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7390803 Tetrahydropyranyl cyclopentyl benzylamide modulators of chemokine receptor activity  
The present invention is directed to compounds of the formula (I) (wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 27 , R 28 , R 29 , R 30 , R 31 , X, m, n and the...
6306845 Method for treating demyelinating disease  
The present invention provides a method for treating a demyelinating disease in a subject which includes administering to the subject a therapeutically effective amount of a high affinity...
5198537 Digoxigenin derivatives and use thereof  
The present invention provides digoxigenin derivatives of the formula: ##STR1## wherein n is a whole number of from 1 to 4 and Z is a carboxyl group or a functional derivative derived therefrom....
5003054 Ouabain triacetate derivative compounds  
A method for performing a diagnostic immunoassay by solid phase separation for digoxin. To a reaction mixture of a test sample and labeled anti-digoxin antibody, which forms a complex of any...
4847246 Antiviral compositions derived from fireflies and their methods of use  
This invention relates to antiviral organic steroid compositions and derivatives thereof; a process of producing the antiviral compositions; and a method for inhibiting viruses utilizing the...
4788136 Diagnostic immunoassay by solid phase separation for digoxin  
A method for performing a diagnostic immunoassay by solid phase separation for digoxin. To a reaction mixture of a test sample and labeled anti-digoxin antibody, which forms a complex of any...
4380624 Novel isomers of bufalin and resibufogenin and their preparation  
This invention relates to novel isomers of naturally occurring cardiotonic compounds, specifically novel isobufalins and novel isoresibufogenins. This invention also relates to a novel method of...
4334069 Chemiluminescent phthalhydrazide-labeled hapten conjugates  
Chemiluminescent-labeled conjugates of the formula: ##STR1## wherein one of R 1 and R 2 is hydrogen and the other is --NR 3 R 4 ; R 3 is hydrogen or straight chain alkyl containing 1-4 carbon...
4331802 Organometallic reagents and their use in the synthesis of cardenolides and isocardenolides  
A method for synthesizing a cardenolide or isocardenolide by subjecting an α,β-unsaturated steroidal 17-ketone to a double bond shift and hydrogenation to produce a (C/D cisoid) ketone which is...
4259240 Synthesis of furyl intermediates, and cardenolides and their isomers prepared therefrom  
The invention relates to furyl intermediates and the preparation thereof, said intermediates being particularly useful in the preparation of synthetic cardenolides and their isomers. The process...
4255329 Double receptor fluorescent immunoassay  
A novel sensitive method for determining qualitatively and quantitatively the presence of a wide variety of physiologically active organic compounds (ligand) and their receptors is provided. The...
4218447 Acyl derivatives of hellebrigenin  
There are prepared compounds corresponding to the general formula: ##STR1## in which R represents a 2,2-dimethylethenyl; isopropyl; nonyl; a C 3 -C 6 -cycloalkyl radical; a phenyl group...
4175078 Cardenolide and bufadienolide derivatives of ajmaline and process for producing same  
According to the invention, the novel substances are the cardenolide and adienolide derivatives of ajmaline of the general formula ##STR1## wherein R is cardenolide or bufadienolide of the general...
4115539 Analytical or clinical derivatives, tagged derivatives and methods of analysis using such derivatives  
Novel isocyanates such as, for example, blocked L-tyrosine methyl ester isocyanate, are reacted with compounds of biological, clinical interest or the like such as, for example, digoxin, to form...
4102884 14 β-Hydroxy 3-deoxycardenolides  
Novel compounds of the formula ##STR1## useful as pharmaceutical compounds are disclosed. Processes are also disclosed for their preparation.
4097477 Steroid compounds and processes thereof  
Novel steroids of the formula ##STR1## Also there are provided processes for preparing such compounds. The new compounds are useful as intermediates in the preparation of known cardenolides;...
4030886 Saturation analysis  
The invention provides a method and a kit for the saturation analysis of a steroid characterized by the use of a selenium-75 labelled version of the steroid to be assayed. Selenium-75 derivatives...
4000125 Novel cardiotonic steroids, process for their preparation and therapeutical use  
The invention relates to novel steroid compounds having the formula ##STR1## and their glycoside derivatives containing a pyridazine ring, in which particularly the substituent R 4 is a hydroxy...
3981982 Radioimmunoassay for determining the digoxin content of a sample  
A competitive radioimmunoassay for the measurement of digoxin in a serum sample in which the non-radioactive digoxin competes with a constant amount of a radioactively labeled digoxin tyramine...
3954739 Biological reagent  
Compounds of formula (VIII) wherein R 1 , r 2 , r 3 , r 4 and R 5 are each selected from hydrogen and an hydroxyl group and at least four are hydrogen; B is an alkylene chain of from 1 to 4...
3953431 Derivatives of digoxigenin  
Derivatives of digoxigenin which are either unlabeled or radioiodinated having the following structural formula: ##SPC1## Wherein R' is hydroxyl or acetoxy; B is succinyl, phthaloyl, maleyl or...
3952030 Selenium-75 steroids  
Novel dimeric and monomeric selenium-75 derivatives of steroids are made by reacting a keto steroid with selenium-75 dioxide or selenious acid-Se75. The resulting diselenide dimers can be converted...
3939187 15α,-Sulfonyloxy-12β-hydroxypregnanes and process for the preparation thereof  
15α-Sulfonyl-12β-hydroxypregnanes of the formula ##SPC1## Wherein Ac is lower-acyl and R is alkyl, cycloalkyl, aralkyl or aryl, which are useful as intermediates for the production of...
3939156 Cardenolides  
Novel cardenolides having desirable cardiac activity and which are readily reabsorbed internally, a process for their preparation and therapeutic compositions containing said cardenolides are...
3895008 Digoxigenin-12-formiate and process for its manufacture  
Digoxigenin-12-formiate prepared by a selective acylation of digoxigenin with a mixed anhydride of formic acid and acetic acid in the presence of a tertiary organic base. The product is suitable...
3879379 3-Amino-cardenolides and process for their manufacture  
Cardioactive 3-amino-cardenolides and a method for preparing them by reacg a 3-oxo-cardenolide with hydroxylamine or its salts to form a cardenolide-3-oxime and then catalytically hydrogenating...
3859272 19-ALKYLENE-14- β-HYDROXY-CARDENOLIDE DERIVATIVES AND PROCESS FOR PREPARING THEM  
Cardiotonically active 19-alkylene-14 β-hydroxy-cardenolides of the mula ##SPC1## Wherein R 1 taken alone is --CH, --CO 2 R 5 , --CON(R 6 ) 2 , --CH(OR 6 ) 2 , --C 6 H 5 , --CH=CH 2 , or --SCH...
3687944 PROCESS FOR THE PREPARATION OF BUFALIN AND RELATED COMPOUNDS  
There is provided a novel method of preparing the cardiac active agents bufalin and its immediate precursor resibufogenin from the well known cardenolide, digitoxigenin. The method comprises...
3684801 REMOTE OXIDATION OF UNACTIVATED STEROID METHYLENE GROUPS  
There is provided a method of activating inactive methylene groups of the 5α-steroid nucleus. This method comprises forming a 3α-m- or p-benzoylphenyl 5α-steroid alkanoate and irradiating said...
3681344 CERTAIN CARDIOACTIVE OXIDO-BUFADIENOLIDES  
Cardioactive oxido-bufadienolides of the formula ##SPC1## Wherein R is hydrogen or lower acyl. Methods of making such compounds.
3674779 4-CHLORO-3-OXO-14-HYDROXY-OR 4-CHLORO-3,14-DIHYDROXY-CARDA-4,20-DIENOLIDES AND PROCESS FOR THEIR MANUFACTURE  
Process for the manufacture of 4-chloro-3-oxo-14β-hydroxy- or 4-chlo3,14β -dihydroxy-carda-4,20(22)dienolides wherein 3-oxo-carda-4,14,20(22)-trienolides are at first treated with chlorine, the...
3621015 PROCESS FOR THE MANUFACTURE OF (ANDROST-17β-Y1)-α-PYRONES  
The method of making androst-(17β-α y1)-α -pyrones havingnotropic, cardiovascular, and diuretic activity by Wittig reaction of a 20-keto-21-acetal pregnene with a methyl-triphenyl-phosphonium...
3543307 DECOMPOSITION PRODUCTION OF DELTA4,20,22-BUFATRIENOLIDES AND PROCESS FOR THEIR SEPARATION  
3535314 PROCESS FOR THE PREPARATION OF 14BETA-HYDROXY-3-KETO-5BETA-CARD-20(22)-ENOLIDES  
3531475 PROCESS FOR THE OXIDATION OF ALCOHOLS AND OXIDIZING AGENT UTILIZED THEREIN  
3510478 15ALPHA - HALOGENO - 14BETA - HYDROXY-CARD-20(22) - ENOLIDES AND PROCESS FOR THEIR MANUFACTURE  
3455910 UNSATURATED LACTONES OF THE STEROID SERIES AND PROCESS FOR THEIR MANUFACTURE  
3454563 PROCESS FOR THE MANUFACTURE OF 14BETA-HYDROXY-CARD-20(22)-ENOLIDES  
3451994 14BETA-HYDROXY-16BETA,21-OXIDONORCHOLAN-23-OIC ACID LACTAMS AND DERIVATIVES  
3420820 UNSATURATED LACTONES OF THE STEROID SERIES AND PROCESS FOR PREPARING THEM  
3398138 Novel cardenolides and derivatives  
3325484 Process for preparing periplogenia and intermediates secured therein  
3318789 Process for the manufacture of 19-nor-steroids  
3287377 19-oxygenated steroids from 5alpha-halogen-6beta:19-oxido-steroids  
3264328 10alpha-steroids and process for their manufacture  
3256274 Process for the introduction of a double bond into the alpha, beta-position of the carbonyl of a steroid lactone  
3211719 19-norcardenolides  
3194804 19-norcard-20(22)-enolides, derivatives thereof, and intermediates thereto  
3178419 19-nor-steroids and process for their manufacture  
3177200 Process for the manufacture of cardioactive monoglycosides  
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