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7560545 |
Process for obtaining cefotetan with high yield
The invention relates to a method for obtaining cefotetan acid substantially free of tautomer, by treating crude cefotetan with Al 3+ ions which cause the tautomer to precipitate. The precipitate...
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7544677 |
Inhibitors of Akt activity
The present invention is directed to compounds which contain substituted 5-deazapteridine moieties which inhibit the activity of Akt, a serine/threonine protein kinase. The invention is further...
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7507813 |
Amorphous cefuroxime axetil and preparation process therefore
A novel process for the preparation of amorphous cefuroxime axetil particles and the amorphous cefuroxime axetil particles therefrom are disclosed in the invention. Specifically, the invention is...
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7045618 |
Cefpodixime proxetil
The present invention relates to an improved and cost effective process for the industrial manufacture of cefpodoxime proxetil. More specifically, the present invention relates to the preparation...
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6949641 |
Crystalline β-lactam intermediate
The novel intermediate compound crystalline 7-[2-(2-fomylaminothiazol-4-yl)-2 -(Z)-(methoxyimino)acetamido]-3-methoxymethyl-3-cephem-4-car
boxylic acid-1 -(isopropoxy/crystallization of cefpodoxime...
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6835829 |
Purification process
Processes for the depletion of 7-ADCA in mixtures of vinyl-ACA with 7-ADCA via novel salts of vinyl-ACA or via chromatography.
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6803460 |
Process for the fermentative production of cephalosporin
A method for the recovery of an N-substituted cephalosporanic acid compound of general formula (I), wherein R 2 is selected from the group consisting of adipyl (1,4-dicarboxybutane), succinyl,...
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6602999 |
Amorphous form of cefpodoxime proxetil
A novel process for the production of an improved amorphous form of cefpodoxime proxetil...
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6552185 |
Process for the fermentative production of cephalosporin
A method for the recovery of a compound formula (I) from a complex mixture, comprising the steps of: (a) acidifying the complex mixture to a pH below 6.5 and maintaining the mixture below said...
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6504026 |
Process for production of ceftiofur
Process for preparing ceftiofur having formula I: in the form of the sodium salt.
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6489470 |
Process for the preparation of cefpodoxime proxetil diastereoisomers
A process for increasing the diastereoisomeric ratio (B/A+B), wherein B is the more apolar and A is the more polar of two diastereoisomers, of a mixture of diastereoisomers of a compound of formula...
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6350869 |
Crystalline amine salt of cefdinir
Cefdinir in the form of a salt with dicyclohexylamine, a process for its production and its use in the purification of impure cefdinir.
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6288223 |
Process for the selective preparation of Z-isomers of 3-2(substituted vinyl)cephalosporins
There can be produced, at a high selectivity and in a high yield, the Z-isomer of a 7-N-unsubstituted or substituted-amino-3-[2-(4-substituted or unsubstituted-thiazol-5-yl)...
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6284888 |
Vinyl-ACA purification process
A process for purification of vinyl-ACA of formula ##STR1## from a mixture of vinyl-ACA and 7-ADCA of formula ##STR2## is provided. The process comprises a) producing a mixture of a salt of...
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6172221 |
Clavulanic acid extraction process
A back extraction process in which beta-lactam antibiotics or clavulanic acid is extracted from an organic solvent phase into an aqeous medium phase, using a mixing region in which the phases are...
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6100393 |
Process for purifying 7-substituted aminodeacetoxy-cephalosporins through the use of filtration membranes
Process for purifying 7-substituted aminodeacetoxycephalosporins through the use of filter membranes. A process for purification by ultrafiltration and/or nanofiltration with a cut-off for...
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5874571 |
Process for the recovery of cephalexin
The disclosed process is for the recovery of cephalexin from a mixture containing cephalexin and 7-aminodesacetoxy cephalosporanic acid (7-ADCA), wherein a mixture of cephalexin and 7-ADCA, with a...
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5693790 |
Crystalline form of a cephalosporin antibiotic
The preparation of a novel crystalline cefaclor and the conversion of such a product to cefaclor monohydrate are described. The new intermediate cefaclor is a particular crystalline form and...
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5686588 |
Amine acid salt compounds and process for the production thereof
A stoichiometric acid moiety transfer reaction for the preparation of an acid salt of an amine compound is disclosed. The acid moiety transfer reaction provides amine acid salts of high purity and...
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4973685 |
Heteroannellated phenylglycine-β-lactam antibiotics
Heteroannellated penicillins and cephalosporins of the formula ##STR1## in which R 1 --stands for a radical of the formula ##STR2##
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4820833 |
Preparation of a highly pure, substantially amorphous form of cefuroxime axetil
There is described a product which is a highly pure substantially amorphous form of cefuroxime axetil (cefuroxime 1-acetoxyethyl ester) which is stable, which has increased absorption via the...
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4775751 |
Process for cephalexin hydrochloride alcoholates
The crystalline ethanol or methanol solvates of cephalexin hydrochloride are isolated in high yield from solutions of cephalexin hydrochloride in substantially anhydrous ethanol or methanol,...
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4727070 |
3-Propenzl cephalosporin isomer separation process and derivative
The antibiotic 7-[D-2-amino-2-(4-hydroxyphenyl)acetamido]-3-[(Z)-1-propenyl
]ceph-3-em-4-c arboxylic acid (BMY-28100) forms imidazolidinone derivatives on reaction with ketones. These derivatives...
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4719287 |
Higher alkyl pyrrolidone extractants for water soluble phenolic or carboxylic antibiotics
The extraction of water soluble antibiotics containing a phenolic or carboxylic group from an aqueous solution or fermentation broth using a N--C 8 --C 14 alkyl pyrrolidone extractant and the...
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4668782 |
Anhydrous crystalline or crystalline hemihydrate monohydrate or trihydrate of cephalosporin derivative
An anhydrous crystalline, or crystalline hemihydrate, monohydrate or trihydrate of cephalosporin derivative of (6R,7R)-7-[(Z)-2-(2-aminothiazole-4-yl)-2-methoxy-iminoaceto
amido]-3(1-qui...
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4594417 |
Crystalline antibiotic salt
Crystalline cephalosporin hydrochloride salt represented by the formula ##STR1## wherein the oxime is in the syn configuration, is a useful pharmaceutical form of, and tool for purification of, the...
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4581166 |
Method for isolating and purifying antibiotics
A process is proposed for the isolation and purification of antibiotics wherein an antibiotic containing solution is extracted with an extraction agent at a temperature of from 0° to 40° C. and...
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4560749 |
Cephem-3-imidates and 3-amidines
3-Azido-3-cephem esters are reacted with electron rich olefins, e.g., enamines and cyclic enol ethers, to provide C 3 amidines and imidates having antibacterial activity in the free acid form. For...
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4535155 |
Method for separating cephalosporins
The interseparating of desacetyl-cephalosporin C, desacetoxy-cephalosporin C and cephalosporin C can be accomplished by adsorbing these available cephalosporins on activated carbon and effecting a...
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RE31730 |
Process for the preparation of the crystalline monohydrate of 7-(D-α-aα-(p-hydroxyphenyl)acetamido)-3-methyl-3-cephem-4-ca rboxylic acid
A novel crystalline monohydrate of 7-[D-α-amino-α-(p-hydroxyphenyl)acetamido]-3-methyl-3-caph
em-4 -carboxylic acid is prepared and found to be astable useful form of the cephalosporin antibiotic...
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4477659 |
Cephalosporin compound
A cephalosporin compound of the general formula (I): ##STR1## wherein X is a hydrogen atom, a chlorine atom, a methyl group, a methoxy group, an acetoxymethyl group or --CH 2 SHet wherein Het is a...
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4477658 |
Process for the preparation of cepham and cephem compounds
The invention concerns 7β-amino-cepham-3-one-4-carboxylic acid compounds, particularly esters thereof, and the N-substituted, especially N-acylated derivatives of such compounds. They can be used...
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4456753 |
Process for the manufacture of highly crystalline sodium cefoperazone
A process for the preparation of highly crystalline sodium cefoperazone comprising the controlled addition of acetone to a water/acetone/sodium cefoperazone solution and subsequent separating and...
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4448958 |
Purification of ceforanide
Crude cephalosporin 7-[α-(2-aminomethylphenyl)acetamido]-3-[(1-carboxymethyltet
razol-5-y lthio)methyl]-3-cephem-4-carboxylic acid is purified by converting it to its salt with...
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4339575 |
Substituted-imidazolidinyl-3-chloro-3-cephem-4-carboxylic acid
7β-[2-(substituted or unsubstituted)-5-oxo-4-phenylimidazolidin-1-yl]-3-chloro-3-c
ephem-4-carbox ylic acid represented by the formula: ##STR1## (wherein R is hydrogen or hydroxy: R 1 and R 2 ...
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4298732 |
Crystallization process
A process for the preparation of crystalline sodium cefuroxime (the sodium salt of (6R,7R)-3-carbamoyloxymethyl-7-[(Z)-2-(fur-2-yl)-2-methoxyim
ino-acetamido] ceph-3-em-4-carboxylic acid) which...
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4277601 |
Preparation of sodium cefuroxime
A process for the preparation of the sodium salt of the antibiotic (6R,7R)-3-carbamoyloxymethyl-7-[Z-2-(fur-2-yl)-2-methoxyimin
oacetamido]-ce ph-3-em-4-carboxylic acid (cefuroxime) which comprises...
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4252951 |
Isolation of syn-7-(2-amino-4-thiazolyl)-(methoxyimino)acetamido-3-acetoxymethyl-3-ce phem-4-carboxylic acid
Syn-7-(2-amino-4-thiazolyl)-(methoxyimino)-acetamido-3-aceto
xymethyl-3-ceph em-4-carboxylic acid is isolated by formation of cyclic ether solvates.
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4237051 |
Stereospecific production of 6- or 7-carbon-substituted-β-lactams
Reaction of 6- or 7-diazo-β-lactams with allylic halides in the presence of a catalytic amount of metallic copper or a copper salt affords 6- or 7-carbon-substituted-β-lactams with the desired...
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4224371 |
Sodium 3-acetoxylmethyl-7-[2-(2-amino-4-thiazolyl)-2-methoxyimino-acetamido]-ce ph-3-eme-4-carboxylate
Novel stable crystalline hydrate of D form of the syn isomer of sodium 3-acetoxymethyl-7-[2-(2-amino-4-thiazolyl)-2-methoxyimino-ac
etamido]-ceph- 3-eme-4-carboxylate having the formula ##STR1##...
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4217275 |
β-Lactam antibiotic esterification process using methoxymethyl methane sulfonate
Disclosed is an improved process for esterifying carboxylic acids, particularly 3-carboxylic acid groups of penicillins and 4-carboxylic acid groups of cephalosporins, to form methoxymethyl esters....
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4211702 |
Process for preparation of penicillin and cephalosporin imino halides
Penicillin and cephalosporin imino halides are prepared by reacting of 6-acylaminopenicillins or 7-acylamino cephalosporins with a novel chlorinating compound derived from a triaryl phosphite and...
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4205165 |
Processing of cephalosporin C
A process for the recovery of cephalosporin C comprises (a) contacting a fermentation broth containing cephalosporin C with an anion exchange resin which is either a weak-base resin in the weak...
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4204058 |
Process for obtaining cephalosporin C and the salts and derivatives thereof from culture filtrates or culture solutions
A novel process for obtaining cephalosporin C and the salts and derivatives thereof from culture filtrates or culture solutions is provided which comprises drying the culture filtrate or culture...
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4196285 |
Antibiotic purification process
Cephamycin C is concentrated and purified by subjecting a fermentation broth which contains Cephamycin C to the following sequence of steps: filtration at acidic pH, passage through a methylene...
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4168375 |
Process for the recovery of cephalosporin C and derivatives thereof
A process for the recovery of cephalosporin C from an aqueous medium, including the steps of treating the medium with a sulphonyl chloride of formula R--SO 2 Cl, in which R is a substituted or...
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4167630 |
Process for epimerizing beta-lactam antibiotic compounds, and related products
Through total synthesis methods developed in the assignee's laboratories, new as well as old penicillin and cephalosporin compounds (all containing the beta-lactam functional group) have been...
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4145539 |
Process for isolation and purification of cephalosporin compound
A process for the isolation and purification of cephalosporin from a solution containing impurities which includes treating the solution with macroporous non-ionic adsorption resin to adsorb the...
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4137405 |
Isolation of antibiotic Cephamycin C
Fermentation broths or impure solutions containing Cephamycin C, a substance having antibiotic activity against gram-negative and gram-positive microorganisms, are isolated using liquid anion...
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4115645 |
Decolorizing process for 7-amino-3-(((2-methyl-1,3,4-thiadiazol-5-yl)thio)methyl)-3-cephem-4-carb oxylic acid
The present invention is directed to the use of sodium sulfite and sodium dithionite for the decolorization of 7-amino-3-(((2-methyl-1,3,4-thiadiazol-5-yl)thio)methyl)-3-c
ephem-4-carbox ylic acid.
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