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6927284 |
1:2 metal complex dyes, their compositions, their production and their use
1:2-metal complex dyes of the formula
wherein the symbols R 1 , R 1 ′, R 2 , R 2 ′, R 3 , R 3 ′, Y, Z, n, n′, Me, M and (Kat) + are defined as in the Claims, mixtures thereof, their...
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6764524 |
1:2 chromium complex dyes, their production and use
Asymmetrical 1:2 chromium complex dyes of formula (I), wherein X signifies —SO 3 M, —SO 2 NR 1 R 2 or chlorine, Y signifies hydrogen, —SO 3 M or chlorine, R 1 signifies hydrogen, C 1-6...
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6132894 |
1:2 Iron azo-dyestuff complexes
A compound of formula (I) or a mixture thereof ##STR1## The compounds are useful as solvent dyestuffs and exhibit high solubility in alcoholic solvents, e.g. ethanol.
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5962657 |
Complex polymethine dyes and their use
A cyanine dye complex of formula I ##STR1## consisting of a cyanine dye and a chromium or cobalt metal azo ligand complex is particularly useful in a process for optically recording, storing or...
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5853431 |
1:2 Chromium complexes, their production and use
Compounds of formula (I) ##STR1## wherein R 1 is H or SO 3 M, ##STR2## M is hydrogen or a non-chromophoric cation and X + is hydrogen or a non-chromophoric cation, are useful as dyes for...
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5484900 |
1:2 chromium complex dyestuffs
1:2 chromium complex dyestuffs of the formula (I) ##STR1## in which A, B, R 1 , R 2 , R 3 , R 4 , p, m, n, n' and Cat (+) have the meaning given in the description, are suitable for dyeing and...
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5401834 |
Asymmetrical 1:2 chromium and cobalt complexes of further substituted 6- or 7-amino-1-hydroxy-2-(nitro-phenylazo)-3-sulfonapthalenes
Complexes of the formula ##STR1## which are in free acid or salt form, and mixtures thereof, wherein each of R 1 and R 3 is independently hydrogen, C 1 -4 alkyl or C 1 -4 alkyl monosubstituted...
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5283325 |
1:2 chromium and cobalt complexes of monoazo compounds having further unsubstituted or substituted nitro-2-hydroxyphenyl diazo component radicals and 6- or 7-acyl-amino-1-hydroxy-3-sulfonaphthalene coupling component radicals
1:2 metal complexes of the formula ##STR1## wherein each of R 1 and R 3 is independently hydrogen or nitro, with the proviso that when a ring has two nitro groups, they are meta to each other, ...
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5250671 |
Unsymmetrical 1:2 chromium complex dyestuffs
The novel unsymmetrical 1:2 chromium complex dyestuffs of the formula ##STR1## in which the substituents R 1 , R 2 , R 3 , n and Cat (+) have the meaning given in the description, are highly...
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5229502 |
Preparation of 1:2 chromium complexes one sulfo substituted and one sulfonamido or the like substituted azo dyes
A process is described for the preparation of pure, asymmetric 1:2 chromium complex dyes containing at least two groups which impart solubility in water, which process comprises reacting a mixture...
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4997917 |
Preparation of 1:2 chromium complex azo dyes asymmetrically substituted with solubilizing
The invention relates to a process for the preparation of asymmetrical 1:2 chromium complex dyes of not less than 90% purity and containing at least one water-solubilizing group, which process...
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4996303 |
Preparation of 1:2 metal complex dyes by coupling in the presence of a metal donor in an inert gas atmosphere
The invention relates to a process for the preparation of 1:2 metal complex azo dyes of formula ##STR1## wherein each X is hydrogen, halogen or nitro, K and K' are each independently of the other...
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4977249 |
Metal of hydroxy-phenylaze and hydroxy-naphthylazo compounds as near-red absorbers
A metal complex compound having the formula: ##STR1## wherein each of X 1 and X 2 which may be the same or different, is a nitro group, a halogen atom, a phenylazo group (inclusive of a...
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4960870 |
Heavy metal complex azo dyes containing a benzothiophene-1,1-dioxide, 2,1-benzothiazine-2,2-dioxide, 1,4-benzothiazine-1,1-dioxide or thienopyridine-1,1-dioxide coupling component
The heavy metal complex dyes of azo or azomethine dyes of the formula ##STR1## in which D is the radical of a dizao component of the benzene, naphthalene or heterocyclic series, K--OH is the...
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4904767 |
Asymmetric 1:2-chrome complexes of benzene-azo-naphthalene/naphthalene-azo-naphthalene acid dyes for leather
Asymmetric 1:2-chrome complex dyes of the formula: ##STR1## wherein A is the radical of 1-hydroxynaphthalene or 2-hydroxynaphthalene, R 1 is hydrogen, chlorine or methyl, R 2 is hydrogen,...
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4874849 |
Asymmetric 1:2-chromium complex dyes containing two azo dyes, one containing an acetoacetanilide coupling component
Dyes suitable for dyeing wool, polyamide and leather in orange, brown or olive-brown shades are disclosed, the dyes having the formula ##STR1## wherein A and D are each independently of the other a...
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4820309 |
1:2-chromium complex dyes for tanned leather
Complexes of the formula ##STR1## wherein each R 1 is independently (a) the radical of a coupling component of the active methylene non-cyclic or homocyclic series, (b) the radical of a coupling...
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4804386 |
Chromium complex dye for polyamides or leather
A chromium complex dye of the formula ##STR1## and salts thereof are used for dyeing polyamides or leather.
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4710198 |
1:2 chromium or cobalt metal complex dyes and use thereof for dyeing leather
A process of dyeing polyamide-containing material is disclosed using dyes of the following formula: ##STR1## wherein Me is cobalt or chromium, Ka ♁ is a cation, p is 0 or 1, R and R' are...
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4665162 |
1:1 and 1:2 metal complexes of sulfo group-free azo compound having on average at least 1.3 basic water-solubilizing groups
Metal-free azo compounds of the formula ##STR1## wherein Ra is an aromatic group or an active methylene coupling component radical as defined in the specification, R t is an arylazo group or a...
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4663441 |
Asymmetric 1:2 chrome complex dye of a phenylazosulphonaphtholamine and a naphtholazosulphonaphthol
Compounds of the formula I ##STR1## where K ♁ is a cation, R is methyl or is phenyl which is unsubstituted or substituted by chlorine, bromine, methyl, methoxy or ethoxy, R 1 is hydrogen,...
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4661587 |
Bis 1:2 chromium complexes of disazo and azo or azomethine dyes
Disclosed are chrome complex dyes of the formula ##STR1## and of the formula ##STR2## wherein Z and Z' independently of one another are each nitrogen or --CH--; X and X' independently of one...
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4625017 |
Metal complexes of azo dyes containing a 2-(P-N-aceloacetylaminophenyl) benzothiozole moiety
Metallizable azo dyes of the formula I ##STR1## wherein A is the radical of a diazo component of the benzene or naphthalene series, which diazo component contains in the o-position with respect to...
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4624907 |
Electrophotographic toner containing metal complex
An electrophotographic toner capable of being electrified negatively comprising: (a) a binder resin; and (b) a charge-controlling and coloring agent comprising at least one 2:1 type metal...
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4594410 |
Azo compounds containing both sulfo groups and basic or cationic groups which compounds are in metal-free or 1:1 metal complex form
Azo dyes of the formula ##STR1## and external salts thereof, wherein F is the residue of a monoazo or disazo compound in 1:1 metal complex form or of a trisazo, disazoazoxy or tetrakisazo compound...
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4582896 |
1:2-metal complex dyes containing one atom of chromium or cobalt and two azo dyes each formed by coupling two diazo compounds to resorcinol
Dyes of the formula ##STR1## in which Me is cobalt or chromium, A is a diazo component of a benzene or naphthalene which carries a hydroxyl or carboxyl group in the o-position relative to the azo...
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4560747 |
Process for producing granulates of water-soluble dyes by fluidized bed granulation
A process for producing granulates of water-soluble dyes by means of fluidized bed granulation, wherein there is added a granulating auxiliary having a softening point or softening range between...
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4560744 |
Azo dye 2:1-chromium complexes
Compounds which in the form of the free acids correspond to the formula ##STR1## where A is a radical of a diazo component or of an amine, B is a radical of a coupling component or of an...
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4553976 |
Process for dyeing or printing polyamide fibres
The invention describes a process for dyeing or printing natural or synthetic polyamide fibre material by a rapid fixation method, which comprises the use of dyes or mixtures of dyes of the...
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4544739 |
Fibre-reactive chromium complex Azo-azomethine dyes
Chromium complex dyes which, in the form of the free acid, have the formula ##STR1## wherein Z is hydrogen, nitro, chlorine or naphthylazo or phenylazo, wherein naphthyl or phenyl is unsubstituted...
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4537955 |
Unsymmetrical 1:2 chromium complex of a monoazo dyestuff and a disazo dyestuff which is non-fiber reactive and contains no sulfonamido or amino groups
An unsymmetrical 1:2 chromium complex of a monoazo dyestuff and a disazo dyestuff which is non-fiber reactive and is free of sulfonamido and amino groups and which, in the form of the free acid has...
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4502865 |
Fibre-reactive chromium complex dyes, process for their manufacture and use thereof to dye cellulose or wool
Novel chromium complex dyes are disclosed which have the formula ##STR1## wherein S 1 represents a hydrogen or halogen atom, a nitro group, a sulpho group, an alkyl or alkoxy radical, an acylamino...
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4432898 |
Sulfo-substituted fibre-reactive 1:2-chromium complex azo dyes
Chromium complex dyes are disclosed which have the formula ##STR1## wherein S 1 represents a hydrogen or halogen atom, a nitro group, a sulpho group, an alkyl or alkoxy radical, an acylamino or...
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4416815 |
Fiber-reactive unsymmetrical 1:2 chromium complex azo dyes
Chromium complex dyes which, in the form of the free acid, have the formula ##STR1## wherein Z is hydrogen, nitro, chlorine, or an arylazo group, Q is a nitrogen atom or the CH-- group, A is the...
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4396544 |
Asymmetric 1:2 chromium complexes of monoazo compounds
1:2 Chromium complexes of the formula, ##STR1## in which R 1 is hydrogen, chlorine, bromine, nitro (being meta to the first nitro group), C 1 -4 alkyl or C 1 -4 alkoxy, R 2 is hydrogen or...
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4370268 |
Reactive dyestuffs
Reactive dyestuffs of the formula ##STR1## wherein D, R, R 1 , R 2 , n, p, R 3 , R 4 and m have the meaning indicated in the description, and their use for dyeing and printing various materials,...
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4340536 |
Chrome-complex dyes and the production and use thereof
Chrome-complex dyes for dyeing natural and synthetic polyamide materials, which dyes, in the form of the free acid, correspond to the formula ##STR1## wherein X, W, R 1 , A, q, p, B, Z, D, Y and n...
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4328220 |
Non-dusty pulverulent and granulated organic dye preparations
Non-dusting pulverulent or granulated dye preparations are provided which contain (1) an organic dye, (2) a non-ionic compound having a hydrotropic action and at least one of the components (3) or...
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4322529 |
Tertiary-alkylamine salts of azine dyestuffs
New dyestuff salts of the formula ##STR1## wherein A denotes the radical of an azine dyestuff, R, R 1 and R 2 denote alkyl radicals with a total of 10-24 carbon atoms and n denotes the number...
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4315854 |
Chromium and cobalt complex amino hydroxy azomethine dyes
1:2 Metal complex dyes of azomethines of the formula ##STR1## wherein R is hydrogen, unsubstituted or substituted alkyl, aralkyl, aryl, alkylsulfonyl or arylsulfonyl, A is the radical of an...
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4219472 |
5-Aminomethyl-2-amino naphthyl-(1) azo dyes
The invention relates to novel azo dyes of the formula ##STR1## wherein R 1 represents hydrogen, alkyl of 1 to 8 carbon atoms or the phenyl radical, R 2 represents hydrogen, an acyl radical or a...
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4212802 |
1:2 Chromium complexes of disazo compounds
Complexes of the formula ##STR1## in which each of X 1 and X 2 , independently, is --COO-- or --O--, each of B 1 and B 2 , independently, is the radical of a coupling component of the benzene...
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4180502 |
Manufacture of concentrated solutions, having a low salt content, of cobalt and chromium 1:2 complex dyes which are free from sulfonic acid groups
A process for the manufacture of concentrated solutions, having a low salt content, of o,o'-dihydroxy-or o,o'-dihydroxycarboxy-cobalt and -chrominum 1:2 complex dyes which are free from sulfonic...
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4165314 |
Mixtures of 1:2 cobalt complexes of monoazo compounds having an acetoacetanilide coupling component radical
Mixtures of symmetrical and asymmetrical 1:2 cobalt complexes of compounds of the formulae ##STR1## wherein, EACH R 1 , independently, is hydrogen or (C 1 -4)alkyl, and Each R 2 and R 3 ,...
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4159983 |
Pure and substantially pure asymmetric 1:2 cobalt complexes of monoazo compounds
Pure and substantially pure asymmetric 1:2 cobalt complexes of the formula, ##STR1## and mixtures of such complexes, in which X is hydrogen or nitro, either, R 1 and R 2 , independently, are...
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4155903 |
Asymmetrical 1:2 cobalt complexes of certain substituted phenylazonaphthalenes
Disclosed are homogeneous complexes of the formula ##STR1## wherein R 1 is hydrogen, alkyl, phenyl or substituted phenyl, ##STR2## WHEREIN ONE Q is hydrogen and the other is sulfo, and N IS 0 OR 1...
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4085097 |
Process for the manufacture of chromium complexes from metallizable azo or azo methine dyes
A process is described for the manufacture of chromium complexes of metallizable dyes in the form of solid dyestuff powders of low salt to salt-free content, or of concentrated solutions of low...
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4053462 |
Unsymmetrical phenyl azo naphthyl chromium complex dyes
Chromium complex dyes which, in the form of their free acid, have the formula ##STR1## wherein one X represents the sulphonic acid group and the other X represents the nitro group, Y is a sulfone...
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4051116 |
Assymmetrical 1:2 cobalt complexes of metallizable monoazo compounds having one sulfo group per complex
Complexes of the formula ##STR1## wherein R 1 is hydrocarbyl or substituted hydrocarbyl, EACH OF R 2 and R 3 is independently hydrogen, lower alkyl or substituted lower alkyl, Each of X 1 ...
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4045424 |
Salt of a sulfonic acid substituted 1:2 metal complex dye with a basic dye and an amine
A dye salt of the formula ##STR1## WHEREIN Me is cobalt or chromium, X is --O-- or --COO--, Y and Y' each is hydrogen, chlorine or nitro, n is 1 or 2, a + b = n + 1 and neither a nor b is zero, the...
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