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5314989 |
Absorbable composition
A block copolymer for use in the fabrication of bioabsorbable articles such as monofilament surgical sutures is prepared by copolymerizing one or more hard phase forming monomers and...
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5310599 |
Method for making polymers of alpha-hydroxy acids
A method providing a catalyzed ring opening polyester polymerization at a high reaction rate wherein the amount of organic acid in the reaction medium is maintained at an acid: catalyst ratio below...
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5302693 |
Process for preparing poly-D,L-lactide and the use thereof as a carrier for active substances
The invention relates to a process for preparing poly-D,L-lactide and its use as a carrier for active substances.
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5292859 |
Rare earth metal coordination compounds as lactone polymerization catalysts
A process for polymerizing lactide and up to 20 mole percent of another lactone is disclosed. The cayalysts used have the formula MZ 3 wherein M is scandium, yttrium, bismuth, a lanthanide series...
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5284938 |
Polysiloxane modified thermoset compositions
A polysiloxane-modified epoxy-based encapsulation composition comprising an epoxy resin, a curing agent for the epoxy resin, a polylactone-polysiloxane block copolymer, and a filler is described....
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5274073 |
Continuous process for manufacture of a purified lactide
A process for the continuous conversion of crude lactic acid to a substantially purified lactide or polylactide including the steps of polymerizing the lactic acid to form a prepolymer with...
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5264491 |
Compatibilization of polymer blends
Compatibilizing agents suitable for blending otherwise immiscible polymers comprise a block or graft copolymer in which at least one of the block segments is formed by a living anionic...
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5264547 |
Optically active ether lactone, optically active polymer thereof, and process for producing the polymer
An optically active 7-substituted-1,4-dioxepan-5-one derivative represented by the general formula (I): ##STR1## wherein R represents an alkyl group having from 1 to 5 carbon atoms; and * means an...
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5262492 |
Siloxane-modified polyester resins and production processes thereof
Siloxane-modified polyester resins are disclosed. These resins comprise a copolymer of a siloxane compound, which contains at least one active hydrogen atom, and a lactone compound. The copolymer...
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5256739 |
Graft copolymer, method of producing the same, and covering composition containing the same as main component
Graft copolymers containing a vinyl polymer as a trunk polymer component, and both organopolysiloxane and polylactone as a branch polymer component, and methods of producing them. Covering...
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5256711 |
Starch-containing biodegradable plastic and method of producing same
A biodegradable plastic composition, which may be in the form of a molded dy, includes gelatinized starch and a biodegradable, aliphatic polyester resin having a melting point of 45°-130 ° C. The...
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5252701 |
Segmented absorbable copolymer
A copolymer comprising a bioabsorbable, segmented molecular architecture has been invented. The copolymer has at least two different ester linkages. The segmented molecular architecture comprises a...
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5252642 |
Degradable impact modified polyactic acid
An environmentally degradable composition comprises blends of a physical mixture of a poly(lactic acid), comprising about 1 to 99 weight percent of the composition, and an elastomeric blend...
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5241000 |
Curable resin and composition containing the same
The curable resin having a number average molecular weight of 600 to 6000 and at least two hydrolyzable silyl groups which is prepared by reacting an aliphatic polyester resin having acryloyl group...
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5238978 |
Peroxide masterbatches using polycaprolactone as the carrier
A masterbatch composition is provided, comprising greater than about 10% to about 70% by weight of organic peroxide homogeneously dispersed in a polycaprolactone carrier. The peroxide masterbatches...
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5236444 |
Absorbable polymers and surgical articles made therefrom
Block copolymers have a first polymer block wherein glycolide is the predominant component and a second block having glycolide, lactide and trimethylene carbonate linkages. The copolymers are...
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5235031 |
Polymerization of lactide
A process for polymerizing lactide and up to 20 mole percent of another lactone in the absence of solvent at 100° to 220° C. using an yttrium or lanthanide series rare earth metal catalyst.
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5231148 |
Mixture of predominantly one polyhydroxyalkanoate and a compound which contains at least two reactive groups, such as acid and/or alcohol groups, and a polymer prepared by melting the mixture
Mixture containing at least 70% by weight of polyhydroxyalkanoate and one or more compounds which contain reactive alcohol and/or acid groups, mixtures of poly-D (-)-3-hydroxybutyric acid with a...
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5227412 |
Biodegradable and resorbable surgical material and process for preparation of the same
Biodegradable and resorbable surgical materials of molded articles of poly(lactic acid) or copolymers of lactic acid and glycolic acid, characterized in that the articles are molecular-orientated,...
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5225489 |
Composites of thermoplastic and thermoplastic polymers having therein short fibers derived from anisotropic polymers
This invention relates to mixtures of short fibers of varying lengths, diameters and aspect ratios composed of an anisotropic polymer, to compositions containing said fibers and one or more...
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5225521 |
Star-shaped hydroxyacid polymers
Star-shaped poly (hydroxyacid) chains and the process for preparing them are disclosed. The star shaped polymers have the residue of a central polyfunctional compound having at least 5 hydroxyl or...
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5202413 |
Alternating (ABA)N polylactide block copolymers
Polymers of the general formula R--(A-B-A-I)- x A-B-A-R and their preparation are disclosed. In the general formula, -A- is a polyhydroxy acid residue preferably a polymer of either 98 to 100%...
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5198500 |
Process for preparing crosslinked resin particles
Disclosed is an improved process of the post-emulsion method capable of forming crosslinked resin particles which do not have fusion bonds between particles and which have good storage stability...
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5185408 |
Medical devices fabricated totally or in part from copolymers of recurring units derived from cyclic carbonates and lactides
This invention relates to novel copolymers containing carbonate repeat units and ester repeat units.
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5185421 |
Fluorinated hydroxy-containing macromonomers
Disclosed are fluorinated macromonomers containing one or more hydroxy groups, which are useful as monomers in other polymerization. Also disclosed are processes and an intermediate for making such...
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5183861 |
Polyalkyloxazoline/polylactone copolymers, processes for making, and uses
Block copolymers of polyoxazoline and polylactone moieties can be used as polymeric compatibilizers for polyamides and polyolefins.
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5162461 |
Thermoplastic polyblends of aromatic polycarbonates and thermoplastic polyurethanes
This invention relates to binary thermoplastic polyblend that comprises a thermoplastic aromatic polycarbonate and a polycaprolactone polyol-based thermoplastic polyurethane (TPU). The polyblends...
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5151489 |
Copolymers containing polybenzoxazole, polybenzothiazole and polybenzimidazole moieties
Block copolymers can be formed from heterocyclic polymers such as PBO and thermoplastic polymers such as polyamide or poly(aromatic ether ketone). The block copolymer compositions are thermoplastic...
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5137984 |
Non-hairing, moisture curable compositions
A mixture of hydroxy functional polymers which can be used to form isocyanate prepolymers which are non-hairing at application temperature are disclosed. Examples of suitable mixtures of hydroxy...
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5132374 |
Expoxide flexibilizers based on polylactone adducts
Adducts of the formula I ##STR1## are described in which R 1 is an e-valent aliphatic radical after the removal of the functional groups, X is --O--or --NH--, R 2 is a d+l-valent...
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5132397 |
4-valerolactone copolymers
Copolymers of lactic acid, from 0.5 to 20 weight % of 4-valerolactone and from 0 to 20 weight % of a C 6 -8 lactone form polymers having a higher intrinsic viscosity than homopolymers of lactic...
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5116918 |
Crosslinked copolymers based on cyclic esters and carbonates
Crosslinked copolymers of A) cyclic aliphatic esters and B) cyclic aliphatic carbonates in which part of B contains crosslinking-active side groups, their production and their use for...
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5112887 |
Formable coatings
A coating composition capable of substantial deformation without loss of continuity, adhesion or protective properties. The coating composition comprises a phenoxy resin mixed with a relatively...
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5106446 |
Polyurethane mixtures and the use thereof as adhesives
The present invention is directed to a mixture which can be used as an adhesive. The mixture broadly contains 1) a hydroxy group containing polyurethane, and 2) a polycarbonate and/or a...
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5089561 |
Alkylcarbamylmethylated aminotriazine crosslinking agents and curable compositions containing the same
Novel alkylcarbamylmethyl aminotriazines self-cure and also function as crosslinkers for compounds containing active hydrogen groups. When the active hydrogen-containing compounds are hydroxylated...
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5089568 |
Process of making thermoplastic copolymers containing polybenzoxazole, polybenzothiazole and polybenzimidazole moieties
Block copolymers can be formed from heterocyclic polymers such as PBO and thermop STATEMENT OF GOVERNMENT INTEREST This invention was made with Government support under contracts F49620-86-C-0057...
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5084524 |
Block copolymers based on cyclic aliphatic carbonates and/or esters on the one hand and cyclic aromatic carbonates on the other hand
Copolymers of blocks of polymers of cyclic aliphatic carbonates, cyclic aliphatic esters or cyclic aliphatic carbonates and cyclic aliphatic esters on the one hand and blocks of polymers of cyclic...
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5076983 |
Polyhydroxy acid films
The present invention relates to a process for producing degradable, shrinkable films of polyhydroxy acid and plasticizers including melt processing the materials to obtain uniform composition,...
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5047048 |
Crystalline copolymers of p-dioxanone and ε-caprolactone
Crystalline copolymers of ε-caprolactone and a monomer having the formula: ##STR1## Surgical filaments, especially monofilament sutures, prepared by melt spinning the crystalline copolymers...
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5043398 |
Grafting of functional compounds onto functional oxymethylene polymer backbones, with diisocyanate coupling agents, and the graft polymers thereof
Novel oxymethylene graft polymers are obtained by grafting a functional compound (i.e., a polymer or compound having one or two hydroxyl, carboxyl, or amine functional groups) onto an oxymethylene...
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5041493 |
Moldable polyblends
A moldable polyblend of an aromatic polycarbonate, a polyester of an aromatic dicarboxylic acid, an elastomeric rubber, and a polylactone, which polylactone is present within the range of from...
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5037898 |
Polysiloxane-polylactone block copolymer modified thermostat compositions
A polysiloxane-modified epoxy-based encapsulation composition comprising an epoxy resin, a curing agent for the epoxy resin, a polylactone-polysiloxane block copolymer, and a filler is described....
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5037899 |
Lactone-primary amine modified epoxy resin and process for preparing the same
A modified epoxy resin provided with improved flexibility and curing properties is prepared by subjecting a bisphenol type epoxy resin (a) to steps (i) and (ii): (i) the step wherein the epoxy...
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5010145 |
Polylactic acid fiber
A polylactic acid fiber comprises a blend of poly-L-lactic acid and poly-D-lactic acid and is improved by spinning and then drawing.
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5007939 |
Article made of lactic acid polymer capable of being employed particularly as a biodegradable prosthesis and process for its manufacture
Article made of lactic acid polymer capable of being employed particulaly as a biodegradable prosthesis exhibiting at 23° C. a tensile regidity modulus higher than 5000 MPa and a tensile...
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5007923 |
Crystalline copolyesters of amorphous (lactide/glycolide) and p-dioxanone
A crystalline copolyester of p-diaxanone and a prepolymer of lactide and glycolide, and absorbable surgical filaments derived therefrom.
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5003038 |
Process for the manufacture of vinyl chloride polymers modified with lactone polymers and product thereof
In a first stage, a lactone is polymerized by an ionic route in vinyl chloride with the aid of a catalyst consisting of the product, optionally complexed with tetrahydrofuran, of the reaction of an...
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5003025 |
Process for the preparation of water dilutable binders for cationic electrocoating finishes using monofunctionally modified polyepoxides
The invention relates to water-dilutable binders for cationic electrocoating finishes. For the preparation of the binders, a di-epoxide compound, together with at least one mono-epoxide compound if...
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4983689 |
Process for making macromolecular monomers of polylactones with terminal acryloyl unsaturation and block copolymers thereof
Preparation of a macromolecular monomer of a lactone having an alpha-beta monoolefinically unsaturated "head" is effected at low temperature with a strong oxonium salt, such as a trialkyloxonium...
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4965300 |
Sequential copolymers based on cyclic carbonates and esters
Polymers having a sequential structure of the following formula --A--X--B] r (I) with r=1 to 20, in which --A-- is a polymer of a cyclic carbonate,...
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