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7431831 |
Integrated in-line pretreatment and heavy oil upgrading process
A new residuum full hydroconversion slurry reactor system has been developed that allows the catalyst, unconverted oil, products and hydrogen to circulate in a continuous mixture throughout an...
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6258259 |
Iron sulfide and process for producing the same
The invention provides an iron sulfide characterized in that it comprises FeS 2 , Fe 1 -X S, Fe 3 O 4 and FeSO 4 , and that the secondary particles thereof, have a 50% volume-cumulative particle...
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6190542 |
Catalytic multi-stage process for hydroconversion and refining hydrocarbon feeds
A multi-stage catalytic hydrogenation and hydroconversion process for heavy hydrocarbon feed materials such as coal, heavy petroleum fractions, and plastic waste materials. In the process, the...
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5783065 |
Method for coal liquefaction
A process is disclosed for coal liquefaction in which minute particles of coal in intimate contact with a hydrogenation catalyst and hydrogen are reacted for a very short time at a temperature in...
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5454934 |
Coal liquefaction using atomically dispersed metals
A method for converting solid carbonaceous materials to liquid products. The solid carbonaceous material is first treated with a aqueous composition of a metal carbonate or bicarbonate. This...
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5389230 |
Catalytic hydroconversion process
This invention relates to a catalytic process for converting a carbonaceous material to a liquid product. More specifically, this invention relates to a process for hydroconverting coal in a...
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5338441 |
Liquefaction process
The present invention relates to a catalytic process for converting a solid carbonaceous material, such as coal, to a liquid product in the presence of hydrogen. More particularly, this invention...
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5200063 |
Coal hydroconversion process comprising solvent enhanced pretreatment with carbon monoxide
This invention is directed to a staged process for producing liquids from coal or similar carbonaceous feeds combining a pretreatment stage and a liquefaction stage. In the process, the feed is...
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5130013 |
Process for producing a liquefied coal oil and a catalyst for the process
A process for producing a liquefied coal oil by a two step hydrogenation reaction of coal, which comprises subjecting coal to a first hydrogenation and subjecting at least a part of the reaction...
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5120429 |
Co-processing of carbonaceous solids and petroleum oil
In a process for producing distillates from coal by a first stage thermal liquefaction followed by a catalytic hydrogenation, liquefaction solvent is added at points spaced over the length of the...
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5110452 |
Method of refining coal by catalyzed short residence time hydrodisproportionation to form a novel coal-derived fuel system
This invention generally relates to a catalyzed short residence time decomposition and volatilization of coal to produce liquid co-products while minimizing production of char and gas without...
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5096569 |
Catalytic hydropyrolysis of carbonaceous material with char recycle
Disclosed is a method for catalytically hydropyrolyzing carbonaceous material to produce liquid products boiling under about 550° C. with reduced amounts of methane being formed. The process...
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5071540 |
Coal hydroconversion process comprising solvent extraction and combined hydroconversion and upgrading
An improved process for the hydroconversion of coal comprising pretreating coal in an aqeuous carbon monoxide-containing environment, followed by extracting a soluble hydrocarbon material from the...
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5064527 |
Catalytic process for hydroconversion of carbonaceous materials
An improved hydroconversion process for carbonaceous materials wherein a dihydrocarbyl substituted dithiocarbamate of a metal selected from any one of Groups IV-B, V-A, VI-A, VII-B, and VIII-A of...
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5061363 |
Method for co-processing waste rubber and carbonaceous material
In a process for the co-processing of waste rubber and carbonaceous material to form a useful liquid product, the rubber and the carbonaceous material are combined and heated to the...
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5055181 |
Hydropyrolysis-gasification of carbonaceous material
Disclosed is a process for obtaining liquids and gases from carbonaceous material, such as coal. The carbonaceous material is first treated with a gasification catalyst, and optionally a...
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5055174 |
Hydrovisbreaking process for hydrocarbon containing feed streams
At least one decomposable molybdenum compound selected from the group consisting of molybdenum dithiophosphates and molybdenum dithiocarbamates is mixed with a hydrocarbon-containing feed stream....
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4923838 |
Process for preparing an iron-coal slurry catalyst for hydrocracking heavy oils
A process for the conversion of a heavy hydrocarbon oil in the presence of hydrogen and iron-coal catalyst is described in which the iron-coal catalyst is prepared by grinding coal particles and...
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4853111 |
Two-stage co-processing of coal/oil feedstocks
A process for two-stage catalytic co-processing of coal and heavy petroleum hydrocarbon liquid fractions to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the...
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4851107 |
Process for the hydrogenation of heavy and residual oils
A process for the hydrogenation of heavy oils, residual oils, waste oils, used oils, shell oils, and tar sand oils by hydrogenating a slurry of the oil at a partial hydrogen pressure of 50-300 bar,...
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4842719 |
Catalytic two-stage coal hydrogenation and hydroconversion process
A process for two-stage catalytic hydrogenation and liquefaction of coal to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal is...
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4820405 |
Method of liquefying coal
When low-quality iron ore is used as a coal liquefaction catalyst, in order to improve its catalytic activity it is subjected to one or a combination of reduction, heat-treatment, or washing with...
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4816141 |
Catalytic two-stage liquefaction of coal utilizing cascading of used ebullated-bed catalyst
A multi-stage catalytic process for hydrogenation and liquefaction of coal using ebullated-bed catalytic reactors to produce low-boiling hydrocarbon liquid products, in which used catalyst is...
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4750991 |
Method for hydrogenating a solvent-refined coal
A method for hydrogenating a solvent-refined coal, comprising: (a) hydrogenating coal in the presence of a hydrocarbon solvent and an iron catalyst; (b) obtaining a solvent-refined coal...
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4740294 |
Method for sequentially co-processing heavy hydrocarbon and carbonaceous materials
A method for sequentially co-processing heavy hydrocarbon materials and carbonaceous materials comprising first subjecting the heavy hydrocarbon material in the presence of a disposable metal...
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4661237 |
Process for thermal cracking of carbonaceous substances which increases gasoline fraction and light oil conversions
A process for thermally cracking carbonaceous substances, such as coal, is described, comprising: rapidly heating the carbonaceous substance to 500° to 950° C. in an atmosphere consisting...
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4617106 |
Catalysts for coal liquefaction processes
Improved catalysts for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprise a combination of...
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4602991 |
Coal liquefaction process
A liquefaction process for coal or lignite is set forth. In the preferred and illustrated embodiment, coal or lignite is ground to a suitable particle size and placed in a reactor vessel. The...
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4561964 |
Catalyst for the hydroconversion of carbonaceous materials
An improved hydroconversion process for carbonaceous materials wherein a monohydrocarbyl substituted dithiocarbamate of a metal selected from Group VIII-A of the Periodic Table of Elements or a...
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4541914 |
Process for converting coal
A process for converting coal, comprising, subjecting a slurry composed essentially of coal, a hydrocarbon solvent and a hydrogenation catalyst to primary hydrogenation to liquify the coal,...
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4534848 |
Coal liquefaction with a selenium catalyst
Disclosed are a catalyst for direct liquefaction of coal, which consists of selenium, a selenium compound, or a mixture of selenium or the selenium compound with a metal oxide, and a method of...
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4515678 |
Process and catalyst for the hydrogenation of coal
Blast furnace flue dust is used as a catalyst in a process for the hydrogenation of coal. A flowable mixture of finely divided coal particles and liquid hydrocarbons is brought to high pressure and...
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4511455 |
Catalysis using hydrous metal oxide ion exchanges
In a process which is catalyzed by a catalyst comprising an active metal on a carrier, said metal being active as a catalyst for the process, an improvement is provided wherein the catalyst is a...
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4511454 |
Process for use of novel boride catalyst
Novel heterogeneous boride catalysts comprising a polyborane anion and a Group VIII metal for the treatment of carbonaceous materials. The catalyst is prepared by the steps of contacting a...
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4510039 |
Process for the liquid phase hydrogenation of coal
A process for hydrogenating coal in the liquid phase in the presence of a catalyst comprising an iron oxide obtained by decomposition of an iron compound in a flame, in particular in the flame of a...
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4502941 |
Non-aqueous hydrogenation of solid carbonaceous material
A nonaqueous process of hydrogenating and liquefying solid carbonaceous material which includes heating the material in contact with a catalyst derived from FE(CO) 9 in the presence of hydrogen.
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4435280 |
Hydrocracking of heavy hydrocarbon oils with high pitch conversion
A process is described for the hydrocracking of heavy hydrocarbon oils which permits pitch conversions of over 90%, and preferably over 95%. A slurry of a heavy hydrocarbon oil and carbonaceous...
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4428820 |
Coal liquefaction process with controlled recycle of ethyl acetate-insolubles
A process for increasing the conversion of coal to ethyl acetate-soluble products comprising: (a) heating a slurry comprising a solvent and particulate coal in a dissolution zone to produce a...
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4428818 |
Liquefaction of coal
Solvent refining of coal is conducted with a blend of coals calculated to maintain the phenols of the steady state recycle solvent within desired limits.
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4427532 |
Coking of coal with petroleum residua
A hydrotreated petroleum residuum is coked in the presence of coal to improve the yield and quality of the liquid coker products. The coal is preferably of low rank with a carbon content below 75...
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4424111 |
Regeneration of ZnC12
A method of hydrocracking using a zinc catalyst in the hydrogenation step comprising providing a hydrocarbonaceous feed of coal or tar to a hydrogenation means, removing spent zinc and catalyst...
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4422922 |
Coal liquefaction and hydroprocessing of petroleum oils
This invention comprises a process for hydroprocessing a petroleum oil containing soluble metals compounds while suppressing the accumulation of coke within the hydroprocessing zone, comprising the...
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4417972 |
Recovery of coal liquefaction catalysts
Metal constituents are recovered from the heavy bottoms produced during the liquefaction of coal and similar carbonaceous solids in the presence of a catalyst containing a metal capable of forming...
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4411767 |
Integrated process for the solvent refining of coal
A process is set forth for the integrated liquefaction of coal by the catalytic solvent refining of a feed coal in a first stage to liquid and solid products and the catalytic hydrogenation of the...
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4411766 |
Iron catalyzed coal liquefaction process
A process is described for the solvent refining of coal into a gas product, a liquid product and a normally solid dissolved product. Particulate coal and a unique co-catalyst system are suspended...
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4405437 |
Process for coal liquefaction employing a superior coal liquefaction process solvent
A process for liquefying coal utilizing an indigenously derived solvent enriched in basic nitrogen heterocyclic compounds. Particulate coal is slurried with an aromatic hydrocarbon distillate...
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4397732 |
Process for coal liquefaction employing selective coal feed
An improved coal liquefaction process is provided whereby coal conversion is improved and yields of pentane soluble liquefaction products are increased. In this process, selected feed coal is...
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4396786 |
Method for producing fuel oil from cellulosic materials
A method for producing fuel oil from cellulosic materials (especially domestic or agricultural waste) in which the material is contacted with water and treated with a reducing gas (eg hydrogen or...
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4394248 |
Coal liquefaction process
A process for liquefying coal which comprises contacting coal and solvent in the presence of a residual oil containing asphaltenes and at least one finely divided, unsupported metal sulfide and...
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4391699 |
Coal liquefaction process
Disclosed is a two-stage process for the production of liquid hydrocarbons from coal. More particularly, disclosed is a two-stage coal liquefaction process wherein subdivided coal is substantially...
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