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7622540 |
Metal carbonate initiator and method for polymerizing isocyanates using the same
Disclosed herein is a metal enolate initiator for polymerizing isocyanates and a method for polymerizing isocyanates by anionic polymerization using the same, in which the initiator forms a cluster...
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7538061 |
One-step production of 1,3-propanediol from ethylene oxide and syngas with a cobalt-iron catalyst
Disclosed is a new catalyst composition comprising a bimetallic Co—Fe catalyst, optionally complexed with a ligand selected from a N-heterocycle, phosphine, or porphorine ligand, that provides a...
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7169875 |
Organometallic compositions
A composition suitable for use as a catalyst for the reaction of an isocyanate compound or prepolymer thereof with an alcohol to form a polyurethane comprises a mixture of (a)an organometallic...
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7115540 |
Synthesis of aliphatic 1,3-diols utilizing reduced ligand concentration and water extraction
This invention is a process for synthesizing aliphatic 1,3-diols in one step by hydroformylation and hydrogenation of oxirane, carbon monoxide, and hydrogen employing a catalyst comprising a cobalt...
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7022800 |
Organosiloxane compositions
A moisture curable composition capable of cure to an elastomeric body, comprising a polymeric material having not less than two hydroxyl or hydrolyzable groups an alkoxysilane curative and a...
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7001864 |
Catalyst composition for production of a polyurethane resin, and method for producing a polyurethane resin
A catalyst composition for production of a polyurethane resin, which comprises a metal complex catalyst represented by the following formula (1):
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6852664 |
Double metal cyanide catalysts for the preparation of polyether polyols
The present invention relates to novel double metal cyanide (DMC) catalysts for the preparation of polyether polyols by a polyaddition reaction between alkylene oxides and starter compounds having...
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6852865 |
Catalytic carbonylation of three and four membered heterocycles
Epoxides, aziridines, thiiranes, oxetanes, lactones, lactams and analogous compounds are reacted with carbon monoxide in the presence of a catalytically effective amount of catalyst having the...
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6821920 |
Polymerization catalysts and processes therefor
Novel catalyst systems which comprise diimine nickel complexes comprising additional ligands selected from the group consisting of acetylacetonate, hexaflourylacetylacetonate, halogens and mixtures...
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6800583 |
Suspension of multimetal cyanide compounds, their preparation and their use
Catalyst suspensions for the ring-opening polymerization of alkylene oxides comprise a) at least one multimetal cyanide compound having a crystalline structure and a content of platelet-shaped...
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6717018 |
Production of oxygenated products
A process for producing oxygenated products from an olefinic feedstock, which process includes reacting, in a hydroformylation reaction stage, an olefin feedstock with carbon monoxide and hydrogen...
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6706656 |
One step process for preparing a 1,3-diol
The invention provides a process for an improved oxirane hydroformylation catalyst, the improved oxirane hydroformylation catalyst, and a one step process for preparing a 1,3-diol in the presence...
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6693219 |
Epoxide stabilization of fluorophosphite-metal catalyst system in a hydroformylation process
A process for stabilizing a fluorophosphite ligand in a hydroformylation reaction mixture having an α-olefin, hydrogen, carbon monoxide and a catalyst composition having a combination of a rhodium...
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6664462 |
Metal complex having β-diketonate, process for production thereof, photoelectric conversion element, and photochemical cell
A metal complex having a β-diketonate represented by the following formula (1): wherein M represents a metal atom of the VIII group, R 1 , R 2 and R 3 represent a group or an atom selected...
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6555717 |
Catalytic dehydroxylation of diols and polyols
Secondary alcohols, specifically diols and polyols, are dehydroxylated to the corresponding primary alcohols using a homogeneous organometallic ruthenium complex catalyst.
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6509288 |
Polymerization catalysts
Catalyst system suitable for preparing substantially terminally unsaturated atactic polymers or copolymers of α-olefins having a molecular weight (Mn) in the range 200-500,000. The catalyst system...
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6492480 |
Method of polymerizing a silalkylenesiloxane
Disclosed is a method for the preparation of a linear polysilalkylenesiloxane from four- to seven-membered cyclic silalkylenesiloxane by subjecting the cyclic silalkylenesiloxane to ring opening...
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6455740 |
Process to separate a group 8-10 metal/phosphite ligand complex from an organic liquid
Process to separate a group 8-10 metal/phosphite ligand complex from an organic liquid mixture, wherein the following steps are performed (1) contacting the organic liquid with a support having...
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6455649 |
Catalyst for producing living olefin polymer and process for producing the polymer
A catalyst comprising an organoaluminum compound and a vanadium chelate compound having the lability to cause olefins to undergo living coordination polymerization is contacted with a terminal...
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6433113 |
Ring-opening metathesis polymerization (ROMP) of cyclo-olefins with molybdenum catalysts
A polymerization system for ring opening polymerization of cycloolefins, comprising a catalyst [MoOX 2 L 2 ], a Lewis acid as co-catalyst, and a chain-transfer agent, wherein (1) both X groups...
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6372879 |
Polyester polycondensation with catalyst and a catalyst enhancer
The present invention is based upon the discovery that nontitanyl oxalates can enhance the catalytic functionality of titanyl oxalate catalysts. This invention provides a novel catalytic...
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6335304 |
Metal salts of phosphoric acid esters as cross linking catalysts
A metal (M) alkyl acid phosphate catalyst for the reaction of an epoxy compound with a carboxyl compound to provide a coating formulation that is stable at room temperature; that is humidity...
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6258925 |
Polyester polycondensation with titanyl oxalate catalyst and a catalyst enhancer
The present invention is based upon the discovery that nontitanyl oxalates can enhance the catalytic functionality of titanyl oxalate catalysts. This invention provides a novel catalytic...
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6075102 |
Polymerization catalyst and process for producing polymers
The present invention provides a polymerization catalyst comprising (a) a specific transition metal compound, (b) (i) a compound which can form a complex by reaction with the transition metal...
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6037507 |
Oxidation process of branched aliphatic hydrocarbons and process for producing the oxide
A non-cyclic branched aliphatic hydrocarbon (e.g., isobutane) is oxidized with oxygen in the presence of an oxidation catalyst comprising an imide compound of the following formula (1) (e.g.,...
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5958197 |
Catalysts for gas diffusion electrodes
A gas diffusion electrode comprising an electrically conductive web provided on at least one side thereof with a coating containing a rhodium--rhodium oxide catalyst on a carbon black support and a...
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5929289 |
Stabilization of phosphite ligands in hydroformylation process
The present invention provides a hydroformylation process comprising: (1) forming a reaction mixture containing: (a) an olefinic compound, (b) hydrogen, (c) carbon monoxide, (d) a phosphite in...
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5916432 |
Process for dispersing transition metal catalytic particles in heavy oil
A transition metal salt, preferably ammonium heptamolybdate, is dissolved in water to provide a solution containing the dispersed catalyst precursor. The solution is atomized by passing it through...
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5900521 |
Catalysts for converting methane or purified natural gas, preparation thereof, and process for preparation of ethylene using the catalysts
Catalysts for preparing ethylene by conversion of methane or purified natural gas and preparation thereof, and process for preparation of ethylene by direct conversion of methane or purified...
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5847204 |
Process for producing an iridium solution and use of same as catalyst
An iridium-based solution is prepared by contacting components in a liquid phase containing (a) a carbonylated iridium compound, (b) hydriodic acid, a precursor of such an acid, or mixture thereof,...
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5789333 |
Catalyst system comprising a first catalyst system tethered to a supported catalyst
The present invention provides new catalyst formats which comprise a supported catalyst tethered to a second and different catalyst by a suitable tethering ligand. A preferred system comprises a...
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5759941 |
Process for the preparation of dialkyltin dialkoxide from alkyl carbamate and alcohol
A process for making a catalyst product which comprises reacting dialkyltin oxide with an alcohol and the corresponding alkyl carbamate at a temperature in the range between about 160 to 190° C....
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5696046 |
Cold sterilant solution
A sterilant-disinfectant solution which may be used in the cleaning of metallic objects, particularly medical instruments. Medical instruments, which may include brass, copper, aluminium, stainless...
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5625107 |
Catalyst for conversion of methane to ethylene, preparation thereof, and process for manufacturing ethylene using said catalyst
The present invention relates to a new catalyst for converting methane into ethane, preparation thereof, and process for manufacturing ethylene using said catalyst. The conversion reaction catalyst...
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5623047 |
Catalytic compositions for the preparation of poly(ethylene terephthalate) with improved color
A catalyst composition for use in a polycondensation reaction for making poly(ethylene terephthalate) from terephthalic acid comprising: (a) an antimony salt catalyst present in a range from about...
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5608032 |
Catalytic compositions for the proparation of poly(ethylene terephthalate) with attenuated yellow color
A catalyst composition for use in a polycondensation reaction for making poly(ethylene terephthalate) from terephthalic acid comprising: (a) an antimony salt catalyst present in a range from about...
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5593932 |
Process for sweetening a sour hydrocarbon fraction using a mixture of a supported metal chelate and a solid base
A catalytic mixture of discrete solid materials and a mercaptan oxidation process for using the catalytic mixture have been developed. The catalytic mixture comprises a metal chelate dispersed on a...
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5561094 |
Dialkyl isocyanato tin alcoholate catalysts and dimers thereof
A process for making a dialkyl carbonate which comprises reacting urea with a first alcohol in a carbamate reactor at a temperature and pressure sufficient to convert said urea to an alkyl...
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5561231 |
Homogeneous hydrosilylation catalysts
Transition metal-containing organosiloxanes of at least three organosiloxane units, comprising at least one transition metal complex, chemically bonded via ligands selected from among amino,...
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5545600 |
Process for the preparation of dialkyltin dialkoxide
A process for making a catalyst product which comprises reacting dialkyltin oxide with an alcohol and the corresponding dialkyl carbonate at a temperature in the range between about 50° to 200°...
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5519108 |
Catalytic compositions containing tetrabutyl titanate and a mixture of cocatalysts for the preparation of poly(butylene terephthalate)
A catalyst composition for use in the preparation of poly(butylene terephthalate) from dimethyl terephthalate, comprising: (a) a titanium compound primary catalyst, from about 0.0005 PHR to about 5...
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5516879 |
Catalytic compositions for the preparation of poly(butylene terephthalate)
A catalyst composition for use in the preparation of poly(butylene terephthalate) from dimethyl terephthalate, comprising: (a) a titanium compound primary catalyst, from about 0.01 PHR to about 1...
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5491266 |
Asymmetric syntheses
This invention relates to asymmetric syntheses in which a prochiral or chiral compound is contacted in the presence of an optically active metal-ligand complex catalyst to produce an optically...
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5449653 |
Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyaldehydes
A process for producing a 1,3-diol, e.g., 1,3-propanediol, and/or a 3-hydroxyaldehyde, e.g., 3-hydroxypropionaldehyde, is disclosed which comprises contacting a combination of an epoxide, carbon...
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5286372 |
Process for sweetening a sour hydrocarbon fraction using a solid base
A process for treating a hydrocarbon fraction which contains mercaptans has been developed. The process uses a novel catalyst which is composed of a metal chelate dispersed on a basic support which...
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5272124 |
Ethylene polymerization catalyst comprising a nickel compound and an aromatic carboxylic acid compound
Olefins are polymerized with a catalyst system composition comprising a nickel compound and an aromatic carboxylic acid wherein there is an atom linkage between the aromatic moiety and the...
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5232887 |
Catalyst for sweetening a sour hydrocarbon fraction
A catalyst has been developed. The catalyst is a metal chelate dispersed on a basic support which is either a solid solution of metal oxides or a layered double hydroxide (LDH). The process...
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5225387 |
Catalysts for producing 1,3-diols and/or 3-hydroxyaldehydes, and processes for making and using same
A process for producing a 1,3-diol, e.g., 1,3-propanediol, or a 3-hydroxyaldehyde is disclosed which comprises contacting a combination of an epoxide, carbon monoxide and hydrogen in the present of...
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5210318 |
Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyldehydes
A process for producing a 1,3-diol, e.g., 1,3-propanediol, and/or a 3-hydroxyaldehyde, e.g., 3-hydroxypropionaldehyde, is disclosed which comprises contacting a combination of an epoxide, carbon...
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5182246 |
Catalyst for hydrogenation, dehydrosilylation or hydrosilylation and use thereof
A catalyst for hydrogenation, dehydrosilylation of ketones, or hydrosililation of dienes or acetylenes, comprising a complex represented the the formula: A + [M 2 H(C)) 10 ] - wherein A + ...
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