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4558118 |
Two phase interfacial polycondensation polycarbonate process
This invention relates to an improved interfacial polycondensation aromatic polycarbonate process which does not require large quantities of strong base to provide a particulate product. The...
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4558106 |
Polymerization process using metal formate to reduce the color of thermoplastic copolymers
Described is a process for improving the color of thermoplastic polymers by contacting the monomer(s) before or during polymerization with an alkali or alkaline earth metal formate.
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4535143 |
Process for the preparation of copolycarbonates of sulfonyl diphenol
The present invention is directed to a continuous process for the preparation of copolycarbonates of sulfonyl diphenol (SDP) containing at least about 15, preferably about 15 to about 80 percent by...
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4533722 |
Interfacial polycondensation polycarbonate process with quaternary phosphonium amino halide catalyst
This invention relates to an improved interfacial polycondensation polycarbonate process wherein a dihydric phenol is reacted with a carbonyl halide in the presence of a quaternary-phosphonium...
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4529791 |
Interfacial polycarbonate preparation by adding additional solvent
An interfacial process for the preparation of polycarbonates having improved optical properties is disclosed wherein dihydric phenols are reacted with phosgene in the presence of an aqueous alkali...
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4520187 |
Polycarbonates and polyester carbonates exhibiting improved heat resistance
Novel heat resistant polycarbonates are provided which are the polymerized reaction products of: (i) a carbonate precursor; and (ii) at least one dihydric phenol selected from dihydric...
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4518747 |
Polycarbonates having terminal groups which contain conjugated double bonds
The present invention is directed to molding compositions comprising aromatic, thermoplastic polycarbonate resins at least some molecular chains thereof are characterized in that their terminal...
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4515936 |
Catalyzed interfacial polycondensation polycarbonate process
This invention relates to a catalyzed interfacial polycondensation aromatic polycarbonate process which comprises forming an agitated two-phase mixture comprising an organic solvent phase with...
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4506066 |
Thermoplastic polycarbonates, their preparation and their use as shaped articles and films
The present invention relates to high molecular weight thermoplastic hexahydro-furo-(3,2-b)-furane-3,6-diol based copolycarbonates useful as molding resins and to a method for their preparation.
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4503213 |
Process for the preparation of polycarbonates having N-alkyl-perfluoroalkyl sulfonamide terminal groups
The instant invention relates to a process for the preparation of linear aromatic polycarbonate resins by the known two-phase interfacial process and is directed to the use of perfluoroalkyl...
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4471104 |
Process for the preparation of polycarbonates having sulfonanilide terminal groups
The present invention relates to the preparation of aromatic polycarbonates by the known two-phase interface process, from diphenols characterized in that aromatic sulfonanilides are used as chain...
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4452966 |
Process for the production of polycarbonate
A process for producing polycarbonate is described, comprising reacting a chloroformate group-containing polycarbonate oligomer with an aqueous alkaline solution of a compound containing at least...
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4448950 |
Polycarbonate having improved critical thickness
Polycarbonates are provided having improved critical thickness values based on an aromatic diphenol preferably bisphenol A and an aromatic diphenol thioether. By incorporating 2 up to 20 mole...
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4448953 |
Preparation of benzoate ester terminated polycarbonate with aroyl halide
A process for preparing an aromatic polycarbonate of controlled molecular weight which comprises interfacially reacting in water and an organic solvent, a dihydric phenol, a carbonate precursor and...
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4436839 |
Process for preparing polycarbonate-polyether-blockcopolymers
A method for production of polycarbonate-polyether-blockcopolymers is provided. One or more solutions comprising bisphenol A and polyalkyleneglycol and a phosgene solution are added to a cooled...
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4393190 |
Carbonate copolymers prepared from imide reactants
Novel carbonate polymers comprised of the reaction product of a dihydric phenol, a carbonate precursor, and at least one imide selected from the group of compounds represented by the formulae ##STR1##
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4388455 |
Process for preparing ester carbonate copolymers
Ordered ester/carbonate copolymers having improved properties at higher solids are provided by (1) contacting a dihydric organic compound such as bisphenol-A with a diacid halide such as...
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4384108 |
Two-phase interfacial polycarbonate process
An improved interfacial polycondensation polycarbonate process, the improvement comprising an initial equilibrated pH range of 11 to 13, a temperature range of 15° to 40° C., a carbonyl halide...
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4378454 |
Preparation of polycarbonates in a homogeneous solution
Polycarbonates are prepared in homogeneous solutions from dihydric phenols and phosgene wherein the stoichiometric end point for the addition of phosgene is accurately controlled by using...
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4363905 |
Polycarbonate transesterification from bis(ortho-nitroaryl)carbonate
A polycarbonate transesterification process comprising reacting a bis(ortho-nitroaryl)carbonate and a dihydric phenol under transesterification reaction conditions.
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4361693 |
Preparation of poly(arylene ketones) using thio- and dithiocarbonic acid derivatives
Poly(arylene ketones) are prepared by the reaction of difunctional aromatic compounds with derivatives of thio- or dithiocarbonic acids in the presence of a superacid catalyst system. In a...
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4346210 |
Process for the preparation of polycarbonates catalyzed by cyclic aza compounds
The present invention relates to a process for the preparation of aromatic polycarbonates from diphenols by the phase boundary process, which is characterized in that cyclic, preferably monocyclic...
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4345062 |
Polycarbonate transesterification with tetraborate or tetraaluminate anion containing catalyst
An improved aromatic polycarbonate transesterification process comprising reacting a bis(aryl)carbonate and a phenol in the presence of a transesterification catalyst containing tetraborate or...
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4330664 |
Polycarbonate transesterification with catalyst containing aluminum hydride or borohydride group
An improved aromatic polycarbonate transesterification process comprising reacting a bis(aryl)carbonate and a dihydric phenol in the presence of a transesterification catalyst, the improvement...
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4327015 |
Flame resistant, transparent polycarbonates comprising bisulfite adducts
The invention is directed to flame-resistant, transparent aromatic polycarbonate compositions comprising polycarbonate resin and an additive amount of a member selected from the group consisting of...
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4316980 |
Process for the preparation of tetramethylated bisphenol polycarbonates
The present invention relates to a process for the preparation of thermoplastic, aromatic polycarbonates which contain structural units of the formulae 1 and/or 2 ##STR1## in which R denotes C 1 ...
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4299948 |
Macrocyclic polycarbonates
The subject of the instant invention are polycarbonates based on diphenols of the formula I ##STR1## wherein Y is a single bond, an elkylene- or alkylidene-radical with 1 to 7 carbon atoms, a...
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4297455 |
Process for the preparation of carbonic acid aryl esters of polyester-diols lengthened via carbonate groups and their use for the preparation of polyester-diol bis-diphenol carbonates and polyester/polycarbonates
The present invention relates to a process for the preparation of bis-carbonic acid aryl esters of polyester-diols, lengthened via --OCOO-- groups, characterized in that polyester-diols with...
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4291151 |
Process for preparing polycarbonate using cyclic di- or triamine catalyst
An interfacial polymerization process for preparing high molecular weight aromatic polycarbonates by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount of...
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4291150 |
Process for preparing polycarbonate using non-cyclic polyamine catalysts
An interfacial polymerization process for preparing high molecular weight aromatic polycarbonates by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount of...
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4286083 |
Method of preparing polyester carbonates
A novel process is disclosed for the preparation of copolyesters containing both carboxylate and carbonate groups. The process comprises reacting a carbonyl halide with a difunctional carboxylic...
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4286085 |
Process for preparing polycarbonates using substituted pyridine catalysts
An interfacial polymerization process for preparing a high molecular weight aromatic carbonate polymer by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount...
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4286084 |
Process for preparing polycarbonate using certain nitrogen-containing heterocyclic compounds as catalysts
An interfacial polymerization process for preparing high molecular weight aromatic polycarbonates by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount of a...
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4286086 |
Process for preparing polycarbonate using sterically hindered secondary amine catalysts
An interfacial polymerization process for preparing high molecular weight aromatic polycarbonates by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount of...
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4281101 |
Process for the preparation of aliphatic-aromatic polycarbonates with diphenol carbonate end groups and their use for the preparation of high-molecular, segmented, aliphatic-aromatic polycarbonate elastomers which can be processed as thermoplastics
The subject of instant invention is a process for the preparation of aliphatic-aromatic polycarbonates with diphenol carbonate end groups, the polycarbonates obtained therefrom and their use for...
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4277597 |
Process for preparing polycarbonates using sterically hindered heterocycloaliphatic secondary amine catalysts
An interfacial polymerization process for preparing high molecular weight polycarbonates by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount of a...
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4277598 |
Process for preparing polycarbonates using cyclic amidine catalysts
An interfacial polymerization process for preparing high molecular weight aromatic polycarbonates by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount of a...
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4277599 |
Process for preparing polycarbonates using pyrrole catalysts
An interfacial polymerization process for preparing a high molecular weight aromatic carbonate polymer by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount...
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4268658 |
Process for preparing polycarbonates using iminoethers as catalysts
An interfacial polymerization process for preparing high molecular weight polycarbonates by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount of an...
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4267305 |
Process for preparing polycarbonates using nitrogen crown-cyclic compounds as catalysts
An interfacial polymerization process for preparing a high molecular weight aromatic carbonate polymer by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount...
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4267303 |
Process for the preparation of polymers with diphenol carbonate end groups
This disclosure is concerned with a single step process for the production of diphenol terminated polycarbonates by the transesterification of diphenols, bis-aryl carbonates and polymeric diols...
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4262111 |
Process for preparing polycarbonates using amidine catalysts
An interfacial polymerization process for preparing high molecular weight polycarbonates by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount of a...
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4262113 |
Process for preparing polycarbonates using amino guanidine or amino amidine catalysts
An interfacial polymerization process for preparing high molecular weight aromatic polycarbonates by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount of...
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4262110 |
Process for preparing polycarbonate using cyclic iminoethers as catalysts
An interfacial polymerization process for preparing a high molecular weight aromatic carbonate polymer by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount...
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4262112 |
Process for preparing polycarbonates using cyclic isourea catalysts
An interfacial polymerization process for preparing a high molecular weight aromatic carbonate polymer by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount...
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4258174 |
Process for preparing polycarbonates using isourea catalysts
An interfacial polymerization process for preparing a high molecular weight aromatic carbonate polymer by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount...
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4252939 |
Method for manufacture of aromatic polyester-polycarbonate
An aromatic polyester-polycarbonate is prepared by (a) forming a low molecular weight polyester oligomer possessing terminal -OH groups by reacting a solution of a terephthaloyl chloride...
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4247475 |
Chloroformates of cyanoacrylates
Certain cyanochloroformates are described which have utility for imparting UV stability to polycarbonate resins.
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4219635 |
Process for poly (bisphenol A/terephthalate/carbonate) using pyridine reaction medium
Poly(ester/carbonates) are produced by adding phosgene to a reaction mixture of bisphenol A and terephthalic acid as ester-forming reactants, at mole ratios in the range between 2.0:0.8 and...
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4217437 |
Process for the preparation of carbonic acid bis-diphenol esters of polyalkylene oxide-diols lengthened via carbonate groups and their use for the preparation of high-molecular, segmented polyether/polycarbonates which can be processed as thermoplastics
The present invention relates to the transesterification of the carbonic acid aryl esters obtainable according to German Published Patent Specification No. 2,650,533 with an excess of diphenol for...
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