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6197715 |
Supported catalysts and olefin polymerization processes utilizing same
Non-ionic late transition metal chelates of salicylaldimine and pyrrolaldimine can be tethered to an inert support by a covalent bond to provide a catalyst useful in slurry and gas phase...
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6177529 |
Polymerization of olefins with bridged metallocene catalysts
Bridged metallocenes of Group IVb metals provide improved results when the bridge comprises a neutral electron-donor substituent of general formula R'"ZR"" j wherein R'" is a rigid unsaturated...
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6177528 |
Substituted aminomethylphosphines, compositions and coordination complexes of same, their synthesis and processes using same
Novel aminomethylphosphine ligands have particular substituents on the central carbon atom. Such ligands form coordination complexes that may be catalysts for the polymerization of monomers or...
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6174976 |
Neutral nickel complexes for olefin polymerization
Provided are novel olefin polymerization catalysts based on neutral nickel complexes of bidentate ligands containing a nitrogen atom and an oxygen atom and a process for the preparation of...
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6169152 |
Olefin polymerization catalyst comprising transition metal compound containing a cyclic ligand having at least two nitrogen atoms in its main chain skeleton
An olefin-polymerizing catalyst which comprises (A) a transition metal compound having at least one cyclic amide ligand and (B) an organoaluminum compound and/or an aluminoxane compound with or...
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6162884 |
Olefin oligomerization and processes thereof
Novel catalyst systems which comprise 2-pyridine carboxaldimine nickel dihalide complexes can be used with an organoaluminum cocatalyst in slurry oligomerization or polymerization processes to...
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6150482 |
Polymerization of propylene
Propylene may be polymerized by contacting it with certain iron complexes of selected 2,6-pyridinecarboxaldehydebis(imines) and 2,6-diacylpyridinebis(imines). The polymers produced are useful as...
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6147172 |
Phosphinimine/heteroatom catalyst component
Organometallic complexes having a phosphinimine ligand, a (non-phosphinimine) heteroligand and at least one activatable ligand are catalyst components for olefin polymerization. Preferred...
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6137019 |
Process for converting a geminally substituted cyclopentadiene
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6133386 |
Metal oxide solid acids as catalysts for the preparation of hydrocarbon resins
Metal oxide solid acids are used as catalysts for the polymerization of a feed stream containing at least one of pure monomer (e.g., styrene based monomers), C5 monomers, and C9 monomers to produce...
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6127497 |
Elevated pressure polymerization processes with late transition metal catalyst systems
The invention encompasses late transition metal catalyst systems and their use in polymerization processes, particularly in solution, 2-phase suspension and super-critical phase polymerization of...
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6121181 |
Cyclic oligomeric oxo- and imido- metal complexes as olefin polymerization catalysts
Single site nitrogen and oxygen metallacyclic catalysts comprising at least two polymerization-stable anionic ancillary ligands and a Group 4-10 metal are disclosed wherein the nitrogen or oxygen...
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6121371 |
Application of atom transfer radical polymerization to water-borne polymerization systems
A process is provided for the preparation of (co)polymer emulsions or suspensions from a full range of free radically (co)polymerizable monomers, wherein the (co)polymers exhibit the...
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6121401 |
Propylene copolymer
A propylene copolymer obtainable by polymerizing a propylene, at least one of α-olefin having 4-20 carbon atoms, and ethylene, in the presence of a catalyst for olefin polymerizaton including the...
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6114483 |
Polymerization of olefins
Mixtures of different polyolefins or branched polyolefins may be made by direct, preferably simultaneous, polymerization of one or more polymerizable olefins using two or more transition metal...
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6114482 |
Process for the controlled radical polymerization or copolymerization of (meth) acrylic and vinyl monomers and (co) polymers obtained
This process is characterized in that at least one of the said monomers is polymerized or copolymerized in bulk, solution, emulsion or suspension at a temperature which may be as low as 0° C., in...
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6111041 |
Palladium (II) catalyized polymerization of norbornene and acrylates
Homopolymers or copolymers of acrylates, homopolymers or copolymers of norbornenes, and copolymers of acrylates with norbornenes, may be prepared by contacting acrylate and/or norbornene monomer...
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6107232 |
Polymerization catalyst and process for preparing polymer by use of same
The present invention is directed to a polymerization catalyst which comprises (A) a transition metal compound represented by the general formula (I) L d MX e Y f Z g ...
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6100356 |
Methods of (co)polymerizing vinyl and/or diene monomers and curing or crosslinking polymeric resins using a heteropoly acid peroxide promoter
A method of (co)polymerizing vinyl and/or diene monomers comprising contacting the monomers with a (co)polymeriztion composition under conditions effective to (co)polymerize the monomers, wherein...
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6093779 |
Polymerizable acetylene composition and acetylene photopolymerization process
Compositions comprising at least one nonvolatile acetylene alone or together with a strained cycloolefin and catalytic amounts of a catalyst for metathesis polymerization, which comprise at least...
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6087292 |
Metallocene catalysts comprising indenyl ligands substituted with electronegative groups
A highly effective catalyst system for the polymerization of olefins comprises a cocatalyst, preferably an aluminoxane, and a metallocene of the formula I ##STR1## where M 1 =Zr or Hf, R 1 and R...
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6075068 |
Dental compositions curable by ROMP
The invention relates to dental compositions, containing (a) 5 to 70 wt. %, based on (a)+(b)+(d), of polymerizable monomers and/or polymers, (b) 0 to 95 wt. %, based on (a)+(b)+(d), of...
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6069213 |
Mixed catalyst system
It has been found that the use of at least one unsupported metallocene polymerization catalyst with at least one supported metallocene polymerization catalyst in the polymerization of olefins...
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6063881 |
Oligomerization of propylene
Propylene may be oligomerized by contact with cobalt complexes corresponding to the following structure: ##STR1## wherein R 1 -R 7 are hydrogen, hydrocarbyl or inert functional groups, and X is...
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6051667 |
Olefin polymerization using a catalyst having a bridged cyclopentadienyl-phosphole ligand
An olefin polymerization process uses a catalyst with an organometallic complex of a group 4 metal having a bridged cyclopentadienyl-phosphole ligand, as defined by the formula: ##STR1## wherein:...
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6031057 |
Polymers of olefinically unsaturated monomers
Polymers are obtained by polymerising olefinically unsaturated monomers in the presence of a metal complex having the general formula (I), in which the substituents and indexes have the following...
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6020443 |
Polymerization of low grade DCPD monomers using an olefin metathesis catalyst
Methods for synthesizing polyDCPD via ROMP of low grade DCPD starting materials using Ruthenium or Osmium carbene complex catalyst. Transparent or translucent polyDCPD materials. The Ruthenium or...
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6013745 |
Phosphorus based catalysts for the polymerization of olefins
The present invention relates to the polymerization of one or more alpha olefins in the presence of a transition metal catalyst having either a heterobifunctional ligand, having a phosphorus and a...
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6011127 |
Process for the production of ethylenic polymers
A process for the production of ethylenic polymers is disclosed in which an ethylenic monomer is polymerized in the presence of a catalyst comprising a chromium compound, an alumoxane and an...
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6008306 |
Thermal metathesis polymerization process and a polymerisable composition
Composition of (a) at least one strained cycloolefin and (b) a catalytic quantity of at least one divalent-cationic compound of ruthenium or osmium with a metal atom, to which are bound 1 to 3...
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5986029 |
Catalyst composition and process for the polymerization of an olefin
The invention relates to a new catalyst composition which is suitable for the polymerization of an olefin and which comprises a reduced transition metal complex and a co-catalyst. The invention is...
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5986027 |
Olefin polymerization using a catalyst comprising a group VIIIB metal, and acid, and a bidentate chelating compound
Polymers are obtainable by polymerizing olefinically unsaturated monomers in the presence of a catalyst system which comprises as active constituents a) a salt of a metal of group VIII B of the...
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5977393 |
Schiff base derivatives of ruthenium and osmium olefin metathesis catalysts
The present invention generally relates to ruthenium and osmium carbene catalysts for use in olefin metathesis reactions. More particularly, the present invention relates to Schiff base derivatives...
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5969062 |
Process for producing ethylene copolymers under high pressure
In a process for preparing copolymers of ethylene with C 3 -C 10 -alk-1-enes, the polymerization is carried out at pressures in the range from 1000 to 3500 bar and at from 200 to 280° C. in the...
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5965677 |
Supported phosphinimine-Cp catalysts
A catalyst component which is especially useful in so-called "slurry" or "gas phase" olefin polymerizations and which comprises an organometallic complex of a group 4 metal (having a...
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5962609 |
Free radical polymerisation process
Process for the free-radical polymerisation of olefinically unsaturated monomer(s) using a free-radical initiator, the polymerisation being performed in the presence of a compound for effecting...
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5959047 |
3-aryl substituted indenyl containing metal complexes and polymerization process
Group 4 metal constrained geometry complexes comprising a 3-aryl-substituted indenyl ligand, catalytic derivatives thereof and their use as olefin polymerization catalysts, especially for preparing...
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5883277 |
Metallocene complexes with cationic bridges
Metallocene complexes having a cationic bridge of the formula ##STR1## where the substituents have the following meanings: M is a metal of transition group III, IV, V or VI of the Periodic Table of...
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5866663 |
Processes of polymerizing olefins
Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The...
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5854165 |
Transition metal compound, catalyst for olefin polymerization, process for preparing olefin polymer by use of catalyst
A transition metal compound which is a multiple crosslinking type transition metal complex represented by the general formula (I) ##STR1## wherein M is a metallic element in the groups 3 to 10 or a...
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5851945 |
Olefin polymerization catalyst compositions comprising group 5 transition metal compounds stabilized in their highest metal oxidation state
The invention addresses Group 5 metal compounds suitable as polymerization catalysts characterized by comprising one Group 15 element polyanionic ancillary ligand and three single or multidentate...
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5851946 |
Coordination catalyst systems comprising intramolecularly stabilized organometallic compounds
The invention relates to the use of intramolecularly stabilized organometallic compounds as components in coordination catalyst systems, corresponding coordination catalyst systems and processes...
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5847060 |
Functionalized diene oligomers
This invention relates to the controlled molecular weight production of macromonomers and polymers with terminal conjugated double bonds from starting monomers including, but not limited to...
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5840238 |
Process for the manufacture of fibre-reinforced composites
Fiber-reinforced composites are made from introducing a fabric into the lower part of an open two-part mold, closing the mold and injecting into the mold under pressure and curing a reactive resin...
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5830821 |
Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands
Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts A very effective catalyst system for olefin polymerization comprises a...
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5821278 |
Process for polymerizing of cyclic olefins and a photopolymerizable composition
Process for the photocatalytic polymerization of a cyclic olefin or at least two different cyclic olefins in the presence of a metal compound as catalyst, which comprises carrying out a...
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5821310 |
Organometallic compounds and catalyst compositions
There is provided an organometallic compound comprising a metal M of Group 3 to 6 of the Periodic Table or the Lanthanide series and at least one (hetero)cyclohexadienyl ligand of the general...
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5811500 |
Process for the controlled radical (CO) polymerization of (Meth) acrylic vinyl vinylidene and diene monomers in the presence of an Rh Co OR Ir
This process is characterized in that at least one of the said monomers is polymerized or copolymerized in bulk, solution, emulsion or suspension, at a temperature which may be as low as 0° C., in...
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5770665 |
Free radical polymerization process
A compound for effecting molecular weight control in polymerisation is a CoII chelate of formula, wherein each group R is an organic cyclic group which, independently, is a monovalent group which...
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5767211 |
Synthesis of multi-functional hyperbranched polymers by polymerization of di-or tri-vinyl monomers in the presence of a chain transfer catalyst
This invention concerns the synthesis of multi-functional hyperbranched polymers by free radical polymerization of di- or tri-vinyl monomers in the presence of a chain transfer catalyst and a...
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