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8088868 |
Polymers functionalized with protected oxime compounds
A method for preparing a functionalized polymer, the method comprising the steps of (i) polymerizing conjugated diene monomer by employing a lanthanide-based catalyst to form a reactive polymer,...
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8084565 |
Catalyst for polymerization of conjugated diene and method of polymerizing conjugated diene using the catalyst, rubber composition for tires, and rubber composition for golf balls
A catalyst for polymerization of conjugated diene is provided, which facilitates manufacture of a conjugated diene polymer with a high 1,4-cis structure content, leaves less aluminum residue on...
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7956141 |
Metal complex containing tridentate ligand, and polymerization catalyst comprising the same
The present invention provides 1) a complex comprising a mono-anionictridentate ligand, represented by the following general formula (I); 2) a polymerization catalyst composition, comprising the...
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7956146 |
Tire with tread of polybutadiene rubber
Pneumatic rubber tire with an outer, circumferential tread comprised of specialized cis 1,4-polybutadiene rubber based silica/carbon black reinforced rubber composition.
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7919571 |
Polybutadiene as well as rubber composition using the same and tire
This invention provides a polybutadiene capable of improving wear resistance and resistance to crack growth in a rubber composition and a tire, wherein values of e, f and g derived from the...
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7799725 |
Catalyst for polymerization of conjugated diene and method of polymerization conjugated diene using the catalyst, rubber composition for tires, and rubber composition for golf balls
A catalyst for polymerization of conjugated diene comprises (A) an yttrium compound; (B) an ionic compound including a non-coordinate anion and a cation; and (C) an organometallic compound...
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7741418 |
Process for producing polydienes
A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing employs a...
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7691957 |
Butadiene-based polymer and method of producing the same as well as rubber composition and tire using the same
This invention is concerned with a butadiene-based polymer having a high cis-1,4 bond content, a low vinyl bond content and a molecular weight distribution of a specified range, and more...
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7625979 |
Process for preparing block copolymer and resulting composition
Lithium-terminated polymers of one or more conjugated dienes and of one or more mono alkenyl arenes are coupled by reaction with an alkoxy silane coupling agent having the formula...
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7585805 |
Nickel-based catalyst composition
A catalyst composition that is the combination of or the reaction product of ingredients comprising (a) a nickel-containing compound, (b) an alkylating agent, (c) a fluorine-containing compound,...
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7534835 |
Golf ball
A golf ball is composed at least in part of a material molded under heat from a rubber composition which includes: (a) a base rubber composed primarily of a mixture of at least 60 wt % of a...
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7511108 |
Pneumatic tire
The invention relates to a pneumatic tire having excellent mechanical properties by using a rubber composition containing a polybutadiene rubber having a high cis-1,4 bond content, a low vinyl bond...
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7485765 |
Process for obtaining a butadiene homopolymer in the presence of monoolefin(s) with 4 carbon atoms
A process is described for obtaining a 1,3-butadiene homopolymer by the reaction of a catalytic system in the presence of 1,3-butadiene and one or more monoolefin(s) with 4 carbon atoms. This...
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7411027 |
Modified diene-α-olefin copolymer and method for producing same
A modified diene-α-olefin copolymer which is represented by the formula (1) below and has H2C═C(R5)—COO— in at least a part of the ends. wherein R1 and R2 independently represent a hydroxyl group ...
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7396889 |
Method for preparing a diene elastomer
A method for preparing a diene elastomer, such as a butadiene homopolymer or copolymer, in particular, a polybutadiene, with a high level of cis-1,4 linkages that has both a Mooney viscosity...
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7351776 |
Bulk polymerization process
A method for the continuous production of polydienes, the method comprising the steps of (a) charging a mixture of one or more monomer, catalyst system, and less than 50% weight percent organic...
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7294680 |
Method of producing conjugated diene polymers with narrow molecular weight distribution and polymer produced
Conjugated diene polymers having good wear resistance, mechanical properties, storage stability, processability and a reduced cold flow are produced by polymerizing a conjugated diene compound with...
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7288611 |
Methods for preparing a rare-earth cis-1,4-polybutadiene rubber with a controlled molecular weight distribution
Disclosed herein are a method for preparing a cis-1,4-polybutadiene with a controlled molecular weight distribution, comprising polymerizing butadiene monomers using a rare-earth catalyst system...
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7148299 |
Polymerization catalyst
The present invention relates to a catalyst for polymerization of a conjugated diene or the like, which is composed of a metallocene-type cation complex of a gadolinium compound. Examples of such...
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7112632 |
Process for the preparation of low branch content polybutadiene
A process for the preparation of low branch content polybutadiene comprising: (a) a first butadiene polymerisation stage;(b) treatment of the polymer solution obtained upon completion of stage (a)...
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7094849 |
Bulk polymerization process for producing polydienes
A method of producing cis-1,4-polydienes, the method comprising the step of contacting conjugated diene monomer with a lanthanide-based catalyst system in the presence of less than 20% by weight of...
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7081504 |
Synthesis of 1,4-polybutadiene
This invention is based upon the unexpected discovery that alkylated diphenylamines can be used in conjunction with nickel based catalyst systems which contain (a) an organonickel compound, (b) an...
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6908975 |
Method for preparing high 1,4-cis polybutadiene having controlled cold flow
The present invention relates to a method for preparing a high 1,4-cis polybutadiene having a controlled cold flow and, more particularly, to a novel method for preparing a high 1,4-cis...
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6897270 |
Continuous process for the production of conjugated diene polymers having narrow molecular weight distribution and products therefrom
A continuous process for producing conjugated diene polymers comprising the steps of contacting, within an hydrocarbon solvent and within a continuous reactor, conjugated diene monomer and a...
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6887956 |
Catalyst system for high-cis polybutadiene
A catalyst system suitable for use in the production of high cis polybutadiene is disclosed. The catalyst system includes a cobalt salt of the formulaCoAx?, where A is a monovalent or divalent...
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6875827 |
Hydrogenated polymer and process for producing the same
The present invention relates to a hydrogenated polymer which is a hydrogenation product of a conjugated diene polymer having an average vinyl bond content of 20% by weight or more and less than...
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6727330 |
Termination and reduced gel in high cis polybutadiene
The present invention is directed to a process for forming a high-cis polydiene. The process includes catalyzing a diene polymerization, and terminating the polymerization with a termination...
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6683140 |
Catalyst for polymerization
A catalyst in a solid state for polymerization of a conjugated diene or copolymerization of a conjugated diene and an aromatic vinyl compound, which comprises a metallocene-type cation complex of a...
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6664347 |
Polybutadiene and process for producing the same
Modified polybutadiene having a high-cis and low-trans structure with a moderate 1,2-structure content and exhibiting improved characteristics such as cold flow properties, which is obtained by...
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6653430 |
Butadiene polymers and process for producing conjugated diene polymers
A butadiene polymer (i) having a cis bond unit content of at least 50% based on the total butadiene units, a number average molecular weight (Mn) of 1,000 to 10,000,000, and at least 80%, based on...
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6627713 |
Gas phase polymerization process
A process for producing polymer in a gas phase reactor by introducing a stream of monomer and gas into a polymerization zone while providing at least one liquid component in the polymerization zone.
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6596825 |
Low gel high cis polydiene
The present invention is directed to a process for forming a high-cis polydiene. The process includes catalyzing a diene polymerization, and terminating the polymerization with an amine-water...
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6566468 |
Nitroxyl derivatives with glycidyl or alkylcarbonyl groups as initiators for radical polymerization
Glycidyl and alkylcarbonyl functional nitroxide radical polymerization initiator compounds of formula (Ia) or (Ib), where R1, R2 and A are as defined within,R3 is a radical of formula (II) whereX...
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6562917 |
Method for preparing polybutadiene having controlled molecular weight and high 1,4-cis content
A method for preparing polybutadiene having controlled molecular weight and high 1,4-cis content over 95% in the presence of a diethylzinc compound as a cocatalyst (i.e., alkylating agent) and...
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6521726 |
Method of producing a polymer
A polymer of ethylenically unsaturated monomer, for example, 1,3-butadiene, having a desired molecular weight and distribution thereof is produced, with a high stability, by preparing a solution of...
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6506865 |
Monomeric neodymium carboxylate and its use in polymerization of conjugated diene
The invention is related to a novel compound represented by NdHA4 wherein A is a carboxylate, and to a diene polymerization catalyst using the novel compound. NdHA4 has monomeric structure and does...
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6451934 |
Process for preparation of high 1,4-CIS polybutadiene
This invention relates to a process for preparation of high 1,4-cis polybutadiene and more particularly, to the process for preparing polybutadiene by polymerizing 1,3-butadiene monomer in the...
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6441107 |
Molecular weight control of gas phase polymerized polybutadiene when using a rare earth catalyst
A process for controlling the molecular weight (Mw) and molecular weight distribution (MWD) of polybutadiene polymerized in an otherwise gas phase process using a rare earth catalyst is provided.
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6437205 |
Low molecular weight high-cis polybutadienes and their use in high molecular weight-low molecular weight high-cis polybutadiene blends
A process for polymerizing 1,3-butadiene into a low molecular weight high-cis polybutadiene is described using a catalyst system comprising: (a) a neodymium-containing compound, (b) an aluminoxane...
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6426387 |
Golf ball core
A golf ball core incorporates a cobalt-catalyzed polybutadiene rubber falling within particular specifications for various material values. The material allows for manufacture of a core having a...
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6388149 |
Process for reacting an organic compound in the presence of a supported ruthenium catalyst
A process for the reaction of an organic compound in the presence of a catalyst comprising, as active metal, ruthenium alone or together with at least one Group Ib, VIIb, or VIIIb metal in an...
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6350833 |
Method for the suspension polymerization of conjugated dienes
This invention relates to a method for the suspension polymerization of conjugated dienes in hydrocarbon mixtures comprising a fraction by volume greater than 80% of C4 hydrocarbons wherein...
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6344527 |
Method for the production of polydienes with regulated mooney viscosity
This invention relates to a process for the production of polydienes having controlled Mooney viscosity, carried out by means of catalysts based on rare earth compounds, which is characterized in...
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6291615 |
Catalyst system, the use thereof in the polymerization of dienes in a solution, suspension and vapor phase and the use of diene rubbers produced therewith
The present invention is directed to a catalyst system, the use thereof in the polymerization of dienes in a solution, suspension and vapor phase, and the use of diene rubbers produced therewith,...
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6255420 |
Start-up process for gas phase production of polybutadiene
A process for starting a polymerization of butadiene to produce polybutadiene in a gas phase reactor having a seed bed which comprises (i) passivating the reactor and the seed bed by introducing an...
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6156861 |
Carbamate-functional allyl monomers and polymers therefrom
Carbamate-functional allyl monomers and methods for making them are disclosed. The monomers, which are easy to prepare, readily polymerize with common ethylenic monomers to give...
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6136931 |
Process for preparing polybutadiene using catalyst with high activity
This invention relates to a process for preparing polybutadiene with high 1,4-cis content (over 97%) and high conversion (over 90%) in such a manner that 1,3-butadiene is polymerized using an aging...
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6066705 |
Vapor phase synthesis of cis-1, 4-Polyisoprene
By utilizing the vapor phase polymerization techniques of the present invention, numerous distinct and highly beneficial advantages are realized. For instance, cis-1,4-polyisoprene rubber and high...
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6013746 |
Process for controlling the molecular weight distribution of high 1,4-cis polybutadiene
This invention relates to a process for controlling the molecular weight distribution of high 1,4-cis polybutadiene and more particularly, to a process of easily controlling the molecular weight...
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5981667 |
Impact-resistant polystyrene resin composition
Rubber-modified, impact-resistant polystyrene resin compositions having a well balanced combination of improved properties such as tensile strength and tensile elongation as well as reactivity with...
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