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7119245 |
Synthesis of an un-supported, high-flow ZSM-22 zeolite membrane
Novel methods for synthesizing wholly un-supported, high-flow catalytic membranes consisting of 100% crystalline ZSM-22 crystals with no binder phase, having sufficient porosity to allow high...
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6469226 |
Delaminated microporous solid
The invention concerns a microporous oxide material ITQ6, with a characteristic X-ray diffraction pattern, and surface areas for which microporous surface area may be of at least 20 m 2 /g the...
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6346140 |
Porous solid for gas adsorption separation and gas adsorption separation process employing it
A gas adsorption separation process characterized by adsorption separation of components in a gas by contacting the gas with a porous solid which is a porous solid having an X-ray diffraction...
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5958367 |
Methods for preparing porous metal oxides
The present invention relates to a composition and a method for producing hexagonally-packed mesoporous metal oxides wherein the metal oxide is selected from transition metals and lanthanide...
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5885546 |
Process for the preparation of titanium silicates
A process for the preparation of crystalline, microporous titanium silicates having the chemical formula: x TiO 2 : (1-x) SiO 2 wherein x is greater than 0.04 and less than or equal to 0.075....
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5830429 |
Metal silicate compositions and catalysts
A high silica zeolite (UTD-1) using bis(pentamethyl-cyclopentadienyl)cobalt(III) hydroxide, Cp* 2 CoOH is disclosed. UTD-1 is a large pore molecular sieve having one dimensional channels running...
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5800799 |
Porous inorganic oxide materials prepared by non-ionic surfactant and fluoride ion
A method for the preparation of new quasi-crystalline, porous inorganic oxide compositions formed in the presence of fluoride ion possessing a disordered assembly of worm-like channels. The method...
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5783167 |
Structure material of the zeolite type with ultralarge pores and a lattice comprised of silicone and titanium oxides: its synthesis and utilization for the selective oxidation of organic products
The invention relates to a material comprised of silicotitanates having a crystalline structure similar to MCM-41 zeolites, said material being characterized in that it contains in its lattice...
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5707601 |
Process for preparing zeolites having MTT crystal structure using small, neutral amines
The present invention relates to a process for preparing zeolites having the MTT crystal structure, such as zeolites SSZ-32 and ZSM-23, using small, neutral amines capable of forming the zeolite,...
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5707600 |
Process for preparing medium pore size zeolites using neutral amines
The present invention relates to a process for preparing medium pore size zeolites using small, neutral amines capable of forming the zeolite, the amine containing (a) only carbon, nitrogen and...
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5675050 |
Crystalline microporous solids consisting of aluminophosphates substituted by a metal and optionally by silicon and belonging to the FAU structure type, their synthesis and applications
Crystalline microporous solids of the aluminophosphate type consisting of MeAPO-FAU and MeAPSO-FAU with Me denoting a metal which can adopt tetrahedral coordination in an oxide, for example Co and...
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5670131 |
Synthetic porous crystalline MCM-61, its synthesis and use
This invention relates to a new synthetic porous crystalline material, designated MCM-61, a method for its preparation and use thereof as a sorbent or in catalytic conversion of organic or...
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5648058 |
Synthesis of novel molecular sieves using a metal complex as a template
The synthesis and characterization of novel molecular sieves containing bis(pentamethylcyclopentadienyl) cobalt(III) ion are described. Several types of molecular sieves were prepared using the...
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5603914 |
Synthesis of novel molecular sieves using a metal complex as a template
The synthesis and characterization of novel molecular sieves containing bis(pentamethylcyclopentadienyl) cobalt(III) ion are described. Several types of molecular sieves were prepared using the...
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5593655 |
Process for preparing a large molecular sieve
The present invention relates to a process for the preparation of a large-pore molecular sieve, comprising crystallizing the molecular sieve from a starting mixture at a pH in the range of from 3...
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5549881 |
Process for preparing a seeded high-silica zeolite having the faujasite topology
A process to make a seed high silica zeolite having a faujasite structure and a silica to alumina ratio greater than 6, and containing tetrapropyl ammonium and/or tetrabutyl ammonium trapped within...
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5489424 |
Synthesis of novel molecular sieves using a metal complex as a template
The synthesis and characterization of novel molecular sieves containing bis(pentamethylcyclopentadienyl) cobalt(III) ion are described. Several types of molecular sieves were prepared using the...
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5350722 |
MTW-type zeolite and its preparation process
The invention relates to a synthetic crystalline zeolite of the MTW type, characterized by: a) the following approximate general formula: M 2 /n O, Al 2 O 3 , xSiO 2 in which M...
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5346685 |
Synthetic porous crystalline MCM-51, its synthesis and use
This invention relates to a new synthetic porous crystalline titanium phosphate material, a method for its preparation and use thereof in catalytic conversion of organic compounds. The new...
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5300277 |
Synthesis of mesoporous crystalline material
This invention relates to an improvement in the method for synthesis of a new synthetic composition of porous crystalline material. The new crystalline material exhibits a large sorption capacity...
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5264203 |
Synthetic mesoporous crystalline materials
This invention relates to a new synthetic composition of ultra-large pore crystalline material, e.g., [metallo]silicoaluminophosphate, having a composition, expressed on an anhydrous basis as...
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5227151 |
Method of preparing silicoaluminophosphate compositions using a reagent containing both quaternary ammonium and silicon reactive sites in the same molecule
A method of preparing silicoaluminophosphate (SAPO) compositions from a forming mixture which comprises sources of oxides of silicon, aluminum and phosphorus and quaternary ammonium-functionalized...
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5116590 |
Crystalline zeolite ECR-35 and a method for producing same
A synthetic large pore crystalline metalsilicate zeolite composition, designated as ECR-35, having the formula, expressed in term of mole ratio of oxides: ##STR1## where T is an organic cation...
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5098686 |
Synthesis of zeolites of faujasite structure
A process is provided for the preparation of zeolites belonging to the faujasite structural class and exhibiting a Si:Al ratio higher than 1 in which a reaction mixture is first produced which has...
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5063038 |
Zeolite synthesis using an alcohol or like molecule
There is provided a method for preparing a zeolite other than ZSM-5 from a reaction mixture comprising a mixed organic directing agent which is a combination of (a) an organic nitrogen containing...
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5057296 |
Method for synthesizing mesoporous crystalline material
This invention relates to an improved method for synthesizing a new synthetic composition of ultra-large pore crystalline material which can be used as a sorbent or catalyst component for...
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5053211 |
Manufacture of AMS-18 crystalline borosilicate molecular sieve
AMS-1B crystalline borosilicate molecular sieve is prepared by reacting under crystallization conditions, in substantial absence of a metal or ammonium hydroxide, an aqueous mixture containing an...
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4975258 |
Novel crystalline (metallo) silicates and germanates
A crystalline material having, in the dehydrated form, the empirical formula: m(m 2/a O):X z O xz /2 : y YO 2 (I) in which m is 0.5 to 1.5; M is a cation of valency a; X is a metal of...
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4857288 |
Zeolite LZ-135 and process for preparing same
Novel crystalline aluminosilicate composition denominated LZ-135 and having uniform pore diameters of approximately 4.3 Angstroms is prepared hydrothermally from a reaction mixture containing as...
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4721607 |
Process for the production of boronaaronate molecular sieve using ethylenediamine and quinoline or isoquinoline
A new crystalline borosilicate molecular sieve, boronaaronate, having a composition in terms of mole ratios of oxides: 0.9±0.2M 2 /n O:B 2 O 3 :ySiO 2 :zH 2 O wherein M is a cation of...
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4680170 |
Synthesis of zeolitic materials using ion-exchange resin
Crystalline zeolites and zeolitic materials are prepared by crystallization from an aqueous mixture comprising a source of silica, optionally a source of alumina, and an ion-exchange resin...
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4663140 |
Process for the preparation of crystalline aluminum silicate compounds using pyridine and a quaternary ammonium compound
A process of manufacture of a crystalline aluminum silicate is disclosed wherein the aqueous forming solution has augmented thereto both a pyridine compound and a quaternary ammonium hydroxide. The...
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4627968 |
Synthesis of crystalline aluminosilicate with alkylurea or alkylthiourea
In the synthesis of a crystalline aluminosilicate by heating an aqueous mixture containing a silica source, an alumina source and an alkali metal source, at least one compound selected from lower...
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4613488 |
Process for the preparation of crystalline aluminum silicate compounds using pyridine and a quaternary ammonium compound
A process of manufacture of a crystalline aluminum silicate is disclosed wherein the aqueous forming solution has augmented thereto both a pyridine compound and a quaternary ammonium hydroxide. The...
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4578259 |
Process for preparing a crystalline aluminosilicate
Crystalline aluminosilicates, a process for the production thereof and uses therefor are disclosed. The crystalline aluminosilicates are of new crystalline structure, which, as determined after...
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4560542 |
Method for the preparation of zeolites using a low water low alkali metal content gel
An improved method is provided for the preparation of organic cation-containing zeolites and their thermal decomposition products, by adding the organic templating agent to a preformed...
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4526879 |
Synthesis of zeolite ZSM-5
As synthesized by conventional technique, zeolite ZSM-5 is crystallized in the presence of substantial amount of tetraalkylammonium cations, the alkyl groups of which contain 2 to 5 carbon atoms,...
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4522800 |
Process for the production of a crystalline aluminosilicate zeolite
A method for making crystalline aluminosilicate ZSM-34 zeolites, useful as catalysts for making C 2 -C 4 -olefins from methanol, from a reaction mixture containing silicon, aluminum, sodium,...
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4495166 |
Synthesis of ZSM-5 utilizing a mixture of quaternary ammonium ions and amines
A novel process for the preparation of ZSM-5 and ZSM-11 utilizing a mixture of both quaternary ammonium ions and amines in the forming solution is disclosed in order to enhance the rate of...
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4481173 |
Manufacture of low sodium zeolite
The alkali metal content of zeolite ZSM-11 in its as-synthesized form is reduced by crystallizing the zeolite from a solution containing a source of benzyltrimethyl ammonium ions.
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4474741 |
Preparation of a crystalline aluminosilicate (zeolite)
A process for the preparation of a crystalline aluminosilicate of the pentasil type by hydrothermal crystallization of SiO 2 and Al(OH) 3 in the presence of an alkali metal salt at from 80° to...
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4420467 |
Zeolite Nu-5
A synthetic zeolite material, designated zeolite Nu-5, having a molar composition expressed by the formula; 0.5 to 1.5 R 2 O: Y 2 O 3 : at least 10 XO 2 : 0 to 2000 H 2 O wherein R is a...
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4407728 |
Method for producing crystalline aluminosilicates and their use as catalysts and catalyst supports
The invention relates to a method for preparing a crystalline aluminosilicate having a high silica to alumina molar ratio and an X-ray diffraction pattern substantially the same as that of ZSM-5...
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4404175 |
Preparation of zeolites
A process for the preparation of zeolites of the ZSM-5 structural type from a mixture of SiO 2 and Al(OH) 3 by hydrothermal crystallization in an aqueous amine solution, in the absence of alkali,...
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4375458 |
Synthesis of large crystallite zeolites
The invention provides a method of making large crystallite zeolites by a method comprising forming the zeolite in a medium containing a combination of two different alkylammonium cations or a...
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4331643 |
Use of diazobicyclooctane (DABCO) as a template in zeolite synthesis
A process for preparing a ZSM-4 type crystalline zeolite material wherein 1,4-diazobicyclo (2.2.2) octane (DABCO), triethylenediamine (TED) is used as the source of an organic cation.
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4259306 |
Synthesis of ZSM-39
A new and useful method for preparing synthetic zeolite ZSM-39 is provided. This new method comprises synthesizing zeolite ZSM-39 in the presence of pyrrolidine as a template rather than the...
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4209498 |
Silica-containing material FU-1
A silica-containing material related to zeolites and referred to hereinafter as FU-1 has the composition 0.6 to 1.4 R 2 O.Al 2 O 3 .over 5 SiO 2 .O to 40 H 2 O, (where R is a monovalent cation...
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4205053 |
Manufacture of nitrogenous zeolites
A process for manufacturing synthetic nitrogenous zeolites such as ZSM-5 in which the shape or some other feature of the microscopic crystals is controlled by including in the forming solution an...
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4199556 |
Method for producing zeolites
As synthesized by previous methods, ZSM-5 or ZSM-11 zeolites are crystallized in the presence of substantial amounts of a nitrogen-containing compound. When synthesized in this way, they contain an...
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