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4975403 |
Catalyst systems for producing polyolefins having a broad molecular weight distribution
The invention provides catalyst systems for use in the polymerization of olefins to produce a polymer product having a broad molecular weight distribution. The catalyst system includes at least two...
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RE33452 |
Method for making alkylhalosilanes
A method is provided for making alkylhalosilanes by effecting reaction between an alkyl halide, such as methyl chloride and powdered silicon in the presence of a copper-zinc-tin catalyst....
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4956323 |
Catalysts prepared from tetrakis(dialkylamide or diarylamide) derivatives of titanium and polymerization of olefins therewith
Ziegler-Natta catalysts for polymerizing α-olefins are prepared by the addition of tetrakis(dialkylaminde or diarylamide) derivatives of titanium, and a metal-containing reducing agent such as...
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4952540 |
Finely divided aluminoxane, process for producing same and its use
A finely divided aluminoxane comprising an aluminoxane represented by formula [I] or [II] ##STR1## wherein R denotes a hydrocarbon group having 1 to 10 carbon atoms and m denotes an integer of 2 to...
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4948770 |
Method for crystallizing magnesium chloride and method for using in a catalyst composition
Disclosed is a method for making crystalline magnesium halide particles usable for preparing catalyst and usable in the polymerization of alpha olefins having the formula MgnEmXp * y ROH wherein y...
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4940682 |
Solid catalyst component for olefin polymerization
A solid catalyst component for olefin polymerization which comprises a catalyst component comprising at least titanium and chlorine fixed onto a porous substance of which the pore volume, at a pore...
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4937299 |
Process and catalyst for producing reactor blend polyolefins
Polyolefin reactor blends obtained by polymerization of ethylene and higher alpha-olefins in the presence of a catalyst system comprising two or more metallocenes and alumoxane.
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4918038 |
Process for the production of polyethylene with a broad and/or bimodal molecular weight distribution
A process for the production of an ethylene homopolymer or copolymer comprising passing ethylene with or without at least one alpha-olefin comonomer having 3 or more carbon atoms into contact with...
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4918039 |
Binuclear metathesis polymerization catalyst system
A metathesis polymerization catalyst composition comprising a binuclear catalyst, wherein said binuclear catalyst is a mixture of at least two transition metal components, wherein a first...
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4912074 |
Catalyst composition for preparing high density or medium density olefin polymers
There is disclosed a catalyst composition for the polymerization of olefins, particularly alpha-olefins. The composition is prepared by synthesizing a catalyst precursor and then combining it with...
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4877763 |
Supported chromium oxide/boron catalyst
A catalyst system useful for the polymerization of ethylene and other α-olefins comprising (a) a silica-supported chromium oxide catalyst and (b) a dihydrocarbylboron monohydrocarbyloxide...
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4874734 |
Process for producing solid catalyst for polymerization of olefins
A process for producing a solid catalyst for polymerization of olefins, which comprises bringing a solution of an aluminoxane into contact with a suspension of a particulate carrier having...
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4870041 |
Process for the oligomerization of alpha olefins and catalyst therefor
A process for the preparation of alpha olefin oligomers having predominantly terminal unsaturation using a catalyst system comprising an alkyl aluminum halide component and a second component...
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4864005 |
Preparation of homopolymers and copolymers of α-monoolefins using a Ziegler catalyst system
A process for the preparation of homopolymers and copolymers of α-monoolefins by polymerization of the monomer or monomers using a Ziegler catalyst system comprising (1) a transition metal...
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4859733 |
Polyolefin compositions containing trialkanolamines
A method is disclosed for the reduction of the extractability of trialkanolamines from polyolefins containing such compounds e.g. as a result of the use of trialkanolamines as catalyst deactivators...
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4849390 |
Catalysts for polymerization of olefins
A catalyst for polymerization of olefins is disclosed which comprises a titanium and/or vanadium compound supported on a silicon and/or aluminum oxide carrier. This carrier has peculiar...
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4831090 |
Preparation of homopolymers of ethene and copolymers of ethene with higher α-monoolefins using a Ziegler catalyst system
Homopolymerization and copolymerization of ethene are carried out using a Ziegler catalyst system consisting of (1) a transition metal catalyst component prepared by a method in which (1.1) first...
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4822763 |
Catalyst component for polymerization of olefin
A catalyst component for polymerization of olefin, comprising a contact product of a component (A) which is a solid component containing titanium having at least one OR 1 group (where R 1 ...
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4816432 |
Catalyst composition for polymerizing alpha olefins
A modified catalyst for polymerizing alpha-olefins, for example, ethylene, is prepared by combining a chromium-compound-comprising catalyst, supported on a refractory oxide support with at least...
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4769428 |
Solution process for the preparation of polymers of alpha-olefins
A solution process, and a catalyst therefor, for the preparation of high molecular weight polymers of alph-olefins viz. homopolymers of ethylene and copolymers of ethylene and C 3 -C 12 ...
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4717701 |
Olefin polymerization
Density and flexural modulus of olefin polymers can be controlled using a chromium catalyst on a iron and aluminum phosphate and/or polyphosphate gel base.
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4711865 |
Olefin polymerization catalysts, production and use
A catalyst for the polymerization of olefins, said catalyst comprising a transition metal containing support catalyst component and an aluminum alkyl cocatalyst, said transition metal containing...
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4705835 |
Preparation of homopolymers and copolymers of α-monolefins using a Ziegler catalyst system
α-Monoolefins are polymerized using a Ziegler catalyst system comprising (1) a transition metal catalyst component and (2) an organoaluminum catalyst component, in which (1) is a solid-phase...
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4681866 |
Polymerization catalyst, method of making and use therefor
Polymerization catalyst consisting essentially of treated silica support and zerovalent chromium compound is provided, as well as process for preparation and polymerization process with the...
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4663404 |
Method for the polymerization of ethylene and for the copolymerization of ethylene with alpha-olefins and catalysts for use in the method
Method for the polymerization of ethylene and for the copolymerization of ethylene with alpha-olefins to give polymers and copolymers particularly suited to working by blow-moulding, by using a...
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4659685 |
Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound
Catalyst compositions are disclosed which are a combination of a supported titanium compound such as titanium tetraisopropoxide supported on magnesium dichloride and at least one other supported...
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4657883 |
Ester-modified olefin polymerization catalyst
An olefin polymerization catalyst component comprises an organoaluminum-reduced titanium trihalide on which a pretreatment amount of olefin polymer has been placed complexed with an alkyl aliphatic...
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4656151 |
Intermetallic compound
An intermetallic compound is disclosed formed by (a) mixing a compound having the structural formula R(R')Mg where R and R' are the same or different and are hydrocarbyl of 1 to 10 carbon atoms...
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4649182 |
Polymerization catalysts and methods of preparation thereof
The catalysts are composed of an organometallic compound and a solid catalytic component which is the reaction product of a transition metal derivative and a solid support having a composition, at...
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4647550 |
Catalyst component for polymerization of olefins
A catalyst component for the polymerization of olefins which is prepared by contacting a contact reaction product of (a) a metal oxide, (b) an organic magnesium compound, and (c) an alkoxy...
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4629714 |
Intermetallic compounds and catalytic use thereof
An intermetallic compound is disclosed. The compound is formed by reacting a first reaction product, the first reaction product being the product of reaction of a polymeric transition metal oxide...
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4623634 |
Low temperature catalysts for methanol production
A catalyst and process useful at low temperatures (below about 160° C.) and preferably in the range 80°-120° C. used in the production of methanol from carbon monoxide and hydrogen is disclosed....
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4617284 |
Catalyst component for polymerization of olefins and process for production thereof
A catalyst component for polymerization of olefins, which consists essentially of a particulate contact reaction product of an average particle size of 10 to 100 microns, obtained by contacting the...
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4613655 |
Catalysts for the polymerization of olefins
New catalysts for the polymerization of olefins and more particularly of ethylene and mixtures thereof with higher alpha-olefins and/or diolefins, are disclosed. The catalysts are prepared by...
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4612300 |
Novel catalyst for producing relatively narrow molecular weight distribution olefin polymers
Polymers of α-olefins having a relatively narrow molecular weight distribution are prepared by employing a Ziegler-Natta magnesium halide supported catalyst containing both titanium and vanadium.
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4610974 |
Intermetallic compounds of Lewis base bridged transition metal-reducing metal complexes and catalytic use thereof
Lewis base-bridged intermetallic compounds comprising the reaction product of a transition metal alkoxide with a reducing metal having a higher oxidation potential than the transition metal in the...
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4591577 |
Solid catalyst component for alpha-olefin polymerization and process for producing same
A solid catalyst component for α-olefin polymerization which, when produced, causes any troubles due to its small particle size and when used, yields a spherical polymer of a suitably less...
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4588703 |
Polyolefin polymerization process and catalyst
An olefin polymerization catalyst prepared by reacting a metal dihalide and a transition metal, then reacting that component with a precipitating agent, and then reacting the resulting solid with...
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4582816 |
Catalysts, method of preparation and polymerization processes therewith
Method for the production of milled supports useful for the preparation of mono-1-olefin polymerization catalysts is provided by comminuting Mg(O)mX 2 -m or Mn(O)mX 2 -m, and high density...
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4578373 |
Polymerization catalyst system
An olefin polymerization catalyst system comprising (I) a polymerization catalyst produced by treating an inert support material, preferably a hydrated high surface area silica support having 1.00...
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4568659 |
Preparation of a transition metal catalyst component for Ziegler catalyst systems
A transition metal catalyst component (1) for Ziegler catalyst systems is prepared by (1.1) first combining (1.1.1) an inorganic oxidic substance (I), as the carrier, with (1.1.2) a solution (II)...
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4567153 |
Polymerization catalyst comprising copulverized solid magnesium compound and solid halide of scandium
An olefin polymerization catalyst produced by copulverizing a magnesium compound and a scandium halide, such as magnesium chloride and scandium chloride which is thereafter treated with one or more...
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4556648 |
Solid catalyst component for olefin polymerization
A solid catalyst component for olefin polymerization which is produced by reacting (A) a silicon compound with (B) a compound of transition metal of Groups IVa, Va and VIa of the periodic table to...
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4551439 |
Solid catalyst component for olefin polymerization and process for producing same
A solid catalyst component for olefin polymerization having a high polymerization activity and affording a highly stereoregular polymer having a good particulate form, and a process for producing...
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4550094 |
Solid catalyst component for olefin polymerization
A solid catalyst component for olefin polymerization comprising a hydrocarbon-insoluble product (III) obtained by reacting (A) a silicon compound selected from the group consisting of (1)...
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4550093 |
Alumina-based aerogel supported transition metal catalyst useful as a Ziegler-Natta olefin polymerization catalyst and process for preparing same
A new polymerization catalyst system comprising an aluminum compound and a transition metal compound on an alumina-based aerogel support, a process for preparing the polymerization catalyst system...
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4547473 |
Process for the preparation of polymers of alpha-olefins at high temperatures
A solution process for the preparation of high molecular weight homopolymers of ethylene and copolymers of ethylene and C 3 -C 12 α-olefins is disclosed. The process involves feeding monomer, a...
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4540680 |
Intermetallic compounds of polymeric transition metal oxide alkoxides and catalytic use thereof
An intermetallic compound comprising the reaction product of a transition metal and a reducing metal of a higher oxidation potential than the transition metal obtained by the reaction of a...
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4537869 |
Tetravalent titanium treated calcined vanadium catalyst with trialkylaluminum cocatalyst
A supported vanadium catalyst is provided by impregnating a vanadium compound onto a refractory support, subjecting the resulting support to calcination and thereafter contacting with a titanium...
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4525468 |
Olefin polymerization catalyst
High activity catalysts for the polymerization of ethylene and other α-olefins are made by contacting a soluble magnesium compound of the general formula Mg(OSiR 1 R 2 R 3 ) 2 , wherein each of...
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