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7504464 |
Process for control of polymer fines in a gas-phase polymerization
A gas phase polymerization process comprising: (1) preparing a solution of a catalyst precursor comprising a mixture of magnesium and titanium compounds, an electron donor and a solvent; (2) adding...
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7211535 |
Enhanced polyolefin catalyst
The present invention provides a novel process for preparing a catalyst useful in gas phase polymerization of olefins wherein the physical properties of the polymer and the productivity of the...
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7183234 |
Multi-donor catalyst system for the polymerization of olefins
The present invention provides catalyst systems including a Ziegler-Natta or Ziegler-Natta-type catalyst in combination with a mixture of certain electron donors.
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7153803 |
High activity and good hydrogen response Ziegler-Natta polyethylene catalyst
Disclosed are catalyst systems and methods of making the catalyst systems/supports for the polymerization of polyethylene containing a solid titanium catalyst component containing a titanium...
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7084217 |
High activity polyethylene catalysts prepared with borates reagents
An improved supported Ziegler-Natta catalyst especially useful for olefin polymerisation, the catalyst including a carrier, an organomagnesium compound, a borate compound, and one transition metal...
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7060764 |
Method for polymerization and copolymerization of ethylene
A method for polymerization and copolymerization of ethylene is disclosed. The polymerization is carried out in the presence of a preactivated titanium solid complex catalyst supported on a carrier...
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6992034 |
Catalyst component for olefin polymerization
A solid catalyst component useful for the (co)-polymerization of olefins is disclosed. The catalyst component is prepared by reacting an activated magnesium halide composite support with a...
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6956002 |
Process for polymerization of olefins
A catalyst for olefin polymerization, comprising:
a solid catalyst component comprising [A] a solid component having substantially no hydroxyl group, [B] a compound of a transition metal...
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6784133 |
Method for preparing catalyst for olefin polymerization
Disclosed is a preparation method of titanium catalyst for olefin polymerization, the method comprising (1) preparing magnesium compound solution by resolving non-deoxidative magnesium halide and...
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6770586 |
Solid catalyst component and catalyst for olefins polymerization
Solid catalyst components and catalysts which contain (a) magnesium compound, (b) titanium tetrachloride, and (c) a phthalic acid diester or its derivative are useful in the synthesis of olefin...
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6610802 |
Process for synthesis of polymer compositions, polymer compositionS obtainable by the process, and use of the same
The present invention relates to a process for synthesis of polymer compositions with reduced catalyst content, wherein ethylenically unsaturated monomers containing less than 0.5 wt % of...
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6545106 |
Process for the polymerization of olefines
Process for the polymerization of olefins, according to which at least one olefin is placed in contact with a catalytic system comprising: a) a solid catalytic complex based on magnesium,...
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6537942 |
Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer
Olefin polymerization catalyests are formed from: (I-2) a contact product obtained by contacting (A) a solid titanium catalyst component, (B) an organometallic compound catalyst component, and (D)...
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6531553 |
Process for increasing molecular weight in polyolefins using Ziegler-Natta catalysts and lithium compounds
This invention relates to a conventional supported heterogeneous Ziegler-Natta catalyst for the polymerization of olefins. It has been found that adding a lithium compound to a transition metal...
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6348554 |
Method for preparation of a liquid polymer composition and use of this composition
The invention concerns a method for preparation of a liquid polymer composition, where ethylenically unsaturated monomers are polymerized by means of initiators that have a transferable atomic...
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6294624 |
Modified diene elastomer and its preparation
A modified diene elastomer prepared by a process comprising the steps of polymerizing a diolefin compound containing a conjugated double bond in a liquid phase in the presence of a cobalt compound,...
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6201079 |
Propylene polymer resin made from a high activity catalyst having a broad thermal processing window and articles made therefrom
A propylene polymer made using a magnesium halide-supported, titanium-containing solid catalyst component having a broad processing window is produced by incorporating into the polymerization...
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6084042 |
Mixed titanium-vanadium catalysts for solution ethylene polymerization
The present invention provides a Ziegler-Natta catalyst based on titanium and vanadium useful in solution processes for the polymerization of olefins having a low amount of aluminum and magnesium....
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6043326 |
Process for copolymerizing ethene and alpha-olefins
Ethene having a profitable α-olefin distribution and an α-olefin copolymer have been prepared with a process comprising reacting of at least the following components with each other: a) a...
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6001939 |
Process for the polymerization of olefins
Process for the polymerization of olefins, in which at least one olef in is placed in contact with a catalytic system comprising: (a) a solid catalytic complex based on magnesium, on transition...
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5925587 |
Supported polymerization catalyst component and system, Polymerization process using same for the production of ultra-fine particle size resins with improved crystallization rates
A supported polymerization catalyst component and a catalyst system useful in the production of polyolefin resins that have a narrow particle size distribution and enhanced crystallization rates is...
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5922632 |
Vanadium based components and catalysts for the polymerization of olefins and polymerization processes using the same
Catalysts component of the (co)polymerization of alpha-olefins CH 2 CHR, wherein R is hydrogen or an alkyl radical having from 1 to 8 carbon atoms, comprising a product of the composition: ...
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5777050 |
Process for polymerizing ethylene in the presence of a catalyst composition
A process is disclosed for the homopolymerization of ethylene or copolymerization of ethylene with one or more α-olefins with 3-12 carbon atoms and optionally one or more non-conjugated dienes in...
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5747595 |
Catalyst for the polymerization of olefines and processes for the polymerization of olefines using the same
A catalyst for the polymerization of olefines comprises a solid catalytic component obtained by pre-polymerizing propylene in the presence of (A) a solid component containing magnesium, titanium,...
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5731393 |
Ethylene polymer, process for preparing the same, solid titanium catalyst component for ethylene polymerization and ethylene polymerization catalyst
An ethylene polymer having small values of Mw/Mn and Mz/Mw, a small proportion of long-chain branches and a high swell ratio and a process for preparing the polymer are disclosed. A solid titanium...
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5631334 |
Process for the manufacture of a catalytic solid, catalytic solid and process for (co)polymerisation of olefins by means of this catalytic solid
Catalytic solid for the (co)polymerisation of at least one olefin, comprising a coprecipitate of magnesium and of at least one transition metal, obtained by means of a process comprising the...
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5623033 |
Titanium catalyst component for ethylene polymerization, ethylene polymerization catalyst, and process for ethylene polymerization using the same
Disclosed is a titanium catalyst component for ethylene polymerization obtained by contacting [A] a solid magnesium aluminum complex containing magnesium, halogen, aluminum and an alkoxy group...
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5612427 |
Catalyst for the polymerization of diolefins, method for its preparation, and its use for the preparation of polymers
A supported solid catalyst which can be used for the polymerization and clymerization of conjugated dienes having as its basis the reaction product of: A) a solid MgCl 2 support, B) an...
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5607655 |
Olefin polymerization catalyst and precursor therefor
A generally dipyramidal-shaped catalyst precursor is prepared by dissolving magnesium dichloride and a suitable alcohol in a suitable solvent and then cooling to obtain a precipitate of the desired...
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5597770 |
Titanium-based catalyst composition for polymerizing ethylene
A catalyst compound of the formula (I) is useful in the polymerization of ethylene into homopolymers or copolymers of high density and high melt flow ratio. The catalyst is prepared with a partial...
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5571877 |
Method of preparing low or medium-density straight-chain polyethylene, and catalysts suitable for this purpose
Low or medium-density straight-chain ethylene polymers are prepared by copolymerising ethylene with a C 4 -C 6 alpha-olefin at elevated temperature and pressure in a tubular reactor and in the...
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5519098 |
Activation of catalyst in ethylene polymerization at high temperatures
The present invention relates to a method for activating coordination catalysts suitable for the polymerization of alpha olefins using a alkoxy aluminum alkyl compound prepared by mixing an alcohol...
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5489634 |
Method for producing a stereospecific polyolefin
A method for producing a stereospecific polyolefin in the presence of a catalyst comprising a transition metal compound and an organometallic compound, wherein a catalyst system is used which...
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5439995 |
Catalyst and prepolymer used for the preparation of polyolefins
The present invention relates to a solid catalyst suitable for polymerizing olefins in a heterogeneous process, the catalyst consisting of spheroidal particles having a narrow particle size...
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5426162 |
Production of olefin polymers
Ziegler polymerization of α-olefins is disclosed which is characterized by a solid catalyst component and an organoaluminum component used in the Ziegler catalyst, and also by the temperature used...
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5411926 |
Olefin polymerization catalyst
A high activity olefin polymerization catalyst catalyzes the production of polymeric lower α-olefin having good properties. The catalyst is produced from an organoaluminum cocatalyst, a...
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5408016 |
Process for producing ethylene polymers
A process for producing an ethylene polymer comprising bringing ethylene or ethylene and an α-olefin having 3 to 10 carbon atoms into contact with a catalyst comprising the following components...
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5382557 |
Procedure for the preparation of a solid component of catalyst for the (co)polymerization of ethylene
A solid component of catalyst highly active in the (co)polymerization of ethylene containing titanium, magnesium, aluminum, chlorine and alkoxy groups, and obtained by means of a procedure wherein:...
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5374695 |
Process for the preparaton of elastomeric copolymers of ethylene
Process for the preparation of elastomeric copolymers of ethylene, wherein ethylene is copolymerized with an α-olefin, and possibly with a diene as termonomer, in the presence of a Ziegler-Natta...
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5350818 |
Process for preparing a high density polyethylene of low n-paraffin content and high melt index ratio
A process for producing a high density polyethylene resin which has a negligible n-paraffin content while having a melt index ratio of at least 75 by polymerizing ethylene with a minor amount of a...
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5324805 |
Ethylene/pentene-1 copolymer and ethylene/pentene-1 copolymer composition
The present invention relates to a novel ethylene/pentene-1 copolymer whose molded film has a good balance between impact resistance and tear properties and high transparency, also is prominently...
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5322911 |
Polymerization process employing metal halide catalyst and polymer produced
A polymerization catalyst is formed by producing a solution of a Group IIA or Group IIB halide and an alcohol; contacting the solution with an organometallic compound to form a soluble complex; and...
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5322830 |
Method for the preparation of catalyst components for the polymerization of ethylene with a relatively narrow molecular weight distribution and protocatalyst composition
The invention relates to a method for the preparation of a supported procatalyst intended for the polymerization of olefins, in which particles are formed from magnesium halide and alcohol, the...
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5300597 |
Olefin polymerization catalyst and process
A method is disclosed for preparing an olefin polymerization catalyst of improved particle size from a solution of magnesium containing component and a transition metal containing component which...
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5296431 |
Ziegler-natta catalyst systems containing organometallic compounds
Ziegler-Natta-type catalyst systems containing, as active constituents, a) a titanium-containing solid component which also contains magnesium, halogen and a carboxylic acid ester as electron...
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5290745 |
Process for producing ethylene polymers having reduced hexane extractable content
A catalyst system of the Ziegler-Natta type suitable for producing ethylene copolymers having a reduced hexane extractable content comprising (a) an organoaluminum component and (b) a titanium...
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5278118 |
Catalysts for the preparation of elastomeric olefinic copolymers
Catalysts for the preparation of copolymers of ethylene and/or alpha-olefins and optionally dienes, are obtained by reacting an Al-alkyl with a solid catalytic component comprising: (A) a...
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5275993 |
Olefin polymerization catalyst
An olefin polymerization catalyst which is obtained by contacting the following components (A) and (B): component (A): a product of contacting the following components (A 1 ) and (A 2 ): ...
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5252688 |
Process for preparing a Ziegler-Natta type catalyst
The present invention relates to a process for preparing a Ziegler-Natta type catalyst based on a vanadium compound. The process comprises sequentially contacting within a liquid hydrocarbon a...
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5247031 |
Olefin polymerization catalyst component, process for production thereof, olefin polymerization catalyst, and process for polymerizing olefins
A catalyst component (X") obtained by treating an olefin polymerization catalyst (X) formed from (A) a solid titanium catalyst component comprising magnesium, titanium, halogen and an electron...
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