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4112211 |
Process for the manufacture of homo- and copolymers of tetrafluoroethylene employing as the reducing agent in the redox catalyst an ayodicarboxylic acid, salt of ayocarboxylic acid, azodicarbonamide, or mixtures thereof
Polymers on the basis of tetrafluoroethylene are produced in the presence of a redox system as catalyst consisting of a usual peroxidic compound as oxidizing component and a water-soluble nitrogen...
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4104457 |
Bulk polymerization of vinyl chloride to control grain size
Polymers and copolymers of vinyl chloride having a narrow grain size distribution and a large average mean diameter and a process for the preparation of same in which the polymerization of vinyl...
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4098980 |
Non-aqueous dispersion polymerization of conjugated diolefins
A process for the non-aqueous dispersion polymerization of a conjugated diolefin monomer, for instance, butadiene or isoprene, in a liquid hydrocarbon dispersion medium, for instance, n-butane or...
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4098987 |
Non-ionic surfactants from water soluble copolymers of acrylamide with hydrophobic monomers
Polymeric surfactants are copolymers of acrylamide with 30 - 60 wt. percent of acrylic esters or alkyl or alkoxymethyl acrylamides having molecular wt. from 800 to 10,000 amu.
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4092470 |
Stable, pumpable, aqueous suspensions of organic peroxides
Stable, pumpable, highly concentrated aqueous suspensions of organic peroxides containing (a) nonionic emulsifiers having a maximum HLB value of 12.5 and (b) nonionic emulsifiers having a minimum...
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4090994 |
Process for preparing a polyvinylchloride composition by polymerization in the presence of molding additives
A process for preparing a polyvinylchloride composition by polymerizing vinyl chloride or vinyl chloride and a comonomer comprises polymerizing vinyl chloride or a mixture of vinyl chloride and a...
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4091054 |
Process of preparing styrenic polymer particles
In a suspension polymerization process of preparing styrenic polymer particles from a styrenic monomer and small particles of a styrenic polymer in a definite particle size range, styrenic polymer...
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4089815 |
Photopolymerization initiators
Ethylenically unsaturated monomers in the presence of a novel aromatic oligomeric compound or polymer having a polyhaloacetyl moiety attached thereto are polymerized upon exposure to a source of...
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4079101 |
Diolefin polymerization process in the presence of seed polymers
A polymerization process is described in which conjugated diolefin polymers are prepared by free-radical polymerization at improved rates by conducting the polymerization in a batch charge of all...
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4060680 |
Production of acrylonitrile copolymers
A process which comprises producing a uniform copolymer of acrylonitrile and at least one faster-reacting aromatic olefine containing 50-95% molar of acrylonitrile units wherein the polymerization...
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4048147 |
Carboxylic acid of cyclopentadiene derivative, salt thereof, or ester thereof and process for producing these compositions
A novel compound represented by the formula, ##STR1## WHEREIN R is a hydrogen or an alkyl group having 1 to 3 carbon atoms, said four R's being the same or different; R 1 is hydrogen, an alkali...
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4036794 |
Manufacture of expandable styrene polymers
A process for the manufacture of expandable styrene polymers by suspension polymerization of the monomers in the presence of blowing agents and suspension stabilizers, the latter having been...
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4036909 |
Process for the polymerization and copolymerization of vinyl and diene compounds
Monomeric conjugated or unconjugated organic compounds are polymerized in an initiator systems consisting of an organic peroxide and a macromolecular compound consisting of a polymer or copolymer...
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4035563 |
Method of suspension polymerizing vinyl chloride with salts of nitrous acids and polyvalent metal salts
A method of suspension polymerizing in an aqueous medium vinyl chloride or a mixture of 50% or more vinyl chloride and remainder other monomers copolymerizable therewith in the presence of an oil...
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4026962 |
Dispersion-polymerization process using block copolymers
There is disclosed a process of dispersion-polymerizing vinyl monomers promoted by free-radical catalysts. This process comprises dispersing under stirring in water a block copolymer of the A-B...
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4011388 |
Process for preparing emulsions by polymerization of aqueous monomer-polymer dispersions
Process for the preparation of aqueous homogeneous polymer emulsion which comprises mixing, generally with agitation or under shear conditions, water, surfactant, at least one polymer, e.g.,...
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3975339 |
Manufacture of polymers of net-shaped structure
A process for the manufacture of polymers of net-shaped crosslinked structure and with uniform length of the crosslinks. In this process, polyfunctional organoalkali metal compounds which have been...
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3975341 |
Water in oil emulsion process for preparing gel-free polyelectrolyte particles
There is provided a process for preparing polyelectrolytes by a water-in-oil emulsion process. A water-in-oil azeotropic emulsion is heated with agitation and a concentrated aqueous solution of...
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3966696 |
Process for producing vinylchloride resin having a highly porous uniform granular structure
A process for suspension polymerization of vinyl chloride or a mixture of vinyl chloride and a monomer copolymerizable therewith in an aqueous medium in the presence of an oil-soluble...
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3959235 |
Method of polymerizing vinyl chloride
Vinyl chloride monomer, or a monomeric mixture comprising vinyl chloride as a main component and other monomers co-polymerizable therewith in an aqueous reaction medium, is polymerized in a...
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3954909 |
Method of producing solid polymers
A method for producing solid polymers having a molecular weight greater than 50,000 from olefins wherein the olefin is polymerized in the absence of a liquid dispersion agent of a nature different...
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3951600 |
Acrylamide aqueous solution handling method
There is disclosed a method for handling acrylamide aqueous solutions with safety wherein acrylamide aqueous solutions obtained through catalytic hydration reaction of acrylonitrile are handled...
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3941729 |
Styrene suspension polymerization system for spheres
An aqueous suspending agent solution or vehicle useful for suspension polymerization of a styrene-monomer such as styrene as well as derivatives of it and also mixtures with it to produce...
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3926934 |
Polyethylene powders
Polyethylene powders containing adsorbed water are prepared by the high-pressure polymerization of ethylene employing a water-soluble initiator, a controlled concentration of water, a dispersing...
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3907730 |
Resinous initiator suspension for olefinic polymerization reactions
A free-radical initiator suspension for use in olefinic polymerization reactions comprising a suspension of said initiator in a water-swellable lightly cross-linked polymer of one or more...
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3887528 |
Precipitation polymerization of 1:1 copolymerizates of maleic acid anhydride and allyl acetate
This invention relates to a method of precipitation polymerization of 1:1 copolymerizates of maleic acid anhydride and allyl acetate consisting of polymerizing a solution of a monomer mixture of...
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3882195 |
Pre-emulsification-delayed initiation suspension pearl polymerization process
A process for preparing vinyl chloride based polymers by suspension polymerization provides granular products characterized by improved uniformity of particle size, high porosity and rapid fushion...
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3880771 |
AQUEOUS SUSPENSION VEHICLE USEFUL IN SUSPENSION POLYMERIZATION SYSTEM FOR SPHERES
There is disclosed an aqueous suspension vehicle consisting essentially of water having dissolved therein a water-soluble suspending agent, such as one or more hydroxyethylcelluloses, in a...
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3879328 |
CURABLE COMPOSITIONS OF POLYMERS CONTAINING LABILE HYDROXYL GROUPS
Compositions of synthetic polymers containing labile hydroxyl groups such as vinylbenzyl alcohol polymers are efficiently cured by incorporating therein an acid catalyst such as hydrochloric acid...
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3870691 |
METHOD FOR POLYMERIZING TETRAFLUOROETHYLENE AND THE POLYMERS OBTAINED THEREFROM
This invention relates to a method for polymerizing tetrafluoroethylene in suspension comprising initiating polymerization with a previously prepared tetrafluoroethylene polymer, in the absence of...
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3863014 |
High acrylonitrile terpolymer containers and packages
Disclosed herein are oriented containers for food, beverages, and medicines wherein the container is the interpolymerization product of A. 65 to 78% by weight of acrylonitrile; B. from 3 to 10% by...
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3862915 |
Process for aqueous polymerization of N-vinylpyrrolidone utilizing finely divided suspension of water insoluble catalyst
Solutions of N-vinylpyrrolidone polymers can be prepared with particular advantage by polymerization of N-vinylpyrrolidone in an aqueous medium by adding the polymerization catalyst in portions or...
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3857824 |
PROCESS FOR THE PREPARATION OF BEAD POLYMERS USEFUL IN GEL PERMEATION CHROMATOGRAPHY
The present invention relates to an improved process for preparing in bead form polymers useful in the gel permeation chromatography of water soluble polymers, e.g. polyethylenimines. The process...
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3843616 |
VINYL CHLORIDE-ETHYLENE COPOLYMERS AND THE PREPARATION THEREOF
A method for producing porous vinyl chloride-ethylene copolymers containing at least 98.1 per cent by weight of vinyl chloride and 0.3 to 1.9 per cent by weight of ethylene which comprises...
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3839310 |
N-VINYL LACTAM-C10-22 VINYL ETHER COPOLYMER AS PROTECTIVE COLLOIDS IN VINYL CHLORIDE SUSPENSION POLYMERIZATION
A copolymer of an N-vinyl lactam and a C 10 -22 vinyl ether is disclosed as a protective colloid in the suspension polymerization of vinyl chloride. There is also disclosed a method of making...
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3742091 |
VINYL MONOMER POLYMERIZATION PROCESS
Agglomeration of vinyl polymers produced by liquid phase polymerization reactions is substantially inhibited when the polymerization is effected in the presence of certain polymeric additives which...
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3723395 |
BATCH-CONTINUOUS REACTION PROCESS IN A FLUIDIZED BED
Material increases in throughput and output of batch-type reactors are obtained by avoiding operational time-losses in dumping and filling and start-up. The improvements are achieved by a flexible...
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3723571 |
DISPERSION POLYMERIZATION OF VINYLIDENE CHLORIDE COPOLYMER
A process for preparing a copolymer of vinylidene chloride is provided wherein the copolymer is of between 70 percent and 85 percent by weight of vinylidene chloride and is of spherical particle...
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3721657 |
HYDROPHILIC GEL POLYMERS OF VINYLPYRROLIDINE AND HYDROXYALKYL METHACRYLATE
A plastic or resin product obtained by mixing a comminuted pyrrolidone such as polyvinylpyrrolidone, and optionally modifiers and additives such as organic methacrylates, and optionally...
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3714097 |
PROCESS FOR PRODUCING LOW FOAMING LATEXES OF INTERPOLYMERS CONTAINING VINYL CHLORIDE AND ETHYLENE
This invention relates to stable vinyl chloride/ethylene interpolymer latexes polymerized at between about 50 and 15,000 psi., which latexes can be removed from said reactors without the usual...
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3697493 |
PREPARATION OF POLYVINYLCHLORIDE
Process for preparing an improved polyvinyl chloride comprising polymerizing vinyl chloride in the presence of a peroxide and/or azo compound as catalyst, a protective colloid and in the additional...
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3678021 |
PROCESS FOR PREPARING VINYL BASED POLYMERS AND COPOLYMERS INSOLUBLE IN THEIR MONOMERS
Process for preparing vinyl based polymers and copolymers which are insoluble in their monomeric compositions comprising dispersing a small amount of a suspension of an aqueous solution of at least...
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3676413 |
PROCESS FOR THE POLYMERIZATION AND COPOLYMERIZATION OF VINYL MONOMERS AND THE RESIN COMPOSITIONS OBTAINED THEREBY
Vinyl monomers are polymerized and copolymerized in mass or in the gaseous phase in the presence of a water-soluble polymerization catalyst which is mixed with an inert support material and water...
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3624036 |
INVERT EMULSION POLYMERIZATION OF ACROLEIN UTILIZING COMMERCIAL MONOMER
The present invention is directed towards an invert emulsion process for the polymerization of an α,β ethylenically unsaturated aldehyde, and in particular is directed to the homopolymerization...
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3548034 |
POLYMERIZATION OF VINYL CHLORIDE IN THE PRESENCE OF AN ACRYLIC ESTER POLYMER
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3548035 |
SUSPENSION POLYMERIZATION PROCESS
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3539661 |
PROCESS FOR PRODUCING SELF-CURING POLYMERS
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3536676 |
POLYMERS OF ALKYLENE DIPEROXYESTERS
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3535301 |
PROCESS FOR OBTAINING POWDERS OF POLYTETRAFLUOROETHYLENE
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3530080 |
STABLE VINYL ACETATE COPOLYMER EMULSION,ITS PREPARATION AND COATING COLORS PREPARED THEREFROM
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