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8334232 |
Porous heterogeneous catalyst coated with an ionic liquid
The invention relates to a porous heterogeneous catalyst. In order to prepare a catalyst which catalyzes with a relatively high selectivity the hydrogenation of individual unsaturated bonds of...
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8288488 |
Process for producing solid catalyst component for olefin polymerization
The present invention aims at providing a process for producing a solid catalyst for olefin polymerization, the solid catalyst component being capable of providing a polymer having high...
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8211819 |
Internal and external donor compounds for olefin polymerization catalysts
The present invention relates to catalyst systems containing solid catalyst components comprising titanium, magnesium, halogen and a 1,8-naphthyl diaryloate internal electron donor compound;...
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8105970 |
Olefin polymerization catalyst component and production process thereof, and production proces of olefin polymerization catalyst and olefin polymer
A solid catalyst component for olefin polymerization containing a titanium atom, a magnesium atom, a halogen atom, and a defined internal electron donor such as dodecanedioyl dichloride; a...
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8053606 |
Alkoxylation of fluorinated alcohols
A fluorinated alkylalkoxylate, and a process for its preparation in which at least one fluorinated alcohol is contacted with at least one alkylene epoxide in the presence of a catalyst system...
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7928031 |
Catalyst comprising indium salt and organic ionic liquid and process for friedel-crafts reactions
Disclosed is a catalyst composition based on an indium salt and an organic ionic liquid, a process for making the catalyst composition, and uses thereof. The catalyst composition is particularly...
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7871953 |
Late transition metal catalysts for olefin oligomerizations
As series of novel late transition metal catalysts for olefin oligomerization have been invented. The catalyst system includes a Group 8, 9 or 10 transition metal and an activator. The catalysts...
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7687581 |
Heterogeneous organotin catalysts
Supported heterogeneous organotin catalysts of the formula X1, X2, or X3: wherein Z is a spacer group;Y is an insoluble phenyl-group containing copolymer;R1, R2, R3, R5, and R6 are independently...
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7666811 |
Ionic liquid catalyst having enhanced activity
A process for producing acidic ionic liquid catalyst having enhanced activity comprising combining fresh acidic ionic liquid catalyst, a metal and a Broensted acid in a reaction zone for a time...
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7622414 |
Organometal catalyst compositions
This invention provides compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides compositions that are useful for polymerizing at least...
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7538235 |
Process for preparing a catalyst, the catalyst, and a use of the catalyst
A process for preparing an epoxidation catalyst comprising silver and a high-selectivity dopant on a support, which process comprises depositing a base having a pKb of at most 3.5 when measured in...
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7501075 |
Synthesis agent containing methyllithium/lithium bromide, and process for the preparation thereof
A synthesis agent containing methyllithium and lithium bromide is described, in which MeLi and LiBr are dissolved in a solvent of the general formula (I) wherein R1 and R2 independently of one...
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7468339 |
Diketonate complex-derived catalysts useful for preparing polyolefins
An olefin polymerization catalyst may be prepared using a process including contacting a metal compound of the formula M(OR1)2 with a diketone to form a catalyst precursor having the general...
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7402546 |
Magnesium chloride support
The invention relates to supports comprising inorganic oxide particles coated with magnesium chloride and a method for making them. The inorganic oxide has a mean particle diameter of less than 5...
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7268095 |
Transition metal catalysts for (co) polymerizing of olefinic monomers
A compound of the formula Ia or Ib; where,in the formula Ia,E1 is O, S, Se, Te, NR, CR2, or PR;E2, E3 are each CR, N, or P;E4 is N, or P;E5 is OH, SH, NHR, OR′, SR′, or NRR′;E6 is NH, PH, NR′, ...
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7261872 |
Method for producing metal fluoride materials
A method of producing nano metal fluoride powders comprising the steps of mixing an aqueous or organic continuous phase comprising at least one metal cation salt with a hydrophilic or organic...
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7262258 |
Process for producing copolymer
There are provided (I) a process for producing a copolymer of ethylene, an α-olefin having from 3 to 20 carbon atoms and optionally a polyene, which comprises the step of copolymerizing those ...
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7256150 |
Preparation of olefin polymerization catalyst component
A process for producing a Gp 2/transition metal olefin polymerisation catalyst component, in which a Gp 2 complex is reacted with a transition metal compound so as to produce an oil-in-oil...
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7220696 |
Solid titanium catalyst component for olefin polymerization, catalyst for olefin polymerization, and process for olefin polymerization
Disclosed is a catalyst for olefin polymerization comprising [I] a solid titanium catalyst component [S] comprising titanium, magnesium, halogen and an electron donor (b), which is obtained by...
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7211534 |
Preparation of a magnesium halide support for olefin polymerization and a catalyst composition using the same
A magnesium halide support material for a polyolefin catalysts is disclosed. The magnesium halide of present invention is prepared by reacting magnesium with an alkylhalide in a non-polar...
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7122611 |
Catalyst for polymerization of norbornene
This invention is based upon the discovery that a catalyst system which is comprised of (a) palladium or a palladium compound and (b) a fluorinated alcohol is effective for polymerizing...
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7087549 |
Calcium-based catalyst system
This invention reveals a catalyst system for use in isothermal polymerizations which consists essentially of (a) an organolithium compound, (b) a calcium alkoxide and (c) a lithium alkoxide. The...
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7049266 |
Layered double hydroxides supported nanopalladium catalysts for Heck-, Suzuki, Sonogashira-, and Stille type coupling reactions of haloarenes
Processes for the preparation of nanopalladium (0) catalysts are disclosed. In some embodiments, the nanopalladium (0) catalysts may be reusable. In some embodiments, the nanopalladium (0)...
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6984605 |
Method for manufacturing ionic liquid catalysts
A method for manufacturing ionic liquid compositions by use of a two-step process which includes the contacting, under first reaction conditions, an amine compound with a hydrogen halide that is...
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6982238 |
Supported catalyst
The invention provides a supported chromium catalyst system comprising a chromium catalyst precursor bound via at least one heteroatom to a functionalised support, said heteroatom being connected...
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6969693 |
Immobilised ionic liquids
Ionic liquids are immobilized on a functionalized support which carries or contains one component of the ionic liquid, or a precursor to such a component. The ionic liquid may be immobilized via...
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6903042 |
Catalytic composition and process for oligomerizing ethylene, in particular to 1-hexene
A catalytic composition for oligomerizing ethylene, in particular to 1-hexene, is obtained by mixing at least one chromium carboxylate characterized in that it also contains a free carboxylic acid...
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6903045 |
Tin promoted platinum catalyst for carbonylation of lower alkyl alcohols
A carbonylation catalyst useful for producing esters and carboxylic acids in a vapor phase carbonylation process, wherein the catalyst includes a solid component having a catalytically effective...
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6893996 |
Process for the preparation of a nickel/phosphorous ligand catalyst for olefin hydrocyanation
A process for preparing a hydrocyanation catalyst comprising contacting a bidentate phosphorous-containing ligand with a molar excess of nickel chloride in the presence of a nitrile solvent and a...
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6881698 |
Ion liquids derived from Lewis acid based on titanium, niobium, tantalum, tin or antimony, and uses thereof
The ionic liquids according to the invention result from the reaction of a halogenated or oxyhalogenated Lewis acid based on titanium, niobium, tantalum, tin or antimony with an organic salt of...
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6869903 |
Synthesis of polymerization catalyst components
The present invention provides a method of synthesizing fluorided metallocene catalyst components comprising contacting at least one fluoriding agent comprising fluorine with one or more alkylated...
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6861385 |
Process for the preparation of a spherical support comprising a Mg dihalide
A process for preparing spherical support particles used in the preparation of catalytic components for the polymerization of olefins by (a) forming an emulsion of an adduct of a Mg dihalide and a...
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6828269 |
Catalytic composition and a process for oligomerizing ethylene, in particular to 1-hexene
A catalytic composition is obtained by mixing at least one chromium compound with at least one aryloxy compound of an element M selected from the group formed by magnesium, calcium, strontium and...
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6825148 |
Nickel-containing ethylene oligomerization catalyst and use thereof
A process for the oligomerization of ethylene to a mixture of olefinic products having high linearity is provided, by using a catalyst comprising a reaction product of a simple divalent nickel...
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6806224 |
Process for producing a supported metal catalyst
A process for producing a supported metal catalyst which comprises reducing a metal halide in the liquid phase in the presence of a support material, an organic base and a reducing agent. In...
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6803428 |
Process for preparing a catalyst support for polymerization of α-olefins, and support thus obtained
A process is provided for preparing a catalyst support for polymerizing α-olefins comprising the steps of: (i) reacting, in the presence of a first electron donor, a chlorine-containing organic ...
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6794525 |
Optically active chiral diphosphine ligands
An (R) or (S) chiral diphosphine of formula (I): wherein R and R1, which can be identical or different, represent an optionally saturated C1-10 alkyl group, an optionally saturated C3-9 cycloalkyl...
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6759362 |
Mixed metal alkoxide complexes and polymerization catalysts made therefrom
A process for making a solid composition comprising alkoxide groups, chloride groups, one or more metals, M, in the +2 oxidation state selected from Mg, Ca, Mn, Cu, Co or Zn, and one or more...
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6753288 |
Oxidative carbonylation of hydroxyaromatic compounds
Organolead compounds such as tetraethyllead are useful in catalyst compositions for the oxidative carbonylation of hydroxyaromatic compounds to diaryl carbonates. They are employed in combination...
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6734327 |
Alkoxylation process using antimony catalyst
Novel active catalyst compositions comprising a compound or mixture of compounds represented by the formula SbFXmY4−ma complex of such a compound or mixture of such compounds being represented by t...
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6706657 |
Catalytic composition for dimerizing, co-dimerizing and oligomerizing olefins
A catalytic composition comprising at least one nickel compound mixed or complexed with at least one tertiary phosphine or a phosphite carrying a functional group, at least partly dissolved in a...
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6686307 |
Magnesium dichloride-alcohol adducts
The present invention relates to MgCl2.mROH.nH2O adducts, where R is a C1-C10 alkyl, 2≦m≦4.2, 0≦n≦0.7, characterized by an X-ray diffraction spectrum in which, in the range of 2θ diffract...
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6683146 |
Heterogeneous polymerization catalyst, process for producing acrylic polymer, and acrylic polymer
A process for producing an acrylic polymer capable of providing a polymer controlled in molecular weight and free of colorization, and a heterogeneous polymerization catalyst used in the process...
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6617279 |
Catalyst composition and method for producing diaryl carbonates, using bisphosphines
Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a Group VIIIB metal, preferably palladium; an iodide salt,...
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6602817 |
Combination approach to chiral reagents or catalysts having amine or amino alcohol ligands
Functionalized amine derivatives are prepared by reacting an amine, a carbonyl derivative, and an organoboron compound under mild conditions. Organoboronic acids react with amines and alpha-hydroxy...
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6455459 |
Antimony catalyst compositions
Novel active catalyst compositions comprising a compound or mixture of compounds represented by the formula SbFXmY4−ma complex of such a compound or mixture of such compounds being represented by t...
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6420303 |
Production of powder catalysts
A process for the production of a magnesium chloride powder for use in a catalyst, the process comprising vaporizing magnesium chloride in a plasma torch and quenching the vapor with a liquid...
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6417132 |
Process for preparing a carrier used in olefin polymerization catalysts
The present invention relates to a process for preparing a carrier used in olefin polymerization catalysts, comprising suspending anhydrous magnesium chloride in an inert hydrocarbon solvent and...
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6407299 |
Alkyl magnesium catalyzed synthesis of ethylene and α-olefin polymers
The present invention is a two-component catalyst system comprising (a) an alkyl magnesium (MgR2) component and (b) a Lewis acid component. The catalyst system is used for catalyzing the...
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6403522 |
Polymeric homogeneous catalysts
A homogenous catalyst is prepared by reacting a ruthenium or molybdenum carbene catalyst of formula (I): in a non-reactive organic solvent or solvent mixture with a bicyclic olefin of formula (II):...
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