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[0001] This application claims the benefit of U.S. Provisional Patent Application No. 60/482,516 filed Jun. 24, 2003, (Attorney Docket CC-0604) U.S. Provisional Patent Application No. 60/441,652 filed Jan. 22, 2003, (Attorney Docket CC-0585); U.S. Provisional Patent Application No. 60/441,395 filed Jan. 21, 2003, (Attorney Docket CC-0581); which are all incorporated herein by reference.
[0002] 1. Technical Field
[0003] The present invention generally relates to a device for measuring dissolved air in a fluid or process mixture flowing in a process line.
[0004] 2. Description of Related Art
[0005] Monitoring levels of entrained and dissolved gases is desirable in many industrial processes. For example, entrained and dissolve gases in the approach system of paper making machines are often problematic, leading to a wide variety of problems, including flow line pulsations, pin-holes in the produced paper, reduced paper sheet strength, and excessive build-up of aerobic growths.
[0006] Entrained gases are gases that exist in a gaseous form, mixed in the process fluid. For many industrial applications with small, less than ˜20% gas fraction by volume, the gas is typically in the form of small bubbles contained in a liquid continuous mixture. Entrained gases exist as either free bubbles moving within the stock or as bound (or residual) air that is adhered to the fiber. In either cases, entrained air can generally be detected by monitoring the compressibility of the mixture and correlating the compressibility to volumetric percentage of entrained air.
[0007] Dissolved gases are dissolved within the mixture on a molecular level. While in the solution, dissolved gases pose few operation problems. Typically dissolved gases have a negligible effect on the compressibility of the mixture. Thus, dissolved gases are difficult to detect via compressibility measurements.
[0008] Although dissolved gases are typically not problematic while dissolved, problems arise when dissolved gases come out of a solution as a result of either decreases in pressure or increases in temperature. One example of this is in pressurized head boxes on paper machines where the pressure drop associated with spraying the pulp/water mixture on to the paper machine can cause dissolved gases to come out of the solution and form entrained air.
[0009] Thus, to accurately monitor problems associated with entrained and dissolve gases, it is desirable to be able to measure both quantities.
[0010] In its broadest sense, the present invention provides a new and unique device having a first module arranged in relation to a process line for providing a first signal containing information about a sensed entrained air/gas in a fluid or process mixture flowing in the process line at a process line pressure. The device features a combination of a bleed line, a second module and a third module. The bleed line is coupled to the process line for bleeding a portion of the fluid or process mixture from the process line at a bleed line pressure that is lower than the process pressure. The second module is arranged in relation to the bleed line, for providing a second signal containing information about a sensed bleed line entrained air/gas in the fluid or process mixture flowing in the bleed line. The third module responds to the first signal and the second signal, for providing a third signal containing information about a dissolved air/gas flowing in the process line based on a difference between the sensed entrained air/gas and the sensed bleed line entrained air/gas.
[0011] In one embodiment, the first module is a primary process line entrained air measurement module that includes an array of sensors that measures the speed of sound propagating through the fluid or process mixture flowing within the process line and determines the entrained air based on a measurement using the speed of sound. The second module is a bleed line entrained air measurement module that also includes an array of sensors that measures the speed of sound propagating through the fluid or process mixture flowing within the bleed line and determines the bleed line entrained air based on a measurement using the speed of sound. The third module is a dissolved air determination processor module that processes the first and second signals and provides the third signal containing information about a dissolved air/gas flowing in the process line.
[0012] The device also includes a bleed line control module for controlling the bleeding off of the portion of the fluid from the process line via a bleed valve and the reinjection of said portion back to the process line via a boost pump, and also includes a controller module for controlling and coordinating the operation of the first, second and third modules, as well as a bleed line control that communicates with the bleed valve and the boost pump.
[0013] In operation, the device according to the present invention measures dissolved gases at an operating pressure by measuring entrained gases present in a process line once the fluid or process mixture is expanded to ambient (or other known and relevant) pressure. This measurement is performed using a small amount of process mixture bled-off, either continuously or periodically, from the process. The bled-off process fluid can be recirculated or, via a boost pump, re-pressurized and reinjected. The bleed line and flow rates may be sized to minimize the amount of stock bleed off while maintained sufficiently high flow rates to maintain sufficiently homogenous flow within the bled-off liquid test section (i.e. minimize slip) such that the measured gas volume fraction within the bleed line is indeed representative of the amount of gas dissolved in the process fluid. Maintaining sufficiently high velocities avoids problems associated with stratification of the mixture and the problems associated with either the liquid of gas phases “holding up” in the process pipe. For most mixtures of liquids and gases at or near ambient pressures, flow velocities of several feet per second through the line are sufficient.
[0014] The process of the throttling of the process fluid to the reduced pressure provides sufficient noise to perform a sonar-based speed measurement.
[0015] The present invention also provides a method for measuring the entrained gas fraction at two relevant pressures, and thus provides practical measurement of the amount of both entrained and dissolved gases contained in the process fluid at the process operating conditions.
[0016] The foregoing and other objects, features and advantages of the present invention will become more apparent in light of the following detailed description of exemplary embodiments thereof.
[0017] The drawing, not drawn to scale, includes the following Figures:
[0018]
[0019]
[0020]
[0021]
[0022]
[0023]
[0024]
[0025]
[0026] In
[0027] The controller module
[0028] The primary process line entrained air measurement module
[0029] Similarly, the bleed line entrained air measurement module
[0030] The bleed line
[0031] The device
[0032] The modules
[0033] Although the invention is described in relation to measuring or sensing entrained air in a fluid or process mixture using an array of sensors, the scope of the invention is intended to include other ways of measuring or sensing entrained air either known now or developed in the future. Moreover. although the invention is described in relation to using an array of sensors to determine the speed of sound, the scope of the invention is intended to include other ways of measuring the speed of sound either known now or developed in the future.
[0034] The present invention uses the speed at which sound propagates within a conduit to measure entrained air in slurries. This approach may be used with any technique that measures the sound speed of a fluid or process mixture. However, it is particularly synergistic with sonar based volumetric flow meters such as described in aforementioned U.S. patent application Ser. No. 10/007,736 (CiDRA's Docket No. CC-0122A), in that the sound speed measurement, and thus gas volume fraction measurement, can be accomplished using the same hardware as that required for the volumetric flow measurement. It should be noted, however, that the gas volume fraction (GVF) measurement could be performed independently of a volumetric flow measurement, and would have utility as an important process measurement in isolation or in conjunction with other process measurements.
[0035] Firstly, the sound speed may be measured as described in aforementioned U.S. patent application Ser. No. 09/344,094 (CiDRA's Docket No. CC-0066A), U.S. patent application Ser. No. 10/007,749 (CiDRA's Docket No. CC-0066B), U.S. patent application Ser. No. 10/349,716 filed Jan. 23, 2003 (Cidra's Docket No. CC-0579) and/or U.S. patent application Ser. No. 10/376,427 filed Feb. 26, 2003 (Cidra's Docket No. CC-0596), all incorporated herein by reference, using an array of unsteady pressure transducers. For a two component mixture, utilizing relations described in U.S. patent application Ser. No. 09/344,094 (CiDRA's Docket No. CC-0066A) and/or U.S. patent application Ser. No. 10/007,749 (CiDRA's Docket No. CC-0066B), knowledge of the density and sound speed of the two components and the compliance properties of the conduit or pipe, the measured sound speed can be used to determine the volumetric phase fraction of the two components.
[0036] The sound speed of a mixture can be related to volumetric phase fraction (φ
[0037] One dimensional compression waves propagating within a fluid contained within a conduit exert an unsteady internal pressure loading on the conduit. The degree to which the conduit displaces as a result of the unsteady pressure loading influences the speed of propagation of the compression wave. The relationship among the infinite domain speed of sound and density of a fluid; the elastic modulus (E), thickness (t), and radius (R) of a vacuum-backed cylindrical conduit; and the effective propagation velocity (a
[0038] Note: “vacuum backed” as used herein refers to a situation in which the fluid surrounding the conduit externally has negligible acoustic impedance compared to that of the fluid internal to the pipe. For example, meter containing a typical water and pulp slurry immersed in air at standard atmospheric conditions satisfies this condition and can be considered “vacuum-backed”.
[0039] For paper and pulp slurries, the conditions are such that for slurries with non-negligible amounts of entrained gas, say <0.01%, the compliance of standard industrial piping (Schedule 10 or 40 steel pipe) is typically negligible compared to that of the entrained air.
[0040]
[0041]
[0042] A flow chart of the proposed measurement is shown in
[0043] Other information relating to the gas volume fraction in a fluid and the speed of sound (or sonic velocity) in the fluid, is described in “Fluid Mechanics and Measurements in two-phase flow Systems”, Institution of mechanical engineers, proceedings 1969-1970 Vol. 184 part 3C, Sep. 24-25 1969, Birdcage Walk, Westminster, London S.W. 1, England.
[0044] Based on the above discussion, one may use a short length scale aperture to measure the sound speed.
[0045] The characteristic acoustic length scale is: λ=c/f, where c is the speed of sound in a mixture, f is frequency and λ is wavelength.
[0046] If Aperture=L and if L/λ is approx. constant.
[0047] Then Lwater/λwater=Lwater*f/C
[0048] Therefore: L
[0049] Thus for SOS of water (Cwater=5,000 ft/sec) , and SOS of the Gas volume fraction (C GVF=500 ft/sec) and a length aperture of L water=5 ft (which we have shown is sufficient to accurately measure the SOS of water), the length aperture for a gas volume fraction L
[0050] Note that this entrained air or gas volume fraction measurement GVFair may be used with any flow meter or consistency meter to correct for errors introduced into a measurement by entrained air. In particular, an electromagnetic flow meter will show an error when entrained air exists in the mixture. The present invention may be used to correct for this error. In addition, a consistency meter will show an error when entrained air exists in the mixture. The present invention may be used to correct for this error.
[0051] The scope of the invention is also intended to include using other models and corrections for determining entrained air in a fluid that may be used to compensate for gas volume fraction.
[0052] As shown in
[0053] The connection between speed of sound of a two-phase mixture and phase fraction is well established for mixtures in which the wavelength of the sound is significantly larger than any inhomogenieities, i.e. bubbles, in the flow.
[0054] The mixing rule essentially states that the compressibility of a mixture (1/(ρ a
[0055] Conversely, however, detailed knowledge of the liquid/slurry is not required for entrained air measurement. Variations in liquid density and compressibility with changes in consistency have a negligible effect on mixture sound speed compared to the presence of entrained air.
[0056] As mentioned earlier, the relationship between mixture sound speed and entrained air in bubbly liquids is well established. However, as will be developed below, in bubbly flows, these relations are only applicable for the propagation of relatively low frequency, long wavelength sound. While this restriction does not present any significant obstacles for the sonar meter, it does present significant challenges to ultrasonic sound speed measurement devices.
[0057] Ultrasonic meters typically operate in 100 Khz to several Mhz frequency range. For these meters, entrained air bubbles have length scales on the same order as the acoustic waves generated by the ultrasonic meters. The posed several problems. Firstly, the bubbles scatter the ultrasonic waves, impairing the ability of the ultrasonic meter to perform a sound speed measurement. Also, ultrasonic meters rely on information derived from only a small fraction of the cross sectional area of the pipe to be representative of the entire cross section, an assumption that breaks down for flows with inhogenieties on the same length scale as the ultrasonic wavelength.
[0058] Sonar flow meters use an approach developed and commercialized specifically for multiphase flow measurement in the oil and gas industry. Sonar meters measure the propagation velocity of operationally generated sound in the ˜100 to 1000 Hz frequency range. In this frequency range, sound propagates as a one-dimensional wave using the process pipe as a waveguide. The wavelength of sound in this frequency range (>1 m) is typically several orders of magnitude larger than the length scale of the any bubbles. The long wavelength acoustics propagate through the bubbles unimpeded, providing a robust and representative measure of the volumetrically averaged properties of the flow.
[0059] For the sound speed measurement, the sonar flow meter utilizes similar processing algorithms as those employed for the volumetric flow measurement. As with convective disturbances, the temporal and spatial frequency content of sound propagating within the process piping is related through a dispersion relationship.
[0060] As before, k is the wave number, defined as k=2π/λ, ω is the temporal frequency in rad/sec, and a
[0061]
[0062] In an embodiment of the present invention shown in
[0063] The apparatus
[0064] Generally, the apparatus
[0065] The apparatus in
[0066] The apparatus
[0067] In accordance with one embodiment of the present invention, the speed of sound propagating through the mixture
[0068] As shown in
[0069] The frequency signals P
[0070] The data from the array of sensors
[0071] One such technique of determining the speed of sound propagating through the flow
[0072] The signal processor
[0073] The flow meter of the present invention uses known array processing techniques, in particular the Minimum Variance, Distortionless Response or other adaptive array processing techniques (MVDR, Music, or Capon technique), to identify pressure fluctuations, which convect with the materials flowing in a conduit and accurately ascertain the velocity, and thus the flow rate, of said material. These processing techniques utilize the covariance between multiple sensors
[0074] Also, some or all of the functions within the processor
[0075] For certain types of pressure sensors, e.g., pipe strain sensors, accelerometers, velocity sensors or displacement sensors, discussed hereinafter, it may be desirable for the pipe
[0076] The pressure sensors
[0077] For any of the embodiments described herein, the pressure sensors, including electrical strain gages, optical fibers and/or gratings among others as described herein, may be attached to the pipe by adhesive, glue, epoxy, tape or other suitable attachment means to ensure suitable contact between the sensor and the pipe
[0078] It is also within the scope of the present invention that any other strain sensing technique may be used to measure the variations in strain in the pipe, such as highly sensitive piezoelectric, electronic or electric, strain gages attached to or embedded in the pipe
[0079] In certain embodiments of the present invention a piezo-electronic pressure transducer may be used as one or more of the pressure sensors
[0080] The pressure sensors incorporate a built-in MOSFET microelectronic amplifier to convert the high-impedance charge output into a low-impedance voltage signal. The sensor is powered from a constant-current source and can operate over long coaxial or ribbon cable without signal degradation. The low-impedance voltage signal is not affected by triboelectric cable noise or insulation resistance-degrading contaminants. Power to operate integrated circuit piezoelectric sensors generally takes the form of a low-cost, 24 to 27 VDC, 2 to 20 mA constant-current supply. A data acquisition system of the present invention may incorporate constant-current power for directly powering integrated circuit piezoelectric sensors.
[0081] Most piezoelectric pressure sensors are constructed with either compression mode quartz crystals preloaded in a rigid housing, or unconstrained tourmaline crystals. These designs give the sensors microsecond response times and resonant frequencies in the hundreds of kHz, with minimal overshoot or ringing. Small diaphragm diameters ensure spatial resolution of narrow shock waves.
[0082] The output characteristic of piezoelectric pressure sensor systems is that of an AC-coupled system, where repetitive signals decay until there is an equal area above and below the original base line. As magnitude levels of the monitored event fluctuate, the output remains stabilized around the base line with the positive and negative areas of the curve remaining equal.
[0083] The pressure sensors
[0084] A piezo-electronic pressure transducer may be used (or alternatively even a common strain gage may be used) as one or more of the pressure sensors
[0085] For any of the embodiments described herein, the pressure sensors, including electrical strain gages, optical fibers and/or gratings among others as described herein, may be attached to the pipe by adhesive, glue, epoxy, tape or other suitable attachment means to ensure suitable contact between the sensor and the pipe
[0086] It is also within the scope of the present invention that any other strain sensing technique may be used to measure the variations in strain in the pipe, such as highly sensitive piezoelectric, electronic or electric, strain gages attached to or embedded in the pipe
[0087] While the sonar-based flow meter using an array of sensors to measure the speed of sound of an acoustic wave propagating through the mixture, one will appreciate that any means for measuring the speed of sound of the acoustic wave may used to determine the entrained air volume fraction of the mixture/fluid.
[0088] It should be understood that, unless stated otherwise herein, any of the features, characteristics, alternatives or modifications described regarding a particular embodiment herein may also be applied, used, or incorporated with any other embodiment described herein.
[0089] Although the invention has been described and illustrated with respect to exemplary embodiments thereof, the foregoing and various other additions and omissions may be made therein without departing from the spirit and scope of the present invention.