[0001] 1. Field of the Invention
[0002] The present invention relates to a semiconductor device having a conductive film connected to a pad on a semiconductor substrate and a production process thereof.
[0003] 2. Description of Related Art
[0004] In a chip-on-chip structure in which active surfaces of a pair of semiconductor chips are overlapped with each other, and in a flip chip bonding structure in which a semiconductor chip is joined to a wiring board with its active surface opposed to the wiring board, a projection for electrical connection called a bump is provided on the active surface of the semiconductor chip.
[0005] A pad
[0006] The bump
[0007] However, it takes long to form the thick film by the electroless plating. Accordingly, it takes significantly long to fill in the opening
[0008] An object of the present invention is to provide a semiconductor device, having a connecting member, whose productivity can be improved and a production process thereof.
[0009] Another object of the present invention is to provide a process of producing a semiconductor device, in which a low-resistive conductive film having good adhesive properties can be formed on a surface of an insulating film on a semiconductor substrate in a short time.
[0010] A semiconductor device according to the present invention comprises a pad for electrical connection provided on a semiconductor substrate; a first insulating film with which a surface of the semiconductor substrate is coated and having an opening to which the pad is exposed; a conductive film joined to the pad on a bottom surface of the opening of the first insulating film and extending to a surface of the first insulating film outside the opening; a second insulating film with which the conductive film is coated and having an opening to which a part of the conductive film is exposed; and a connecting member arranged so as to be joined to the conductive film inside the opening of the second insulating film.
[0011] The semiconductor device can be produced by a production process comprising the steps of coating a surface of a semiconductor substrate, provided with a pad for electrical connection, with a first insulating film having an opening to which the pad is exposed; modifying a surface of the first insulating film and an inner wall surface of the opening; forming by an ion-exchange reaction a thin conductive film with which the surface of the first insulating film, the inner wall surface of the opening, and a surface of the pad exposed on a bottom surface of the opening is coated; thickening the thin conductive film by electroplating with power being fed using the thin conductive film; forming a second insulating film with which the thickened conductive film is coated and having an opening to which a part of the conductive film is exposed; and forming a connecting member joined to the thickened conductive film inside the opening of the second insulating film.
[0012] According to the process, by modifying the surface of the first insulating film and the inner wall surface of the opening formed in the first insulating film, the thin conductive film having good adhesive properties can be formed by utilizing the ion-exchange reaction on the modified surfaces. Power can be fed using the thin conductive film, thereby making it possible to thicken the thin conductive film by the electroplating. The conductive film can be thickened in a short time by the electroplating. As a result, the thickened conductive film having good adhesive properties can be quickly formed on the first insulating film. After the thickened conductive film is then coated with the second insulating film, and the opening is formed in the second insulting film, the connecting member joined to the thickened conductive film may be formed in the opening.
[0013] The surface modification processing for the first insulating film may be processing for introducing a cation exchange group into the surface of the first insulating film. The surface of the first insulating film which has been subjected to the surface modification processing is brought into contact with a solution containing ions of a metal material to compose the conductive film, thereby making it possible to produce the ion-exchange reaction. By the ion-exchange reaction, the metal ions are replaced with the cation exchange group, and the cation exchange group is sucked by the surface of the first insulating film.
[0014] The connecting member may be a bump for connection to another solid device (e.g., another semiconductor chip or wiring board).
[0015] The connecting member may be another conductive film joined to the conductive film on the bottom surface of the opening in the second insulating film and extending to the surface of the second insulating film. In this case, a so-called multi-layered wiring structure is constituted by a two-layer conductive film insulated by the second insulating film.
[0016] The first insulating film may be composed of polyimide resin. In this case, the modification processing for the surface of the first insulating film and the inner wall surface of the opening formed in the first insulating film may be processing for cleaving an imide ring of the polyimide resin using a potassium hydroxide solution, for example, and introducing a carboxyl group serving as the cation exchange group into the surface of the first insulating film. Thereafter, the first insulating film is immersed in the solution containing the ions of the metal material composing the connecting member, thereby making it possible to produce the ion-exchange reaction on the surface of the first insulating film and form the connecting member composed of the metal material on the surface of the first insulating film, the inner wall surface of the opening, and the surface of the pad.
[0017] As a material for the first insulating film, epoxy resin, for example, can be used in addition to the polyimide resin. In this case, the surface modification processing for the first insulating film may be processing for immersing the first insulating film in a sulfuric acid solution to introduce a sulfo group serving as the cation exchange group into its surface. When an epoxy resin film which has been thus subjected to the surface modification processing is immersed in the solution containing the metal ions to produce the ion-exchange reaction, the metal ions are sucked by the surface of the first insulating film.
[0018] As a material for the first insulating film, resin including an imide bond or an acido bond or including both an imide bond and an acido bond can be used in addition thereto.
[0019] As the second insulating film, the resin including an imide bond or an acido bond or both an imide bond and an acido bond can be used, in addition to the polyimide resin or the epoxy resin, as a material composing the second insulating film, similarly to the first insulating film. Particularly when a multi-layered wiring structure is formed using a pair of conductive films insulated by the second insulating film, it is preferable that the surface of the second insulating film and the inner wall surface of the opening are subjected to the above-mentioned surface modification processing using the polyimide resin or the epoxy resin as the material composing the second insulating film.
[0020] A process according to another mode of the present invention comprises the steps of forming an insulating film on a semiconductor substrate; modifying a surface of the insulating film; forming a thin conductive film by an ion-exchange reaction on the modified surface of the insulating film; and thickening the thin conductive film by electroplating for feeding power using the thin conductive film.
[0021] According to the process, the conductive film having good adhesive properties can be formed on the surface of the insulating film by performing the ion-exchange reaction subsequently to the surface modification processing for the insulating film. The thin conductive film is thickened by the electroplating, thereby making it possible to form a low-resistive conductive film having good adhesive properties in a short time on the insulating film. This can contribute to an improvement in the productivity of the semiconductor device.
[0022] The foregoing and other objects, features, aspects and advantages of the present invention will become more apparent from the following detailed description of the present invention when taken in conjunction with the accompanying drawings.
[0023]
[0024]
[0025]
[0026]
[0027] In the device forming region corresponding to each of the semiconductor chips, a pad P for electrical connection to another solid device (a semiconductor chip or a wiring board, etc.) is provided on an active surface Wa. The pad P is exposed from an opening
[0028] A thin conductive film
[0029] Specifically, the surface of the first polyimide film
[0030] The thin conductive film
[0031] After the thin conductive film
[0032] Since the thin conductive film
[0033] As shown in
[0034] The conductive film
[0035] If an opening
[0036] Thereafter, the wafer W is cut by a dicing saw along the scribe line region L, thereby obtaining respective pieces of semiconductor chips.
[0037] As described in the foregoing, according to the present embodiment, the thin conductive film
[0038] The semiconductor chip produced in accordance with the process according to the present embodiment has the bump B serving as a connecting member to another solid device at a position shifted from the opening
[0039]
[0040] In the second embodiment, a multi-layered wiring structure is formed on a wafer W. That is, a second conductive film
[0041] The second conductive film
[0042] The second conductive film
[0043] As described in the foregoing, according to the second embodiment, a wiring having a two-layer structure can be provided on the wafer W by forming the thin conductive film using the surface modification processing and the ion-exchange reaction for the polyimide films and thickening the thin conductive film using the electroplating.
[0044] Although description has been made of the two embodiments of the present invention, the present invention can be embodied in another mode. Although in the above-mentioned first and second embodiments, polyimide resin is used as a material for the first and second insulating films, for example, epoxy resin can be also used. In this case, it is preferable that surface modification processing is processing for immersing in a sulfuric acid solution a wafer having a film composed of epoxy resin formed therein to introduce a sulfo group into a surface of the epoxy resin film. The sulfo group is replaced with metal ions by ion-exchange resin, thereby making it possible to form a thin conductive film on the surface of the epoxy resin film.
[0045] Although in the above-mentioned first and second embodiments, the depressions
[0046] A metal material having conductive properties, for example, cobalt or nickel can be used in addition to copper as a material for the conductive films
[0047] Although in the above-mentioned second embodiment, description has been made of an example in which the wiring having a two-layer structure is provided on the active surface Wa of the wafer W, a multi-layered wiring structure comprising three or more layers can be also formed in the same manner.
[0048] Although in the above-mentioned first and second embodiments, description has been made of an example in which both the first and second insulating films are composed of polyimide resin, they may be composed of epoxy resin, as described above, and they may be respectively composed of different insulating resin materials.
[0049] Although the present invention has been described and illustrated in detail, it is clearly understood that the same is by way of illustration and example only and is not to be taken by way of limitation, the spirit and scope of the present invention being limited only by the terms of the appended claims.
[0050] The application corresponds to Japanese Patent Application Serial No. 2000-89174 filed with the Japanese Patent Office on Mar. 28, 2000, the disclosure of which is incorporated herein by reference.