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5008253 |
Sulfoamino derivatives of chondroitin sulfates of dermatan sulfate and of hyaluronic acid and their pharmacological properties
Novel derivatives are disclosed as obtained from chondroitin sulfate, dermatan sulfate and hyaluronic acid, having a molar ratio between sulfate groups and carboxylic groups like that of heparin...
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5003060 |
Readily dispersed/dissolved porous biopolymer granules
Solid, free-flowing and nondusting porous biopolymer, e.g., xanthan gum, granules are produced in fluidized bed and are quickly dispersed/dissolved in aqueous media for use as thickening agents for...
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4996305 |
Process for producing the antibiotic and antitumor agents LL-E33288.epsilon . ε-Br
Processes for producing antibacterial and antitumor agents designated LL-E33288εI and LL-E33288ε-Br using triphenylphosphine or a sulfhydryl-containing reagent are disclosed. Processes for...
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4986991 |
Chewing gum having an extended sweetness
A chewing gum composition having an extended sweetness and flavor comprising a chewable gum base and a sweetener comprising 4,1',6'-trichloro-4,1',6'-trideoxy-galactosucrose (TGS), also known as...
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4987223 |
Derivatives of the uronic acid
The invention relates to derivatives with a uronic acid structure having substituents selected among a reactive group, a functionalisable group and --OH functions blocked by protective groups....
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4985550 |
Polyhydroxylated and highly fluorinated compounds, their preparation and their use as surfactants
Compounds having a polyhydroxylated hydrophilic moiety, a highly fluorinated moiety and a functional junction group linking said moieties together, wherein said hydrophilic moiety is derived from a...
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4983724 |
Inversion of 2,2-difluororibose to a 2,2-difluoroxylose and intermediates therefor
A process and intermediates useful for the invrsion of 2-deoxy-2,2-difluororibose analogs to provide 2-deoxy-2,2-difluoroxylose analogs is described.
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4980463 |
Sucrose-6-ester chlorination
A process for the chlorination of sucrose-6-esters to produce 6',4,1'-trichlorosucrose-6-esters which comprises the steps of: (a) adding at least seven molar equivalents of an acid chloride to a...
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4980462 |
Antiviral agents
A second-step virus binding receptor is found in nature on the surface of animal and plant cells. This receptor is thought to be needed for virus penetration into target cells. The second-step...
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RE33509 |
Brominated sucrose derivatives, compositions and methods of use
Compounds of the general formula (I) are potent sweeteners, especially 4,1',6'-tribromo-4,1',6'-trideoxygalactosucrose: ##STR1## in which R' represents a chlorine or bromine atom; R 2 and R 3 ...
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4978748 |
Intermediate and process for producing the antibacterial and antitumor agents LL-E33288ε-I and LL-E33288Epsilon-Br
Processes for producing antibacterial and antitumor agents designated LL-E33288ε-I and LL-E33288ε-Br using triphenylphosphine at ice bath temperature are disclosed. Novel intermediates prepared...
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4977143 |
Antibacterial and antitumor agents LL-E33288EPSILON-I and LL-E33288EPSILON-BR
Antibacterial and antitumor agents designated LL-E333288ε-I and LL-E33288ε-Br and their production by strains of Micromonospora echinospora ssp. calichensis designated NRRL-15839, NRRL-15975 and...
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4977254 |
Process for the chlorination of sugars
Sugars and partly protected sugar derivatives are chlorinated by reaction of unprotected hydroxyl groups with thionyl chloride to form a persulphite followed by decomposition of the sulphite groups...
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4977253 |
Process for the sulfation of alkyloligoglycosides
An alkyloligoglycoside having an alkyl group content of 8 to 22 carbon atoms and having an average degree of oligomerization of 1 to 5 is sulfated with a sulfating agent in an organic solvent...
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4975373 |
Process for the preparation of sulphur-containing hydrocarbon chains
Process for the preparation of sulphur-containing hydrocarbon chains, which consists in producing a fermentative action of two types of bacteria, lactic bacteria and bacteria of the genus...
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4975531 |
Sakyomicin E and the derivatives thereof, a process for the preparation thereof and the use thereof
The compounds of the formula I ##STR1## in which R 1 to R 3 denote, independently of one another, hydrogen or a (C 1 -C 18 )-acyl group, and a process for the preparation thereof are described....
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4973686 |
Process for the sulfonation and/or sulfatization of organic components with SO.sub.3 in an organic reaction medium
The invention relates to the use of selected carboxylic acid esters which are liquid under reaction conditions and correspond to general formula (I) X--COOR 1 ...
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4956459 |
Platinum compounds suitable for use as pharmaceuticals
Compounds of the formula: ##STR1## wherein each of R 1 and R 2 is independently selected from the group consisting of halogen, hydroxy, or mono carboxylic acid or R 1 and R 2 together is a...
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4954623 |
Recovery of difluoro sugar
A process for recycling the difluoro sugar in the synthesis of 2,2-difluoronucleosides proceeds by removing the base moiety of α-difluoronucleosides by reduction and hydrolysis, followed by...
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4950746 |
Process for synthesizing sucrose derivatives by regioselective reaction
Sucrose is reacted with a 1,3-di(hydrocarbyloxy)-1,1,3,3-tetra(hydrocarbyl)distannoxan
e to produce a 1,3-di-(6-O-sucrose)-1,1,3,3-tetra(hydrocarbyl)distannoxane,
which can be acylated to produce...
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4948883 |
Preparation of hydrogen and bismuth (phosph/sulf) ated saccharides
Bismuth salts of phosphorylated and/or sulfonated saccharides are prepared from a corresponding metal salt reactant, a water soluble organic acid, and a bismuth substance. For example, a complex...
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4948881 |
Process for the depolymerization and sulfation of polysaccharides
Process for the depolymerization and sulfation of polysaccharides by reaction of said polysaccharides with a sulfuric acid/chlorosulfonic acid mixture.
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4940786 |
One-pot preparation of bismuth (phosph/sulf)ated saccharides
Bismuth salts of phosphorylated and/or sulfonated saccharides can be prepared in one reaction vessel from a corresponding metal salt reactant, a water soluble organic acid, and a bismuth substance....
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4939244 |
Pseudoaglycones of LL-E33288 antibiotics
Degradation products, termed pseudaglycones, of LL-E33288, BBM-1675, FR-900405, FR-900406, PD 114759, PD 115028, CL-1577A, CL-1577B, CL-1577D, CL-1577E and CL-1724 antibiotics/antitumor agents are...
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4935503 |
Azidochlorination and diazidization of glycals
The invention describes a one-pot single step procedure for the azidochlorination or diazidization of glycals, including glycal elements of carbohydrates. Compounds such as...
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4935506 |
3-phenylthiosialic acid derivative, sialic acid-containing oligosaccharide derivative and process for preparing these compounds
Sialic acid derivatives and process for preparing these compounds. In these compounds, a phenylthio group is stereo-selectively incorporated at the 3-position of the sialic acid. These compounds...
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4921950 |
Preparation of 3'azido-3-'-deoxythymidine
This invention relates to a new synthetic process for the manufacture of zidovudine from the starting material D-xylose involving: (i) Conversion of D-xylose to a 1-(β-D-xylofuranosyl)thymine...
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4920207 |
Selected removal of trityl groups from trispa
2,3,4,3',4'-penta-O-acetyl sucrose (4-PAS), a key intermediate in the preparation of sucralose, is prepared by the selective removal of trityl groups from 6,1', 6'-tri-O-trityl-penta-O-acetyl...
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4918056 |
2-substituted arabinopyranosyl nucleosides and nucleotides
Novel arabinopyranosyl nucleoside derivatives having the heterocyclic moiety and fluorine at the 2' position of the sugar ring (pyranose configuration), which have antitumor, antiviral and...
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4918182 |
Sweetener
Crystalline sucralose having a mean particle size of at most 10 microns, the maximum particle size being no more than twice the mean, exhibits enhanced stability to heat. Preferably the sucralose...
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4916219 |
Oligosaccharide heparin fragments as inhibitors of complement cascade
There is disclosed oligosaccharide compounds having heparin-like anticomplement activity and reduced anticoagulant activity as compared with heparin on a weight or molar basis. The oligosaccharide...
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4916218 |
1-(β-D-xylofuranosyl)thymine derivatives
This invention relates to a new synthetic process for the manufacture of zidovudine from the starting material D-xylose involving: (i) Conversion of D-xylose to a 1-(β-D-xylofuranosyl)thymine...
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4914035 |
Process for producing sialic acid derivatives
The present invention provides a process for selective production of a 2-α-O-glycoside compound of sialic acid which is useful as a starting material or intermediate for medicines and biochemical...
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4914196 |
Complexes containing optically active sugar ligands, a process for their preparation and their use
Compounds of the formulae I and Ia ##STR1## in which R 1 is a group which can be transferred to carbonyl or imine compounds, for example alkyl, allyl, vinyl or the radical of an enol or enamine, R...
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4912204 |
Fluoro-substituted epipodophyllotoxin glucosides
The present invention provides antitumor fluoro-substituted 4'-demethylepipodophyllotoxin glucosides.
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4906579 |
New catalytically oxidized polyglucosic units and methods of making same leading to aldehyde groups on the C-6 position of polyglucosic product and new products therefrom
A method to selectively oxidize a polyglucose, on the oxygen of the hydroxy groups of the C-6 position of the glucose rings, while substantially maintaining the degree of polymerization of the...
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4900816 |
Hemoglobin complexes
There is described a water soluble compound having a molecular weight of from about 70,000 to about 2,000,000 and having the formula I, B--X--(PS)--X--(H) ...
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4889843 |
Salt of trisaccharide, and composition and process for re-stimulating hair growth
The salt formed between the polyanions forming the Trichosaccharide and the NH 2 groups of 2,4-diamino-6-piperidino-pyrimidine-3-oxide represents a novel trichogenic factor by which the activity...
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4889928 |
Sucrose alkyl 4,6-orthoacylates
Sucrose 6-acylates, key intermediates in the preparation of sucralose, can be prepared by subjecting a sucrose alkyl 4,6-orthoacylate to mild aqueous acidic hydrolysis to provide a mixture of...
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4871776 |
2,5-anhydro-1,6-dihalo-1,6-dideoxy-D-mannitol
A novel fructose analog is disclosed which has been found to modify the food intake of mammals. If administered during the diurnal fasting period, the mammals increase their food intakes. If...
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4855416 |
Method for the manufacture of dextran sulfate and salts thereof
A method for the preparation of dextran sulfate and salts thereof which comprises first forming a complex between sulfur trioxide and formamide at a controlled temperature between 15°-40° C. in...
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4847372 |
Process for the single-stage preparation of glycosyl fluorides
A process for the single-stage preparation of glycosyl fluorides by dissolving saccharides in liquid hydrogen fluoride and evaporating the hydrogen fluoride, wherein the resulting glycosyl fluoride...
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4826962 |
Tetrachlororaffinose and its use in the preparation of sucralose
The novel chlorinated sugar O-α-D-6-chloro-6-deoxygalactopyranosyl-(1➝6)-α-D-4-chlo ro-4-deoxygalactopyranosyl-(1➝2)-β-D-1, 6-dichloro-1, 6-dideoxyfructofuranoside (TCR) can be used to...
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4820692 |
Methylthioribose analogs, their preparation and use as medicinal agents and biocides
Compounds of the formula: ##STR1## wherein R is H, Cl, F, Br, I or R 1 S--, in which R 1 is C 1 -C 10 linear or branched chain alkyl or halogenated linear or branched chain alkyl, and ...
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4816573 |
Separation of carrageenan containing sea plants
Sea plants containing kappa carrageenan are separated from those containing lambda carrageenan by subjecting a mixture of such plants to preferential hydration of the lambda plants without...
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4810695 |
Chitosan derivatives in the form of coordinated complexes with ferrous ions
Chitosan derivatives in the form of coordinated complexes with ferrous ions in which coordinated bonds are established between the ferrous ion and the amino group and hydroxyl group present...
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4806275 |
Ionic derivatives of alkyl mono and polyglycosides
New anionic derivatives of mono and polyglycosides which are surface-active agents are described which anionic derivatives have the general formula ##STR1## wherein G is a glycosyl moiety which is...
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4801700 |
Process for the preparation of 1,6-dichloro-1,6-dideoxy-β-D-fructofuranosyl-4-chloro-4-deoxy-α -
A process for the preparation of 1,6-dichloro-1,6-dideoxy-β-D-fructofuranosyl-4-chloro-4-deo
xy-α -galactopyranoside comprising the steps of (a) reacting sucrose with a tritylating agent; (b)...
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4794178 |
Process for the production of .sup.18 F-labeled organic compounds by nucleophilic substitution
Organic compounds labeled with no-carrier-added fluorine 18 are processed yield a compound having a formula in the form of 18 F-R through a nucleophilic substitution reaction. The process has a...
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4783526 |
Chlorination of carbohydrates and other alcohols
Chlorination of carbohydrates and alcohols utilizing a chlorinating reagent selected from triphenylphosphine oxide/thionyl chloride, thiphenylphosphine oxide/phosgene, triphenylphosphine...
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