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8173569 |
Robust spray-dried ziegler-natta procatalyst and polymerization process employing same
A Ziegler-Natta procatalyst composition in the form of solid particles and comprising magnesium, halide and transition metal moieties, said particles having an average size (D50) of from 10 to 70...
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7985817 |
Homogeneous catalyst system for producing ethylene homopolymer or ethylene copolymers with alpha-olefins
Disclosed is a homogeneous catalyst system for producing an ethylene homopolymer or an ethylene copolymer with α-olefin. Specifically, this invention pertains to a transition metal catalyst which ...
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7977437 |
Process for producing polydienes
A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing employs a...
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7956139 |
Polymerization catalysts for producing polymers with high comonomer incorporation
The present techniques relate to catalyst compositions, methods, and polymers encompassing a Group 4 metallocene compound comprising bridged η5-cyclopentadienyl-type ligands, typically in ...
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7825201 |
Process for producing polydienes
A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing takes place...
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7820580 |
Nickel-based catalysts for preparing high cis 1,4-polydienes
A nickel-carbene polymerization catalyst system for preparing high cis polydienes is provided. The catalyst system comprises (a) a nickel N-heterocyclic carbene complex, (b) an organoaluminum...
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7811956 |
Supported olefin polymerization catalyst
A supported catalyst system comprises (a) a dehydrated support material, (b) a transition metal compound, and (c) an activator and is characterised in that the support material has been pretreated...
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7799721 |
Polymerization catalysts for producing polymers with high comonomer incorporation
The present techniques relate to catalyst compositions, methods, and polymers encompassing a Group 4 metallocene compound comprising bridged η5-cyclopentadienyl-type ligands, typically in ...
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7741418 |
Process for producing polydienes
A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing employs a...
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7691957 |
Butadiene-based polymer and method of producing the same as well as rubber composition and tire using the same
This invention is concerned with a butadiene-based polymer having a high cis-1,4 bond content, a low vinyl bond content and a molecular weight distribution of a specified range, and more...
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7662894 |
Polymer supported metallocene catalyst composition for polymerizing olefins
A catalyst composition for polymerizing olefins to polymers having bimodal molecular weight distribution comprises two transition metal-containing metallocene compounds, a magnesium compound, an...
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7572867 |
Polymerization process for producing polydienes
There is disclosed a process for producing a conjugated diene-containing polymer wherein a stream comprising conjugated diene monomer and a specified catalyst, that includes a lanthanide compound...
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7468416 |
Catalyst composition for olefin polymerization
A process for the preparation of a catalyst system includes the steps of combining a Lewis base, an organic compound having at least one functional group containing active hydrogen, and an...
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7429635 |
Preparation of ultra high molecular weight linear low density polyethylene
Disclosed is a method of preparing an ultra-high molecular weight, linear low density polyethylene with a catalyst system that comprises a bridged indenoindolyl transition metal complex, a...
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7396889 |
Method for preparing a diene elastomer
A method for preparing a diene elastomer, such as a butadiene homopolymer or copolymer, in particular, a polybutadiene, with a high level of cis-1,4 linkages that has both a Mooney viscosity...
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7288611 |
Methods for preparing a rare-earth cis-1,4-polybutadiene rubber with a controlled molecular weight distribution
Disclosed herein are a method for preparing a cis-1,4-polybutadiene with a controlled molecular weight distribution, comprising polymerizing butadiene monomers using a rare-earth catalyst system...
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7230056 |
Catalyst preparation method
A two-step catalyst preparation method is disclosed. First, a support is combined with an indenoindolyl Group 3-10 metal complex and a first activator comprising an alkyl alumoxane to give a...
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7214745 |
Process for producing polymer
A process for producing an olefin polymer with high polymerization activity without using an expensive co-catalyst or using a limited amount of the co-catalyst, more particularly a process for...
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7214638 |
Olefin polymerization catalyst composition comprising group 13 amide derivatives
Catalyst compositions that are highly tolerant of catalyst poisons for use in addition polymerizations comprising a catalytic derivative of a Group 4 metal complex, a cocatalyst, and a Group 13...
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7208441 |
Polymerization catalyst systems and processes therefor and therewith
A copolymer of ethylene and a higher alpha olefin, preferably 1-hexene, can be produced using an activated chromium containing catalyst system and a cocatalyst selected from the group consisting of...
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7202315 |
Process for the preparation of ethylene polymers
A process for polymerizing ethylene comprising contacting under polymerization condition ethylene and optionally one or more olefins with a catalyst system obtainable by contacting: a bis amido...
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7169870 |
Method for preparing butadiene/isoprene copolymers and resulting copolymers
The present invention relates to a process for the preparation random copolymers of butadiene and isoprene, essentially consisting of reacting a catalytic system in the presence of butadiene and...
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7157533 |
Process of obtaining an isoprene-enriched FCC C5 fraction and selective polymerization of isoprene from said fraction
A process is described for obtaining from an “FCC” initial C5 fraction which is enriched with isoprene and purified and usable for the selective polymerization of isoprene. A process is also des...
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7151146 |
Neodymium-carbon nanotube and method of preparing high 1,4-cis-polybutadiene using the same
The present invention relates to a method for preparing neodymium-carbon-nanotube and a process for preparing 1,4-cis-polybutadiene utilizing the same and more particularly,...
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7101940 |
Chemical compound, method for the production thereof and its use in catalyst systems for producing polyolefins
The invention relates to a chemical compound of formula (I), wherein M1 represents an element selected from main groups II, III or IV of the periodic table of elements; x is equal to 1, 2, 3 or 4;...
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7078466 |
Process for the preparation of branched polydienes in the presence of catalysts based on rare-earth
A process is described for the preparation of polydienes with a low vinyl content and having a branched structure effected by means of the polymerization of conjugated dienes in the presence of...
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7056998 |
Catalytic system for the preparation of polybutadienes and preparation process
The present invention relates to a catalytic system usable for the preparation of polybutadienes by polymerisation, to a process for the preparation of said catalytic system and to a process for...
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7026415 |
Clathrochelates as olefin polymerization catalyst components
Catalyst systems and methods for olefin polymerization are disclosed. The polymerizations are performed in the presence of a clathrochelate which comprises a transition metal ion and an...
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7009014 |
Process for the polymerization olefins
A process for polymerizing an olefin is capable of polymerizing an olefin with excellent polymerization activity, and comprises polymerizing or copolymerizing an olefin at a polymerization reaction...
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6995235 |
Methods of producing polyolefins and films therefrom
Films and methods of forming films comprising first combining in a reactor olefins, a catalyst composition and an activator; wherein the activator is present from less than 50 wt % in a diluent by...
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6992157 |
Synthetic polyisoprenes and a process for their preparation
The present invention provides synthetic polyisoprenes having a high cis-1,4 linkage content and a process for their preparation. The synthetic polyisoprenes according to the invention have a...
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6933354 |
Aluminoboronate activators for single-site olefin polymerization catalysts
Single-site catalyst systems useful for polymerizing olefins are disclosed. The catalyst systems comprise an organometallic complex and an activator. The complex includes a Group 3-10 transition...
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6908972 |
Method for making polyolefins
A method for making ethylene polymers and copolymers is disclosed. The method uses a catalyst system comprising a low level of an aluminum-containing activator, a bridged indenoindolyl transition...
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6903170 |
Olefin polymerization process using triisobutylaluminum as a scavenger
Ethylene and optional comonomers are polymerized using a supported metallocene catalyst, an alumoxane activator, and triisobutylaluminum (TIBAL). A silica support is first pretreated with a silane...
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6887956 |
Catalyst system for high-cis polybutadiene
A catalyst system suitable for use in the production of high cis polybutadiene is disclosed. The catalyst system includes a cobalt salt of the formulaCoAx?, where A is a monovalent or divalent...
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6870017 |
Transition metal compound, catalyst for addition polymerization, and process for producing addition polymer
A catalyst for addition polymerization obtained by bringing the following (A) into contact with (B) a specific organic aluminum compound and/or aluminoxane, and (C) a specific boron compound, and a...
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6867276 |
Vinylaromatic polymers having high melt flow
A process for preparing syndiotactic polymers of vinylaromatic monomers having improved melt flowability comprising contacting one or more vinylaromatic monomers with a catalyst system comprising a...
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6858686 |
Process for obtaining a polyisoprene with a high cis-1,4 linkage content
The present invention relates to a process for obtaining a polyisoprene having a high cis-1,4 linkage content, from a steam-cracked C5 naphtha fraction enriched with isoprene. The process of the...
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6838534 |
Catalytic system and process for the preparation of elastomers by means of this system
The present invention provides a catalytic system that can be used to prepare by polymerization diene elastomers comprising polyisoprenes and polybutadienes. The invention also provides a process...
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6825294 |
Catalysts for polymerizing styrene and other monomer and process for producing styrene polymer
Provided are catalysts for styrene polymerization capable of efficiently and inexpensively producing styrenic polymers having a syndiotactic structure; and a method for producing styrenic polymers....
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6803430 |
Polymerization process for improved reactor performance of metallocenes
The present invention relates to a process for polymerizing olefin(s) in the presence of metallocene-type catalyst compound, an activator and an inorganic oxide support, a Group 13 containing...
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6790917 |
Process for producing vinyl compound polymer
A process for producing a polymer, which comprises polymerizing a vinyl compound (I) represented by the general formula CH2═CH—R, wherein steric parameters Es and B1 of the substituent R are res...
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6787617 |
Process for producing olefin living polymer
A process for preparing olefinic living polymers having a molecular weight distribution (Mw/Mn) of 1 to 1.3, comprising polymerizing an olefinic monomer having 2 to 20 carbon atoms at low...
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6777509 |
Solution polymerization process
A solution polymerization process using a phosphinimine catalyst and a boron activator is conducted at a temperature of about 170° C. or greater in the presence of trialkyl aluminum to produce ...
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6774194 |
Supported catalysts for the polymerization of olefins
Supported catalysts for the polymerization of olefins comprise the following components: (A) a porous organic support functionalised with groups having active hydrogen atoms;(B) an organo-metallic...
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6765074 |
Olefin polymerization process
An olefin polymerization process is disclosed. The process comprises polymerizing olefins in the presence of a supported indenoindolyl catalyst system and an organoboron or organoaluminum-treated...
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6762255 |
Prealkylated olefin polymerization catalysts and olefin polymerization employing such catalysts
Prealkylation of a supported catalyst system comprising a transition metal or inner transition metal complex precatalyst and a bulky, non-coordinating anion on an inorganic support by treatment...
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6730755 |
Halosulfonic acid treated catalyst support for olefin polymerization
A supported catalyst for olefin polymerization comprises a combination of a novel metal oxide support and an activator which is an aluminoxane or a boron activator. The novel metal oxide support of...
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6720394 |
Supported olefin polymerization catalyst composition
Alumoxanes having C2-C12 alkyl groups can conveniently be used in supported olefin polymerization catalyst compositions prepared by contacting, either previous to or immediately before the...
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6716940 |
Catalyst for the polymerization of olefins
Catalyst system for the polymerization of olefins CH2═CHR, wherein R is hydrogen or a hydrocarbon radical having 1-12 carbon atoms, comprising the product of the reaction between (a) a solid c...
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