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7417097 |
Organometal compound catalyst
This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides catalyst compositions that are useful for...
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7414099 |
Hindered polyalicyclic alkyl catalysts and their use in a gas-phase polymerization reactor
Embodiments of the present invention include a method of polymerizing olefins comprising contacting olefins with a catalyst composition made by the process of combining a hindered polyalicyclic...
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7414005 |
Preparation of catalyst compositions having improved activity
The present invention relates to a process for preparing a catalyst composition for olefin polymerization, which comprises preparing a catalyst solid in a first step by bringing A) at least one...
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7410927 |
Catalysts for olefin polymerization
This invention relates to the field of olefin polymerization catalyst compositions, and methods for the polymerization and copolymerization of olefins, including polymerization methods using a...
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7402638 |
Propylene polymer particle method of producing the same and use thereof
The present invention relates to a propylene random copolymer which satisfies the following requirements [1] to [4], and to various useful molded products obtained by molding the propylene random...
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7385015 |
Trialkylaluminum treated supports
This invention relates to a process to prepare a trialkylaluminum treated support comprising: 1) combining a support with first trialkylaluminum compound(s), where the alkyl groups have at least 2...
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7381780 |
Catalyst compositions comprising small silica support materials and methods of use in polymerization reactions
Improved catalyst compositions, and polymerization processes using such improved catalyst compositions, are provided. An example of an improved catalyst composition is a supported catalyst system...
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7368411 |
Supported metallocene catalysts and their use in producing stereospecific polymers
Supported stereospecific catalysts and processes for the stereotactic propagation of a polymer chain derived from ethylenically unsaturated monomers which contain three or more carbon atoms or...
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7354981 |
Polyethylene catalyst and a process for preparing the same
The present invention discloses a polyethylene catalyst and a process for preparing the same, said catalyst being composed of a main component of catalyst and a cocatalyst, wherein the main...
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7345119 |
Olefin polymerization catalyst and olefin polymerization method using the same
An olefin polymerization solid catalyst including a reaction product of a transition metal compound and an organoaluminum compound carried on a support having silica treated with an...
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7342078 |
Transition metal compound, ligand system, catalyst system and the use of the latter for polymerisation and copolymerisation of olefins
A process for the polymerization of olefins, in particular a process for the copolymerization of propylene with further olefins, is carried out in the presence of highly active catalyst systems...
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7326759 |
Compositions for solid freeform fabrication
Chemical compositions are disclosed. One exemplary composition, among others, includes: a basic component, an acidic component, at least one acrylate component, oxidizing agent, reducing agent, and...
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7326757 |
Supported catalyst for olefin polymerization
Disclosed are catalyst systems and methods of making the catalyst systems for the polymerization of an olefin containing a solid titanium catalyst component containing an inorganic titanium...
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7319125 |
Supercritical polymerization process and polymers produced therefrom
This invention relates to a process to produce propylene polymers comprising contacting a metallocene catalyst compound and an activator in a reaction medium comprising propylene, from 0 to 30...
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7312283 |
Polymerization catalysts and process for producing bimodal polymers in a single reactor
Catalyst compositions comprising a first metallocene compound, a second metallocene compound, an activator-support, and an organoaluminum compound are provided. Methods for preparing and using such...
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7300988 |
Single catalyst low, medium and high density polyethylenes
A method of polymerizing olefins comprising combining in one embodiment ethylene and optionally one or more α-olefins with a catalyst composition in a continuous polymerization reactor at a...
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7294680 |
Method of producing conjugated diene polymers with narrow molecular weight distribution and polymer produced
Conjugated diene polymers having good wear resistance, mechanical properties, storage stability, processability and a reduced cold flow are produced by polymerizing a conjugated diene compound with...
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7294679 |
Catalyst support method and polymerization with supported catalysts
This invention relates to a method to support one or more catalyst compounds comprising contacting the catalyst compounds with a pretreatment agent comprising an aluminum alkyl and or an alumoxane...
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7294600 |
Supported hybrid metallocene catalyst, method for preparing the same, and method for preparing polyolefin using the same
The present invention relates to a supported metallocene catalyst used for preparing polyolefin whose physical properties and molecular weight distribution can be easily controlled, a method for...
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7294599 |
Acidic activator-supports and catalysts for olefin polymerization
This invention relates to the field of olefin polymerization catalyst compositions, and methods for the polymerization and copolymerization of olefins, typically using a supported catalyst...
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7268195 |
Mesoporous catalyst support, a catalyst system, and method of making and using same for olefin polymerization
This invention relates to a catalyst system comprising a catalyst and a support comprising a non-layered inorganic porous crystalline phase material, wherein the support comprises a hexagonal...
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7262259 |
Method of preparing a treated support
This invention relates to a method to polymerize olefins comprising contacting a solid aluminum or solid titanium compound with a supported catalyst compound, heating the solid aluminum or solid...
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7259215 |
Process for producing propylene/ethylene block copolymer and propylene/ethylene block copolymer
A process for producing a propylene-ethylene block copolymer in a good morphology using a catalyst system comprising a metallocene catalyst (1) preparing high crystalline polypropylene, a...
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7259125 |
Catalyst compositions comprising small silica support materials and methods of use in polymerization reactions
Improved catalyst compositions, and polymerization processes using such improved catalyst compositions, are provided. An example of an improved catalyst composition is a supported catalyst system...
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7256243 |
Silicon compound
The present invention provides a novel silicon compound represented by Formula (1) having a living radical polymerization initiating ability for addition-polymerizable monomers and a polymer...
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7256150 |
Preparation of olefin polymerization catalyst component
A process for producing a Gp 2/transition metal olefin polymerisation catalyst component, in which a Gp 2 complex is reacted with a transition metal compound so as to produce an oil-in-oil...
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7247686 |
Solid cocatalyst component for olefin polymerization and catalyst system thereof
A solid cocatalyst for olefin polymerization in which an ion-containing compound comprising a cation expressed by [R 4 M]+, wherein the group R are each individually selected from the group...
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7247594 |
Catalysts for olefin polymerization
This invention relates to the field of olefin polymerization catalyst compositions, and methods for the polymerization and copolymerization of olefins, including polymerization methods using a...
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7238756 |
Polymerization process and control of polymer composition properties
Methods of controlling the flow index and/or molecular weight split of a polymer composition are disclosed. The method of producing a polymer composition in one embodiment comprises incorporating a...
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7232869 |
Catalyst composition for olefin polymerization
A process for the preparation of a catalyst system includes the steps of combining a Lewis base, an organic compound having at least one functional group containing active hydrogen, and an...
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7232785 |
Solid catalytic component and catalytic system of the ziegler-natta type, process for their preparation and their use in the polymerization of alk-1-enes
The present invention relates to a new solid catalytic component, which can be used in combination with an aluminum compound as co-catalyst and optionally an external electron donor as additional...
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7223823 |
Catalyst system and process
This invention relates to a process of polymerizing ethylene in a reactor comprising contacting a catalyst system comprising a supported chromium catalyst and an aluminum alkyl cocatalyst, where...
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7220804 |
Method for preparing a catalyst system and its use in a polymerization process
The present invention relates to a supported catalyst composition and a method for making the supported catalyst composition and its use in a process for polymerizing olefin(s). In particular, the...
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7220695 |
Supported activator
This invention relates to supported activators comprising the product of the combination of an ion-exchange layered silicate, an organoaluminum compound, and a heterocyclic compound, which may be...
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7211536 |
Supported metallocene catalysts and their use in producing stereospecific polymers
Supported stereospecific catalysts and processes for the stereotactic propagation of a polymer chain derived from ethylenically unsaturated monomers which contain three or more carbon atoms or...
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7205363 |
Polymerization processes using antistatic agents
The invention relates to a process for the polymerization of olefins using an antistatic agent. In particular, the invention relates to a polymerization process to produce propylene polymers using...
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RE39561 |
Metallocenes containing ligands of 2-substituted indenyl derivatives, process for their preparation, and their use as catalysts
The novel metallocenes of the formula I
in which, preferably, M 1 is Zr or Hf, R 1 and R 2 are alkyl or halogen, R 3 and R 4 are hydrogen, R 5 and R 6 are alkyl or haloalkyl, —(CR 8 R...
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7202190 |
Supported catalyst system for the polymerization of olefins
A supported catalyst system for polymerizing olefins comprising a) a support, b) a Lewis base of the formula
M 3 R 6 R 7 R 8 ...
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7199073 |
Resins that yield low haze films and the process for their production
Catalyst compositions comprising a first metallocene compound, a second metallocene compound, a third metallocene compound, a chemically-treated solid oxide, and an organoaluminum compound are...
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RE39532 |
Metallocenes containing ligands of 2-substituted indenyl derivatives, process for their preparation, and their use as catalysts
The novel metallocenes of the formula I
in which, preferably, M 1 is Zr or Hf, R 1 and R 2 are alkyl or halogen, R 3 and R 4 are hydrogen, R 5 and R 6 are alkyl or haloalkyl, —(CR 8 R...
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7172988 |
Catalyst component for ethylene polymerization, a process for preparing thereof and catalyst comprising the same
A catalyst component for ethylene polymerization, including an inorganic oxide support, and at least one alkyl metal compound, at least one halide, at least one dihydrocarbyl magnesium compound, at...
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7169864 |
Metallocene catalysts, their synthesis and their use for the polymerization of olefins
A process for the preparation of a catalyst system includes the steps of combining a support material with a first composition which includes at least one aluminoxane in a first solvent to provide...
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7163993 |
Electrical devices from polymer resins prepared with ionic catalysts
This invention relates to olefin polymers particularly suited to satisfying the dielectric properties required in electrical device use. The olefin polymers can be prepared by contacting...
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7160833 |
Spray-dried polymerization catalyst and polymerization process employing same
A spray-dried composition comprising the reaction product of a magnesium halide, a solvent, an electron donor compound, and a transition metal compound and an inert filler comprising substantially...
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7148298 |
Polymerization catalysts for producing polymers with low levels of long chain branching
This invention relates to catalyst compositions, methods, and polymers encompassing a Group 4 metallocene with bridging η 5 -cyclopentadienyl-type ligands, in combination with a cocatalyst and an...
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7141633 |
Olefin trimerization using a catalyst comprising a source of chromium, molybdenum or tungsten and a ligand containing at least one phosphorous, arsenic or antimony atom bound to at least one (hetero) hydrocarbyl group
A process for the trimerization of olefins is disclosed, comprising contacting a monomeric olefin or mixture of olefins under trimerization conditions with a catalyst which comprises (a) a source...
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7125937 |
Polyorganosilsesquioxane supported metallocene catalysts
Supported stereospecific catalysts and processes for the stereotactic propagation of a polymer chain derived from ethylenically unsaturated monomers such as the polymerization of propylene to...
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7074865 |
Azaborolyl group 4 metal complexes, catalysts and olefin polymerization process
Metal complexes, catalysts derived therefrom, and polymerization processes using the same, characterized by the presence of one or more nitrogen and boron containing, anionic 5-membered cyclic...
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7071137 |
Method of making a ziegler-natta catalyst
A method for making a Ziegler-Natta catalyst support includes the steps of contacting a fumed silica with a surface modifying agent such as a compound having the formula RMgX MgR′R″ wherein R,...
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7067598 |
Process for the continuous gas-phase (co-)polymerisation of olefins in a fluidised bed reactor
The present invention relates to a process for the gas-phase (co-)polymerization of olefins in a fluidized bed reactor using a chromium oxide catalyst characterized in that the polymerization is...
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