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7556750 |
Photochromic materials with reactive substituents
Various non-limiting embodiments of the present disclosure relate to photochromic materials comprising a reactive substituent. For example, the present disclosure contemplates photochromic...
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7122642 |
Method for producing crystal polymorphs and crystal polymorphs produced thereby
A method to prepare new or unexpected polymorphs of materials which have not been observed, or to obtain a known polymorph under different conditions than those in which it is usually made, by...
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7038068 |
Method for liquid/liquid extraction of molecular weight fractions of perfluorinated polyethers
A liquid/liquid extraction method is used for separating a perfluorinated polyether (PFPE) into two molecular-weight distributions using an alcohol or cyclic ether as one solvent and a fluorinated...
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6863782 |
Method of preparing di(ketene acetals)
Di(ketene acetals) are prepared by photoisomerizing the corresponding di(vinyl acetals).
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6759521 |
Polarization switching to control crystal form
A method to select and prepare polymorphs of materials by switching the polarization state of light employing non-photochemical laser-induced nucleation.
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6551467 |
Microwave facilitated allyllic substitution
The present invention is draw to microwave heating of a transition metal-catalysed organic reaction, in which a catalyst complex between a transition metal and an auxiliary ligand or ligands, the...
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6506285 |
Syntheses of 5,5′-diformyl-2-2′difuran and derivatives thereof
A method of synthesizing 5,5′-diformyl-2,2′-difuran and derivatives thereof, including the steps of subjecting a reaction mixture of furfural or a derivative thereof to photochemical...
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6444098 |
Process for the preparation of tocol acylates and tocopherol acylates
The present invention relates to a process for preparing tocol acylate or tocopherol acylate having the following steps: a) combining tocol or tocopherol with an acylating agent to form a reaction...
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6426406 |
Method for using laser light to control crystal form
A method to prepare new or unexpected polymorphs of materials which have not been observed, or to obtain a known polymorph under different conditions than those in which it is usually made, by...
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6384239 |
Method for producing monohalogenated 2-oxo-1,3-dioxolanes
The invention relates to a process for the preparation of monohalogenated 2-oxo-1,3-dioxolanes of the general formula C 3 H 3 XO 3 (I) in which X is Cl or Br, characterized in that the...
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6180805 |
Photochemical process for the production of previtamin D3
A photochemical process for the production of previtamin D 3 or a derivative thereof from 7-dehydrocholesterol is disclosed. The process includes irradiating the 7-dehydrocholesterol in a reactor...
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6136157 |
Method for organic reactions
Organic reactions catalyzed by palladium, except Pd/C, are conducted with heating by microwave energy. The preferred inorganic reactions involved are coupling reactions in which a new carbon-carbon...
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5854370 |
Epoxy resin stilbenes and process for producing the same by photoisomerization
The invention provides a cis-stilbene type epoxy resin having lower melting point and lower viscosity than the trans-stilbene type epoxy resin hitherto known. The stilbene type epoxy resin has a...
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5705596 |
Epoxy resin and process for producing the same
The invention provides a cis-stilbene type epoxy resin having lower melting point and lower viscosity than the trans-stilbene type epoxy resin hitherto known. The stilbene type epoxy resin has a...
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5484932 |
Halogenation processes in advantageous solvents, and novel bistrifluoromethyl-polyfluoroalkoxybenzenes
Compounds such as ##STR1## wherein R is F, CF 3 , CF 2 H, CHF CF 3 or CF 2 CF 3 , as well as related compounds containing chlorine, are used as solvents in halogenation processes.
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5441612 |
Radiation-enhanced recovery of maltol
The yield and recovery of desirable aromatic principles such as maltol, from source material and especially from plant material, are improved by irradiating the source material with gamma radiation...
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5380935 |
Process for preparing 5-aminolevulinic acid
A process for preparing 5-aminolevulinic acid or a salt thereof, which comprises reacting furfurylamine, of which the amino group has been protected, with oxygen molecule under irradiation by light...
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5344974 |
Process for the preparation of N-acyl derivatives of 5-aminolevulinic acid, as well as the hydrochloride of the free acid
The invention relates to a process for the preparation of N-acyl derivatives of 5-aminolevulinic acid of general formula R-CO-NH-CH 2 -CO-CH 2 -CH 2 -COOH, in which R stands for methyl, ethyl,...
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5277772 |
Chemical modification of surfaces using heterocyclic azides
The invention concerns a method for the chemical modification of a surface based on the reaction of photolytically generated reactive intermediates derived from azido heterocycles with said surface.
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5233054 |
Process for the preparation of halophthalic anhydrides
Halophthalic anhydrides are prepared by the liquid phase reaction of a brominating agent with halogen substituted hexa- or tetra-hydrophthalic anhydrides.
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5149842 |
Process for preparing peroxide perfluoropolyethers
A process is disclosed for preparing peroxidic perfluoropolyethers comprising perfluoroalkylenoxy units having at least two carbon atoms, characterized in that one or more perfluoroolefins, except...
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5024743 |
Methylendioxyphenathrene and stilben derivatives, process for the preparation thereof, pharmaceutical compositions using these, and therapeutic applications
The present invention provides compounds of the general formula: ##STR1## where R 1 is a hydrogen atom or a methoxy or ethoxy radical and R 2 and R 3 are hydrogen atoms or R 2 and R 3 together...
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4992561 |
Simple conversion of artemisinic acid into artemisinin
This invention relates to a novel process for producing artemisinin from emisinic acid. The artemisinic acid is reduced to dihydroartemisinic acid by reduction of the exocyclic methylene group. The...
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4976834 |
Asymmetric photochemical reaction process
An optically active substance having an optical purity of at least 50% e.e. is obtained by an asymmetric photochemical reaction by converting a starting, achiral material in a chiral crystalline...
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4956477 |
Synthesis of 1,2-dioxetanes
Compounds having the formula: ##STR1## wherein T is a polycycloalkylidene group (e.g., adamant-2-ylidene); R is a C 1 -20 alkyl, aralkyl or cycloalkyl group; and Y is a fluorescent chromophore...
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4935454 |
Broad spectrum light and heat curable sealant composition and method of using same
A dielectric composition capable of being polymerized for use in sealing electrical and electro-optical connectors and devices is disclosed. Said composition is comprised of a major proportion of...
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4886735 |
Photopolymerizable recording materials and photoresist layers and lithographic printing plates based thereon
Photopolymerizable recording materials suitable for producing photoresist layers and lithographic printing plates are composed of one or more photopolymerizable olefinically unsaturated organic...
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4874488 |
Photochemical dimerization and functionalization of alkanes, ethers, primary and secondary alcohols, phosphine oxides and silanes
The space-time yield and/or the selectivity of the photochemical dimerization of alkanes, ethers, primary and secondary alcohols, phosphine oxides and primary, secondary and tertiary silanes with...
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4849076 |
Continuous oxidation method
A method for oxidizing a substrate which is oxidizable by singlet oxygen is discolded. The first step of the method comprises establishing a flow to and from each of a plurality of successive...
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4845166 |
Compositions containing a mixture of a polyhydric alcohol and charge transfer complex of irradiated anhydrides and cyclic ethers, used to cure epoxy resins
A curing agent is made by admixing (a) an irradiated mixture of carboxylic acid anhydride and carbon containing cyclic compound and (b) a polyhhydric alcohol, where the curing agent can be added to...
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4672132 |
Process for producing an aldehydelactone
A process for producing 3-oxo-6-formyl-2-oxabicyclo[3.3.0]-6-octene useful as an intermediate for producing prostaglandins, via a few steps from raw materials which can be relatively easily...
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4667050 |
Preparation of pyrethroid precursors
Substituted vinylcyclopropane carboxylates, useful precursors to pyrethroid insecticides, are prepared by noble metal catalyzed addition of 1-methyl-3-buten-2-yl or 4-methyl-3-penten-1-yl...
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4571290 |
Process for the selective oxidation of olefins with photochemical illumination of semiconductor powder suspensions
A process for the selective oxidation of olefins comprises the steps of forming a suspension of semiconductor powder in a solvent media, adding an olefin to the solvent media in the presence of an...
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4568375 |
2-Substituted 5-amino-3-oxo-4-(substituted-phenyl)-2,3-dihydrofuran herbicides
2-Halo and 2-alkoxy-5-amino-3-oxo-4-(substituted-phenyl)-2,3-dihydrofur
an and derivatives thereof. The 2-alkoxy and 2-fluoro compounds generally exhibit both pre-emergence and post-emergence...
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4526986 |
Halomethyl, methyl maleic anhydride and synthesis of bromomethyl, methyl maleic anhydride
Quaternary ammonium compounds containing anhydride groups are prepared by halogenating dimethylmaleic anhydride and reacting the halogenated product with a tertiary amine. The products are useful...
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4517125 |
Novel vitamin D.sub.3 derivatives and process for producing the same
There are disclosed 6,19-epidioxyvitamin D 3 derivatives which are represented by the formula ##STR1## wherein R 1 , R 2 and R 3 are each a hydrogen atom or a hydroxyl group; when R 1 is a...
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4508605 |
Nonaromatic dianhydride and polyimides from tricyclo[4.2.1.0.sup.2,5 ] nonane-3,4-dimethyl-3,4,7,8-tetracarboxylic acid dianhydride
Novel polyimides and molding compositions are prepared from novel tricyclo[4.2.1.0 2 ,5 ] nonane-3,4-dimethyl-3,4,7,8-tetracarboxylic acid dianhydride. The dianhydride is useful for the manufacture...
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4507186 |
Dianhydrides and polyimides
Novel polyimides, copolyimides and molding compositions are prepared from novel dianhydrides such as bicyclo[4.2.0]octane-2,5 diphenyl-7,8-dimethyl,3,4,7,8-tetracarboxylic dianhydride and...
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4490545 |
Cyclic dianhydrides prepared from maleic anhydride
Cyclic dianhydrides and polyimides are prepared from maleic anhydride compounds and diolefins. The diolefins are alpha-, omega-linear diolefins of up to 100 carbon atoms or cyclic diolefins of up...
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4481092 |
Photo-initiated epoxidation of allyl chloride
Epichlorohydrin is prepared by the epoxidation of allyl chloride by a process which comprises irradiating an oxygen-saturated solution of allyl chloride in an aprotic solvent in the presence of an...
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4466870 |
Organic sonochemistry process
The method of causing or promoting chemical changes involving the step of subjecting reactants to ultrasonic energy as a key treatment step, including methods of: (1) reducing aryl halides by...
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4428806 |
Process for producing brominated 1,3-dioxolen-2-ones
A process for producing a brominated 1,3-dioxolen-2-one of the following general formula (I) ##STR1## wherein R 1 represents a hydrogen atom, a methyl group, or an aryl group, and R 2 represents...
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4411753 |
Synthesis of 6-t-alkyl-3-pyridazinones
A class of 6-t-alkyl-3-pyridazinones are prepared from 3-t-alkanoyl-2-propenoic acids by irradiation with strong light and reaction with hydrazine.
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4398033 |
4-Chloro-4-chloromethyloxetan-2-one and a process for its production
The new compound 4-chloro-4-chloromethyloxetan-2-one can be prepared by reacting diketene with sulphuryl chloride under conditions in which free radicals are formed. The...
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4383904 |
Photochemical epoxidation
This invention provides a process for photochemical epoxidation of olefins with molecular oxygen in a liquid phase with irradiation in the presence of a combination of 1,2-diketone...
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4363923 |
4-Halgeno-oxetan-2-ones and process for their production
Novel compounds having the formula I ##STR1## are described wherein X is a chlorine, bromine or iodine atom and Y is a residue having the formula R 1 R 2 R 3 C- wherein R 1 and R 2 are the...
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4349481 |
Tritiated gibberellin aldehydes
Is the objective of the invention to develop a process for the production of tagged gibberellin-(7)-aldehydes which is of general applicability. As per the invention a gibberellin-(7)-aldehyde is...
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4344884 |
Process for producing cis-3-(2,2-disubstituted-ethenyl)-2,2-dimethylcyclopropanecarboxylic acid and intermediates
Novel intermediates for production of insecticidal cis-3-(2,2-disubstituted-ethenyl)-2,2-dimethylcyclopropaneca
rboxylates, processes for preparing the intermediates, and processes for preparing...
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4342694 |
Processes for producing pyrethroid insecticide intermediates
Processes for producing a (1α, 4α, 5α)-6,6-dimethyl-4-halo-substituted-methyl-3-oxabicyclo[3.1
.0]hexan- 2-one and its novel intermediates from known and inexpensive starting materials are...
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4324725 |
Preparation of 5-(2,2-dihalovinyl)-4,4-dialkyl-tetrahydro-furan-2-ones
Preparation of 5-(2,2-dihalovinyl)-4,4-dialkyl-tetrahydro-furan-2-ones of the formula I ##STR1## where R 1 and R 2 are each alkyl of 1 to 4 carbon atoms and X is halogen, by reacting a carboxylic...
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