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7311807 |
Process for the separation of mixtures containing m-and p-dichlorobenzene
A process for the separation of dichlorobenzene mixtures containing m- and p-dichlorobenzene in which:
(i) the mixture is as an extracting agent contacted with a phosphoric ester of the...
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7306705 |
Method for dehydrating composition comprising lithium bis(pentafluoroethanesulfonyl)imide
A method for dehydrating an aqueous composition comprising lithium bis(pentafluoroethanesulfonyl)imide and at least one organic solvent, wherein a part of solvent is distilled off by distillation.
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7205438 |
Solvent recovery blends from diene production
A diene production stream comprising a solvent recovery blend from diene production comprising one or more fouling agent, one or more extractive distillation solvent, and from about 1 ppm to about...
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7182839 |
Preventing deposition of fouling agents onto equipment
Methods and compositions effective to prevent deposition of fouling agents, preferably polymerization precursors, on handling equipment, particularly during solvent recovery.
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6458249 |
Process for purifying perfluorinated products
Nitrogen trifluoride (NF 3 ) containing less than 10 parts-per-million molar impurities, e.g., tetrafluoromethane (PFC-14), is disclosed. Azeotropic and extractive distillation processes using...
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6358402 |
Extractive distillation process for the reduction of sulfur species in hydrocarbons streams
A method for separating sulfur species from hydrocarbon streams, particularly cracked naphtha streams, using extractive distillation. The method effectively separates sulfur species from cracked...
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6120652 |
Method for purifying crude 1,1,1,3,3-pentafluoropropane
The invention relates to a method for purifying a crude 1,1,1,3,3-pentafluoropropane (HFC-245fa) containing HFC-245fa and 1-chloro-3,3,3-trifluoro-trans-1-propene (HCFC-1233zd(t)), by distillation....
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5964987 |
Neutral oil removal from natural cresylic acid mixtures
Natural cresylic acid is processed to remove neutral oil impurities by countercurrent liquid/liquid extraction using a heavy phase solvent of a mixture of glycerol and another polyhydric alcohol,...
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5882485 |
Process for the separation of dimethyl ether and chloromethane in mixtures
A process for the separation of dimethyl ether and chloromethane in mixtures A process for the separation of dimethyl ether and chloromethane in mixtures by two distillation steps. In the first...
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5817729 |
Vapor precipitation of polymers from solvent polymer blends by azeotropic spray drying
A process for removing contaminating solvents from solutions containing solid solutes comprising contacting a co-solvent that forms an azeotrope with the contaminating solvent forming a mixture...
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5772852 |
Separating HCI and halocarbons
A process for separating HCl from pentafluoroethane, chloropentafluoroethane, chlorotrifluoroethane, trifluoromethane, and other fully saturated and unsaturated fluorocarbons, chlorofluorocarbons...
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5730844 |
Liquid phthalic anhydride recovery process using a rectification tower with benzoic acid control
A process for recovering phthalic anhydride as a liquid from a vapor phase oxidation product which comprises mixing the vapor phase oxidation product having a temperature of about 130° C. or...
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5718808 |
Solvent assisted process for recovery of phthalic anhydride in the liquid phase by distillation
A process for recovering phthalic anhydride as a liquid from a vapor phase oxidation product which comprises mixing the vapor phase oxidation product having a temperature of about 130° C. or...
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5693193 |
Process for recovering propylene oxide
Propylene oxide is recovered through the use of an additive in a distillation solution, resulting in suppressed side reactions and reduced loss of product. Propylene oxide is produced by oxidizing...
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5453167 |
Separation of xylenes by extractive distillation
p-Xylene cannot be separated from m-xylene by distillation or rectification because of the proximity of their boiling points. p-Xylene can be separated from m-xylene by means of extractive...
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5430232 |
Enhanced volatilization of polychlorinated biphenyl compounds
Polychlorinated biphenyls and chlorinated hydrocarbons are separated from soil by oil assisted desorption followed by vacuum stripping in presence of a sweep gas.
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5429720 |
Solvent recovery from waste oils
A distillation process for separating spent organic solvents such as trichloroethane or d-limonene from their contaminants such as oil is improved by the addition of a perfluorinated alkane or...
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5421964 |
Process for separating HCl and halocarbons
The present invention discloses an extractive distillation process for separating HCl from pentafluoroethane, chloropentafluoroethane, chlorotrifluoroethane, trifluoromethane, and other fully...
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5399751 |
Method for recovering carboxylic acids from aqueous solutions
Disclosed is a method for recovering carboxylic acids having from one to ten carbon atoms, and particularly formic acid, acetic acid and mixtures of formic and acetic acids, from aqueous solutions,...
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5399244 |
Process to recover benzene from mixed hydrocarbons by extractive distillation
Benzene and other aromatics are separated from a stream of mixed hydrocarbons containing both aromatics and non-aromatics by extractive distillation with a solvent system containing dimethyl...
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5391263 |
Process for the separation of glycols from dimethyl terephthalate
Separation of ethylene glycol and diethylene glycol from dimethyl terephthalate is accomplished by distillation using methyl benzoate or the methyl ester of p-toluic acid as an azeotropic agent.
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5288370 |
Process for the separation of butenes and butanes by extractive distillation
For the separation of butenes and butanes by extractive distillation, a charge mainly containing butenes and butanes is contacted in an extractive distillation column under pressure with a first...
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5235117 |
Process for the preparation of boric oxide by hydrolysis of methyl borate and its use in the oxidation of alcohol-saturated hydrocarbons
For preparing at least one boric oxide in an anhydrous or hydrated form and of general formula B 2 O 3 , xH 2 O, in which x is a number from 0 to 3, a methyl borate hydrolyzate comprising boric...
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5232558 |
Separation of 4-methyl-2-pentanone from formic acid by extractive distillation with DMSO
4-Methyl-2-pentanone cannot be easily separated from formic acid by distillation because of the closeness of their boiling points. 4-Methyl-2-pentanone can be readily removed from formic acid by...
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5228956 |
Separation of 3-pentanone from formic acid by extractive distillation
3-Pentanone cannot be completely removed from 3-pentanone and formic acid mixtures by distillation because of the presence of the maximum azeotrope. 3-Pentanone can be readily removed from...
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5194123 |
Separation of 4-methyl-2-pentanone from acetic acid by extractive distillation with DMSO
4-Methyl-2-pentanone cannot be easily separated from acetic acid by distillation because of the closeness of their boiling points. 4-Methyl-2-pentanone can be readily removed from acetic acid by...
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5194122 |
Method for recovering volatile, organic compounds from manure
A method for recovering volatile, organic compounds from manure, by: i) acidifying and concentrating the manure; ii) condensing the formed vapor; and iii) separating the volatile, organic...
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5190619 |
Separation of 3-methyl-2-butanone from formic acid by extractive distillation with DMSO
3-Methyl-2-butanone cannot be separated from formic acid by distillation because of the presence of the maximum boiling azeotrope. 3-Methyl-2-butanone can be readily removed from formic acid by...
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5173156 |
Dehydration of formic acid by extractive distillation
Formic acid cannot be completely removed from formic acid--water mixtures by distillation because of the presence of the maximum azeotrope. Formic acid can be readily removed from mixtures...
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5154802 |
Separation of unsaturated hydrocarbons by extractive distillation
The separation of alkadienes from close-boiling alkenes by extractive distillation employs as solvent either N-(β-mercaptoethyl)-2-pyrrolidone alone, or a mixture of...
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5151161 |
Separation of olefinic hydrocarbons by extractive distillation
The separation of alkadienes from close-boiling alkenes by extractive distillation employes as solvent N-methyl-2-thiopyrrolidone, alone or in admixture with unsubstituted sulfolane...
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5147512 |
Separation of ketone isomers by extractive distillation
The higher boiling ketone isomers are difficult to separate one from another by conventional distillation or rectification because of the close proximity of their boiling points. Ketone isomers can...
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5145562 |
Extractive distillation of mixtures containing aromatic and olefinic hydrocarbons
Aromatic hydrocarbons containing 6-10 carbon atoms per molecule are separated from close-boiling olefinic hydrocarbons by extractive distillation employing as solvent either...
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5145561 |
Removal of water and methanol from propylene oxide by extractive distillation
An extractive distillation agent consisting essentially of ethylene carbonate, propylene carbonate or a mixture thereof is fed to an extractive distillation column used for the distillation of...
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5106459 |
Separation of p-menthane from p-cymene by extractive distillation
p-Cymene and p-menthane are difficult to separate one from another by conventional distillation or rectification because of the close proximity of their boiling points. p-Cymene and p-menthane can...
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5085740 |
Separation of alkenes from alkanes
An extractive distillation process for separating at least one C 4 -C 10 alkene (monoolefin) from at least one close-boiling alkane (paraffin) employs as solvent a mixture of (a) at least one...
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5069757 |
Separation of aromatics from alkanes
An extractive distillation process for separating at least one aromatic hydrocarbon from at least one close-boiling alkane employs as solvent a mixture of (a) at least one...
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5069756 |
Separation of cyclohexane from cyclohexene by azeotropic or extractive distillation
Cyclohexane cannot be readily separated from cyclohexene by conventional distillation or rectification because of the close proximity of their boiling points. Cyclohexane can be separated from...
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5068011 |
Separation of monoolefins from paraffins
An extractive distillation process for separating at least one C 4 -C 10 alkene (monoolefin) from at least one close-boiling alkane employs solvent at least one N-mercaptoalkyl-2-pyrrolidone,...
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5037512 |
Process for the purification of benzoic acid by distillation with an amine
A process for the purification of crude benzoic acid obtained by the catalytic oxidation of toluene in the liquid phase, which is contaminated with impurities including phthalic acid and...
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5032232 |
Extractive distillation of hydrocarbon mixtures
Extractive distillation processes for separating aromatic hydrocarbon(s) or cycloalkane(s) or alkene(s) from close-boiling alkane(s) are carried out with a solvent including at least one...
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4994150 |
Process for the purification of esters of mercapto acids
The present invention provides a process to recover esters of mercapto acids from solutions containing water by mixing an extraction mixture comprising cycloalkane, arene, and an aqueous inorganic...
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4969977 |
Separation of 2-methyl-butanol-1 from pentanol-1 by extractive distillation
2-Methyl butanol-1 cannot be completely removed from 2-methyl butanol-1-pentanol-1 mixtures by distillation because of the proximity of their boiling points. 2-methyl butanol-1 can be readily...
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4956052 |
Process for separation using supercritical fluid
A process for separation of components of a mixture of more than one organic substance or of a mixture of at least one organic substance and water by extraction using a supercritical fluid as an...
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4954224 |
Extractive distillation of hydrocarbon feeds employing mixed solvent
Cycloalkanes (preferably cyclopentane and/or cyclohexane) are separated from close-boiling alkanes by extractive distillation employing as solvent a mixture of (a) at least one...
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4948471 |
Separation of 4-methyl-2-pentanone from formic or acetic acid by extractive distillation with sulfolane
4-Methyl-2-pentanone cannot be easily separated from formic acid or acetic acid by distillation because of the closeness of their boiling points. 4-Methyl-2-pentanone can be readily removed from...
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4948470 |
Extractive distillation of alkane/cycloalkane feed employing mixed solvent
A mixture of (a) at least one N-alkyl-2-pyrrolidone (preferably N-methyl-2-pyrrolidone) and (b) at least one sulfolane (preferably unsubstituted sulfolane) is used as solvent in the extractive...
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4948469 |
Separation of formic acid from dioxane by extractive distillation with amides
Dioxane cannot be completely removed from dioxane and formic acid mixtures by distillation because of the presence of the maximum azeotrope. Dioxane can be readily removed from dioxane - formic...
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4939294 |
Preparation of ultra high purity methyl acetate
In a process for the production of methyl acetate from methanol and glacial acetic acid involving countercurrently flowing acetic acid and methanol through a single reactive distillation column...
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4935103 |
Separation of n-propanol from t-amyl alcohol by extractive distillation
n-Propanol and t-amyl alcohol cannot be separated from each other by distillation because of the proximity of their boiling points. n-Propanol can be readily separated from t-amyl alcohol by using...
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