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4975258 |
Novel crystalline (metallo) silicates and germanates
A crystalline material having, in the dehydrated form, the empirical formula: m(m 2/a O):X z O xz /2 : y YO 2 (I) in which m is 0.5 to 1.5; M is a cation of valency a; X is a metal of...
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4973461 |
Crystalline zeolite composition
A synthetic crystalline zeolite is provided characterized by having a composition, in terms of mole ratios of oxides, in the range: 0.9 to 1.1 M 2 /n O:Al 2 O 3 :2.5 to 5.1 SiO 2 :xH 2 O...
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4963337 |
Zeolite SSZ-33
A crystalline zeolite SSZ-33 is prepared using a quaternary ion as a template.
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4960578 |
Zeolite ECR-10
The present invention relates to a gallo-aluminosilicate zeolite designated as ECR-10 which contains cesium. It also relates to a process for preparation of the zeolite. It may be employed in...
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4954325 |
Composition of synthetic porous crystalline material, its synthesis and use
This invention relates to a new synthetic porous crystalline material, a method for its preparation and use thereof in catalytic conversion of organic compounds. The new crystalline material...
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4902844 |
New zeolite SSZ-23 and xylene isomerization therewith
A crystalline zeolite SSZ-23 is prepared using an adamantane quaternary ammonium ion as a template.
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4892721 |
Crystalline zeolite materials constituting maz-morite intermediates
Disclosed are unique orthorhombic porous tectosilicates intermediate between mordenite (MOR), mazzite (MAZ), and "Omega". Such materials are characterized by an `a` axis value of 7.3Å, a `b` axis...
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4879103 |
Composition and process for preparing ECR-30
A zeolite characterized by having an x-ray diffraction pattern as shown in Table 1, a silica to alumina mole ratio of at least six, and containing triethyl methyl ammonium, wherein said organic...
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4873067 |
Zeolite ZSM-57
This invention relates to a synthetic porous zeolite, identified as ZSM-57, a method for its preparation. This crystalline material may have a ratio of XO 2 :Y 2 O 3 of at least 4, wherein X...
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4861570 |
Novel silicate
A novel crystalline silicate has been prepared under hydrothermal conditions using as diquaternary ammonium salts derived by reaction of diazabicyclo [2.2.2] octane with α,ω-dibromoalkanes.
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4859442 |
Zeolite SSZ-23
A crystalline zeolite SSZ-23 is prepared using an adamantane quaternary ammonium ion as a template.
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4857288 |
Zeolite LZ-135 and process for preparing same
Novel crystalline aluminosilicate composition denominated LZ-135 and having uniform pore diameters of approximately 4.3 Angstroms is prepared hydrothermally from a reaction mixture containing as...
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4855270 |
Boronaaronate molecular sieve
A new crystalline borosilicate molecular sieve, boronaaronate, having a composition in terms of mole ratios of oxides: 0.9±0.2M 2 /n O:B 2 O 3 :ySiO 2 :zH 2 O wherein M is a cation of...
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4842836 |
Zeolite LZ-133
A novel crystalline aluminosilicate composition denominated "zeolite LZ-133" or simply "LZ-133" and having uniform pore dimensions of approximately 4.3 Angstroms is prepared hydrothermally from a...
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4840780 |
ZSM-51, method of preparing same and catalytic conversion therewith
A novel crystalline zeolite identified as zeolite ZSM-51 and its method of preparation is disclosed. The use of the material as a catalyst is also disclosed.
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4836996 |
Method of making zeolite Eu-2
Zeolite EU-2 having a molar composition expressed by the formula: 0.5 to 1.5 R 2 O: Y 2 O 3 : at least 70 XO 2 : 0 to 100 H 2 O wherein R is a monovalent cation or 1/n of a cation of valency...
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4837000 |
Crystalline silicates and process for the production thereof
Crystalline silicates and processes for the production thereof are described. These crystalline silicates are of new crystalline structure, which, as determined after calcination in the air at...
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4831202 |
Process for oligomerizing light olefins or their mixtures
A process is disclosed for oligomerizing light olefins or their mixtures, which consists in reacting said olefins, possibly diluted with an inert gas, by means of synthetic zeolites containing...
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4828813 |
Siliceous metal-containing crystalline compositions
A novel siliceous crystalline composition of matter further comprising one or more metals is prepared by admixing a basic silica salt and a dissolved metal salt in the presence of a quaternary...
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4820502 |
Synthetic crystalline silicate
This invention relates to a synthetic crystalline bikitaite-type material, a method for its preparation and use thereof in catalytic conversion of organic compounds.
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4781906 |
Crystalline silicas
A novel crystalline silica composition having a silica to alumina atomic ratio not lower than 80 and having a certain specific X-ray diffraction pattern after calcination in air for at least 3...
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4743437 |
Zeolite Nu-13 and process for its preparation using piperazine compounds
A synthetic zeolite material, designated zeolite Nu-13, is a member of the ZSM-12 family of zeolites and is prepared from an aqueous reaction mixture containing the oxide XO 2 , the oxide Y 2 O 3 ...
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4741891 |
Synthesis of zeolite EU-2
Zeolite EU-2 having a molar composition expressed by the formula: 0.5 to 1.5 R 2 O:Y 2 O 3 : at least 70 XO 2 :0 to 100 H 2 O wherein R is a monovalent cation or 1/n of a cation of valency...
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4732747 |
Magnesium silicate compositions and process for making
Novel crystalline porous magnesium silicates having catalytic activity or other useful properties and processes for preparing said silicates.
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4721607 |
Process for the production of boronaaronate molecular sieve using ethylenediamine and quinoline or isoquinoline
A new crystalline borosilicate molecular sieve, boronaaronate, having a composition in terms of mole ratios of oxides: 0.9±0.2M 2 /n O:B 2 O 3 :ySiO 2 :zH 2 O wherein M is a cation of...
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4717560 |
Crystalline zeolite composition (ECR-5) having a cancrinite-like structure and process for its preparation
A crystalline zeolite may be prepared which has a composition, in terms of mole ratios of oxides, in the range: 1.0 to 1.3 Na 2 O:Al 2 O 3 :2.1 to 8.0 SiO 2 and having a cancrinite-like...
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4708857 |
Process for preparing a crystalline iron-borosilicate
A crystalline ironborosilicate comprises a molecular sieve material having the following composition in terms of mole ratios of oxides 1.0±0.3 M n /2 O; (a Fe 2 O 3 :b B 2 O 3 ):y SiO 2 .z H...
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4705674 |
Synthesis of zeolite EU-13 from a reaction mixture containing tetramethylammonium compound
A new zeolite material designated EU-13 has a molar composition expressed by the formula: 0.8 to 3.0 R 2 O: Y 2 O 3 : at least 10 XO 2 : 0 to 2000 H 2 wherein R is a monovalent cation or...
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4705675 |
Synthesis of molecular sieving metallosilicates using silica-transition metal oxide sols
A method for preparing a molecular sieving metallosilicate is disclosed which comprises (A) providing an aqueous dispersion of colloidal particles comprising contiguous mixtures of silica and...
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4701315 |
Zeolite L and process for its preparation
A zeolite related to zeolite L and having a characteristic cylindrical morphology may be prepared from a crystallization gel comprising (in mole ratios of oxides): K 2 O/SiO 2 --0.22-0.36 H...
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4698217 |
Crystalline silicate ZSM-58 and process for its preparation using a methyltropinium cation
This invention relates to a new synthetic porous crystalline material, a method for its preparation and use thereof in catalytic conversion of organic compounds. The new crystalline material...
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4695440 |
Crystalline aluminosilicate ISI-6
A crystalline aluminosilicate, ISI-6, having a composition represented by the general formula (I) after being calcined in air at 550° C., p M 2 /n O.Al 2 O 3 .q SiO 2 . . . (I) wherein M...
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4681747 |
Process for the preparation of metallosilicates of tetravalent lanthanide and actinide series metals using heterpoly metallates
A molecular sieving metallosilicate is disclosed which comprises a complex represented in terms of mole ratios of oxides by the formula: ##STR1## wherein A is an ammonium, alkyl ammonium, alkyl...
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4670617 |
Propylation of toluene with a high surface area, zinc-modified, crystalline silica molecular sieve
Described are catalyst compositions comprising a high surface area, zinc-modified, crystalline silica molecular sieve, essentially free of aluminum, which has been incorporated into an inorganic...
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4666692 |
Silica-based synthetic material containing titanium in the crystal lattice and process for its preparation
The invention provides a silica-based crystalline material that incorporates titanium into the crystal lattice. A process for preparing this material is also disclosed which is based on the...
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4664775 |
Method for manufacturing low pour point petroleum product with zeolite TSZ
This invention relates to a method for catalytically manufacturing a low pour point petroleum product from distillates of crude oil, and more particularly to a method for economically manufacturing...
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4663140 |
Process for the preparation of crystalline aluminum silicate compounds using pyridine and a quaternary ammonium compound
A process of manufacture of a crystalline aluminum silicate is disclosed wherein the aqueous forming solution has augmented thereto both a pyridine compound and a quaternary ammonium hydroxide. The...
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4661332 |
Zeolite (ECR-18) isostructural with paulingite and a method for its preparation
This invention relates to a synthetic zeolite, designated as ECR-18, having a structure similar to the mineral paulingite and a process for preparation of the zeolite.
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4657748 |
Crystalline zeolite (ECR-1) and process for preparing it
A synthetic crystalline zeolite is provided characterized by having a composition, in terms of mole ratios of oxides, in the range: 0.1 to 0.02 R 2 O:0.90 to 0.98 Na 2 O:Al 2 O 3 :5 to 20 SiO...
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4656016 |
Silica-based synthetic materials containing boron in the crystal lattice and processes for their preparation
The invention is concerned with particular crystalline silica materials that contain boron in the crystal lattice. These materials are useful as catalysts for many reactions.
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4645655 |
Process for the preparation of zeolite Nu-27 using tetramethylmediamine
A crystalline zeolitic material, designated Nu-27, has a composition (in terms of mole ratios of oxides) expressed by the formula: 0 to 9 M 2 O:aY 2 O 3 :100 XO 2 :0 to 35 H 2 O, wherein M...
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4637923 |
Synthetic crystalline silicate
This invention relates to a new synthetic porous crystalline material, a method for its preparation and use thereof in catalytic conversion of organic compounds. The new crystalline material...
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4634686 |
Yttrium silicate molecular sieves
A yttrium-silicate molecular sieve is disclosed which comprises a complex represented in terms of mole ratios of oxides as follows: aA 2 O:Y 2 O 3 :bSiO 2 :cH 2 O wherein A is an alkali...
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4623526 |
Process for the preparation of a crystalline titanoborosilicate
A new crystalline titanoborosilicate comprises a molecular sieve material having the following composition in terms of mole ratios of oxide: 0.9±0.2M 2 /n O: aTiO 2 :bB 2 O 3 : ySiO 2 .zH 2 ...
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4623529 |
Method of making a zeolite of the clinoptilolite type by seeding
The present invention is directed to the preparation of a synthetic crystalline zeolite of the clinoptilolite type wherein a solid amorphous silica, an alumina source, sodium hydroxide, a seed...
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4619820 |
Synthesis of ZSM-23 zeolite and the product produced
An improved method of synthesizing highly siliceous ZSM-23 zeolitic material is disclosed and claimed. The method comprises preparing a reaction mixture which comprises sources of an alkali metal,...
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4610855 |
Synthesis of zeolite ZSM-14
A process for preparing ZSM-14 zeolite, and a product thereof, is disclosed. The process uses an organic directing agent of the formula R"--O--R'--O - --A m + where A is a cation having a...
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4610854 |
Zeolite SSZ-15 and process for preparing the same
A crystalline zeolite, SSZ-15, is prepared from cyclopentyl trimethylammonium and cyclohexyl trimethylammonium cations.
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4582693 |
Synthesis of silica molecular sieves using synthesis directing organic dyes
A method is disclosed for making a silica molecular sieve comprising: (A) providing a mixture comprising: water; an oxide, hydroxide or alkoxide of silicon; a mineralizing agent; and a synthesis...
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4581211 |
Zeolite EU-12
A new zeolite material designated EU-12 has a molar composition expressed by the formula: 0.5 to 2.0 R 2 O: Y 2 O 3 : at least 5 XO 2 : 0 to 1000 H 2 O wherein R is a monovalent cation or 1/n...
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