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6296745 |
Method of operating chlor-alkali electrolytic cells
A method of operating a chlor-alkali electrolytic cell comprising a catholyte compartment containing a cathode, an anolyte compartment containing an anode, and a liquid-permeable diaphragm...
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6217733 |
Bipolar membrane and method for fabricating such bipolar membrane
A bipolar membrane, usable for electrodialysis of aqueous electrolytes, comprises two ion exchange membranes, respectively anionic and cationic, juxtaposed along a common surface, wherein, along...
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6193872 |
Process and plant for treating an aqueous waste stream containing at least one alkali metal carboxylate
The invention proposes a process and waste treatment plant for regenerating alkali metal hydroxide (3) from an alkaline aqueous waste stream (5) that contains alkali metal C3+ carboxylate...
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6123826 |
Method for removal of nickel and iron from alkali metal hydroxide streams without requiring the use of sodium borohydride
The present invention relates to a method to control of the presence of nickel and/or iron in a caustic solution using at least two magnets to remove about one third of the nickel and/or iron...
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5919348 |
Modification of the flow resistance of diaphragms
The flow resistance of a diaphragm based on a fiber material is modified by treating the diaphragm during or after preparation thereof with a dispersion comprising a fluorine-containing component...
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5888368 |
Process for manufacturing an aqueous sodium hydroxide solution
Process for manufacturing sodium hydroxide by the electrodialysis of sodium carbonate in an electrodialysis cell having three compartments, in which an aqueous sodium carbonate solution is...
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5716504 |
Cation exchange membrane for electrolysis and process for producing potassium hydroxide of high purity
A cation exchange membrane for electrolysis, which comprises at least 2 layers of fluorine-containing polymer films having sulfonic acid groups, wherein a first layer facing a cathode is made of a...
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5512143 |
Electrolysis method using polymer additive for membrane cell operation where the polymer additive is ionomeric and added to the catholyte
The operation of electrolytic cells employing ion exchange membranes is improved by addition to the catholyte of a fluorinated ionomer resin resulting in a long-term reduction in the operating...
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5482696 |
Method for the purification and/or electrolysis of an aqueous potassium chloride solution
The present invention concerns a method for the purification and/or electrolysis of an aqueous potassium chloride solution, in which the sulphate ions are removed from the aqueous potassium...
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5290410 |
Electrode and its use in chlor-alkali electrolysis
The invention relates to an electrode for electrolysis, whose front side comprises a plurality of substantially parallel channels defined by substantially parallel threads of electrically...
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5192401 |
Diaphragm for use in chlor-alkali cells
A liquid permeable diaphragm for use in an electrolytic chlor-alkali cell, the diaphragm being made of fibrous material and having particulate zirconia deposited in the interstices of the fibrous...
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5188712 |
Diaphragm for use in chlor-alkali cells
A liquid permeable diaphragm for use in an electrolytic chlor-akali cell, the diaphragm being made of fibrous material and having deposited thereon and cementitiously bonded to the anode face...
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5084149 |
Electrolytic process for producing chlorine dioxide
An electrochemical process and electrolytic cell for manufacturing chlorine-free chlorine dioxide from a dilute alkali metal chlorite solution in a single step is disclosed. The electrolytic cell...
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4919791 |
Controlled operation of high current density oxygen consuming cathode cells to prevent hydrogen formation
A process for the electrolysis of an alkali metal halide brine is operated in an electrolytic cell having an anode compartment containing at least one anode, a cathode compartment containing at...
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4909912 |
Ion exchange membrane cell and electrolytic process using thereof
An ion exchange membrane cell comprises an anode, a cathode, an anode compartment and a cathode compartment formed by partitioning by an ion exchange membrane. A gas and liquid permeable porous...
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4834847 |
Electrochemical cell for the electrolysis of an alkali metal halide and the production of a halogenated hydrocarbon
An electrochemical cell and process for the electrolysis of an aqueous solution of an alkali metal halide and the production of a halogenated hydrocarbon comprising an electrolytic cell having a...
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4832805 |
Multi-layer structure for electrode membrane-assembly and electrolysis process using same
A unitary membrane-electrode assembly includes a structure with multiple layers having different overvoltages for the desired electrochemical reaction. The layer attached to the membrane has a...
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4824534 |
Process for electrically separating the electrolyte-bearing mains from the electrolyte spaces of an electrochemical cell pile
In this process for electrically separating the electrolyte-bearing main from the electrolyte spaces of an electrochemical cell pile, the electrolyte is passed via drop sections directly from the...
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4749452 |
Multi-layer electrode membrane-assembly and electrolysis process using same
A unitary membrane-electrode assembly includes an electrode structure with multiple layers having different overvoltages for the desired electrochemical reaction. In the preferred arrangement the...
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4747917 |
Scale-free process for purifying concentrated alkali metal halide brines containing sulfate ions as an impurity
A process for reducing sulfate ion concentrations in an alkali metal halide brine to be electrolyzed in an electrolytic cell comprises feeding the alkali metal halide brines to a reaction zone...
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4670114 |
Fine, uniform particles, and precipitation or depositing of particles from a solution
The precipitation or deposition of particles from a solution in a cell (61) which an electric field is applied between an anode (65,67,68) and a cathode (66), typically an electrolysis cell for the...
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4666573 |
Synthetic diaphragm and process of use thereof
A non-asbestos, electrolyte permeable diaphragm fabricated of thermoplastic organic polymer material containing ion exchange functional groups or precursor groups thereof is disclosed. The...
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4647351 |
Process for generating chlorine and caustic soda using a membrane electrolysis cell coupled to a membrane alkaline fuel cell
A process for making chlorine gas and concentrating caustic soda comprising: (1) feeding a brine to the anolyte compartment solution and a dilute NaOH solution to the catholyte compartment of an...
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4595469 |
Electrolytic process for production of gaseous hydrogen chloride and aqueous alkali metal hydroxide
Disclosed is a process for the production of gaseous hydrogen chloride and aqueous alkali metal hydroxide from brine, utilizing an electrolytic cell containing a hydroxyl ion producing cathode and...
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4586993 |
Control of sulfates in membrane cell chlor-alkali process
Method of addition of calcium ions to salt-depleted brine prior to resaturation, wherein the concentration of sulfate impurity is controlled. The invention relates to a process for the electrolysis...
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4586992 |
Process for producing potassium hydroxide
A process for producing potassium hydroxide by electrolysis of potassium chloride in an electrolytic cell comprising an anode compartment and a cathode compartment partitioned by a cation exchange...
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4540474 |
Light level electrode setting gauge and method of use
A method of adjusting the position of objects in relation to a datum plane, the method including the step of providing a mark on the objects at a known distance from the surface of the objects that...
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4512857 |
Prevention of corrosion of electrolyte cell components
Disclosed is a method of operating an electrolytic cell having an active, catalytic cathode and an iron structure in contact with an alkaline electrolyte. The dissolution of iron into the...
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4502928 |
Method and apparatus for producing halogen
A halogen production apparatus comprising a halogen production device and a metal-halogen secondary cell which contains in its electrolyte the same halogen as is produced by the production device....
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4466869 |
Photolytic production of hydrogen
Disclosed is a photolytic device comprising a photoelectrode having a plurality of stacked, individual photoelectric or photovoltaic elements between a substrate and an electrode, a...
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4437950 |
Method of controlling aluminum electrolytic cells
Increase or decrease in a quantity of alumina presenting in a bath or a metal in an aluminum electrolytic cell is detected and a quantity of electric power supplied to the cell is increased or...
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4434041 |
Method for conditioning carboxylate/sulfonate composite membranes for producing KOH
A procedure for conditioning new composite laminated membranes in chlor-alkali cells producing KOH, said membrane being comprised of a laminated composite made from individual perfluorosulfonyl and...
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4396473 |
Cathode prepared by electro arc spray metallization, electro arc spray metallization method of preparing a cathode, and electrolysis with a cathode prepared by electro arc spray metallization
Discloses a cathode having a porous surface prepared by electro arc spray metallization of two wires of a leachable metal and a catalytic metal onto a substrate, and removal of the leachable metal....
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4394229 |
Cathode element for solid polymer electrolyte
Disclosed is a solid polymer electrolyte unit, an electrolytic cell containing the unit, and an electrolytic process utilizing the unit. The solid polymer electrolyte unit has anodic and cathodic...
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4381230 |
Operation and regeneration of permselective ion-exchange membranes in brine electrolysis cells
Methods of membrane regeneration of permselective ion-exchange membranes of a brine electrolysis cell are greatly improved when the cells are fed brine which contains little or no carbon dioxide,...
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4379035 |
Method of operating an electrolytic cell
Discloses a method of operating a chlor-alkali cell having a low hydrogen overvoltage cathode and exposed high hydrogen overvoltage metal structure within the cathode compartment, where a...
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4356068 |
Permionic membrane
Disclosed is an electrolytic cell having an anode and cathode separated by and in contact with a permionic membrane. The cathodic surface of the permionic membrane is characterized by microporous...
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4339314 |
Solid polymer electrolyte and method of electrolyzing brine
Disclosed is a solid polymer electrolyte electrolytic cell having a fluorinated carboxylic acid permionic membrane with anodic catalyst embedded in a hydrophobic film on the permionic membrane. The...
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4339313 |
Method of operating an electrolytic cell
Disclosed is a method of preparing a cathode-diaphragm assembly for an electrolytic cell, where the diaphragm is adherent, e.g., to itself and to the cathode. The cathode-diaphragm unit is prepared...
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4333804 |
Method of preventing deterioration of palladium oxide anode
The deterioration of a palladium oxide type anode caused by stopping the operation of a diaphragm type electrolytic cell in the electrolysis of an alkali metal chloride is prevented by increasing...
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4329209 |
Process using an oxidant depolarized solid polymer electrolyte chlor-alkali cell
Disclosed is the ultrasonic treatment of a solid polymer electrolyte to dislodge reaction products. Also disclosed is the use of an amide anodic surface to provide a hydrophobic surface. Disclosed...
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4323436 |
Purification of aqueous solution of potassium chloride
A purification of an aqueous solution of potassium chloride which is used for producing potassium hydroxide by an electrolysisin an electrolytic cell using a cation exchange membrane is carried out...
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4323435 |
Method of operating a solid polymer electrolyte chlor-alkali cell
Disclosed is a method of operating a solid polymer electrolyte chlor-alkali cell by imposing a pulsative current, e.g., pulsed direct current, half wave alternating current, or rectified...
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4311567 |
Treatment of permionic membrane
Disclosed is a method of electrolyzing alkali metal chloride brine in permionic membrane cell where the permionic membrane is hydrolyzed in situ. The membrane is hydrolyzed by electrodialytically...
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4311566 |
Electrolyte permeable diaphragm
Disclosed is an electrolyte permeable, non-asbestos diaphragm for chlor-alkali electrolytic cells. The diaphragm is a cohesive matrix of a non-asbestos structural component and a binder, and is...
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4297182 |
Production of alkali metal hydroxide
A gas and liquid permeable cathode is bonded on an ion-exchange membrane and the composite electrode is used in an electrolytic cell for a production of sodium hydroxide by an electrolysis of an...
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4285786 |
Apparatus and method of monitoring temperature in a multi-cell electrolyzer
An apparatus and method of monitoring temperature in a multicell electrolyzer used to produce a gaseous product from a liquid phase electrolyte by placing a single temperature sensing means in the...
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4282074 |
Electrolytic process utilizing a transition metal-graphite intercalation compound cathode
Disclosed is a method of electrolyzing an alkali metal chloride brine where the cathode is an intercalation compound of graphite and a transition metal. Also disclosed is a solid polymer...
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4274928 |
Process for electrolyzing brine in a permionic membrane electrolytic cell
Disclosed is an electrolytic cell having an anode unit, a cathode unit substantially parallel to and spaced from the anode unit with individual cathodic elements therein, and a permionic membrane...
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4272338 |
Process for the treatment of anolyte brine
A process for removing dissolved halogen gas and oxyhalide ions from an aqueous alkali metal halide solution containing them which comprises reacting said aqueous alkali metal halide solution with...
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