Description:
BACKGROUND OF THE INVENTION
This invention is concerned with molten metal coating of metal sheet material and in particular relates to a novel method and apparatus which provides faster and more efficient production, better product control and improved product.
Although there have been many highly productive improvements in metal coating operations over the last twenty-five years, molten metal coating itself, especially control of coating weight, has remained essentially the same. Prior to this invention, molten metal coating operations, have relied on mechanical contact with strip at the exit side of a coating bath. This has been a slow cumbersome process, making coating weight control one of the biggest drawbacks and bottlenecks, especially in continuous strip practice.
Since hot-dip zinc and zinc alloy coating, herein termed galvanizing, is the commonest form of molten metal coating operations, the invention will be described in this environment.
The invention makes a radical departure from prior art practice by providing a coating control method and apparatus which accurately determine coating weight in continuous strip galvanizing operations. The coating control method and apparatus of the invention leaves the strip free from the marks and damage occasioned by coating rolls, and the like, eliminates changing and cleaning of such mechanical contact devices, and provides numerous unexpected advantages such as increased line speeds, better operational control, a choice of manual or automatic coating weight control, smoother finish, more uniform coatings, and better corrosion protection with less consumption of coating metal.
There are pronounced contrasts between the teachings of the invention and past theories on wiping coating advanced for hot-dip tinplating. For example, the U.S. Pats. to Steele, No. 850,548, Sebell, No. 2,370,495, Sherman, No. 2,390,007, and the British Pat. specification No. 588,281 disclose use of a liquid or equate use of a liquid and compressed gas in tinplating. There are similar contrasts between the teachings of the invention and the wiping action of a high velocity stream of steam passing between a coated surface and internal surfaces of a throat to blow excess metal from the surfaces of a material as disclosed in the U.S. Pats. to Underwood, No. 2,080,518, No. 2,095,537 and No. Re. 19,758. Such theories have no application in the galvanizing industry and in fact none of these prior art theoretical disclosures is known to have found practical application in hot-dip metal coating of any kind. In practice, coating rolls, despite their many shortcomings and difficulties, remain in use throughout the strip steel galvanizing industry.
The present invention overcomes these problems by controlling coating with what is herein termed a gaseous barrier. Coating control by gaseous barrier leaves the strip free from the marks and damage occasioned by coating rolls, eliminates changing of rolls and other mechanical problems and provides numerous unexpected advantages such as increased line speeds, better operational control, smoother finish, and so forth, which will be discussed below.
In making a departure from conventional mechanical contact coating control processes difficulties were encountered in obtaining a smooth finish and in maintaining a uniform coating over sustained periods. These difficulties were encountered even though recognized variables in the process were maintained within normal ranges. In solving these problems a significant discovery was made in uncovering a critical relation of certain bath properties to effective control of the coating. With this discovery, uniformly coated product can be readily produced over sustained periods, an objective difficult to obtain under some conditions.
Sustained, high-yield, hot-dip galvanizing operations are made possible in the present invention by critical control of a number of factors. The strip is guided from the bath and passes into a coating control zone with its travel path determined and with strip travel limited to longitudinal movement. The strip is shaped to a desired cross-sectional configuration and coating metal on the strip is in excess of desired final coating weight. A linearly extended, thin stream of compressed and heated gas is impinged substantially perpendicularly against the moving strip. The compressed gas is at a minimum desired pressure which will establish a gaseous barrier to passage of a quantity of molten coating metal greater than desired final coating thickness. With this apparatus excess coating metal is returned without turbulence to the coating bath and the final coating on the strip is uniform, smooth, and free from surface imperfections.
Just before leaving the bath and coming into a coating control zone, the strip is led through a portion of the bath in which the metal is held at a controlled temperature so that the temperature of coating metal carried from the bath on exiting strip is substantially uniform regardless of changes in strip width or gage and line speed. Applicant has discovered that this uniformity in coating metal temperature eliminates difficulties encountered in maintaining desired coating weight and quality which stem from variations in coating metal viscosity and the compressibility factor of a gaseous barrier.
In further description of the invention, reference will be had to the accompanying drawings wherein like numbers are used to denote like parts wherever possible;
FIG. 1 is a schematic drawing of apparatus embodying the invention and for carrying out the method;
FIG. 2 is a sectional view of typical coating apparatus of the invention;
FIG. 3 is a schematic front elevational view of apparatus embodying the invention with some of the parts shown in section;
FIG. 4 is an enlarged sectional view of nozzle structure of the invention;
FIG. 5 is a reduced plan view of the structure of FIG. 4.
In carrying out the invention steel strip is prepared for hot-dip coating with cleaning and/or annealing apparatus 12 shown diagrammatically in FIG. 1. After preparation, the strip is delivered through controlled atmosphere chute 14 into coating bath 16 where molten coating in excess of desired final coating weight adheres to the strip. The temperature of strip 18 is ordinarily elevated several hundred degrees above atmospheric temperature and heat is added to coating bath 16 by strip 18 or in another practice the coating bath adds heat to the strip. In either situation, with different gages and widths of strip, with changing temperature of the strip itself due to differing heat treatment requirements, and with different strip speeds, which are all part of everyday galvanizing conditions, bath temperature tends to fluctuate widely, with the changing masses of strip entering the bath. Compensation for these differences has been difficult and ordinarily required manipulation of strip temperature or speed to the detriment of efficient operation of a line.
Close control of the coating metal temperature at the strip exit zone of the bath is critical for sustained uniformity when controlling coating weight with the gaseous barrier process taught by the invention. This significant factor was not recognized in the practice described in parent application Ser. No. 282,474, now U.S. Pat. No. 3,499,418. The temperature of the coating metal at the strip exit zone of the bath influences both coating weight control and the behavior of the bath surface below the coating control apparatus. Therefore, in accordance with one embodiment of the invention, a portion 20 of the coating bath is maintained at a substantially constant temperature by submerged temperature regulator tubes 21, regardless of changes in sensible heat effects due to changes in strip steel width, gage, temperature and/or line speed. Strip 18, after passage around sink roll 22, passes upwardly through portion 20 of the bath 16 toward top roll 23. Thus the temperature of the coating metal on strip 18 as the strip exits from the bath is determined by controlled temperature portion 20 and is held substantially constant at a desired level.
The effect of regulating coating metal temperature in the present invention on uniformity of coating and reduction of bath turbulence becomes more clear when the interrelation of temperature and fluidity is considered. As the temperature of the molten metal in the coating pot rises the fluidity of the coating metal increases and less coating metal is dragged from the bath, more coating metal is held back by the gaseous barrier and the bath surface is more easily disturbed.
The effect of substantially constant coating metal temperature and resulting constant viscosity at the strip exit area is especially important in the gaseous barrier taught by the invention. Unlike the rigid nature of the prior art finishing rolls the gaseous barrier of the present invention constitutes a barrier to the passage of undesired coating metal which is of a yielding nature. Final coating weight is determined by the amount of coating metal encountering the gas barrier and its resistance to flow, or viscosity. Therefore, with other factors constant, a uniform viscosity which affects both drag out of coating metal and action of the gas barrier is required if coating weight remaining on the strip is to remain constant. Stabilizing coating metal temperature in the strip exit zone of the bath stabilizes the drag out of metal and the viscosity of the molten metal meeting the barrier, other factors being constant. In practice such temperature stabilization is preferably carried out by selective cooling of a portion of the bath as shown in FIG. 1. However, certain cold strip type lines with borderline bath heating capacity may require selective heating of that portion of the bath in order to maintain a desired temperature level for coating metal.
Uniformity of temperature of the coating metal on the exiting strip is critical where sustained, uniform coating weight production is desired. Other reasons which have not been fully explained at this time may exist for this criticality in applicant's pneumatic process. Additionally, applicant has discovered that more uniform, smoother finish coating results when there is a substantial excess of coating metal to be held back by the gaseous barrier. Of course if less than desired final coating weight were to be dragged out because of excessive fluidity, the need for regulating coating metal temperature to obtain proper drag out of coating metal would be clear. However, the smoother finish referred to is achieved by virtue of acting on a substantial excess of coating metal over and above the minimal required merely to meet coating weight specifications by holding back some coating metal.
Another important teaching of the invention provides for positioning the moving strip as it passes through the coating control zone. The strip is constrained to purely longitudinal movement by eliminating any lateral vibrating or transverse swaying of the strip during its upward travel. The strip should be shaped to minimize buckles and wavy edges in the strip as much as possible. Also the strip is positioned so that each surface of the strip is uniformly spaced across its width from its respective adjacent nozzle.
After exit from the coating bath the strip passes through a coating control zone where a gaseous barrier established by superheated steam jets from nozzles 24 and 26 determines the final coating weight. The steam or other heated gas is made to impinge uniformly across the full width of the strip and is confined to a thin stream (five- to fifteen-thousandths inch) in the direction of strip travel.
FOr proper coating metal removal nozzles 24 and 26 must be positioned to impinge the steam against the strip while the coating metal is molten and at proper temperature. These and other considerations can require the nozzles to be positioned in close proximity, about 4 to 5 inches, above the coating bath.
To obtain desired conformation, movement, and spacing in the coating control zone, roll guides are specially positioned as close as possible to the coating control zone. Referring to FIG. 1, guide roll 28 contacts the strip below but adjacent the bath surface and applies a force to the strip which may cooperate with an upper guide roll 30 to control positioning of the strip.
Guide roll 28 is preferably freely rotatable and not driven. Both guide rolls 28 and 30 make contact with the strip as close as possible to the coating control zone without interfering with the coating operation and the coated surface, respectively. In the latter case, with roll 30, heat is removed from the strip after exit from the coating control zone. Cooling air or wet steam from spout 32 is used to solidify the coating before contact with guide roll 30. An important discovery of applicant, reasons for which are not fully known, is that upper roll 30 can be positioned closer to the bath with the jet process of the present invention than is possible with coating control rolls. For example when wet steam is discharged from spout 32 to minimize spangle formation by rapidly solidifying the coating the spout can be positioned about 5 to 6 feet above the bath rather than the customary 8 to 12 feet above the bath used with coating control rolls. Guide roll 30, which is positioned a short distance (one to three feet) above spout 32, can then be correspondingly closer to the bath. Because of this, roll 30 is more effective in obtaining the desired strip placement in the coating control zone.
The shaft of guide roll 28 is positioned as close to nozzles 24 and 26 as possible without disturbing coating weight control; for example, 7 or 8 inches below nozzles 24 and 26, with the top of the roll submerged about two to three inches beneath the coating bath surface has been found to be optimum in a coil galvanizing lines of present design.
A coating control machine in accordance with the invention is shown in more detail in FIG. 2. The strip 18 passes upwardly from sink roll 22 in contact with guide roll 28 and between nozzles 24 and 26. The nozzles are supported in slides 34, 36, 38 and 40, which permit the nozzles to move toward and away from the strip. Adjustment gearing 42 and 44 which may be operable by motors 42', 44' (see FIG. 3) is connected to each nozzle for selection of spacing between each nozzle and its adjacent surface of strip 18. The adjustment means are mounted on both longitudinal ends of the nozzles, are calibrated and are adjustable from the same side of the machine.
The nozzles and slides are supported by frame members 46 and 48 which are separable to permit installation of the machine without cutting the continuous strip. Frame member 46 also supports arm 49 which holds the bearing for guide roll 28. The lateral displacement of strip 18 between sink roll 22 and guide roll 28 is exaggerated in the FIG. 2 showing. In practice, a shaping and placement force is applied to strip 18 by a lateral displacement of strip 18 of around three inches between sink roll 22 and guide roll 28. An oppositely directed force may be applied at roll 30. Strip 18 moves upwardly along a substantially vertical path since any lateral offsetting is minor compared to the overall length of the longitudinal path between the sink roll 22 and top roll 23, usually forty to sixty feet, or more.
Guide roll 28 is spaced seven and one-half inches from nozzles 24 and 26 in the machine shown. This spacing can be 15 inches or more above roll 28 dependent on a number of conditions. However, the object is to position nozzles 24 and 26 as close to guide roll 28 as possible in order to take advantage of the planar configuration of the strip imposed by roll 28. In positioning the nozzles however, turbulence of the bath and return of coating metal to the bath must be considered.
The coating metal on the strip should preferably be above 800°F. at the time of contact with the coating control jet. Composition of the galvanizing spelter may affect this; conventional galvanizing spelter includes aluminum additions and impurity level percentages of lead, antimony, cadmium, etc., and has a melting temperature in the neighborhood of 790°F. The temperature of zone 20 is maintained in a range of roughly 800° to 860°F. dependent on product and stabilized to avoid changes greater than roughly 10° to 20°; e.g. around 825° to 840°F. is preferred for most of today's flat rolled steel galvanized products. In stabilizing the temperature of zone 20, a temperature differential up to 30° or higher may exist between zone 20 and the remainder of the bath.
FIG. 3 shows a front elevation, partially in section, of coating apparatus in which a fluid coolant tube 50 is submerged in coating bath 16. In practice a plurality of such tubes can be used to define a zone of temperature regulated cooled spelter. For safety purposes tube 50 may be surrounded by conduit 52 containing a heat conductive material 54, such as molten lead. Flow of fluid in tube 50 is controlled by valve 56 and may be responsive to temperature control apparatus 58 which receives signals from temperature measuring device 60. Water is a preferred coolant.
Superheater 62 controls the temperature of a heated gas, such as superheated steam or air. Temperature of the heated gas is preferably held substantially constant with varying flow demands. In practice a temperature around 850°F. is prefered but satisfactory operation can be obtained within a range of, roughly 500° to 1,500°F. Temperature measurements at indicator 64 can be used to automatically control valve 63 which controls fuel flow to superheater 62 to maintain gas temperature at the desired constant value.
The pressure at nozzle 24 or 26 cannot be conveniently measured without disturbing the coating. Pressure measurements read at control meter 66, or a similar location, give satisfactory results once relative values for a given installation are established. Valve 68 controls the pressure of the heated gas delivered to nozzle 24 and is responsive to selected pressures at control meter 66. A similar control is provided for nozzle 26 and substantially equal pressures are used on both surfaces of the strip when equal coating weights on each surface are desired.
For automatic coating weight control, a noncontact coating thickness measurement device, such as beta ray back scattering gate 67 is positioned on each side of strip 18. Thickness measurements from the beta ray gages are delivered to coating weight control apparatus 69 and coordinated with the selected coating weight to vary the pressure delivered to each coating control nozzle or control the spacing between each nozzle and its respective side of the strip 18. Control signals are delivered over the dotted lines shown to a pressure control meter, such as 66, for each surface of the strip and to motors 42', 44' for actuation of the spacing controls 42 and 44.
Details of linearly extended nozzle structure are shown in FIGS. 4 and 5. Nozzle structure 70 includes two die members 72 and 74 which mate to form a linearly extended gas manifold 76. Die members 72 and 74 are joined by a series of bolts 78. The separation between members 72 and 74 determines the nozzle opening or passageway 84 and is set by use of shim stock 80. Spacing means 80 can vary in thickness between 0.005 and 0.015 inches. Passageway 84 has an inlet opening into manifold 76 and an outlet facing the strip. Gas is supplied through a plurality of apertures 82, in order to obtain substantially uniform gas pressures across the full longitudinal length of manifold 76. The gas exits through linearly extended passageway 84. It is to be noted that the angle of entry of the gas with respect to the plane of the exit is shown at 90° but the invention is not limited to 90°; however, a substantial angular relationship is desired in order to obtain uniform gas dispersal and exit velocity across the linearly extended nozzle opening 84. Typical dimensions for nozzle structure used in obtaining data for the examples presented are:
A 573/4 " E 1/2" B 287/8" F 1/2" C 18" G 11/2" D 54" H .015"
One of the primary objects of nozzle structure used in gas barrier coating control of strip is a linearly extended gaseous stream of uniform gas pressure across the strip. The thickness of the gaseous barrier in a direction parallel to the strip motion is dependent on the nozzle opening which will give proper flow. Larger nozzle openings give greater gas mass and permit a greater mass of molten coating to be held back. Larger openings also avoid clogging by foreign matter; openings of .015 inches have been found satisfactory for mill use in this latter regard.
In the gas barrier principle, as taught by the present invention, the mass of the gas impinging against the molten coating is a dominant factor. The effect of mass can be seen from a culvert stock example where approximately 1,090 pounds of steam per hour at a line speed of 110 feet per minute produced 21/2 ounce per square foot coating while at a line speed of 130 feet per minute approximately 2,200 pounds per hour produced light commercial coating near 0.6 ounce per square foot.
From an operational point of view, pressure change can be used for changing the mass of the superheated steam or other gas used. For example, with increasing line speeds the mass of coating to be held back to maintain constant coating weight increases. This increase in mass can be achieved by increasing gas pressure. Alternatively, the mass of the gas can be increased by increasing the area of the nozzle slot without increasing the gas pressure.
Speed of the line is an important factor; it has been observed that on a continuous galvanizing line, under similar operating conditions of nozzle location and superheated steam pressure, a speed of 100 feet per minute produced a "light commercial coat" while 200 feet per minute produced a commercial ounce and a quarter coating. Line speed could be used to control coating weight but, in practice, an operator would run a line at a maximum speed for a particular gage material as determined by other factors. The gas barrier could be set at the optimum height above the bath, the optimum gas opening, the gas pressure or nozzle spacing or both being then varied to control the coating weight.
Final coating weight at a given line speed can be controlled by either gas pressure or proximity of the linearly extended nozzles to the strip, or both. As described above the temperature of the coating metal applied to the strip is held substantially constant. Briefly, higher strip speeds, lower impinging gas pressure, and greater distances between nozzle and strip produce heavier coating weights; lower strip speeds, high impinging gas pressure, and lower distances between the nozzle and the strip produce lighter coating weights. Generally the strip speed is selected based on other limiting factors, e.g., the annealing capacity of the line, and the line is ordinarily run at the maximum speed available considering such limitation factors. It is desirable to maintain a minimum steam pressure regardless of other related coating control factors although to meet variations in required coating weight either steam pressure or nozzle spacing can be changed. In practice changing of nozzle spacing is preferred because of the desire to maintain a minimum gas pressure and to avoid over or under correcting when gas pressure controls are employed. With automatic controls either spacing or pressures can be changed readily to meet coating requirements within a selected low pressure range. Typical production examples are included below.
TABLE I
Continuous-strip galvanizing with nozzles 41/2 to 51/2 inches above bath level, coating metal at exit side of bath held at or near 825°F., nozzle opening of 0.015 inch, substantially perpendicular impingement, superheated steam temperature about 840°F., spacing between each nozzle and its adjacent strip surface about one-half inch.
________________________________________________________
__________________ RUN 1 RUN 2 RUN 3 RUN 4 ____________________________________________________________
______________ Strip thickness (inches) .020 .0183 .018 .0172 Strip width (inches) 36 9/16 28 241/2 27 13/16 Topside pressure (lb./in. 2 ) 35 30 37 32 Bottomside pressure (lb./in. 2 ) 34 30 38 31 Speed of line (fpm) 170 220 230 230 Coating weight (oz./ft. 2 ) .59 .82 .59 .99 (Total of both surfaces) ____________________________________________________________
______________
TABLE II
Continuous-strip galvanizing with nozzles 41/2 to 51/2 inches above bath level, coating metal temperature at exit side of bath held at or near 825°F., nozzle opening 0.015 inch, substantially perpendicular impingement, superheated steam temperature about 840°F., spacing between each nozzle and its adjacent strip surface about three-fourths inch.
______________________________________ RUN 5 RUN 6 RUN 7 RUN 8 ______________________________________ Strip Thickness (inches) .018 .0217 .021 .0157 Strip Width (inches) 36 36 231/4 24 Topside Pressure (lb./in. 2 ) 38 29 42 42 BOttomside Pressure (lb./in. 2 ) 40 29 41 41 Speed of Line (fpm) 200 200 210 230 Coating Weight (oz./ft. 2 ) .54 .76 .53 .56 ______________________________________
TABLE III
The following differing products were run over a 3 hour period on the same line with the nozzles 41/2 to 51/2 inches above bath level, nozzle opening 0.015 inch, substantially perpendicular impingement, and spacing between each nozzle and its adjacent strip surface about three-fourths inch. The coating metal temperature at the exit side of the bath was held at or near 825°F. despite wide changes in strip heat added to pot by changes in steel mass introduced and varying line speeds.
______________________________________ RUN 9 RUN 10 RUN 11 ______________________________________ Strip Thickness (inches) .018 .0157 .0187 Strip Width (inches) 30 30 35 Topside Pressure (lb./in. 2 ) 32 26 28 Bottomside Pressure (lb./in. 2 ) 32 26 28 Speed of Line (fpm) 230 130 180 Coating Weight (oz./ft. 2 ) .94 .94 .97 Product Form Coils Sheets Coils Use Pipes Warehouse Roofing Stock ______________________________________
Differential-coat is readily produced by controlling gas pressure on each surface. From observation or production of differential-coat on a continuous galvanizing line, the light side coating is controlled more effectively by the gas barrier apparatus than with any known method. Imperfections in the strip on the light side of the strip are not a problem with the gas barrier apparatus and a smoother light side coating results. Differential galvanized product having less than 0.1 ounce per square foot on the light side and more than 0.3 ounce per square foot on the heavy side was produced using 55 pounds per square inch steam pressure on the bottom side manifold (light side of the differential coat) and 45 pounds per square inch steam pressure on the top side manifold.
In producing product with equal coating weight on both surfaces, the strip is ordinarily passed midway between the coating control nozzles and the steam pressure on each nozzle is about the same. In order to make differential coat product, the nozzle on the light coating side of the strip can be moved closer to the strip or the steam pressure can be increased or both. In practice, changing the spacing of the nozzles is preferred as shown in the following table.
TABLE IV
With perpendicular disposition of the nozzles, drawing quality stock, 0.0503 inch gage, 373/8 inches width, was produced at a line speed of 80 feet per minute with the following settings:
Nozzle Spacing Pressure Coating Weight (lb./in. 2 ) (lb./ft. 2 ) ______________________________________ Light Side 1/4" 25 .19 Heavy Side 11/4" 22 .48 ______________________________________
Adjustment in spacing between nozzles to change coating weight is an advantage of the substantially perpendicular impingement concept which is not readily available with angled impingement. Spacing of angled nozzles cannot be changed without changing the point of impact of the gas with the strip. Therefore the point of impact for one nozzle may be readily offset from the other with an angled disposition. One result can be an edge buildup of coating metal. With the nozzles disposed substantially perpendicularly to the strip this problem does not exist and a new means of adjusting coating weight, by adjusting nozzle spacing is available to the operator.
With the present invention, high strip speed is not a limiting factor whereas, with mechanical contact methods, coating control was one of the major speed limiting factors. Other operations such as annealing or coiling, etc., may place some limit on a particular line but, with the present invention, the coating operation itself will not limit line speeds with present day molten metal coating lines of any type. In fact, it has been found that the gas barrier principle of this invention produces smoother finishes at higher speeds.
Some of the advantages of the gas barrier principle of coating control include increased production, improved quality and more economic production. Increased production results from the faster line speeds available with this invention over those with the prior art practice; also, less down time for a line since there is no necessity to change coating rolls, etc. Improved quality results from the avoidance of coating roll marks and the smoother finish produced by the gas barrier method. Improved economy results from the increased production referred to above, increased percentage yields, and elimination of a number of post coating treatments to improve coating surface.