |
Obtaining caprolactam by cleaving oligomers of caprolactam
Caprolactam is obtained by cleaving oligomers of caprolactam by a process in which the oligomers, in a liquid or solid state, are introduced into a fluidized alumina bed and cleaved at from 290°...
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4812566 |
Process for preparing 1-dodecylazacycloheptane-2-one
Disclosed is a process for preparing 1-dodecylazacyclo-heptane-2-one, the process comprising reacting azacylcloheptane-2-one with dodecyl halide in a substantially non-aqueous system in the...
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4692523 |
Process for the preparation of 1-substituted aza-cycloalkan-2-ones
A process for the preparation of 1-substituted azacycloalkan-2-ones of the formula I ##STR1## in which R, m and n have the meanings indicated by reaction of corresponding...
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4620949 |
Process for amidocarbonylation of cyclic amides
Amino acid derivatives are synthesized by reacting paraformaldehyde, cyclic amides and synthesis gas with a bimetallic catalyst comprising a rhodium-containing compound and a cobalt-containing...
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4508646 |
Process for the preparation of a catalyst useful for anionic lactam polymerization
An improved process for the preparation of a lactam-magnesium compound which involves bringing into intimate admixture a lactam monomer represented by the following structural formula: ##STR1##...
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4422970 |
Method of synthesis of 1-dodecylazacycloheptan-2-one
In a method of synthesis of 1-substituted azacycloalkan-2-ones with primary alkyl halides and aralkyl halides as alkylating agents, the improvement comprising carrying out the N-alkylation in the...
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4360461 |
Process for obtaining caprolactam by cleaving caprolactam oligomers
In a process for obtaining caprolactam by cleaving caprolactam oligomers by passing them through an alumina catalyst bed at an elevated temperature, the improvement that the oligomers are...
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4296029 |
Process for preparing hexahydroazepine, piperidine and pyrrolidine derivatives
2-Oxo-hexahydroazepine, -piperidine or pyrrolidines of formula ##STR1## wherein n is 2,3 or 4, R is hydrogen, lower alkyl, aryl(lower)alkyl, loweralkenylmethyl or cycloalkylmethyl, R 1 is hydrogen...
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4264503 |
Polymerization process using a sodium carboxylactamate catalyst
The polymerization of 2-pyrrolidone is achieved in high yield in the presence of a sodium-derived catalyst activator produced by the reaction of carbon dioxide with the sodium lactamate derived...
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4234484 |
Process for the preparation of cyclic enamides
Special cyclic enamides are prepared by splitting off alcohols catalytically from the corresponding alkoxylated cyclic amides, in the presence of at least one tetraalkylammonium and/or alkali metal...
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4145352 |
Preparation of thioamides from amides
A method for preparing thioamides from amides by contacting an amide with a source of sulfur in the presence of a sulfactive catalyst. In a preferred embodiment the sulfactive catalysts are...
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3939153 |
Process for producing caprolactam
A non-catalytic method is provided for depolymerizing nylon-6 to produce e-caprolactam. The nylon, as a melt is continuously fed to a reaction zone together with superheated steam and undecomposed...
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3869431 |
POLYAMIDES AND THEIR PRODUCTION
Polyamides are produced by reacting a nitro acid chloride with a lactam the product of which is reduced to the corresponding amino-imide and then heated to split off lactam and obtain a polyamide...
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3865814 |
Process for preparing n-substituted lactams
A process for the preparation of N-substituted lactams of the formula ##SPC1## Wherein A is a substituted or unsubstituted aliphatic hydrocarbon chain having 3 to 11 carbon atoms, said substituents...
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3843630 |
PRODUCTION OF ε-CAPROLACTAM
The present invention relates to a process for producing ε-caprolactam which comprises bringing N-acetyl-ε-caprolactam into contact in a gaseous phase with an acid catalyst or basic catalyst in...
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3674751 |
METHOD OF MANUFACTURING POLYAMIDES BY ALKALINE POLYMERIZATION OF CYCLIC LACTAMS
An improved process for manufacturing polyamides by alkaline polymerization of cyclic lactams which consists of reacting alkali metal hydroxides or alcoholates with the lactams, with water or the...
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3536699 |
ARALKYL-SUBSTITUTED LACTAMS AND CYCLIC UREAS AND PROCESS FOR THEIR PRODUCTION
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3531471 |
PROCESS FOR PREPARING N-VINYL COMPOUNDS
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3377340 |
Process for preparing n-vinyl amides and n-vinyl lactams
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3346566 |
Process of preparing metal salts of lactams
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3332938 |
Alkylated lactams and process of preparation
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3329668 |
Chlorothiocarbanilide complexes
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3324177 |
N-vinylamides and process for preparing them
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3318906 |
Process for the production of ethylenylated lactams
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3317519 |
Simultaneous depolymerization of polycaproamide and polyester with recovery of caprolactam
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3306910 |
Production of thiolactam compounds
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3300513 |
2-acyl-2-azabicyclo [3.2.2]-6-nonenes
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3259634 |
2-azabicyclo[3.2.0]heptan-3-ones
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3249625 |
Process for preparing nu-vinyl pyrrolidone-2
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3249590 |
Anionic polymerization of lactams with pyrimidines or pyrazines as activators
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