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5258484 |
Process for the production of polycarbonate
A process for the continuous production of a thermoplastic aromatic polycarbonate is disclosed. Accordingly, in a reactor system which includes a tube reactor and a tank equipped with a stirrer,...
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5235026 |
Continuous production of polycarbonates
An improvement to the continuous process for the production of polycarbonates by interphase polycondensation is described. Accordingly, the organic phase and the aqueous phase are combined in a...
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5225518 |
Polycarbonate preparation from molten bisphenol-A/water mixture
In the interfacial polymerization process for preparing aromatic carbonate polymers by reacting bisphenol-A with a carbonate precursor, the bisphenol-A is introduced to the reaction medium in a...
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5210173 |
Catalytic, interfacial preparation of aromatic polycarbonates with continuous dosing of carbonate precursor
The invention relates to a method of preparing aromatic polycarbonates by catalytic interface polymerization of at least one bivalent phenol and a carbonyl halide in the presence of a...
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5210172 |
Method for the continuous preparation of carbonate oligomers with loop reactor, static mixer and plug flow
The invention relates to a method for the continuous preparation of carbonate oligomers by boundary face oligomerization of aromatic dihydroxy compounds with phosgene while adding base, in which...
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5200496 |
Process for preparing polycarbonate having reduced carbonate byproduct content
A process for preparing polycarbonate wherein a chain terminator is added to the reaction mixture after substantial reaction of a carbonate precursor, a coupling catalyst is added to the reaction...
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5187255 |
Method of producing a polyether copolymer
A method of producing a polyether copolymer by reacting a dihalogenobenzonitrile, 1,4-bis(4'-halobenzoyl)benzene, with 4,4'-biphenol in an aprotic polar solvent in the presence of an alkali metal...
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5168112 |
Process for the preparation of a polycarbonate with piperidinyl pyridine catalyst
A polycarbonate is produced by melt-polycondensing a dihydric hydroxy compound and a bisarylcarbonate in the presence of 4-(4-methyl-1-piperidinyl)-pyridine, or a salt thereof, as a catalyst. The...
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5151491 |
Catalytic melt condensation preparation of polycarbonate
Disclosed herein are processes for the production of polycarbonates by melt polycondensation of an aromatic dihydroxy compound and a carbonic acid diester or a diphenyl carbonate compound wherein...
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5149770 |
Preparation of a polycarbonate with electron donative amine compound and alkali or alkaline earth metal compound
A polycarbonate is produced by melt-polycondensing a dihydric hydroxy compound and a bisarylcarbonate in the presence of a catalyst system comprising an electron donative amine compound and a...
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5142018 |
Process for preparing polycarbonates
A process for preparing polycarbonates according to the invention by melt polycondensation of aromatic dihydroxy compounds and carbonic acid diesters, is characterized by using an aromatic...
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5115081 |
Process for producing copolycarbonate oligomer from dichloroformate
A process for producing a dichloroformate of a tetrahalogenated bisphenol by an interfacial process in a high yield and a high content and a process for producing an aromatic copolycarbonate...
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5097002 |
Melt, catalytic process for preparing polycarbonates from carbonic acid diester
A process for preparing polycarbonates according to the invention by melt polycondensation of aromatic dihydroxy compounds and carbonic acid diesters, is characterized by using an aromatic...
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5097009 |
Method for making cyclic oligomeric aromatic polycarbonates from monochloroformate
A method for making cyclic polycarbonate oligomers is provided by converting oligomeric monochloroformate carbonates to the cyclic state. Improvements in materials usage, process control, and...
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5077379 |
Coating compositions based on unsaturated polyester, latent polyamine and cyclic ketone
A curable coating composition which comprises a) a condensation polymer in which the backbone contains activated unsaturated groupings. b) a compound containing at least three blocked primary...
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5047497 |
Water-in-oil emulsion process for producing an aromatic polycarbonate
A process for producing an aromatic polycarbonate in a water-in-oil emulsified form, having an improved heat stability during molding at a high temperature, is described. In the process according...
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5043403 |
Polycarbonates containing mesogenic compounds as end groups, their preparation and their use
This invention relates to thermoplastic, aromatic polycarbonates in which mesogenic compounds corresponding to the following formula ##STR1## are incorporated as chain terminating agents, to their...
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5041523 |
Process for production of branched polycarbonate
A process for producing a branched polycarbonate by an interfacial polycondensation method comprising condensing a first reaction mixture comprising an inert organic solvent, an alkaline aqueous...
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5037941 |
Interfacial preparation of polycarbonate prepolymer with motionless mixer
Polycarbonate prepolymers are produced by adding phosgene, one or more dihydric phenols, a halogenated organic solvent, and an aqueous caustic solution together with mixing in motionless mixers to...
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5028690 |
Aromatic polycarbonate end capped with maleimide moiety
An aromatic polycarbonate containing at least one terminal group represented by the formula ##STR1## wherein R and R' are the same or different and are alkyl, aryl or halogen; a and b are the same...
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5026817 |
Catalytic process for preparing polycarbonates from carbonic acid
A process for preparing polycarbonates according to the invention by melt polycondensation of aromatic dihydroxy compounds and carbonic acid diesters, is characterized by using an aromatic...
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5025083 |
Process for preparation of polycarbonate
A polycarbonate is produced by melt-polycondensing (A) a dihydric phenol with a co-monomer selected from the group consisting of (B) bisphenol carbonate, (C) bis(2,4,6-trichlorophenyl) carbonate...
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5021541 |
Polycarbonate resin from bis(hydroxy benzoyl oxy-tetra oxa spiro) cpd.
A polycarbonate resin comprising either a structural unit derived from a spiro ring-containing dihydric phenol, or such a structural unit and a structural unit derived from a dihydric phenol, and a...
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4994594 |
Oligomeric carbonate chainstoppers
Oligomeric carbonate dihydroxyaromatic-based chainstoppers are disclosed. One example of this type of chainstopper is a bisphenol A bischloroformate oligomer monocapped with phenol. These...
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4952664 |
Process for producing weather-resistant polycarbonate with triazine-imide chain terminator
A process for producing a weather-resistant polycarbonate resin by solution polymerization, of at least one dihydric phenol and phosgene in which a compound represented by formula (I): ##STR1##...
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4950731 |
Method for preparing spirobiindane polycarbonates
Homo- and copolycarbonates of spirobiindane bisphenols are prepared by first reacting phosgene with a substantially pure spirobiindane bisphenol in the presence of aqueous base in a heterogeneous...
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4940771 |
Reactive polycarbonate end capped with hydroxy phenyl oxazoline
Polycarbonate and polyarylate resins are chain-terminated with a group selected from those of the formula: ##STR1## wherein each R independently represents one of hydrogen or lower alkyl. The...
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4939231 |
Process for producing fatty acid-terminated polycarbonate resin
A process for producing a polycarbonate resin having excellent heat stability from a dihydric phenol compound represented by the formula (1) shown below by an interfacial polymerization method...
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4933425 |
Aromatic polycarbonate capped with norbornene phenyl imide compound
An aromatic polycarbonate containing at least one terminal group represented by the formula ##STR1## wherein R and R' are the same or different and are alkyl, aryl or halogen; a and b are the same...
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4920198 |
Branched polycarbonate from hydroxy-naphthoic acid or derivative, and process for preparing
Branched, thermoplastic polycarbonates, suitable for being processed according to the blow-molding technique, are prepared by copolymerization with hydroxy-naphthoic acids or their derivatives.
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4918155 |
Process for production of polycarbonate
A process for producing polycarbonate is disclosed, comprising reacting a halogenated bisphenol-containing organic dihydroxy compound and a carbonate-forming derivative in a liquid medium in the...
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4902758 |
Preparation of segmented block copolycarbonates
Segmented block copolycarbonates from diphenols and tetrahalogenated diphenols are prepared by phosgenation, under interfacial reaction conditions, initially at a higher pH during which diphenol...
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4889911 |
Process for the production of fully aromatic, thermotropic polyesters and polyester carbonates
Thermotropic, fully aromatic polyesters and polyester carbonates are produced by esterification of optionally substituted p-hydroxybenzoic acids and aromatic dicarboxylic acids with diaryl...
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4888411 |
Crosslinkable polycyclic polycarbonate oligomer and methods for their preparation and use
Polycyclic polycarbonate (or thiol analog) oligomers are prepared from a mixture of at least one bishaloformate with at least one tetraphenol, or thio analogs thereof. Such mixture may also contain...
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4883856 |
Flame-resistant polycarbonates, containing in their polymeric chain units deriving from mono-halogenated tetra-phenyl compounds
Thermoplastic, branched, high-molecular weight polycarbonates endowed with properties of flame-resistance (self-extinguishing polycarbonates) are characterized by the presence in their polymeric...
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4880897 |
Process for preparing aromatic polycarbonates
High molecular weight polycarbonates are prepared by reacting a sterically hindered, substituted aromatic bischloroformate with an alkali metal hydroxide in the presence of a substituted pyridine.
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4857627 |
Amino phenol end capped aromatic polycarbonate reacted with sulfonate
A composition comprising an aromatic carbonate polymer end-capped with a group of the structure ##STR1## wherein --+NR 1 R 2 R 3 is meta or para to the O and R 1 , R 2 and R 3 are the same or...
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4847352 |
Polycarbonate production with motionless mixer
Polycarbonate prepolymers are produced by adding phosgene, one or more dihydric phenols, a halogenated organic solvent, and an aqueous caustic solution together with mixing in motionless mixers to...
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4794156 |
Two stage catalytic production of high molecular weight polyhalobisphenol polycarbonates
High molecular weight polyhalobisphenol polycarbonates are produced by adding phosgene to a polyhalobisphenol in the alkali metal phenate form whereby the chloroformates of the bisphenol are formed...
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4794160 |
Crosslinkable polycyclic polycarbonate oligomers and method for their preparation
Polycyclic polycarbonate (or thiol analog) oligomers are prepared from a mixture of at least one bishaloformate with at least one tetraphenol, or thio analogs thereof. Such mixture may also contain...
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4772526 |
Electrophotographic element
A reusable electrophotographic imaging element having a photoconductive surface layer in which the binder resin comprises a block copolyester or copolycarbonate having a fluorinated polyether...
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4755586 |
Method for preparing crosslinkable polycyclic polycarbonate oligomer compositions with suppression of aqueous emulsion formation
Polycyclic polycarbonate oligomers are prepared by the reaction of a bishaloformate and a tetrahydroxyaromatic compound (and optionally also a dihydroxy compound) in the presence of an olefinic...
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4737573 |
Method for polymerizing aromatic bischloroformate composition to polycarbonate
Bischloroformate oligomer compositions are prepared by passing phosgene into a heterogeneous aqueous-organic mixture containing at least one dihydroxyaromatic compound, with simultaneous...
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4736013 |
Method for the preparation of hydroxy-terminated polycarbonate polymers
A method for preparing thermoplastic carbonate polymers terminated with hydroxy groups is disclosed, in which a dihydric phenol is reacted with a carbonyl halide in the presence of a...
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4730033 |
Coating compositions
Coating compositions which are capable of curing at room temperature comprise (i) a condensation polymer in which the polymer backbone contains at least one grouping of the formula...
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4722994 |
Method of preparing cyclic oligomeric polycarbonates
A catalyzed interfacial polycondensation aromatic polycarbonate process comprising mixing a water soluble metal salt of a dihydric phenol with an aqueous solution of a strong base and a...
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4661566 |
UV-absorbing condensation polymeric composition
Compositions comprising polyester or polycarbonate having reacted therein a total of from about 1.0 to about 5,000 parts by weight per million parts by weight of polyester of at least one UV...
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4650852 |
Method for controlling polymerization rate of cyclic polycarbonate oligomers with pretreated catalyst
Cyclic polycarbonate oligomers are polymerized to linear polycarbonates by contact with a polycarbonate formation catalyst which has been modified by contacting the same with at least one diaryl...
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4631334 |
Optical articles of branched polycarbonate resin
A transparent optical article is disclosed, which is produced by molding a branched polycarbonate resin having a viscosity average molecular weight of from 13,000 to 20,000 as prepared from at...
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4563516 |
Polyether-polycarbonates for dialysis membranes
The present invention relates to a process for the preparation of polyether-polycarbonates, a process for stabilizing the polyether-polycarbonates thus prepared, a process for the production of...
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