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7629284 |
Acidic activator supports and catalysts for olefin polymerization
This invention relates to the field of olefin polymerization catalyst compositions, and methods for the polymerization and copolymerization of olefins, typically using a supported catalyst...
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7524789 |
Process for producing modified particle, carrier or catalyst component for addition polymerization, pre-polymerized catalyst component therefor, catalyst therefor, and addition polymer
A process for producing a modified particle, a carrier or a catalyst component for addition polymerization, which comprises the steps of (1) contacting a compound (a) represented by the defined...
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7294599 |
Acidic activator-supports and catalysts for olefin polymerization
This invention relates to the field of olefin polymerization catalyst compositions, and methods for the polymerization and copolymerization of olefins, typically using a supported catalyst...
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7288611 |
Methods for preparing a rare-earth cis-1,4-polybutadiene rubber with a controlled molecular weight distribution
Disclosed herein are a method for preparing a cis-1,4-polybutadiene with a controlled molecular weight distribution, comprising polymerizing butadiene monomers using a rare-earth catalyst system...
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7176266 |
Catalyst for vinyl compound polymerization and process for producing vinyl polymer
A catalyst for polymerizing vinyl compounds or α-olefins according to the present invention includes (A) a transition metal complex, (B) a clay, clay mineral or ion-exchangeable layered compound,...
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7098164 |
Process for the polymerization of olefins
A process for the (co) polymerization of olefins of formula CH 2 ═CHR wherein R is a hydrogen atom, a methyl or an ethyl radical, carried out in the presence of a system comprising (a) solid...
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7077977 |
Bulky borate activations
A discrete polyolefin catalyst activator is disclosed. A salient feature of invention borate-based activators is that at least one of the ligands on the borate non-coordinating anion (NCA)...
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7074736 |
Hydrozirconated matrix and process for polyolefin production
A hydrozirconated matrix for the production of polyolefins is disclosed. The hydrozirconated matrix is prepared from the reaction of an organozirconium composition and an olefin based material. A...
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7022793 |
Process for the treatment of polymer compositions
A process for the preparation of heterophasic elastomeric polymer comprising the step of polymerizing ethylene, an alpha-olefin CH2═CHL, where L is an alkyl, cycloalkyl or aryl radical with...
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7019090 |
Catalytic component for the polymerization of olefins obtained by impregnation of a prepolymer with a solution of a catalytic component, prepolymer obtained from the catalytic component and polymerization process using said catalytic component
The present invention relates to a catalytic component for the polymerization of olefins combining a number of catalytic components for the polymerization of olefins and to a process for preparing...
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6972271 |
Supported catalyst systems
Disclosed are methods of producing supported organic catalyst systems which find particular use in polymerization reactions. The methods comprise generally, the steps of (a) providing an organic...
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6867160 |
High activity catalyst for high molecular weight polyolefins
By controlling the hold up times and temperatures for mixing the components of aluminum, titanium and magnesium based catalyst for solution polymerization it is possible to prepare a catalyst...
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6852660 |
Solid metallocene catalyst system
A solid metallocene-containing catalyst system of an organoaluminoxane, at least one metallocene having at least one olefinically unsaturated substituent and a polyolefin is disclosed. The...
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6838534 |
Catalytic system and process for the preparation of elastomers by means of this system
The present invention provides a catalytic system that can be used to prepare by polymerization diene elastomers comprising polyisoprenes and polybutadienes. The invention also provides a process...
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6780948 |
Synthesis of polyisoprene with neodymium catalyst
The neodymium catalyst system prepared by the technique of this invention can be used in the polymerization of isoprene monomer into polyisoprene rubber that is clear (transparent) and of high...
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6746981 |
Particulate group 4 metallocene-aluminoxane catalyst compositions devoid of preformed support, and their preparation and their use
Described are solid olefin polymerization catalysts that have, inter alia, very high productivities (at least 18,000 grams of polyethylene per gram of catalyst in one hour) as shown by a standard...
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6743873 |
Olefin polymerization catalyst composition and preparation thereof
A catalyst composition useful for catalyzing the polymerization of olefinic monomers is disclosed, along with a polymerization method using those catalyst compositions to prepare a variety of...
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6677265 |
Process of producing self-supported catalysts
The process features concurrent feeds into the liquid phase of a prepolymerization reaction mixture. These feeds are: a) separate continuous or substantially continuous feeds of (i) a...
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6605563 |
Catalyst system and its use in olefin polymerization
A polymerization catalyst system and a method for preparing the catalyst system is disclosed. The catalyst system includes a bulky ligand metallocene catalyst compound, preferably containing a...
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6551956 |
Catalytic component for the polymerization of olefins obtained by impregnation of a prepolymer with a solution of a catalytic component, and the prepolymer obtained from the catalytic component
The present invention relates to a catalytic composition for the polymerization of olefins combining a number of catalytic components for the polymerization of olefins and to a process for...
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6551955 |
Particulate group 4 metallocene-aluminoxane catalyst compositions devoid of preformed support, and their preparation and their use
Described are solid olefin polymerization catalysts that have, inter alia, very high productivities as shown by a standard test procedure for measuring this property or characteristic, and...
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6541411 |
Titanium/zirconium catalysts and their use to prepare esters or polyesters
The invention relates to novel titanium/zirconium catalysts, and to a process for the preparation of these titanium/zirconium catalysts. The process comprises reacting orthoesters or condensed...
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6534609 |
Method for making and using a metallocene catalyst system
Methods are disclosed for preparing a highly active solid metallocene-containing catalyst system and its use in the polymerization of olefins. The catalyst system is prepared by creating a catalyst...
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6518214 |
Synthesis of functionalized lithium initiator
This invention discloses a process for making dilithium initiators in high purity. This process can be conducted in the absence of amines which is desirable since amines can act as modifiers for...
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6482967 |
Metallocenes, polymerization catalyst systems, their preparation, and use
Metallocenes having a 9-fluorenyl group and another cyclic dienyl group connected by a single carbon having a terminally unsaturated hydrocarbyl substituent wherein the 9-fluorenyl group has a...
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6482764 |
Method for producing a supported catalyst for ethylene polymerization and ethylene/α-olefin copolymerization
A method for producing a supported catalyst useful in polymerization of ethylene and copolymerization of ethylene and α-olefin is disclosed. The method includes treating the magnesium-containing...
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6458904 |
Catalyst for the (co)polymerization of alk-1-enes
A catalyst composition suitable for the (co)polymerization of alk-1-enes is obtainable by mixing a metallocene complex with a C 3 -C 20 -alk-1-ene in an inert solvent, reacting the resulting...
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6455649 |
Catalyst for producing living olefin polymer and process for producing the polymer
A catalyst comprising an organoaluminum compound and a vanadium chelate compound having the lability to cause olefins to undergo living coordination polymerization is contacted with a terminal...
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6426314 |
Hydrogen scavengers
There has been invented a codeposition process for fabricating hydrogen scavengers. First, a π-bonded allylic organometallic complex is prepared by reacting an allylic transition metal halide with...
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6413901 |
Highly active, supported ziegler-natta catalyst systems for olefin polymerization, methods of making and using the same
A catalyst composition for alpha olefin polymerization is provided. The catalyst composition is prepared by a process including treating PVC containing particles with an organomagnesium compound in...
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6403739 |
Supported catalytic system for the production of ethylene propylene copolymers
Catalytic component for the polymerization of ethylene with propylene prepared by: a) impregnation of an inert support with a solution of a compound of Vanadium having an oxidation state of...
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6383969 |
Process for the preparation of a catalytic composition for the polymerization of alpha-olefins, catalytic composition obtained and polymerization process using such a catalytic composition
Disclosed is for the preparation of a catalytic composition for the polymerization of alpha-olefins. The catalyst comprises a compound of a transition metal (i) of Groups 4 to 6 of the Periodic...
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6350714 |
Method for preparing a catalyst and catalysts prepared accordingly
The present invention relates to a process for preparing a catalyst by activating a catalytic composition which comprises a) at least one metal of group IB or IIB or a compound thereof, b) where...
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6335405 |
Catalysts for olefin polymer production and process for producing olefin polymer
Catalysts for olefin polymerization comprising (a) a compound of a transition metal of Groups 8 to 10 of the Periodic Table, (b) clay, a clay mineral or an ion-exchanging layered compound, (c) a...
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6291382 |
Metallocenes, polymerization catalyst systems, their preparation, and use
Metallocenes having a 9-fluorenyl group and another cyclic dienyl group connected by a single carbon having a terminally unsaturated hydrocarbyl substituent wherein the 9-fluorenyl group has a...
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6255247 |
Optimum external co-catalyst electron donor molar ratio in propylene polymerization
This invention is for a process for the polymerization of propylene to a minimum level of xylene solubles by use of the molar ratio of co-catalyst to external electron donor (selectivity control...
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6239060 |
Supported metallocene catalyst system and method for polymerizing olefins
The present invention provides a new type of supported metallocene catalyst system. In one aspect of the invention, an inorganic oxide support, such as silica, is impregnated with a Group XIII...
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6235854 |
Solid titanium catalyst component and its use in olefin polymerization catalyst
The invention provides a process for preparing a solid titanium catalyst component for use in the preparation of an olefin polymerization catalyst, which comprises: (1) a step wherein a...
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6228791 |
Solid catalyst component and catalyst for olefin polymerization
The present invention is a solid catalyst component for polymerization of olefins prepared by contacting a magnesium compound, a tetravalent halogen-containing titanium compound, a diester of an...
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6218330 |
Process for preparing and using a supported metallocene-alumoxane catalyst
A process for the preparation of supported metallocene-alumoxane catalysts comprising the steps of: a) reacting a metallocene with an alumoxane at a temperature comprised between 15 and 50° C.,...
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6184170 |
Metallocene catalyst systems
This invention relates generally to metallocene catalyst systems and to methods for their production and use. Specifically, this invention relates to a method for preparing metallocene catalyst...
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6136743 |
Olefin polymerization catalyst, olefins polymerization methods, and olefin polymer compositions, and heat molded products
The invention provides catalysts which have a high polymerization activity, enable the obtaining of olefin polymers of wide molecular weight distribution, and which comprise (a)(a-1) a metallocene...
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6124231 |
Supported catalyst system, processes for its preparation, and its use for the polymerization of olefins
The present invention relates to a supported composition, to processes for its preparation and to its use for polymerizing olefins. The supported catalyst composition comprises at least one...
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6124229 |
Process for the preparation of metallocene catalyst systems on inert support material using gas phase reactor
Disclosed is a process for preparing a supported metallocene catalyst by introducing, in a first stage, a gas stream comprising an organoaluminum compound, an inert support material and water, into...
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6117957 |
Process for polymerization of olefins with silicon bridged metallocene catalyst systems
A process for polymerization of olefins having increased molecular weight and melting point uses a catalyst formed by combining a chiral, stereorigid metallocene compound with an organoaluminum...
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6114276 |
Catalyst system for olefin polymerization and its use
A heterogeneous catalyst system comprising a novel titanium catalyst component, the product of a sequential reaction of titanium halide with carbodiimide compound and an organometallic aluminum...
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6087291 |
Polymerization catalyst systems
This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst system of the invention provides for a metallocene...
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6077804 |
Olefin polymerization catalyst and process for preparing polyolefins
According to the present invention, there are provided a catalyst and a process for the preparation of polyolefins having a relatively wide molecular weight distribution, good particle properties,...
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6071846 |
Olefin polymerization catalyst and a polyolefin production method
An olefin polymerization catalyst comprising (A) a solid titanium catalyst component containing a magnesium atom, titanium atom, halogen atom and electron donor, in which divalent titanium atom...
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6060416 |
Prepolymerized solid catalyst, process for preparing the same, and process for heterogeneous polymerization of olefins
A high-performance prepolymerized solid catalyst is prepared by polymerizing an olefin onto an olefin polymerization catalyst in a heterogeneous system under irradiation with an elastic wave,...
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