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6437119 Compounds formed from two or three antibiotics and their processes of preparation  
Processes for preparing compounds having two or three antibiotic functionalities using quinolone derivatives, β-lactams and vancomycin and the like as the starting materials and chloride linking...
6169180 Process for the production of cephalosporines  
The invention relates to a new economical and simple process, using a new intermediate compound, for the production of 3'-substituted 7-amino-3-propenyl-4-cephem-carboxylic acid derivatives of...
5801242 Process for making quinolonyl lactam antimicrobials and novel intermediate compounds  
The present invention provides processes for making compounds of the structure (Q--L 1 )--L--(L 2 --B) wherein (I) Q is a quinolone moiety; (II) B is a lactam moiety; and (III) L, L 1 ,...
5760027 Use of 7-alkylidene cephalosporins to inhibit elastase activity  
The present invention relates to the use of 7-alkylidene derivatives of cephalosporin esters, such as sulfides, sulfoxides, and sulfones, as inhibitors of human leukocyte elastase. These materials...
5700932 Process for preparing cephem derivative  
The present invention relates to a process for preparing a cephem derivative represented by the following formula (I): ##STR1## useful as an intermediate for the preparation of antibiotics.
5580865 2,2-disubstituted cephem sulphones  
The present invention provides cephalosporin sulphones or formula (I), and pharmaceutically or veterinarily acceptable salts thereof; ##STR1## wherein n is zero, one or two; R 1 is hydrogen,...
5567813 Process for preparing cephalosporin compounds from reactive organic acid derivatives  
The present invention provides a process for preparing cephem derivatives having the following general formula (I): ##STR1## in which R 1 represents a carboxy group or a protected carboxy group...
5348952 β-lactam derivatives of the cephem sulphone type  
Cephalosporins of the formula (I): ##STR1## wherein m is one or two; n is zero, one or two; A and B are organic residues; and R 1 and R 2 are halogen or hydrogen atoms or organic groups are...
5281703 Process for making antimicrobial quinolonyl lactams  
The present invention provides methods of making compounds of the structure [Q-L 1 ]-L-[L 2 -B[ wherein (I) Q is a quinolone moiety; (II) B is a beta-lactam moiety; (III) L, L 1 , and...
4931555 Disulfide substituted oxazetidine derivatives  
A process for producing a 2-cephem or 3-cephem derivative compound of the formula: ##STR1## wherein R 1 represents a substituted or unsubstituted amino radical and R 4 represents hydrogen or a...
4845088 Tetrazolyl derivatives of beta-lactams useful as elastase inhibitors  
Tetrazolyl derivatives of β-lactams are found to be potent elastase inhibitors and thereby useful anti-inflammatory/antidegenerative agents.
4761409 Cephem derivatives  
A cephem derivative represented by the general formula ##STR1## wherein R 1 represents hydrogen or methyl, R 2 represents carboxyl or esterified carboxyl, and n represents 0 or 1, or a...
4758558 N-(substituted)-[7-(2-cyanoacetamido)cephalosporanic]amide derivatives having antibiotic utility  
Disclosed herein are the derivatives of substituted cephalosporanic acid represented by the formula (I): ##STR1## wherein R 1 represents a 4-pyridylthiomethyl group, an alpha-aminobenzyl group, a...
4735937 8-oxo-5-thia-1-azabicyclo(4,2,0)oct-2-ene compounds  
The invention concerns 7-amino-ceph-3-em-4-carboxylic acid compounds of the formula ##STR1## wherein R 1 a represents hydrogen or an amino protective group R 1 A and R 1 b represent hydrogen or...
4734407 Alpha-aminoacyl-penicillins and cephalosporins  
Antibacterially active and animal growth-regulating novel β-lactam compounds of the formula ##STR1## in which R 1 represents an optionally substituted radical of the formula ##STR2## Z represents...
4705784 Cephem compounds  
A cephem compound represent by the general formula ##STR1## wherein, R 1 represents hydrogen or lower alkyl, R 2 and R 3 are the same or different and each represents hydrogen or lower alkyl, R...
4622394 Oxygen analogs of cephalosporins  
In accordance with this invention, it has been found that the oxygen analog of 7-amino-cephalosporanic acid and biologically active derivatives thereof can be formed from esters of...
4605651 Antibiotic amino acid derivatives of cephalosporins  
1. A cephalosporin derivatives of the general formula ##STR1## wherein R 1 is an α-, β- or γ-amino acid residue (bonded by the ester linkage), which may optionally be substituted by one or two...
4604457 2-substituted cephem derivatives and process for preparing the same  
A 2-substituted cephem derivative represented by the formula ##STR1## wherein R 1 represents a substituted or unsubstituted phenyl group, substituted or unsubstituted phenylmethyl group or...
4559334 7-Substituted-3-vinyl-3-cephem compounds and processes for production of the same  
The invention relates to novel compounds of high antimicrobial activity of the formula: ##STR1## in which R 1 is amino or a protected amino group, and R 2 is carboxy or a protected carboxy...
4520194 Cephalosporins  
A 7-[2-(2-aminothiazol-4-yl)-2-(syn)-methoxyiminoacetamido]cep halosporin derivative of the formula; ##STR1## wherein R 3 is hydrogen or a residue of a nucleophilic compound; R 2 NH is an amino...
4496561 Cephalosporin derivative  
A cephalosporin derivative having an antibacterial activity similar to a cephalosporin antibiotic in living bodies without affecting the intestinal bacterial colonies, a method for preparing the...
4477660 7-(S)-Acylaminocephalosporin sulfones and process  
This invention encompasses 7-(S)-acylamino-3-acetoxymethyl-3-cephem-4-carboxylic acid sulfones and the epimerization process for making them. The epimerization process employs an organic nitrogen...
4477447 7-Acylaminocephalosporanic acid derivatives  
This invention relates to novel 7-acylaminocephalosporanic acid derivatives of high antimicrobial activity, to processes for their preparation, and to pharmaceutical compositions comprising said...
4460582 3-Carboxybenzyl cephems  
The present invention provides a compound of the formula (I): ##STR1## and pharmaceutically acceptable salts and in-vivo hydrolysable esters thereof wherein R 1 is carboxy, R 2 is hydrogen or...
4456755 7-Oxygen analogs of cephalosporins  
In accordance with this invention, it has been found that the oxygen analog of 7-aminocephalosporanic acid and biologically active derivatives thereof can be formed from esters of...
4426520 3-Carbamoyloxy-cepham-4-carboxylic acid derivatives  
Penicillin sulfoxide esters are reacted with an isocyanate to produce the corresponding (substituted)-2-carbamoyloxymethylpenam, the corresponding (substituted)-3-carbamoyloxycepham or the...
4405782 Process for the preparation of solutions of 7-aminocephalosporanic acids  
A process for the preparation of solutions of 7-aminocephalosporanic acids wherein there is obtained a salt of the general formula III: ##STR1## where R 1 may be a group selected from among...
4393205 Cephapirine esters and salts thereof  
Cephapirine esters having the formula ##STR1## wherein R is selected from the group consisting of ##STR2## Such esters and salts thereof, having antibiotic activity, are prepared by reacting 7-ACA...
4388460 Cephalosporine desacetoxy esters and salts thereof  
Cephalosporine desacetoxy esters having the formula ##STR1## wherein R is selected from the group consisting of ##STR2## and R 1 is selected from the group consisting of ##STR3## Such esters and...
4338439 7-[2-[(Substituted benzoyl]amino]acetamido]cephalosporins  
Cephalosporin antibiotics of the formula ##STR1## wherein R is cyclohexadienyl, phenyl or substituted phenyl, 2-thienyl, 3-thienyl, 2-furyl or 3-furyl; R 1 is a substituted phenyl having 1 to 4...
4322347 2-Carbamoyloxymethyl-penicillin derivatives  
Penicillin sulfoxide esters are reacted with an isocyanate to produce the corresponding (substituted)-2-carbamoyloxymethylpenam, the corresponding (substituted)-3-carbamoyloxycepham or the...
4312982 α-Acylureidocephalosporins and salts and esters thereof  
Compounds which are clinically important cephalosporins and salts and esters thereof having a wide spectrum of activity against Gram-positive bacteria but especially against Gram-negative bacteria...
4307230 3-Vinyl-cephalosporins  
Novel 3-vinyl-cephalosporins of the formula ##STR1## in which n is 0 or 1, R 1 is hydrogen, a radical of the formula ##STR2## [in which R 4 is hydrogen or a protective radical and R 5 is...
4297489 7-α-Amino-substituted acylamino-3-(1-carboxymethyltetrazol-5-ylthiomethyl)-3-cephem-4-carboxyl ic acids  
Certain 7-acylamido-3-(1-carboxy-loweralkyl-tetrazol-5-ylthiomethyl) -3-cephem-4-ca rboxylic acids and their salts and easily hydrolyzed esters of the 4-carboxyl group were synthesized and found to...
4278793 Cephem derivative  
Cephem derivatives of the general formula ##STR1## in which the R 2 O group is in the syn-position, a process for their manufacture and pharmaceutical formulations which are active against...
4275062 Aminothiazolyl ureido sulfoxide cephalosporins  
Cephalosporins of the formula ##STR1## R represents hydrogen, sodium, potassium, or certain ester groups, R 1 is in the α-configuration and is hydrogen or methoxy, X represents hydrogen ##STR2##...
4271157 Imidazole derivatives of 7-[(2-amino-4-thiazolyl)-oximino] cephalosporins  
A compound of the formula ##STR1## wherein R is hydrogen, alkali metal, ##STR2## R 1 is hydrogen or methyl; R 2 is hydrogen or methyl; R 3 is hydrogen or methyl; R 4 is hydrogen, --OCONH...
4269977 Process for the manufacture of 8-oxo-5-thia-1-azabicyclo [4,2,0]oct-2-ene or 3-ene compounds  
The invention concerns the decarbonylation of the formyl group in 7-amino-3-formyl-ceph-2-em-4-carboxylic acid compounds and 7-amino-3-formyl-ceph-3-em-4-carboxylic acid compounds by treatment with...
4252802 Hydroxamic acid derivatives of 7-[(2-amino-4-thiazolyl)-oximino] cephalosporins  
A compound of the formula ##STR1## wherein R is hydrogen, alkali metal, ##STR2## or ##STR3## R 1 is hydrogen or methyl; R 2 is hydrogen or methyl; R 3 is hydrogen, lower alkyl or lower...
4248868 Cephem carbonylmethyl derivatives  
The invention comprises carbonylmethyl derivatives of the formula IA and corresponding carbonylmethylene derivatives of the formula IB ##STR1## in which R 1 a represents a member of the group...
4237128 7-[2-(2-Amino-4-thiazolyl)-2-[(1-carboxy-1, 1-dialkyl)alkoxyimino]acetamido]cephem sulfoxides  
Compounds of the formula ##STR1## wherein R is hydrogen, sodium, potassium, or certain ester groups; R 1 is in the α-configuration and is hydrogen or methoxy; R 2 and R 3 are independently...
4211702 Process for preparation of penicillin and cephalosporin imino halides  
Penicillin and cephalosporin imino halides are prepared by reacting of 6-acylaminopenicillins or 7-acylamino cephalosporins with a novel chlorinating compound derived from a triaryl phosphite and...
4202817 Process for the production of penam and cephem derivatives  
A process for the preparation of penam and cephem derivatives by reacting a phosphite amide of a 6-aminopenicillanic acid or 7-aminocephalosporanic acid with an acyl halide in an aprotic solvent in...
4145538 3-Carbamyloxymethyl-cephalosporins  
The present invention is directed to 7-amino-3-carbamoyloxymethyl-3-cephem-4-carboxylic acid: ##STR1## and to precursors and derivatives. The compound, its precursors, and its derivatives exhibit...
4129732 4(Tetrazol-5-yl)-Δ.sup.3 -cephem compounds  
Certain novel antibacterial 7-acylamino-3-substituted-4-(tetrazol-5-yl)-Δ 3 -cephem derivatives, and salts thereof, and intermediates useful in their preparation.
4113940 7-Amino 2-lower alkyl-2 or 3-cephem-4-carboxylic acid derivatives and processes for preparation thereof  
A compound of the formula ##STR1## wherein R 1 is amino or substituted amino, R 2 is carboxy or protected carboxy, R 3 is lower alkyl and X is --S-- or ##STR2## or a pharmaceutically acceptable...
4112228 7-(D-α-Hydroxy-2-arylacetamido)-3-(2-carboxyalkyl-2,3-dihydro-s-tri azolo-[4,3-b]pyridazin-3-on-6-ylthiomethyl)-3-cephem-4-carboxylic acids and derivatives  
7-(D-α-Hydroxy-2-arylacetamido)-3-(2-carboxyalkyl-2,3-dihyd ro-s-triaz olo[4,3-b]pyridazin-3-on-6-ylthiomethyl)-3-cephem-4-carboxyl ic acids and derivatives containing blocking groups on the...
4107432 7-Diacylimido cephalosporins  
New 7-diacylimido cephalosporins are produced by reacting 7-acylamido cephalosporins with an acylating agent in the presence of a silyl reagent. The 7-diacylimido cephalosporins are cleaved to...
4098999 Certain 2-substituted cephalosporins  
Disclosed herein are novel analogs of cephalosporins. They differ from prior art compounds in that they are substituted in the 2-position and can be prepared by reacting known cephalosporins with...
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